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By C. Cortés

Flotation is a highly interactive process where a change or disturbance in any part of the circuit results in different final grades and recoveries. This high variability of the circuit metallurgical performance complicates the diagnosis of the scavenger stage at the end of the line, as copper losses in the final tailings are erratic and not totally a consequence of problems in the scavenger section. The assessment of the scavenger performance requires a more elaborated procedure than that used for others stages of the circuit. This communication describes the application of an approach that combines results of laboratory flotation tests with those of surveys performed at the plant. The approach is based on running surveys in one of the circuit lines to collect samples for determining grade vs. recovery curves for total mass and size-by-size fractions. Full mineralogical and liberation analyses are also considered on some samples of the feed and tailings streams selected to have a range of feed grades. A separate sample of the feed is used to run laboratory flotation tests to determine optimum flotation time. Two additional pieces of information are the effect of operating variables on recovery, determined through a test program based on design of experiment techniques, and operational data on every cell in the line gathered by visual observation. The application of this approach to one of the scavenger lines at Los Colorados concentrator (Minera Escondida, BHP Billiton) is demonstrated.

Jan 1, 2007

By Simon C. Dominy, Alwyn E. Annels, Paul Wheeler, Suzanne P. Barr, G. Simon Camm

Narrow veins are an important world-wide source of silver, tin, uranium and particularly gold. To potential ?nanciers, this style of mineralization is viewed as high risk because of the often relatively small resource involved and high cost of estimation. In many cases diamond core drilling will not enable resource estimation beyond the inferred and indicated categories. Exploratory under-ground development is required to de?ne measured resources. The de?nition of geological and grade continuity are major factors in narrow vein assessment. A measured resource must be based on strong geological and grade continuities. Narrow veins, generally less than 3 m wide, are complex geological phenomena, which commonly display unpredictable geometry and grade distribution. Variations in structural continuity, dip, strike, width, mineralogy and speci?c gravity are common. Veins may be composite, with ore-grade mineralization restricted to a speci?c structural domain. Branches, intersections and braided zones are common features. Potentially high-grade zones are often localized within ore shoots, which are surrounded by barren/low-grade regions. Resources must be determined as closely as possible to reality and re?ect the distribution of the commodity in the rock. Estimation has three main requirements: (1) geological study to determine orebody nature;(2) estimation of tonnage and grade, and (3) the presentation of this information using a classi?cation that is clear, unambiguous and bankable. Estimation methods employed are either classical or geostatistical; however, classical methods are often used because of the dif?culties in applying geo-statistics. Grades generally show a strong positively skewed distribution testifying the presence of high-grade values. Problems exist in the applicability of cutting outlier values risking over- or under-estimation of grade. It is generally believed that where resource estimates are in error, poor geological control is usually the cause. Overestimation can lead to the closure of a mine through lost revenue and capital. An understated estimate can result in an opportunity missed for pro?t and/or greater economies of scale. De?nition of reserves involves the consideration of economic and engineering data, to decide which part of the resource is economically mineable. Geology plays a similarly important role at this stage in the assessment of likely mining method, dilution, recovery etc. Throughout resource/reserve estimation, it is crucial that the amount and quality of the data and the geologist’s experience are relevant. The impact of geological understanding on estimation is often undervalued or assumed to be of lesser importance than ?nding grades and tonnages. This paper discusses the geology of narrow vein deposits and the importance of geology in their evaluation.

Jan 1, 1997

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed sur?cial mapping and sampling programs in the Separation Lake area of north-western Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of sur?cial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these sur?cial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t)values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sul?de mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from sur?cial samples was compared with that of in situ material. Gahnite from the peraluminous rare-element granite and pegmatite overlapped very well with sur?cial gahnite of Group 1. Gahnite from volcanogenic massive sul?de mineralization and Sedex-type mineralization overlapped well with sur?cial gahnite of Group 2. These results suggest that determination of gahnite composition in indi-cator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

