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By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By J. Yue

The particle breakage kinetics, product size and size distribution, as well as grinding limit for quartz suspensions in a horizontal stirred mill are investigated. Results of grinding studies on quartz suspensions in a horizontal stirred mill confirm "first-order" particle breakage rates. A comparison of equation fits reveal that the product size distribution from stirred mill is best represented by the Rosin-Rammler equation when compared to the Gaudin-Shuhmann equation, but results fit poorly as particle size below five microns. A method of determining breakage rates versus particle size is demonstrated which shows that the 10% top size fraction is most appropriate for the determination of specific breakage rates. The method is used to demonstrate the relationship between particle breakage rate and particle size. As the feed particle size becomes smaller, the size reduction ratio decreases and approaches a grinding limit which depends on the effective stresses created in the mill.

May 1, 2004

In this paper we present the results of preliminary investigations into the applicability of new laboratory scale tests for the prediction of operating gap and specific throughput in high pressure grinding rolls (HPGR). The work is a part of the CAMIRO HPGR research program being conducted at the University of British Columbia, which aims to develop a suite of small-scale tests and procedures for the selection and sizing of HPGRs. A focus of the presented study is to test sample types in terms of their terra-mechanics based characteristics and relate them to specific throughput and gap results from pilot HPGR testing on the same samples.

Jan 1, 2012

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By C. Fortin

The subject of gold flotation has been reviewed extensively in a number of publications. The focus in most of these reviews has been on the theories of gold flotation as well as the physical and chemical effects that may impact the efficacy of the gold flotation process. It is evident that the current status of gold flotation chemistry as it is being applied in industry has not been addressed widely. It is the intent of this paper to review current gold flotation practice and how these applications tie in with the current understanding of the chemistry of gold flotation.

Jan 1, 2011

By Dean Millar

Clean, green, cheap compressed air can be produced efficiently and renewably by modernization of a 19th century technology ?The hydraulic air compressor has no moving parts ?After commissioning, the Ragged Chutes HAC operated for 70 years, only being stopped twice for repairs to the intake heads ?Operates using hydropower from Montreal river ?Produced air for ~29 silver mines in Cobalt, 20 km distant

May 1, 2013

By G. R. Webber

CHEMICAL AN AL YSIS by x-ray emission spectrometry has become increasingly important during the past few years. The method is analogous to optical spectrography ?with x-rays being used instead of light and should not be confused with methods of x-ray diffraction used? for identification of minerals and chemical compounds. X-ray emission spectrometry has many advantages for both qualitative and quantitative analysis. Its optimum concentration range is higher than that of the optical spectrograph, and the group of elements which can be detected is not identical to that which can be detected by the optical spectrograph. Elements which can be detected by the x-ray spectrometer are those elements from magnesium (atomic number 12) to uranium (atomic number 92) in the periodic table. The lightest elements in this range have low sensitivities and more specialized equipment is necessary for their detection than for the heavier elements. A large number of applications of x-ray analysis have been directed toward the analysis of ores, metallurgical products, and related materials (see References at end of paper). A more complete bibliography is presented in the Norelco Reporter, Vol. 3, 1956, pp. 37-39. The periodicals Analytical Chemistry and Applied Spectroscopy are a good source of current articles and references.

Jan 1, 1957

By Ian R. Morrison

"Abstract - The Izok Zn-Cu-Pb-Ag volcanogenic massive sulfide deposit is located 265 km south of Kugluktuk (Coppermine), Nunavut Territory, Canada, in the west-central Slave structural province. The Izok deposit is owned 100% by Inmet Mining Corporation and represents one of the largest undeveloped zinc-copper resources in North America. The Izok deposit is hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks of late Archean age. The hanging-wall stratigraphy includes additional felsic volcaniclastic rocks, andesitic and basaltic flows, thin sulfide-rich iron formations, and turbiditic sedimentary rocks. The felsic volcanic rocks are intruded by intermediate dikes and sills, followed by gabbroic dikes and sills. Both intrusive suites are interpreted to be volcanic feeders to the overlying flows. All lithologies are subsequently cut by younger, irregular, granitic pegmatite and diabase dikes. The volcanic and sedimentary rocks are regionally metamorphosed to pyroxene hornfels grade. The massive sulfides occur within a large (kilometer-scale) Na-depleted sericitic alteration zone. The immediate footwall and hanging-wall rocks to the deposit are characterized by zones of muscovite- biotite-sillimanite, lesser chlorite-biotite-cordierite, and locally intense silicification and sodium metasomatism. All lithologies have been affected by younger Ca-metasomatism. As currently defined, the Izok deposit comprises a cluster of five complexly zoned composite lenses: the Northwest, North, Central West, Central East, and Inukshuk lenses. The first four lenses are amenable to open-pit mining, whereas the Inukshuk lens will require underground development. The total indicated mineral resource presently stands at 16.5 million tonnes with a grade of 2.2% Cu, 11.4% Zn, 1.1% Pb, and 60 g/t Ag. Inmet Mining Corporation is presently reviewing the economic feasibility of developing the property."

Jan 1, 2004

By Free. Michael L.

Crushing ore prior to heap leaching enhances mineral liberation and creates fine particles that may require agglomeration to avoid permeability problems during leaching. Conventional modeling is relatively successful in describing general fluid flow and extraction in heaps. However, most models do not adequately account for the effects of mineral liberation and exposure or the effects of agglomeration, curing, and loading on heap leach performance. This paper will discuss methods to account for mineral liberation and exposure as a function of comminution. It will also discuss methods for incorporating liberation, exposure, and mineral locking as well as curing and fluid flow in heap leach modeling. It will also provide information regarding agglomeration and the effect of loading in heap leach modeling.

