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By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By H. M. Lima, L. A. Gomiero, C. A. de Morais

ABSTRACT The Caetité-Brazil uranium facility produces approximately 400 tonnes U3O8 per year from an ore averaging 0.29% U3O8. The process steps are ore crushing, heap leaching with sulphuric acid, uranium separation and purification by solvent extraction (SX) with a tertiary amine, followed by stripping with a sodium chloride solution, precipitation as ammonium diuranate (ADU), and product drying. A change in the milling process is being evaluated to increase production and uranium recovery. Heap leaching will be replaced by conventional agitated tank leaching of the –590 µm ground ore slurry in a sulphuric acid medium. Replacement of the stripping reagent is also being considered.

Jan 1, 2012

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By M. R. Hegge

The Jabiluka One and Two uranium deposits occur in Lower Proterozoic metasediments of the Cahill Formation, which is part of the Pine Creek Geosyncline in the East Alligator River area, Nothern Territory. The Jabiluka One deposit coincides with a "window" through unconformably overlying Middle Proterozoic sandstone of the Kombolgie Formation; Jabiluka Two is completely covered by that sandstone. The observed part of the Cahill Formation exhibits four horizons which are favourable hosts for uranium mineralization. These have been folded into an east-southeast-striking, gently plunging, open asymmetric syncline-anticline structure. The host rocks are mainly chlorite and/or graphite schists and their brecciated equivalents which have undergone initial regional prograde metamorphism to the amphibolite facies, then retrograde metamorphism to the greenschist facies. Mineralization consists of pitchblende, mainly filling open spaces and to a lesser extent in disseminated form. Chlorite, pyrite and quartz are commonly associated with the uranium mineralization. A portion of the Jabiluka Two deposit contains economic concentrations of gold. Structural preparation with low-pressure conditions at these sites appears to be the most significant ore control. Genetic hypotheses favour initial deposition in Lower Proterozoic sediments, followed by remobilization during later orogenic events. The deposits bear a marked similarity to some pitchblende deposits in central Canada.

Jan 1, 1977

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By P. R. Brito-Parada, A. Norori-McCormac

Positron emission particle tracking (PEPT) has become an important tool for flotation research, as it is able to resolve directly the behaviour of particles in laboratory scale flotation vessels. The first applications of PEPT to flotation showed only the motion of an individual particle in the pulp and the froth, but nonetheless allowed interpretations of behaviour not previously possible. Since then, PEPT measurement and data analysis techniques have improved significantly and now ensure a high level of confidence in the particle behaviour obtained. In particular, statistical analysis of long-duration experiments allows time-averaged data to be collated, ensuring spatial accuracy and allowing rigorous comparison of different conditions. It will be shown that these PEPT techniques can be used to compare directly the effect of operating conditions and particle properties in a laboratory flotation system. Particle tracks will be illustrated, as well as analyses of particle speeds, average flow streamlines and occupancy that show marked differences in behaviour near the interface and impeller.

Jan 1, 2015

By W. E. Bawden

Situation: Creighton mine, situated about twelve miles west of Sudbury, Ont., on the Algoma Eastern railway, is owned and operated by the International Nickel Company, incorporated in the United States under the laws of New Jersey. The ore is smelted at Copper Cliff, near Sudbury, and the matte is refined at Port Colborne, Ont., on lake Erie. Geology: The ore occurs in what is known locally as 'the basin' near Sudbury (Figure 1) the central part of which is composed of the Animikie series of sediments, consisting of sandstones, slates, tuffs and conglomerates. The basin is about 16 miles wide and 36 miles long. The Animikie sediments are surrounded by a sill of norite - a gabbro rock in which the pyroxenes are orthorombic. On the outer contact of this norite the sulphide deposits occur and the Creighton deposit, similar to others, lies on the southern edge of this basin. There are two orebodies at the Creighton, the upper one called the footwall orebôdy, and the lower one the hanging-wall orebody. The hanging-wall of both of these bodies is norite, and the footwall of the upper one is granite. The two are separated by an intrusion of greenstone which forms the footwall of the lower body. The ? maximum length of the deposit is 1000 feet and the maximum width is approximately 300 feet. It narrows at the ends and is somewhat lenticular in shape. The dip is about 45 o to the west, and the strike is north and south. The orè is a mixture of three minerals - pyrrhotite, chalcopyrite and pentlandite. The pentlandite, which is distinguished by its cleavage from the other two, is apparent to the naked eye only in the lower orebody and is more finely disseminated in the upper one. The lower body contains a little higher percentage of nickel.