By S. S. Al-Thyabat, A. M. Ghrair

"Printed circuit board (PCB) is the main part of any electric or electronic device, providing mechanical support and electric connection for the board eclectic components such as capacitors, resistors, diodes etc. PCB consists of non-conductive substrate overlaid with one or more layers of copper sheets. They also contain appreciable amounts of base metals (copper, nickel, tine, and aluminum) and precious metals (gold, silver, and rare earth elements (REE)) which end up in the landfill at the PCB end-of-life.PCB recycling E-waste in general is a profitable business; many valuable raw materials, precious and base metals, can be extracted with high purity. Approximately, one metric tonne of PCBs may contain 80-1500 g of gold and 160–210 kg of copper. The precious metals recovered from PCBs occur at concentrations higher than commercially mined minerals. Also PCB recycling is very important to our environment since many heavy metals (e.g. lead) may be leached from the landfills to the underground reservoirs. In Jordan, however, the work conducted on E-waste and PCB recycling in particular is limited; currently most of the E-waste is either exported or dumped in the landfill.In this work, a combination of physical (magnetic separation), physicochemical (flotation), and chemical methods (leaching) were used to compare metals concentrations in leach liquors produced from a concentrates resulted from a combination of these methods. It was found the leach liquor of the magnetic fraction of the PCB coarse size gave the highest concentration of Fe, Al, and Ni while concentration of Cu was higher in leach liquor of nonmagnetic sink fraction. On the other hand, metals concentration almost similar for both sink and float of the fine size fractions, indicating even distribution of metals concentrations in the fine size fractions."

Jan 1, 2016

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Abstract-Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed surficial mapping and sampling programs in the Separation Lake area of northwestern Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of surficial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these surficial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t) values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sulfide mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from surficial samples was compared with that of in situ material. Gahnite from the peraluminous rareelement granite and pegmatite overlapped very well with surficial gahnite of Group 1. Gahnite from volcanogenic massive sulfide mineralization and Sedex-type mineralization overlapped well with surficial gahnite of Group 2. These results suggest that determination of gahnite composition in indicator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

Iron control and iron residue management and disposal are significant issues in all zinc production processes. This paper briefly reviews the most important primary zinc production routes and discusses the challenges posed by iron control in each of them. The technologies and strategies that have proven successful in controlling and managing iron are discussed. SNC-Lavalin&apos;s experience in designing and commissioning zinc plants provides a unique perspective from which to review this aspect of zinc production.

Jan 1, 2006

By F. K. McKean

THE task of establishing a new corrosion testing laboratory is more difficult than it need be because there is very little information on the subject available in the literature. Many articles describing tests and results may be found, but a wide search will unearth only passing remarks on the different types of equipment that may be selected for accelerated corrosion tests. An article describing some of the apparatus needed in a corrosion laboratory should be of help to those interested in building a new unit or in making additions to an old one. In May of this year, the writer was given the assignment of equipping a laboratory for general corrosion testing, to form a part of the new Physical Metallurgy Research Laboratories of the Department of Mines and Resource~ at Ottawa. With the help of senior members of the staff, along with what could be gathered from other sources, a list of necessary equipment was compiled and a plan for arranging it in the rooms was decided upon. Where possible, the apparatus was constructed in the excellent machine shops at the disposal of this Department, while the rest was placed on order with the manufacturers.

Jan 1, 1945

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By Brad Gunn

Our program has been dictated by the necessity of broadening our markets through converting potash chemicals to fertilizers more in demand than potassium chloride. To this end, we have undertaken studies on methods of preparing potassium sulphate or potassium magnesium sulphate by rather simple conversion. When mixtures of sodium and magnesium sulphates are reacted with potassium chloride, the ratio of sodium to magnesium is quite pertinent. A range of ratios has been selected and the conversions of potassium chloride to sulphate have been assessed by cyclic operations. Results from experimental procedures for producing potassium nitrate are also avail-able. The influence on recovery for systems including organic solvents is assessed for a variety of situations.

Jan 1, 1971

By A. Holland, T. Krumins, E. Olin, J. F. M. Castilleja, J. Geldart, C. Fleming, I. Jackman

A flowsheet has been developed to treat the flotation tailings from a copper mine in Mexico to recover gold and silver by cyanidation and carbon-in-pulp (CIP). The plant will treat ~15,000 t/day of a 60:40 blend of current flotation tailings and the mine’s historic tailings. The tailings also contain a significant amount of cyanide-soluble copper, and the economic viability of the project is strengthened by recovering most of the copper and cyanide associated with this process. The solution and solid phases in the CIP tailings will be separated in a counter current decantation (CCD) circuit and the CCD solution overflow will be treated by a SART Process. Copper precipitates as a salable copper sulphide product in the SART Process and the cyanide that is associated with the copper complex is regenerated as free cyanide. After SART, a portion of the SART product solution will be recycled to leach to reuse the free cyanide, while the remaining solution will be used as wash water in the CCD circuit. Incorporation of the SART Process in the flowsheet allows the CIP circuit to be operated aggressively as a gold plant, which means most of the silver in solution passes through CIP to SART. Silver co-precipitates with copper in SART and is recovered very efficiently with the copper sulphide by-product. Incorporation of SART also allows the leach and CIP circuits to be operated with relatively high levels of free cyanide, which enhances silver leach kinetics and helps keep copper from loading onto the carbon in CIP. The flowsheet was developed in the laboratory and successfully demonstrated in a fully-integrated pilot plant in 2018.

