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By W. J. Mcgaughey, M. A. Vallée

"Abstract -The application of geophysical technology to resource delineation aims to improve the quality of resource/reserve estimates by integrating high-resolution survey methods, geophysical modeling and inversion with three-dimensional representations of geological and mineral deposit data. The use of geophysics can cost-effectively improve a geological interpretation based only on geological and sampling data. Success depends upon the ability to use geological visualization and modeling software, first to develop a three-dimensional geological model and then to modify it interactively by integrating geophysical data with the geological and sampling data.The high resolution required for mineral delineation geophysics results in a focus on borehole seismic and high-frequency electromagnetic methods. Borehole wireline logging is used to develop an understanding of the relationship between physical properties and geological description. Data from core samples and borehole wireline logs allow the construction of a three-dimensional physical property distribution, consistent with the existing geological interpretation. The three-dimensional physical property distribution is used for both geophysical forward modeling (to compare to field data) and as a starting model in iterative inversions.Advanced visualization techniques allow the simultaneous viewing of the three-dimensional physical property model, the geological information and data from which it is derived, and the geological interpretation and the geophysical results. Geophysical results may be simulated responses from a forward model or the output from a numerical inversion in the form of an updated physical property distribution. Iterative refinement of the geological interpretation is required to ensure consistency with the geological and geophysical data. The key to success with this approach is that all relevant geological, geophysical, and rock property data reside in a common, visual model of the earth.Examples from massive sulfide deposits illustrate the benefits obtained by the integration of geophysical and geological data."

Jan 1, 1998

By D. G. Sediako

Chemical composition and the casting/rolling production routes determine the cost and properties of the wrought material. For example, the coarse-grained structure frequently associated with DC casting requires complex rolling schedules to refine the grain size. Hot forming (rolling/forging/extrusion) results in a strong crystallographic texture, which is responsible for the tension-compression strength asymmetry frequently exhibited by magnesium alloys. Understanding the influence of alloy composition on texture evolution during forming provides useful practical information to optimize industrial hot-forming technologies for magnesium alloys. In this study, a series of Mg-based alloys containing varying combinations of Al, Rare Earths, Zn, Ca, and Sr were subjected to identical casting and extrusion processes in order to isolate the effects of alloy composition on texture evolution. Textures were measured by neutron diffraction at the NRC Canadian Neutron Beam Centre. The ability of neutrons to penetrate deeply into materials allowed information to be retrieved from all regions of the bulk specimens without destructive and time-consuming sectioning operations, thereby providing true bulk texture data. {1010} , (0002), {1011}, and {1012} pole figures were generated for all of the as-processed alloys, from which Orientation Density Functions were obtained. The were then used to reconstruct the pole figures and to extract semi-quantitative texture data showing how the (0002) and {1010} planes align themselves with respect to the extrusion axis. It was found that varying the concentration of aluminum (3-4 wt%) and Rare Earths (2-3 wt%) in AE alloys had a weak effect on texture development. All of the alloys showed similar magnesium extrusion textures, in which the (0002) poles align themselves preferentially with the extrusion axis. The substitution of Sr for Rare Earths also did not have a significant impact on texture development. On the other hand, while the presence of small amounts of Zn and Rare Earths did not have a strong effect on texture development, alloys with higher concentrations of these alloying additions (in combination) showed an enhanced tendency for the {1010} poles to align themselves with the extrusion axis. The addition of Ca also enhanced the alignment of the {1010} poles with the extrusion axis. These textures can complicate further processing and introduce a significant anisotropy that could influence creep properties.

Jan 1, 2007

By C. W. Taylor, F. L. Martin

"THE DICTIONARY defines Metallurgy as the ""science or art of separating metals from their ores and refining them for use"". In these days, however, such a definition is not detailed enough.The modern science of metallurgy is based on two fundamental sciences, physics .and chemistry, and is sub-divided into two major fields: Process Metallurgy and Physical Metallurgy. These fields of metallurgy are now so comprehensive and involved that even the graduate metallurgist has to specialize in one or the other.In recent years, the relatively new science or technology of non• destructive testing has also entered the industrial scene, with tremendous impact and ramifications. So much so that, certainly, no .discussion on metallurgy can be complete without including some reference to it.Obviously, one paper cannot hope to cover in detail the relationship of the whole science of metallurgy to the mining industry. Consequently, only a very brief reference will be made to the field of Process Metallurgy, our major concern being with Physical Metallurgy and Non-Destructive Testing."

