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By Waldemar W. Koczkodaj, William O. MacKasey

Abstract - A consistency-driven pairwise comparisons method for mineral potential assessment is presented, using a simplified case of volcanic-associated massive sulfide type deposits as an example. Geological, geochemical, and geophysical criteria are considered on two levels: local and regional. The local geological criteria are subdivided into stratigraphy, lithology, alteration and/or mineralization, and structure. The concept of geomerit index and a procedure for computing this index are introduced. The method of consistency-driven pairwise comparisons can be combined with other quantitative and qualitative assessment methods, enhancing them by incorporation of nonmeasurable geological criteria (e.g., stratigraphy or lithology) and by computation of weights. The consistency-driven approach allows experts to refine at-times subjective judgments concerning exploration and land-use planning, and contributes to the improvement of mineral-potential assessments.

Jan 1, 1997

By M. Kosugi, Y. Kon, M. Kawata, J. V. Satur, K. Mitsuhashi, C. Tokoro, K. Horiuchi, R. Kawarabuki, B. Calabia

"Liberation of copper minerals is important in ensuring high flotation efficiency in copper sulfide flotation. The high pressure grinding roll (HPGR), microwave (MW), and electric disintegration (ED) are known to feature enhanced liberation over conventional comminution machines such as jaw crushers and ball mills by producing internal stresses on minerals or mineral grain boundaries through high compressive forces, thermal expansion of minerals, and pulsed high voltage discharges, respectively. In this study, each of these methods was applied before ball mill grinding to investigate its effect on enhancing the liberation of copper minerals in a low grade and fine-grained copper ore. The copper minerals observed in the tested ore sample are bornite, chalcocite, and chalcopyrite, and their grain sizes range from 10 to over 100 µm. Calcite, quartz, and feldsparare confirmed as gangue minerals. The liberation of the copper minerals by the different methods was analyzed using the mineral liberation analyzer (MLA) and compared. The result showed that the HPGR crushing was the most effective for enhancing copper mineral liberation. HPGR bench-scale test was then conducted on the copper ore and flotation was applied on a HPGR-treated sample to confirm the improvement in the flotation performance by applying HPGR.INTRODUCTIONIn order to recover copper minerals by flotation, copper ore is usually ground by ball milling to liberate the copper minerals from gangue minerals. In the case that the fine size copper minerals are targeted, grinding of the copper ore to a finer size is necessary to increase the copper recovery. However, finer size grinding by ball mill increases energy consumption significantly, which might deteriorate the economies of the mineral processing operation. HPGR, MW, and ED have been recently the focus of researchers as new techniques for enhancing the mineral liberation in mineral processing (Tavares, 2004; Kingman, 1998; Wang, 2010).HPGR crushing is considered to generate micro cracks along mineral boundary when rocks pass between two rolls by applying high compressive force. In the MW treatment, micro cracks are reported to be generated at crystal boundaries by differential thermal expansion of crystals attached to each other. In the ED treatment, micro cracks are known to be produced by plasma current flowing along mineral grain boundaries. These treatments are expected to increase mineral liberation (Fujita, 2001),improve flotation performance(Michaelis, 2005), and reduce ball mill work index(Kaya, 2010)."

