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By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By P. B. Queneau, Peter V. Avotins, Lauch F. Farris

"The Lang Bay germanium property is a carbonaceous sandstone deposit outcropping near the Pacific coast, 100 km north of Vancouver. The germanium-bearing seams are up to 5 m thick. Where one such seam outcrops, it averages 50 to 60 g Ge/tonne. Drill core analyses have shown considerably greater concentrations of germanium at depth. Additional drilling to establish continuity and grade of the germanium-b earing strata is scheduled for 1986. The germanium occurs in association with lignite, which makes up 1 to 2% of the seam. American Cyanamid Company engineers have developed a proprietary flotation reagent effective for concentrating the germanium rich vitrain portion of the Lang Bay lignite. Ongoing laboratory studies are developing procedures for further upgrading and refining of this germanium. This paper outlines progress made by Fargo Oil Corporation on Lang Bay geology, reserve estimation, mine planning, ore dressing, refining, and economic evaluation.IntroductionIn 1871, Mendeleyev specula ted on the properties of a ""missing"" element between silico n and tin on the periodic table. The discovery of germanium fifteen years later proved the Mendeleyev predictions to be remarkably accurate. Almo half a century later, the pioneering work of McCutcheon of Eagle-Picher led to production of germanium dioxide from Oklahoma zinc smelting residues. Demand for the element surged due to development of the Ge02 diode rectifier during World War II, followed by development of the transistor in 1947. The chief commercial sources for germanium during the following two decades were the Cu-Zn mines in the Congo and the Zn-Cu-Pb mines of Tsumeb in Southwest Africa. The germanium was chemically combined in complex Cu-Fe sulphides (germanite and renierite), from which the element was recovered either by leaching the selectively roasted sulphide, or by direct fuming of GeS(I). Although these deposits have reportedly been depleted (2), new deposits of renierite have been discovered in Zaire. Alternative sources of germanium are therefore being sought worldwide for use in infrared optics, semiconductors, fibre optics, and catalysts. One such source is germanium-rich coal (2)."

Jan 1, 1986

In-Country Business Development Agenda ?Siting/Permitting/Operational Planning ?Securing, maintaining, enhancing social license to operate ?Biodiversity conservation and ecosystem services ?IFC Performance Standards ?Environmental, Social, Risk Governance (ESG) ?Climate change plan

Aug 1, 2013

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

"Shales play a major role in the stability of slopes, both natural and engineered. This paper attempts to provide a review of the state-of-the-art in shale slope stability. The complexities of shale terminology and classification are first reviewed followed by a brief discussion of the important physical and mechanical properties of relevance to shale slope stability. The varied mechanisms of shale slope stability are outlined and their importance highlighted by reference to international shale slope failures. Stability analysis and modelling of anisotropic rock slope masses are briefly discussed and the potential role of brittle rock fracture and damage highlighted. A short review of shale slopes in open pits is presented.INTRODUCTIONShales have been stated to form approximately 58% of sedimentary rock so it is not surprising that they are frequently encountered in both natural and engineered slopes. They represent challenging environments for slope stability due to the wide variation in their engineering properties, their changing behaviour with time due to geomorphic processes and the variation in the failure mechanisms as a function of both stratigraphy and tectonics. An extensive body of literature exists on the terminology and classification relevant to shales; it is not possible in the scope and length of the current paper to review these works in detail and the reader is referred to Farrokhrouz and Asef (2013), Bell (2000) and Goodman (1993) for detailed discussions. It is arguably the case that no universally accepted classification of shales exists today and depending on the field of application the terminology varies widely. Shales in slope stability, for the purpose of this keynote paper, are taken to include material varying in properties from weak rocks to soils and therein lies one of the most challenging aspects in shale slope characterisation for engineering purposes. They have been classified as “rock-like” or “soil-like’, (Underwood 1967) or compacted and cemented, Table 1, Yagiz (2001). Classifications have considered numerous factors including composition, cementation and a wide range of engineering properties.The propensity of shales to degrade with time due to geomorphic processes has resulted in an important aspect in their classification, that is, the attempts to incorporate slaking, durability and swelling and softening behavior through purpose developed testing methods (Gamble 1971, Morgenstern and Eigenbrod, 1974). Figures 1 and 2 show examples of terminology used to describe argillaceous materials and some proposed engineering classification schemes (Grainger 1984 and Bott 1986). Corominas (2014) provides a recent classification of argillaceous rocks and their durability relating five stages of slope deterioration to the texture of the rock on Ternary diagrams. No attempt will be made here to discuss the merits of the proposed terminology and classifications, suffice it to say, that the controversy and flux surrounding these issues is a strong indicator of the complexities in the behavior of these materials. In this paper the author will consider slope stability in the materials indicated in Table 1, Figures 1 and 2 without undue focus on terminology. At the lower strength limit of shales the engineer must design slopes using the principles of soil mechanics which may vary from the simple Mohr Coulomb plasticity constitutive criterion to modified critical state models, some even attempting to incorporate softening behaviour in the weaker clay shale materials. Given the transitional nature of shale materials several workers have treated overconsolidated clays and clay shales using concepts such as peak and residual shear strength, brittleness index and softening. Martin and Stacey (2013) provide a useful review of the importance of weak rocks in open pit mining, with mudrocks as a specific member, and note the importance of delayed failure, progressive failure and loosening in the stability of"