Jan 1, 1960

By Omkar N. S. Beruar

Extraction of sill pillars has always been problematic because of high risk of seismicity and rockburst. Depending on a number of factors, a sill pillar can undergo different failure modes and cause problems in the mine. Of these, sudden and uncontrolled failure of part(s) of the pillar leading to highenergy seismic events and rockbursts is a main concern because it is not possible to predict the location and time of a rockburst apart from its potential to cause extensive damage to the mine structures. To date, a comprehensive technique for sill pillar design and recovery does not exist. Conventional methods of pillar design, such as the pillar stability graph method, are utilized to design stiff sill pillars. In these design approaches, the post-peak response of the pillar-rock system is not considered. This is in part due to a lack of clear and comprehensive understanding of the post-peak behaviour and failure mechanism of sill pillars. In general, the strength of a rockmass is described using a failure criterion. When stresses reach the strength of the rockmass, the rockmass does not necessarily become unstable and knowledge of the loads alone is not enough to assess the instability conditions accurately. In fact, it is not possible to predict instability of rockmass based on the strength/stress ratio alone because instability depends not only on this ratio but also on the loading condition and loading system characteristics. The loading system can dictate whether the sill pillar will go through a stable or unstable failure process. This paper examines the influence of various parameters such as the pillar width to height ratio, the extraction rate, and placement of backfill on the Loading System Stiffness (LSS) and the Pillar Stiffness (PSS). The ultimate goal is to design yielding sill pillars that would yield in a stable manner and will reduce the risk of pillar rockburst. Plane strain finite element analysis is conducted using the generalized Hoek-Brown failure criterion with elastic-brittle-plastic parameters. Examples are given to demonstrate how to calculate these stiffness values and assess the stability condition of sill pillars. It is found that increasing the rate of extraction increases the likelihood of unstable yielding of the pillar as has been found in other studies. Placement of backfill in a timely fashion in the stopes above and below the sill pillars increases the stiffness of the loading system. This indicates that backfilling of stopes while creating the sill pillar increases the likelihood of stable yielding of the sill pillar.

Aug 1, 2013

By D. A. Barr

"The Galore Creek copper deposits are situated in the Stikine River district, 640 miles northwest of Vancouver, British Columbia. The deposits are primary cupriferous replacements localized in highly fractured zones lying in altered sedimentary, extrusive and intrusive rocks near the contacts of a potash-rich syenite porphyry complex which forms the core of a structural dome in Upper Triassic volcanic and sedimentary rocks. Ten deposits are distributed over an area of 3.5 by 2 miles and through an elevation range of 4,000 feet. The deposits share many of the characteristic features common to both the porphyry copper type of mineralization and pyrometasomatic deposits.Primary mineralization includes chalcopyrite and bornite, and is associated principally with pyrite and magnetite. The daminant alteration products are hydrothermal biotite and potash feldspar. Gypsum, anhydrite, garnet, chlorite and carbonate are commonly associated with sulphide minerals. Copper oxides, al-though present, are quantitatively of minor importance. The distribution of certain of the primary minerals reveals hypogene zoning characteristics.The results of stream sediment surveys, and airborne magnetic, ground magnetic and induced polarization surveys show important relationships to geologic structure and mineral deposits."

Jan 1, 1966

By Guohong Yin

Oxidized sulfidic tailings contain significant amounts of accumulated acidity in the form of water-soluble secondary sulfate minerals and thus constitute long-term sources of acid drainage at many metal mining sites. As part of site remediation activities, alkaline amendments are often added to the oxidized tailings to increase the pH and immobilize the metals. This study assessed the advantages and limitations of using lime mud, a byproduct of Kraft pulp mills rich in calcium carbonate (> 90 wt. %), as alkaline amendment. The inorganic and organic constituents of lime mud samples were quantified. Leachable impurities were determined by the TCLP method. The performance of lime mud was compared to that of reagent grade quicklime (CaO) and calcite (CaCO3). Tailings treated with lime mud or calcite have strong buffering capacities and remain at neutral pH conditions (pH ~ 6.7) for long times. In contrast, tailings treated with quicklime have a very low buffering capacity, and their pH decreases with time. Furthermore, lime mud has finer particle sizes and thus a greater specific surface area than most forms of commercially available calcite, which results in enhanced reactivity. Dissolved metal concentrations are similar in tailings slurries treated with lime mud or calcite. This study suggests that lime mud is an environmentally and economically attractive alkaline amendment for oxidized mine tailings.