Jan 1, 2019

By Frédéric Bélanger, George P. Demopoulos, Pascal Coursol, Thomas Feldmann

"The use of scandium in industrial applications is expected to rise in the coming years, in large part due to the expected adoption of new, clean energy technologies such as solid oxide fuel cells or Sccontaining high strength aluminium alloys. Given that the supply of Sc is currently dominated by only a few countries (Russia and China) other sources for scandium extraction need to be investigated. This paper looks at different options for the recovery of scandium from waste solutions generated during the production of TiO2 pigments via the chloride process route. In particular, a direct solvent extraction (SX) approach and possible options for concentrating scandium before the SX step were investigated. It was found that the presence of Ti during solvent extraction causes severe formation of stable emulsions, which can complicate the successful application. This was particularly a problem after multiple contacts of the organic phase with fresh aqueous phase. On the other hand it was noticed that the presence of certain elements in the solution, e.g., iron, could possibly be utilized to concentrate scandium in a solid precipitate.INTRODUCTIONMany newly developed high-tech products depend on the use of chemical elements that are only produced in very small quantities. This can result in high and fluctuating prices, as can be seen from Figure 1, which may cause substitution with inferior alternatives, if possible at all (Reck & Rotter, 2012; US Dept. of Defense, 2013; Whittaker, 2011). One example is scandium (Sc) a member of the extended rare earth element family. There are only a few scandium ore deposits, but most Sc is produced from the processing of by-products of other metallurgical processes (Melcher & Wilken, 2013). Increasing demand for scandium metal and oxide (Sc2O3, scandia) is coming from its increased use in applications such as ceramic lasers (Li, Ikegami, & Mori, 2005; Rainer et al., 1982), high strength aluminium alloys (Lathabai & Lloyd, 2002) as well as solid oxide fuel cells (SOFC) (Thijssen, 2011). Especially, the spread of climate friendly SOFC’s, which are a commercial product today (Bloom Energy, 2014), is expected to be a main driver for future Sc2O3 demand. However, the rate of market penetration of this green technology depends on the availability of high purity Sc2O3 (>99.999%), since it specifically contributes to longer life-time and better safety of the SOFC’s (Bloom Energy, 2014; Irvine, Politova, & Kruth, 2005)."

Jan 1, 2016

By D. F. Malan

"This document highlights some of the topical problems associated with the design and support of deep tabular excavations in hard rock. The displacement discontinuity boundary element method has been used for at least five decades to analyse stress and displacement distributions around narrow width excavations with complex plan outlines. The assumption is made in most cases that the rock mass surrounding the excavation is perfectly elastic. Although this approach works well to minimise stress concentrations in practice, it has limitations as important parameters, such as the effect of mining rate, cannot be investigated. Recently, a limit equilibrium model has been studied as a means to enhance standard layout design exercises by including an interactive on-reef damage model. This approach can include explicit energy release dissipation computations. A second problem faced by engineers in the mining industry is the evaluation of pillar and remnant stress. The paper highlights two aspects namely the effect of element size in displacement discontinuity modeling on pillar stress and the difficulty to estimate the effect of total closure on the regeneration of stress in old mining areas. Regarding the support of the tabular excavations, current efforts are focussed on providing improved aerial coverage using hangingwall bolting and temporary nets. An unresolved issue is the installation of permanent mesh in low stoping width areas. INTRODUCTIONSince 1886, more than 50 000 tons of gold has been mined in the Witwatersrand Basin of South Africa (Hartnady, 2009). The nearby platinum mines also saw significant growth in recent years and more than 80% of the world’s platinum group metal reserves are contained in the Bushveld Complex of South Africa (Nell, 2004). Apart from the economic aspects, the mines served as an outstanding rock engineering “laboratory” for many decades owing to the deep, tabular nature of the excavations. The period from 1960 to 1980 was especially lucrative in terms of research and world-renowned researchers investigated the support and rockburst problems (e.g. see Cook et al., 1966; Salamon, 1968; Bienawski, 1973; Wagner, 1984). Many of the rock-related problems nevertheless persist up to the present day and this paper explores some of these problems and recent progress. The production of gold declined substantially in recent years (Hartnady, 2009) and well-directed rock engineering research can play a meaningful role to slow this trend. The objective of the document is to highlight critical areas requiring additional research and not to discuss the topics in detail. The reader is referred to the many references for additional information. The paper only focuses on three areas namely numerical modelling, pillar stress estimation and aerial support. Although these are diverse topics, it is included in one paper to illustrate the many unsolved and practical problems associated with deep tabular excavations."