Jan 1, 2015

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By M. Palfreyman

"Most of the minerals employed in Canadian refractory production are imported; in fact, most of the refractories consumed in Canada are imported. Whereas this situation is partly due to a definite shortage of suitable raw materials, e.g., fire clays, it is possible that the potential of certain mineral deposits which could be usefully exploited has not been recognized. There are exceptions, notably magnesite and dolomite, from which refractories are produced in Canada.In many cases, known mineral deposits are located either in inaccessible areas or in areas where transportation would be a major economic factor. This paper lists some minerals and their respective known deposits which could be employed in the production of refractories, irrespective of economics."

Jan 1, 1973

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By David McMullen

Radiation plays a critical role in the thermal behaviour of hydrometallurgical process equipment. This effect is particularly important when designing refractory lined equipment used in pressure leach/oxidation processes. In order to simplify this non-linear mode of heat transfer, the effects of radiation had previously been incorporated in an equivalent convective film coefficient in finite element methods (FEM). This prior method omits the effects of radiosity, a critical aspect of radiation heat transfer, which affects the design of refractory lining systems in autoclave vessels. Given that 60% of the heat loss in actual plant practice of an autoclave is due to radiation, reliability in the FEM is therefore impacted. This study validates the use of radiosity in FEM through thermal loading using a combination of simple geometries to be applied to complex environments such as vessel nozzle clusters. The added benefits of using a radiosity load includes an increase in confidence in thermal distribution results, greater accuracy in determining appropriate refractory lining systems, weld overlay sizing, and increased accuracy in structural analysis.