Jan 1, 2017

By J. Schmidt

The development of set of laboratory experiments, intended to help undergraduate students meet Canadian Engineering Accreditation Board requirements for Engineering Design outcomes, is described.The laboratory, which is part of a third year level course in hydrometallurgy, is aimed at advancing the ability of students to generate and use experimental results to design an industrial copper leach/SX/EW plant. Emphasis is placed on the students demonstrating the ability to use of their engineering knowledge in weighing the pros and cons of the various process options that they test in converging to a final flowsheet. INTRODUCTION Over the past number of years the Canadian Engineering Accreditation Board, CEAB, has dramatically shifted the way that they evaluate undergraduate programs. In the past, the focus was on measuring of the quantity and quality of material the students were intended to learn as well as the methods and resources used to deliver that material. Now, rather than principally evaluating the inputs of programs, the focus is more on measuring the quality of the outputs from the programs, i.e. the quality of graduating students. In this regard, the CEAB has developed a list of twelve attributes that learners must develop in the course of their studies. Engineering programs must, not only demonstrate that their curriculums provide opportunities to develop these attributes, but must measure student proficiency in each of these attributes as they progress toward graduation. One particular graduate attribute that Laurentian University’s Bharti School of Engineering has encouraged its faculty members to develop content for is “design”. Engineering Canada (2018) defines this attribute as “an ability to design solutions for complex, open-ended engineering problems and to design systems, components or processes that meet specified needs with appropriate attention to health and safety risks, applicable standards, and economic, environmental, cultural and societal considerations”. The previous laboratory component for the hydrometallurgy course was a collection of unconnected experiments covering leaching, solvent extraction, ion exchange, and electrowinning. Like in other undergraduate courses, students would perform stand-alone experiments, make the specified measurements, do the specified analyses of the results, and report the findings, all as strictly detailed in the lab manual. The vision for the new lab was to create an experience that would more closely mimic an industrial research program whereby students would start with a given feed material and would progress through a series of connected experiments. Emphasis is placed on the student demonstrating competency in, not only, generating and analyzing experimental data, but also in using the data along with their engineering knowledge to design and evaluate the pros and cons various plant configuration options. Principally, students are asked to weigh cost, safety, and environmental concerns in converging to their final flowsheet. In designed the leach circuit, students must weigh the costs/benefits of varying leach temperature. Higher leach temperatures will yield faster and more complete copper dissolution, which will allow for the specification of relatively smaller leaching circuits, saving capital costs. However, hotter acid solutions are more dangerous to handle and require increasing amounts of energy to heat the slurry, increasing operating costs. In solid/liquid separation, students must weigh the pros and cons of the addition of a flocculent to assist settling. The flocculant will allow for the design of a thickener circuit that employs units with a relatively smaller area, but will result in a thickener underflow with a lower pulp density, which may necessitate a larger number of thickeners. In addition, the environmental concerns of producing a tailings product that contains an organic contaminant should be addressed. In solvent extraction, students must specify the number of stages of loading and stripping, as well as organic and aqueous flowrates to produce suitable raffinate and rich electrolyte streams. Finally, in electrowinning, students will compare the costs/benefits and risks of the use of precious metal coated titanium dimensionally stable anodes (DSAs) versus conventional Pb based anodes.

Jan 1, 2019

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016

By T. Rigg, J. N. Stone

"The process described has been developed to utilize low-grade scrap -turnings, borings, tin cans and other types of ferrons scrap which currently has been of limited or no use in conventional steelmaking processes. If scrap of this type can be converted into high-purity iron by chemical means then there is a potential saving of several million tons of metal annually in North America.The process is chemically quite simple and consists of dissolving ferrons scrap in hydrochloric acid, followed by evaporation and crystallization of the resultant solution to yield ferrons chloride crystal.s. These crystals are dries, briquetted and converted to non sponge by reduction in hot hydrogen. The HCl produced from the reduction step. is absorbed in water and the hydrochloric acid so produced is returned to the dissolver circuit. The hydrogen produced from the initial dissolution of the scrap is used to reduce the ferrons chloride. Purity is maintained by bleeding off impure chloride solutions from the evaporator-crystallizer circuit, and converting these chlorides to oxides and HCI in a high-temperature spray roaster. The HCl produced in the roaster is absorbed in water and the hydrochloric acid returned to the dissolver."

Jan 1, 1970

SOME months ago a Committee on Deep-level Mining was appointed [by the Government of the Union of South Africa] to consider the possibility of gold mining being carried on at a depth below 8,500 feet. The Committee consisted of Sir Robert Kotze (Chairman) , Mr. H. S. H. Donald (Government Mining Engineer), and Mr. H. R. Hill. The Committee has now made a report which was tabled in the House of Assembly on March 1st. The Committee reported that the tonnage of ore locked up in the deep level areas of the Central Witwatersrand is enormous, and in the 30 miles between Roodepoort and the East Rand Proprietory Mines has a value of about £200,000,000. The Committee says that, with good ventilation, the present system of wet mining, possibly with some modification and with the aid of refrigeration, may be carried to 10,000 feet, but that greater depths will require the adoption of dry mining. "A vigorous campaign of practical experiment into the possibility of dry mining should be initiated, and the Committee recommends to the Government the appointment of a committee of experts, consisting of representatives of the mining industry, the Mines Department, and the medical profession, with the Government Mining Engineer as chairman. The Committee suggests the provision of £30,000 for the first year for the investigations and experiments contemplated, which could best be carried out by an organization which might be styled 'The Rand Mining Research Institute' and constituted somewhat on the Jines of the South African Institute for Medical Research" . The Committee suggests that this committee of experts should arrange for experiments to be made with dry mining in one of the deepest mines, and investigate ventilation, refrigeration, support of workings, and the physiological problems connected with mining. "We emphasize the necessity of treating this whole question as one of importance and urgency. The investigations should be prosecuted with the utmost vigour and should not be delayed at any time for want of funds or for any other reason. If they are not done thoroughly and quickly, the whole scheme might just as well be left severely alone.