Jan 1, 1925

By L. P. Srivastava

Rock bolts have been used since long to enhance the shear strength response of jointed rocks in civil and mining engineering structures. However, the assessment of strength response of a rock mass reinforced with rock bolts remains an unresolved problem till date. In the present article, an attempt has been made to study, through physical model tests, the shear strength enhancement of a blocky mass due to provision of passive rock bolts. Direct shear tests were conducted on large specimens of size 750 mm x 750 mm x 900 mm of rock mass under a normal stress varying from 0 to 2.0 MPa. Concrete was used as a model material to simulate intact rock and, elemental blocks of size 150 mm x 150 mm x 150 mm were used to form the mass specimens. Steel bolts of 6 mm diameter with 2 mm thick grout were used to reinforce the mass. Three different configurations of bolts were adopted. Observations were made on shear stress, horizontal shear displacement, and dilation during the tests. Effect of normal stress and reinforcement on peak shear stress and shear stiffness was studied. It is observed that the rock bolts enhance the shear strength of the mass by preventing sliding along the shearing plane, and by inducing additional normal stress due to tension mobilized in the bolts. The rock mass, therefore, becomes stronger due to the high degree of interlocking produced by the bolts. Shear strength of the mass increases with increasing numbers of bolts. In the case of reinforced mass, the enhancement in shear strength due to provision of bolts decreases with an increase in normal stress. The provision of bolts improves the cohesion of joints substantially. The effect on friction angle is low. The shear strength enhancement depends on the area of the bolts, spacing of the joints, spacing between the bolts and the cohesion of the intact material. A correlation has been established using which the enhancement in shear strength due to the provision of bolts can be assessed.

Jan 1, 2015

By Fatemeh Saeidi, Luis Marcelo Tavares, Malcolm Powell, Mohsen Yahyaei

"Understanding a single breakage mechanism is fundamental to the development of breakage testing techniques appropriate for mechanistic modelling of any breakage equipment. In the light of this insight, it is also possible to compare any two breakage events in a mechanistic manner. This paper presents a new method to compare breakage mechanisms of two-point impact with compression, different in their applied strain rates. This approach regards a single breakage event as a process affected by three sub-processes; first fracture, capture and spatial distribution of fragments. Spatial distribution is influenced by the kinetic energy of fragments and their brittleness. Using this methodology allows us to examine how each sub-process is influenced by applied strain rate and its impacts on progeny size distribution. For this purpose, two rock types of widely different strength, magnetite and silicate, were tested at various energy levels using the impact and compression mechanisms. To isolate the effect of spatial distribution of fragments, particles were forced to remain in the breakage zone. In this condition, similar progenies were generated from compression and impact mechanisms at similar energy levels. However, allowing natural distribution of fragments, coarser progeny was produced from compression of silicate. Additionally, using this approach provides a physical meaning and explanation for rock strength parameters such as A×b in the t10-Ecs relationship. INTRODUCTIONComminution models are rapidly progressing toward a destination that enables us to explain the complete physics of a breakage process as well as the properties of the ores. Eventually, they will be able to take into consideration the micro-events that take place during the comminution process (Bourgeois and Banini, 2002). Thus, considerable efforts have been made in the last few years in the area of ore breakage characterisation to comprehend and unlock a single breakage process that has been treated as a black box event in the majority of conventional methods. In this paper, an attempt is made to explain the effect of applied strain rate on the breakage properties of rock by using the knowledge that has been gained by understanding a breakage event. This is particularly important due to its application for various comminution devices that operate within a relatively broad range of speed."

Jan 1, 2016

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011

Most of automotive magnesium applications are presently produced by high-pressure die casting processes, For further expansion of the alloy usage in automobiles, novel-manufacturing processes needs to be developed, In this study, squeeze casting of AM50 alloy was carried out using a hydraulic press with an applied pressure of 70 MPa, Tensile properties and fracture behavior of the squeeze-cast AM50 were characterized in comparison with the die cast counterpart, The squeeze-cast AM50 alloy exhibits virtually no porosity in the microstructure evaluated by optical microscopy, The results of tensile testing indicate that the improved tensile properties for the squeeze-cast samples over the conventional high-pressure die-cast parts, The analysis of tensile behavior shows that the strain-hardening rate during the plastic deformation of the squeeze-cast specimens is constantly higher than that of the die-cast specimens. The SEM fractography evidently reveals the ductile fracture features of the squeeze-cast alloy AM50.