Jan 1, 2014

By F. Rivard, M. G. Drouet, W. S. Ruff, P. Carabin

"In both the hot rotary-salt-furnace (RSF) treatment of aluminum dross and the cold ball-millsieving (BMS) treatment of zinc dross, enormous amounts of energy and recoverable metal are wasted and large amounts of greenhouse gas are produced. Such wastes and the environment pollution could be avoided by using the DROSRITE PLUS™ technology. Economic and GHG production comparisons between the presently used industrial treatment processes and DROSRITE PLUS™, supported by over one hundred tests conducted in Canada, the US and Europe, are presented. The savings, with DROSRITE PLUS™, would be about $191 and $418 per MT of aluminum and zinc dross, respectively.INTRODUCTIONDross is a material, which forms on the surface of molten non-ferrous metal, such as aluminum or zinc, during melting, metal holding and handling operations when the molten metal is in contact with a reactive atmosphere. Dross normally consists of metal oxides entraining a considerable quantity of molten free (unreacted) metal, and for economic reasons it is desirable to extract the free metal before discarding the residue. In the case of aluminum dross, recovery of the metal is usually carried out by treating the dross in a furnace at a high temperature (Peterson et al., 2002). By contrast, cold zinc dross is crushed in a ball mill followed by sieving to separate the coarse metal portion from the fine oxide residue.The conventional aluminum dross treatment process, using gas or oil-heated rotary salt furnaces (RSF), is thermally inefficient and environmentally unacceptable because of the salt slag and CO2 produced from the combustion of fossil fuels. In the past several years, a number of salt-free processes have been developed and some of these have found limited commercial use (Gripenberg et al., 1994; Lavoie et al., 1990). In all these dross treatment processes, heating of the cold dross in a rotary furnace requires an external energy input that varies between 375 and 2,500 kWh per (metric) tonne of dross. Molten metal separated during processing of the heated dross is tapped, and the remaining solid residue is discharged from the furnace."

Jan 1, 2012

By Wm. T. Bray

SYNOPSIS Canadian Refractories, Limited, produce a wide range of basic refractories. The chief raw material use in their manufacture is the magnesite which is mined, and beneficiated in a heavy media separation plant, at Kilmar, Que. This paper describes the underground operation and the plant and explains how the gravity separation of light, siliceous gangue from the ore has changed the mining practice, increased the ore reserves, and improved the chemical uniformity of the crushed ore. HISTORY REFRACTORIES are essential in the production of steel and base metals and in other high-temperature processes. Basic refractories, chiefly composed of magnesia which is obtained by burning magnesite, are used to line and repair basic furnaces. When World War I cut? off the importation of Austrian magnesite, upon which North American industry had depended, domestic sources bad to be found. In Quebec, work was begun on deposits of magnesite at Kilmar, half way between Ottawa and Montreal and about ten miles north of the Ottawa river. By the end of the war substantial tonnages were being quarried and calcined, but, when Austrian magnesite again became available, the industry declined rapidly. In 1925, the National Research Council, in co-operation with the Federal Department of Mines, began an investigation of the industry's technical problems. The result of this research work, which was taken over fully by the Company in 1943 and is actively continued, is that the single product of the early 1920's has been supplemented by more than forty specialized products serving the metallurgical and chemical industries across Canada and in more than thirty other countries.

Jan 1, 1951

By A. M. Salomon de Friedberg

"With respect to impurities, HBM&S' copper smelter, located in Flin Ron, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Ron is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S' metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.IntroductionHudson Bay Mining & Smelting Co. Ltd. (HBM&s), has been operating its metallurgical complex located in Flin Flon, Manitoba, since 1930. The smelter and zinc plant were originally separate entities with respect to production. The smelting operation consisted of traditional multiple-hearth roasters, a reverberatory furnace and Peirce-Smith converters. The zinc plant also utilized multiple hearth roasters and then followed with sulphuric acid leaching, purification and electrowinning. The zinc plant also recovered cadmium from a separate purification/electrowinning circuit.The two plants operated essentially independently of each other until rising zinc levels in the copper concentrate and large stockpiles of zinc-rich leach residues prompted the construction of the fuming plant in 1949. The smelter used pulverized coal to reduce zinc oxide present in the reverb slag and then captured the resulting zinc bearing fume in the fuming plant baghouse. The fume was sent to a separate ""oxide roaster"" in the zinc plant where it was first roasted to remove halogens and then leached to recover the contained zinc. This oxide fume became a major source of feed to the zinc plant accounting for roughly one quarter of the total zinc production. Furthermore, through the smelter's treatment of sulphide leach residue, both copper and zinc recoveries were improved for the over-all complex."