Nov 1, 2002

The Anglo Platinum Mogalakwena North concentrator was one of the first three hard rock mineral processing applications to utilise a HPGR circuit in preference to a SAG milling circuit. This was driven by the extreme competence of the ore that had given rise to throughput issues on the original South Plant. Despite more than adequate capacity and performance of the individual comminution units, the circuit has struggled to obtain full design capacity. A thorough review of the integrated performance of the circuit revealed a wide range of bottlenecks and underutilised parts of the circuit arising from design issues. Interestingly, the major opportunities lie in materials handling issues and mismatch of loads about the circuit. This paper presents the high-level outcomes and the associated opportunities, and is pertinent to all HPGR circuit designs.

Jan 1, 2012

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Previous testwork by the authors has indicated that both granular coconut shell based activated carbon and a new microporous carbonaceous bead, Lewatit® AF 5, are highly effective in improving the oxidation kinetics and decreasing the elemental sulphur yield when assisting the atmospheric oxidation of pyrite. While the two carbon catalysts show similar results and improvements to the pyrite oxidation, there are differences between them. For example, the activated carbon assisted oxidation showed faster kinetics than the AF 5 assisted oxidation, while elemental sulphur seemed to remain adhered to the surface of the AF 5 after oxidation when much of the elemental sulphur formed during the activated carbon assisted tests was found in the oxidation residue. The objective of this paper is to investigate the differences between the two catalysts through the use of scanning electron microscopy, photography, Raman spectroscopy, surface chemistry analysis, and Brunauer-Emmett-Teller (BET) surface area analysis. With this investigation the authors should be able to achieve a better understanding of the surface chemistry of the two carbon catalysts (i.e. functional groups, charges, acidity etc.) and help explain the strengths and/or the weaknesses of the catalysts when applied to the atmospheric oxidation of pyrite.INTRODUCTION Previous research conducted by the authors, indicated that both a granular coconut shell based activated carbon (activated carbon) and a microporous carbonaceous bead, Lewatit® AF 5 (AF 5), acting as a catalyst enhanced atmospheric pyrite oxidation in ferric sulphate media by approximately 40% when compared to unassisted oxidation and that elemental sulphur yields were increased from 23% to approximately 69 and 63% when assisted by AF 5 and activated carbon respectively (Cowan, Jahromi, & Ghahreman, 2017). The study indicated that although total pyrite oxidation assisted by the two catalysts was similar, differences were noticed in the impact that the two catalysts had on the outcome of the oxidation. Kinetic curves in the Cowan et al. study indicated that atmospheric oxidation of pyrite seemed to reach completion after 48 hours of oxidation when assisted by activated carbon. A similar trend was noticed in the kinetic curves for oxidation when assisted by AF 5, however the oxidation curve did not reach completion until approximately 96 hours (Cowan et al., 2017). This observation indicated that the kinetics of pyrite oxidation are enhanced by both catalysts, oxidation kinetics are much faster when assisted by activated carbon rather than AF 5."

Jan 1, 2017

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By G. V. Fernandez

Sociedad Minera Cerro Verde S.A.A leaches secondary copper sulfides. In recent years, the mine has introduced innovations that have improved the management of mineral crushing, agglomeration, curing, and leaching. The crushing plant, for example, uses the concepts of degree of balance and percentage of time in an operationally balanced state which, displayed in real time, facilitate more intensive and uniform utilization of the crushers. High agglomerate quality is ensured with the correct dose of moisture, which is adjusted to the changing characteristics of the mineral through the use of electrical conductivity measurements. The amount of acid used for curing the agglomerate is also adjusted by using quality control information. Finally, the stockpile irrigation regime is managed using the criteria established by the "Lixiviant Request Rate", which optimizes the addition of leaching solution, creating such benefits as faster recovery, and reduced acid and energy consumption.

Jan 1, 2007

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By Muhammad Zaka Emad

ABSTRACT: Sublevel stoping mining methods with delayed backfill employs cemented rockfill (CRF) as a backfill material. It is used in underground mines to achieve ground control and reduce wall slough. In addition CRF serves to reduce development waste and provides a working surface for mining the upper levels. Efforts to optimize CRF practices have been published. This paper presents a detailed review of CRF practices in open stoping mining systems with reference to case studies. A new methodology is suggested in a simple stepwise approach, which can be adopted for site specific conditions. The need of laboratory testing and quality control program is discussed based on the published literature.