Jan 1, 2005

By S. Parkash, A. J. Szladow

Vigorous agitation of suspensions of coking coals in water (or light mineral oils) will often result in catast rophic loss of caking properties. It is shown that this deterioration is not a consequence of oxidation of the coals (by dissolved oxygen), but that it can be qualitatively connected with internal "solid-state" reactions which appear to derive their activation energies from cavitation of the liquid.

Jan 1, 1971

By F. C. Grensing, W. R. Crib

Copper-15 Nickel-8 Tin alloy is a relatively modern material, having been discovered in the 1970’s. It has complexities with casting, hot working and interdependent solid state phase transformations. A key to the high reliability manufacture of wrought rods, bars, plates and tube is the casting technology, which limits segregation, promotes microstructural uniformity and enables hot working. The EquaCast® continuous casting process has enabled the production of a broadening variety of wrought forms with typical yield strengths ranging from 100 to 180 ksi (690 to 1241 MPa) depending on size, shape and temper. This paper reviews the characteristics of wrought Copper-15 Nickel-8 Tin products which have registration in AMS specifications (4596 and 4597) and MMPDS-04 (CN-1) for use in aircraft. The design limits, microstructures, fracture characteristics and tribological behavior will be examined. This alloy system is emerging as a material of choice for aircraft bearings, corrosion resistant oil and gas exploration components, machinery and demanding off-road equipment applications. ToughMet® 3 is an alternative or upgrade to conventional moderate and high strength aluminum bronze bearing alloys.

Jan 1, 2010

By C. Fortin

ABSTRACT The subject of gold flotation has been reviewed extensively. Most of these reviews focus on the theories of gold flotation and the physical and chemical effects that may impact the efficacy of the gold flotation process. The current status of gold flotation chemistry as it is being applied in industry has not been widely addressed. This paper reviews current gold flotation practice and research advancements and discusses how these applications tie in with the current understanding of gold flotation chemistry. Survey results from worldwide gold flotation operations are analyzed. Potential future areas of gold flotation research are highlighted.

Jan 1, 2013

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By H. Dean

"Mine hoisting machinery, of which wire rope is an essential part, is developing, in Canada as well as in other parts of the North American continent, into highly sophisticated equipment. Heavier payloads are now required to be raised from steadily increasing depths at higher rates of speed and production. These hoisting conditions have, of necessity, brought about a major change in the production of steel roping wires and the wire ropes manufactured from them.Operators and designers of hoisting equipment are requesting a very much more efficient ratio of strength to weight in hoisting ropes, so that heavier loads may be raised from greater depths by ropes which will provide a predeterminable life span on which the operator may depend.The cost of wire rope to the operator is very low indeed, usually less than $0.01 per ton of payload, but the cost of unexpected shutdown periods, due to rope maintenance or change, can be extremely high -particularly in operations where a continuously high rate of production is an absolute necessity. Mine hoist ropes with a higher strength to weight ratio are now being made and used in some areas of Canadian mining, and a general understanding of the performance we may expect from them is required."

Jan 1, 1968

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By Mike Johnson, Greg Andrews, Niels Verbaan, David Dreisinger

"The Search Minerals Foxtrot project in Labrador represents a significant Canadian resource of rare earth elements rich in the sought after heavy rare earth elements (19.8% HREE/TREE). A preliminary economic assessment of the project indicated that the project is technically feasible and economically attractive. A variety of metallurgical test programs have been undertaken which have led to significant streamlining and simplification of the process flowsheet. The improved flowsheet should allow Search to reach production earlier and will use conventional processing equipment. The results of these test programs are presented and discussed in this paper INTRODUCTIONSearch Minerals Inc. (Search) is exploring and developing a number of deposits for rare earth element (REE) recovery in Labrador, Canada. The Port Hope Simpson District is in the southeast of Labrador and is highly prospective for heavy and light rare earth elements. The Foxtrot deposit sits within the Port Hope Simpson REE District (Figure 1), which is 70 km long by up to 10 km wide. The infrastructure available at Foxtrot is excellent; a deep-water port, air strip, and road and power infrastructure are pre-existing at St. Lewis. The three communities of Port Hope Simpson, St. Lewis and Mary’s Harbour are in close proximity to the site."

Jan 1, 2016