Jan 1, 2014

By G. E. Norman, J. F. Jackson, A. L. Mckague

"The treatment of nickel-copper concentrate in the new smelter at Falconbridge Nickel Mines Limited, Falconbridge, Ontario, is described. The concentrate in a slurry form is partially roasted in a fluid-bed roaster and the calcine is smelted in an electric furnace. The roaster gases are treated in an acid plant. IntroductionSmelting began at Falconbridge in 1930 with the first blast furnace treating high-grade ore containing 2-3% nickel. In 1933, the Falconbridge concentrator was built and started producing a bulk sulphide concentrate containing 4% nickel. A sinter plant was built to agglomerate and partially roast this concentrate. The sinter was smelted in blast furnaces along with high. grade magnetic ore. Matte from the furnaces was treated in Pierce-Smith converters to produce shipping matte which was refined at the company's plant in Norway."

Jan 1, 1980

By H. Assadi, S. Reutzel, D. M. Herlach

Intermetallics exhibit unique solidification behaviour due to their chemical longrange order. This includes, for instance, generally slow solidification kinetics, and in some cases, an anomalous partitioning behaviour. In the present work the electromagnetic levitation technique - complemented by theoretical modelling - is used to explore various aspects of this behaviour, as observed in solidification of B2 phase in undercooled melts of the Ni-Al system. Moreover, a phase-field model is developed and used to illustrate the effect of chemical order on the solidification kinetics of a B2 phase in a model system. The phase-field model provides an additional basis for the simulation of solidification microstructures in intermetallic forming systems. Both experimental studies and theoretical work signify the role of chemical order in solidification of intermetallics.

Jan 1, 2006

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

By P. P. Rosario

A research project was conducted at the University of British Columbia (UBC) resulting in the development and evaluation of a novel comminution circuit incorporating autogenous grinding and parallel trains of cone crushers and high-pressure grinding rolls (HPGR). A primary driver for the circuit was to treat ore from deposits with clay and variable hardness. This paper summarizes the unique pilot-plant test program that was developed as a basis for experimental simulation and lists the main findings of the research, including the circuit?s potential operational cost savings compared to a conventional SAG circuit.

Jan 1, 2012

By Y. Chengxian

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967

By D. S. Salonine

Aluminum alloys are widely used in modern industry. Tubes and hollow shapes give great opportunities for structural purposes as well as fluid transport due to their stiffness and lightness, Extrusions on a mandrel or through a bridge die, that requires splitting of the billet with re-welding, produce hollow shapes with varied contours, fins and multiple cavities. Moving and stationary mandrels, mandrel lubrication, tooling for ribbed-tube heat exchangers, and for drilling pipes are considered. Bridge dies can be classified by the bridge position relative to the die face, by mandrel support structure, and by assembly type, The main parameters influencing the quality of the die-welded seams are considered, The difficulties of extruding various alloys through bridge dies are discussed in terms of metallurgical factors, Some approaches to the calculation of the stresses in a bridge are presented.

Jan 1, 2005

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By Smortchevskyk N. J.

THIS paper describes the electrical features of the locomotive now (August, 1962) under construction for Craigmont Mines. Intended for non-specialists, it avoids details of design and calculations interesting to electricians only. The paper is divided into three sections. The first deals very briefly with the mine layout and with operating conditions -existing and expected. Reference is made to economic considerations leading to the selection of the type and size of locomotive, as well as to traction diagrams and the calculations. This material is not included in the paper because of its length and because it does not represent anything new. The second section deals with engineering and economic considerations and shows, in some detail, why the A.C. system was chosen. The third section describes the basic components of the locomotive, including the voltage regulator, the rectifiers, the control arrangement and the filter, and deals with considerations affecting the selection of their rating and design. A concluding sub-section describes, very briefly, the track and trolley details and the power distribution switchgear.

Jan 1, 1963

By Derek Perkins

"Brenda Mines Ltd. operates an open pit copper and molybdenum mine located in south central British Columbia. The main economic mineralization is chalcopyrite and molybdenite. Pyrite, galena and sphalerite are also present in varying quantities. The mineralization is present in small veins and fractures in a porphyritic quartz diorite host rock.The mill processes approximately 30,000 tonnes of ore daily. The ore is crushed in three stages and then ground in conventional rod mill - ball mill circuits with cyclone classification. The cyclone overflow is fed to the bulk flotation circuit as a pulp with a density of 50% solids. The particle size distribution is approximately 35% plus 65 mesh. Bulk rougher and cleaning flotation produce a concentrate grading approximately 20% copper and 4% molybdenum. This concentrate is fed to the separation circuit, where the copper is depressed with sodium hydrosulphide and the molybdenum is floated. These products are further ground and then upgraded by column flotation. The molybdenum concentrate is pumped to the leach plant to reduce concentration of lead and copper. It is then washed, filtered, dried and packed for shipment to Europe. The copper concentrate is filtered, dried and subsequently shipped to Japan.Prior to November 1977, the mill flotation control was carried out by the assay laboratory using a Philips PW 1540 sequential x-ray spectrograph. The assay set consisted of twelve samples, analysed on a two hourly basis for copper, molybdenum, lead, iron and silica.In order to provide elemental composition information on a much shorter sampling interval and to produce speedier control analysis for automating process control, an Applied Research Laboratories PCXQ on stream analyser was purchased. The installation of this analyser, reduced the turnaround time of the control analyses from (2) hours to (20) minutes. At Brenda, the following assays are used in the mill control strategies."

Jan 1, 1989