May 1, 2013

By C. Tissot, R. Palmer

"Due to the low concentrations of gold, direct measurement of gold concentration in ore on belt has not been seriously considered to now. Pre-concentration or sorting strategies have largely consisted of particle sorting based on secondary characteristics such as colour, which can be successful in select cases. CSIRO has produced sample measurement results using gamma activation analysis of ~300 gm samples with accuracies of around 30 ppb at best. With this encouragement, a feasibility study into gold ore measurement on belt for the purpose of sorting pods of gold ore has been undertaken. The study described here included, prototype design options with existing industrial Linacs, extensive Monte Carlo modelling of measurement sensitivity and shielding, further sample measurement, a study of the interaction of target measurement accuracy and sorting efficiency, and a rough estimation of potential economic benefit. The projected model sensitivity of around 0.1-0.15 ppm (1 standard deviation) in 10 seconds for 1 ppm average feed result in good bulk sorting performance and intriguing economic potential.INTRODUCTION Pre-concentration or sorting strategies for gold ores have largely consisted of particle sorting based on secondary characteristics such as colour or density, which can be successful in select cases (Klein, 2010). No method is available to measure gold content for sorting in particles or even in bulk on belt, principally due to the low concentrations of gold present. In fact, in many cases it is difficult to do rapid bulk grade measurements of base metal ores with concentrations many orders of magnitude higher. By a fortunate quirk of nature gold is particularly amenable to gamma activation analysis (GAA). CSIRO has performed extensive work in GAA of samples of crushed ore (Tickner, 2017). This has resulted in the Photon AssayTM technique that is currently being commercialised through the CSIRO spinoff company Chrysos. The technique relies on the recent availability of industrial high intensity X-ray sources such as Linacs which are currently being used in industry for security, medical and sterilisation applications. This development has led to CRC ORE funding a feasibility study to determine whether on-belt measurement of gold concentration is possible at a rate and accuracy sufficient to be useful for bulk sorting, where pods of ore are diverted rather than individual rocks. The study in the first instance is based on Monte Carlo modelling that has successfully predicted the performance of the sample based gold measurements. As well as the measurement feasibility consideration was also given to the likely heterogeneity of gold ores and hence the degree to which useful separation could be achieved. This is then tied to a back of the envelope evaluation of the order of magnitude economics of bulk sorting in an example deposit."

Jan 1, 2017

By W. A. Grell

"The oxygen meter has been in use at MacLeod Cockshutt Gold Mines for over a year, At MacLeod about 200 tons per day of reground concentrate containing roughly 10% pyrrhotite and 20% pyrite is cyanided in four 181 x 18' Dorr agitators. A survey by the Department of Mines showed that oxygen content of some of the agitators was rather low. Experience with our oxygen meter indicates that the oxygen content must at times have been too low for good gold dis solution.We have found that in winter, when pulp temperatures drop to about 50° F, oxygen saturation in the agitators is not difficult to maintain. In summer, however, when pulp temperatures rise to 70or 75°F, the oxygen content will drop very readily. It was found that a high oxygen content can be maintained readily if the pulp is sufficiently dilute. Thus at 50° F, a pulp of specific gravity 1. 75 i.e., about 55% solids, will saturate; but at 70 or 75° F, the specific gravity must be decreased to 1 .45, equivalent to about 40% solids, in order to maintain saturation. Very thick pulps, such as thickener underflows, are noticeably difficult to saturate in the laboratory, and lose their oxygen rapidly.Clear solutions, on the other hand, absorb oxygen readily and hold it. The primary thickener overflow, before agitation, is 100% saturated; after storage of 3 to 4 hours it is still 100% saturated at re clarifier tank. Barren solution after spraying in a launder is 100% saturated.We have not yet attempted to determine what percentage saturation is necessary for good extraction, but it is known that there is a point at which extraction decreases rapidly. So far, the measures required to maintain over 80 or 90% saturation have coincided with measures required to hold the reducing power to the point believed necessary."

Jan 1, 1964

By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By N. Samman, S. N. Lau

"A series of new, grease-based, solvent free open gear lubricants were developed to meet the demanding service requirements of mining equipment. The use of these products has resulted in better performance under conditions of temperature extremes and in terms of longer component lives. They have gained widespread acceptance within the mining communities for such applications as the lubrication of mining shovels, draglines and ball mills.These products are WHMIS non-controlled and are environmentally acceptable. The benefits and advantages of using this type of product to lubricate mining equipment as well as the field evaluation and experience will be discussed."