Jan 1, 2015

By Rene Cane, V. I. Lakshmanan, John Starkey, Richard May

"The Agrium Kapuskasing Phosphate Operation mines and processes up to 6,000 t/d of phosphate ore. Run-of-mine crushing to minus 6 inches is done in a toothed roll-crusher, while grinding is done in a SAG/ball mill circuit with no coarse recycle classification of the SAG mill discharge. The primary grinding mill is an 18 ft. diameter x 9 ft. EGL, 1500 HP variable speed SAG mill and the secondary mill is a 13 ft. diameter x 21 ft. long, 2000 HP fixed speed, ball mill. When hard ore was treated, the SAG mill restricted the tonnage that could be ground. When soft ore was treated, the ball mill and spiral classifier overloaded and restricted throughput.Recommendations from a plant benchmark and an ore hardness testing program, on how to better utilize installed energy in the Agrium SAG mill when treating soft ore, and how to obtain best results when treating hard ore, were checked in a pilot plant investigation in the 3 ft. diameter Starkey-PRO Pilot SAG Mill. Correlation between the ore hardness testing and the results from the 3’ Pilot SAG mill was very good. In addition, the work indicated the results that could be expected for the different ore types when using either smaller SAG discharge grates and/or a vibrating screen with 10 mesh square opening cloth.INTRODUCTIONAgrium Kapuskasing Phosphate Operation consists of a 6800 t/d open pit mine and a concentrator, near the Town of Kapuskasing in Northern Ontario. The two major ore types are sandy ore and cemented ore. Sandy ore is fine, soft and easy to grind in the SAG mill while cemented ore is harder, more blocky and difficult to grind in the SAG mill. The ratio of sandy to cemented ore in the deposit is thought to be in the order of 80:20 but can range as high as 5050, so it was important for the grinding circuit to have the ability to treat sandy ore alone."

Jan 1, 2002

By G. S. Barry

INVESTIGATIONS to date have shown that, should there be the need or the appropriate economic stimulus, Canada&apos;s mineral resources are sufficiently extensive to allow considerable expansion of its non-fuel mineral industry, during the remaining part of this century and possibly beyond (1, 2). The availability of sufficient capital will be one of the critical factors which will determine whether this potential will be fulfilled. The following analysis centers on the capital requirements of the Canadian non-fuel mineral industry under one set of basic assumptions of capacity growth, cost of new and replacement capacity, rates of depletion and depreciation of mines and plant, and the cost of exploration and infrastructure. Mindful of the fact that exploration and development will not thrive in Canada unless a very positive approach is taken, the writers make no apologies for being "optimistic" about long-term production prospects. Furthermore, in the event that world demand does escalate as anticipated and the forecast realistically attainable levels of Canadian production are not reached, then Canada will not have reaped the full range of economic benefits available, and opportunities will have been lost. Projections for Canadian production between 1976 and 2000 are essentially based on the forecast published in the 1974 paper, "Towards a Mineral Policy for Canada - Opportunities for Choice (3), with some updating on the basis of recent developments.

Jan 1, 1977

By F. Liu, S. Rezaei, M. Muinonen, M. Barati, V. L. Lakshmanan, S. Marcuson

Canadian nickel-copper ore deposits have been a major source of nickel, copper, cobalt and precious metals for more than 100 years. The two main minerals of interest, pentlandite (Pn, (Ni,Fe)9S8) and chalcopyrite (Cp, CuFeS2), are usually accompanied by large quantities of pyrrhotite (Po, Fe1-xS). Until the 1950s, Po containing small amounts of nickel was routinely smelted as part of the valuable Ni concentrate. The rapid growth in Ni demand following the Second World War created impetus to treat the Po separately. This action would liberate a valuable smelting capacity for higher value Pn, allow for recovery of Ni locked in Po, convert the Fe to iron oxide or metallic iron pellets, and recover S as sulphuric acid or elemental sulphur. The roasting process also has the potential to produce energy due to the highly exothermic oxidation of Po. The Ni industry would then have a “waste-free” process. Both Inco (now Vale) and Falconbridge (now Glencore) developed processes and built large industrial plants for this purpose that operated with some success. But technical issues and tenuous economics were continual challenges. By the early 1980s these industrial operations were closed. Sophisticated froth flotation methods of rejecting Po were developed, and Po containing up to 1% Ni became a waste material reporting to the tailings stream. As part of a major study on possible processing methods of Po for both value recovery and waste remediation, this paper presents a historical perspective on Canadian Po tailings with regards to their generation, inventory, value, and attempts to process them.