Jan 1, 1945

By A. Ghasemi

An alumina-silica coating was deposited on a nickel substrate by sol-gel process, and the structures and composition were evaluated, The sols were made from aluminium and silicon alkoxide, and an acid catalyst including HCl, To produce adherent silica coatings on nickel, various additives such as surfactant, viscose additive and drying control chemical additives were introduced to the system, and appropriate drying and firing cycles were applied after dipping in solution. The hot corrosion and oxidation resistance of the coating at different temperatures were investigated, The structure and uniformity of the coatings were examined by scanning electron microscopy (SEM), The results indicate that a uniform coating of alumina silica can be produced on a nickel substrate by optimizing the composition and process variables of the sol. Coatings can protect substrates from oxidation and hot corrosion at different temperature up to 1000°C, but is not very effective for hot-corrosion resistance at 1000°C.

Jan 1, 2005

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By J. Paraszczak

ABSTRACT Diesel-powered loaders are a pillar of modern underground metal mining. As these mines are getting deeper and hotter and the emission regulations stricter, ventilation costs are soaring, affecting production cost. Also, the cost of diesel fuel is expected to rise. These may make the use of diesel engines more problematic. Electric load-haul-dump machines (LHDs) are an interesting alternative. This paper compares features and performance of diesel and electric, cable-powered LHDs. It overviews equipment offerings, and compares, analyzes and discusses technical parameters, operational problems and cost issues. The paper gives some conclusions about electric LHD applicability and performance, indicates possible applications, and suggests further research work.

Jan 1, 2013

By S. Mao

Total station has been predominantly applied in stationary survey scenarios in construction. With the moving target tracking and point survey automation functions, a robotic total station (RTS) lends itself well to more dynamic applications. Nevertheless, a RTS unit is still unable to track multiple targets simultaneously or to survey a target point when the line-of-sight is temporarily unavailable. In this paper, we propose a methodology to synchronize and automate multiple RTS units intended to address dynamic tracking and surveying applications in the construction field. By using the application programming interface (API) from the manufacturer, we implement the proposed methodology and the prototype system integrates two RTS units in regard to space and time and communicates survey command instructions among RTS units through wireless networks. The two RTS units can be operated to survey the two ends of one swinging sling concurrently in order to retrieve the actual length of the sling within several millimeters accuracy. Besides, in applications where line-of-sight between a target object and one RTS unit cannot be guaranteed all the time, continuous surveying can be materialized by automatically delegating the task to another synchronized RTS unit with clear view of the target object. A field test was conducted to demonstrate the application of the proposed automation approach in which sling length was measured of a rigging framework used for lifting industrial modules. The testing results are presented and achievable accuracy and reliability are discussed. The proposed solution overcomes the limitations of global positioning system (GPS) and laser scanning and holds high potential to provide cost effective solutions to many dynamic field applications.

Aug 1, 2013

By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By R. Laucournet, E. Billy, M. Joulié

Today Li-ion batteries are considered as one of the most attractive available energy storage solutions. However in order to overcome environmental, legislative and economic issues, the management of used batteries has to be considered and mainly the recycling. The present paper deals with the recycling of used Li-ion batteries and the recovery of high value metals from active materials of electrodes. Lithium nickel cobalt aluminum oxide (NCA) and lithium manganese nickel magnesium oxide (LMNM) cathodes, which contain most of valuable elements typically used in the composition of active materials for Li-ion batteries are investigated by a hydrometallurgy route. The process is divided into two steps: the materials leaching and the elements recovery by a selective chemical separation. Some experimental parameters (acid nature, concentration, time and temperature) are studied to determine the most efficient conditions of dissolution. Then, the valuable elements such as nickel, cobalt and manganese are selectively recovered with a high efficiency close to 100 % and with a high purity by precipitation. By this study, an adaptable hydrometallurgy process can be defined according to the composition of Li-ion batteries to recycle.