Jan 1, 2002

By Du Xinfeng

The resource quantity of the low rank coalbed methane (CBM) accounts for 47% of the total resource quantity of CBM in China. Compared with the exploration and development of the high rank CBM in Qinshui Basin, China and the low rank CBM in Powder River Basin, USA and Albert Basin, Canada, the exploration and development of the low rank CBM are still in the initial test stage. In this paper, on the basis of analyzing the mining geological conditions such as that the Huanglong Jurassic Coalfield is largely situated in the hills and gullies zones, and the coal reservoir has the features such as the low metamorphic degree, large coal seam thickness, simple coal matrix texture, high permeability and small CBM content and so on, it discusses the key technologies such as the development pattern of CBM, well location arrangement, drilling and well completion technology and fracturing technology and so on. It indicates that the underbalanced drilling and the cavity well completion based on the reservoir protection will be the development directions of the CBM development technology in this area.

Aug 1, 2013

By J. Kronsteiner, E. Kabliman

"In the present work, we developed a Smart Process Control Toolkit (SProC) as a single simulation environment for the modelling of materials microstructure and its interaction with the local microchemistry during manufacturing of semi-finished products. This toolkit supports the data communication between sub-sequent processing steps such as casting, homogenization, pre-heating to deformation, etc. The thermo-kinetical simulation software MatCalc of MatCalc Engineering© GmbH was used for modelling of precipitation kinetics, such as formation of primary and secondary phases and their evolution. An import/export functionality of the precipitation distribution after each processing step was implemented to follow the parameter history. For the evolution of the local microstructure, a Mean Dislocation Density based Model (MD2M) was used. This model consists of two parts: (1) Flow Stress Model for calculation of the total strength during the deformation and (2) Static Recrystallization Model for account of the recrystallization and grain growth after the deformation. Validation was done by a comparison of experimental and simulated hot compression tests of a conventional AA2024 alloy.INTRODUCTION Optimization of a semi-finished products quality, elimination of typical production issues and cost savings are of a great demand for supply industries. However, it is currently not feasible to investigate the whole manufacturing process in detail at an industrial level. Concerning the processing parameters, one must understand the correlation mechanisms between macroscopic properties and microscopic material behavior. Numerical simulations, which could reproduce the real processing conditions on the one hand, and employ a physically based modelling on the other, are thus attracting a lot of attention and their power is no longer under the question. It is well known that e.g. the total strength of the material depends directly on distribution of precipitation particles and mean grain size. In order to follow their evolution during the manufacturing process beginning from casting to the final semi-finished product, and thus be able to control the process, one should use the techniques which would at the same time reproduce experimental processing conditions of real size objects (e.g. sheet, extrusions, etc.) and account for the evolution of a local microstructure and its interaction with the microchemistry. A commonly used approach is to implement a model which would describe the evolution of microstructure based on a dislocation density approach into a user defined material subroutine of some finite element solver. There is, however, also an influence of the manufacturing process by e.g. the evolution of a local microchemistry (formation, transformation and dissolution of the precipitation particles) on the microstructure and thus the macroscopic material behavior. Thus, a method is needed to follow the variable history through the simulation of the whole production chain."

Jan 1, 2018

By J. Béland

"Three stages, each characterized by a particular sedimentation, magmatism, mineralization and deformation, are recognized in the geological history of Gaspe. The first stage led to the formation of the Taconian orogen, the second to that of the Acadian orogen and the third stage to the accumulation of a post-orogenic cover. The Taconian orogen includes volcanic and detrital rocks of Late Precambrian or Cambrian and Lower to Middle Ordovician ages in which ultrabasic intrusions have been emplaced. Folding is severe. Mineralization is of the Cr-Ni-Cu type, related to the igneous facies.The rocks constituting the Acadian orogen include two distinctive sequences corresponding to two successive sub-stages. The second substage began in Early Devonian time with the first pulses of the Acadian orogeny. The rocks of the first substage grade southward from a nearly platformal sequence to an assemblage implying less stability and spotty volcanism. The second substage was one of synorogenic deposition of elastic rocks, first in a marine environment and later under terrestrial conditions. Granitic intrusions, surrounded by aureoles of skarn and hornfels in which Cu-Pb-Zn mineralization is found, accompanied the Acadian deformation. The second-stage"

Jan 1, 1969

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005