Jan 1, 2017

By M. F. Ameur, M. Habak, H. Aouici, M. Kenane

Present study interest by aluminium alloy (Al 7175-T5173) drilled without cooling fluid. The influence of the machining parameters (spindle speed and feed rate) on the holes quality was analyzed. Drilling tools are made of carbide (WC); high speed steel (HSS) and TiN coated carbide (WC-Ti).The Experiment design was reinforced by the application of statistical analysis of variance (ANOVA).The results show that the thrust force is influenced principally by the spindle speed and feed rate. Though, both feed rate and tool materials have statistical significance on the surface roughness. In addition, the objective of correlations between spindle speed and feed rate with the evolution of the machining parameters was established. These correlations were obtained by quadratic regression using the response surface methodology. Finally, useful to select optimum values of drilling parameters, that would minimize thrust force, torque, cutting temperature and surface roughness.

Jan 1, 2015

By G. O. Prickett, P. Somasundaran

An application of the statistical and computer techniques in basic mineral processing research is illustrated by means of a case history involving the study of starch adsorption on calcite. Multi-factorial experimental designs and computer techniques were used for determining the effect of different system variables, such as solution pH, sodium oleate concentration and starch concentration, and to obtain a mathematical model of the response. Response maps enabled the investigators to see the effects clearly and to predict the results of changes in factor levels within the design region. Use of time-shared computers and plotters made data processing and analysis efficient and relatively inexpensive.

Jan 1, 1973

By Michel Jébrak, Claude Bellehumeur

Abstract - Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont­ Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not defined by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis . The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

By L. Drisdelle, S. Gendron

"Survival in today&apos;s business climate requires participation of all employees in a Total Quality Management Program encompassing everything - ""safety, quality of products, quality ofet1ch and every job done, and of course production "". We all know what needs to be accomplished, but struggle with how to do it, especially in an industry which has not always experienced management/union cooperation, and mistrust is still present.This paper describes a process to improve team work and employee involvement in Inco&apos;s nickel carbonyl refinery at Copper Cliff The process involves facilitatorship training for all employees, and a system for reinforcing and accomplishing the required behavioural change. The system is described in detail and a number of examples are presented. At the refinery, the staff is starting to understand as Max DePree recently wrote ""Without Quality Behaviour, you cannot have Quality Product"". IntroductionThe Copper Cliff Nickel Refinery (CCNR) is Inco&apos;s largest and most modern nickel refinery, which celebrated its twentieth year of successful operation in April 1993.The heart of the refinery is the Inco pressure carbonyl (IPq plant which produces high purity nickel pellets and specialty powders by refining an approximate 80% nickel granule feed. The carbonyl plant is a modem chemical plant with very special and demanding requirements for safety and environmental protection due to the toxic nature of the refining gas.Since 1987, there has been an emphasis at CCNR on a comprehensive Total Quality Improvement (TQI) Program which was designed based on recognizing customers&apos; needs for improved systems for quality management. This program is customer oriented and comprises such elements as team organizational concepts, customer audits, process assessment and internal quality auditing.A detailed review of progress was made in early 1991 and it became apparent that the ""ownership"" of the TQI program was not broad based. In fact, the program was very much a staff driven effort and fell far short of total employee involvement and relentless continuous improvement that are now considered essential to remain competitive and stay in business.Inco staff has now come to regard that early phase of our TQI program as ""the technical aspects of total quality improvement"".The safety experience was also puzzling. Even though the safety statistics were good with an average lost time frequency of 1.6 for the last five years, the perfonnance improvement had plateaued and remained pretty much the same. Clearly a new approach was required if significant progress and continuous improvement was to be made."

Jan 1, 1994

By T. Crivits

"Freeze lining technologies are used industrially to protect the integrity of furnace walls in pyrometallurgical reactors. This is achieved by solidifying a protective layer of slag on the inner furnace wall. In the current study, laboratory experiments have been undertaken to produce freeze linings in ‘Cu2232 O’-‘FeO’-MgO-SiO slags under controlled conditions using an air-cooled probe technique. Whilst most thermal models of freeze linings have assumed the freeze lining-bath interface to be at the liquidus temperature of the bulk bath and to be planar in geometry, the current research has demonstrated that this is not the case. Experiments undertaken using this high-temperature slag system have shown the interface at steady state conditions to be at subliquidus temperatures. The solid phases present at the interface do not include the primary phase and the interface is non-planar. The study indicates the need for improved understanding of the fundamentals of freeze lining formation, and of the influence of system properties and process parameters"

Jan 1, 2015