Jan 1, 2014

By L. Veleva, Garcia. A., G. Perez

Aluminum is a metal used for the transmission of electricity of high voltage, in the construction industry and other areas. In atmospheric conditions aluminum forms an oxide layer (Alz03'H20) as a result of its corrosion, entering the passive state. The oxide layer can be destroyed by the presence of ions (Cr, SOx-n) developing localized (non uniform) corrosion attack by pitting, difficult for evaluation. The concepts of fractals and self-similarity were used in this study for the characterization of the development of localized corrosion. Images obtained with a scanning electron microscope (SEM) of samples of electrolytic aluminum wire that have been exposed during one year in ruralurban and marine-coastal environments of the humid tropical climate of Mexico, have been processed. The development of pitting has been studied as a function of time, making a statistics of the frequency of appearance of pits versus the area occupied by them. The data show that the distribution of the pits follows a power law. Therefore, the concept of self-similarity can be applied for the study of the phenomenon of localized corrosion, describing their development with time.

Jan 1, 2006

By J. Lui

Inco Copper Cliff Smelter commissioned two new Inco flash furnaces in 1991/1993 as part of its S02 abatement program. Each flash furnace is equipped with a fluid bed dryer. The ~ 12 wt% water content in the concentrate filter cake, flux, reverts and sludge is removed in the fluid bed dryer. The dry solids are discharged from the dryer together with exhaust gases into the baghouses where they are separated. The dry solids are transferred to four storage bins. In September 2003, for the first time since startup in 1991/1993, a large amount of elemental sulfur accumulation was discovered on the walls, roofs and floors of the outlet side of the baghouse chambers. Several baghouse fires were experienced during cleaning and conducting maintenance work in the elemental sulfur contaminated baghouses. Laboratory scale test work at the Inco research lab was conducted to understand the mechanism. A plant solution to minimize elemental sulfur formation was implemented with success. This paper summarizes the efforts to understand and minimize elemental sulfur formation in the baghouse chambers.

Jan 1, 2007

By J. Zollinger, J. R. Kennedy, J. H. Park, D. Daloz

"In order to improve the properties of cast Ti-Al alloys to replace Ni-based superalloys past the low pressure stages of aircraft engines investigations into inoculation for grain refinement were carried out. Previous work showed isomorphic self-inoculation using Ti-Al-Nb particles was effective for grain refinement, however the relatively fast diffusion of Nb in Ti-Al make it difficult to observe the mechanism of nucleation. An alternative alloy was developed in the Ti-Ta system for isomorphic self-inoculation, maximizing the Ta content to improve the particles survivability in the melt. The powder processing produced comparatively small inoculant particles which dissolved, however larger particles were seen to survive solidification. The density difference between the inoculant particles and melt resulted in an inhomogeneous mixing of the particles and the melt with larger particles found near the outer edges of the ingots. Variations on particle size and interaction time between the inoculants and the melt resulted in the Ti-Ta inoculant reducing the as-cast equiaxed grain size by a factor of two compared to non-inoculated samples as well as increasing the equiaxed fraction in the ingot.INTRODUCTION Lightweight metals are of particular interest in aerospace applications. The hot sections of turbines are dominated by blades made of nickel based superalloys. Recently the GEnx turbine introduced TiAl blades in the last low pressure stage of the turbine to reduce weight and improve fuel efficiency (Kim & Dimiduk, 1991). In order to carry these benefits deeper into the turbine the high temperature (>800oC) properties of the alloys must be improved. Current grain refinement methods to improve properties rely on boron additions which may not be applicable for all blades as brittle precipitates may be formed during processing (McCullough, Levi, Mehrabian, & Hyman, 1991). A novel grain refinement process was previously introduced called “isomorphic self-inoculation” using Ti-Al-Nb particles to successfully grain refine TiAl (Kennedy, Zollinger, Bouzy, & Daloz, 2016). In order to better understand the mechanism of this process an investigation was carried out using the same process but with a Ti-Ta alloy which is more stable in the TiAl melt than the Ti-Al-Nb."

Jan 1, 2017

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By S. H. Schulz

100 YEARS AGO, on the first of August, 1877, the mining engineer Friedrich Koepe was granted the patent rights for a hoist driving ropes on the principle of friction. It was named after him: the Koepe hoist. On the occasion of this centenary, the main features of the Kcepe principle are described.

Jan 1, 1977

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner&apos;s pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930