Jan 1, 1993

By M. Dupuis, V. Bojarevics

It is well known that horizontal current density in the metal pad contributes greatly to the generation of MHD driven bath-metal interface wave. It is possible to compute very accurately the metal pad current density using a very detailed finite element model [1], but a MHD model must be compatible to this level of mesh refinement and to recalculate the current distribution at each time step, including the full busbar supply system. The accuracy of the instability prediction of the cell depends on the accuracy of the metal pad current density calculation. This study presents the comparison of the metal pad current density calculation of the detailed finite element model and the MHD-Valdis model for different metal pad heights and ledge thickness. It also presents the corresponding cell MHD stability predictions.

Jan 1, 2006

By Min-Sung Kang

Excavation and earthmoving equipment mostly operate in accident-prone areas. These areas normally have rollover, confinement, and fall or may be considered harmful work areas due to demolitions and sewage removals. It is inevitable that excavation and earthmoving systems should be developed to secure the safety of operators through unmanned and remote control systems. Therefore, this research proposes a system that enables excavators to be unmanned and remote controlled without any renovation, remodeling, change, or transformation by applying attachable and separable mechanism and modules. Moreover, this research proposes the sensor module to evaluate the dynamic status without processing remodeling or transformation the existing hydraulic drive excavation system by adopting the easy attachable and separable mechanism. The study verifies this proposal based on observed possibility and feasibility through the experiments.

Aug 1, 2013

By R. P. van Hille, N. Mooruth

Remediation of acid rock drainage (ARD) was performed within a linear flow channel reactor (LFCR) via a floating sulphur biofilm (FSB). A full sulphur species material balance was conducted in order to characterize the sulphide oxidation. The reactor was able to achieve an 82% and 93% conversion of sulphide with a hydraulic residence time of 2 and 5 days respectively. 92% and 55.5% of the converted sulphide reported to the biofilm as sulphur for the 2 and 5 day residence times respectively. The mass transport limitations within the biofilm were identified via a dissolved oxygen gradient profiling system.

Jan 1, 2011

By R. O. Burt

The original flowsheet of the TANCO mill consisted of a simple two-stage gravity circuit for the recovery of the tantalum concentrates. With decreasing grade and grain size of the tantalum minerals, considerable modifications to the circuit have been required. This paper discusses the various recent improvements carried out 011 all stages of the flowsheet, which have resulted in a 10% increase in recovery. Future improvements, including on stream analysis, and the possibility of tantalum flotation , are also discussed.

Jan 1, 1979

By P. Müller, W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"Abstract -The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was Iow, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization .Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This mode] does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5% of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipitation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994

By J. E. Gebhardt, D. McBride, M. Cross

Heap leach processes can encounter diverse flow conditions, such as infiltration into dry ore material, drainage, perched water tables and heterogeneous materials, leading to large variations in permeability and the creation of preferential flow pathways. Climate and meteorological conditions, such as precipitation, evaporation, and temperature, can also have a significant effect on the hydrodynamics of the heap. Nonuniform and adverse flow behavior within the heap contributes to reducing the leaching efficiency of the heap leading to lower metal recoveries. The variability of flow within the heap can result in solute transport problems, which limit the leach reaction kinetics. Therefore, understanding the flow and transport phenomena within the heap is critical in its design and optimization. A comprehensive heap leach model, developed within a computational fluid dynamics (CFD) framework, employs robust algorithms to solve diverse variably saturated flow conditions. The model allows for a wide array of complex thermo-fluid physics to be represented and captures suites of very complex reactions that are closely coupled with thermal conditions and key microbial populations. Employing a three-dimensional heterogeneous ‘test’ heap, a number of flow conditions are investigated and the sensitivity of metal recovery is discussed.

Jan 1, 2014

By M. Bozorgtabar

Metal Matrix Composites (MMC) have a ductile matrix containing ceramic particles, Due to their improved wear properties, Al?SiC composites have economical applications in many industrial uses where wear is a problem, One of the most serious difficulties in manufacturing Al-SiC composites is obtaining adequate 'wetting' of the particles by the melt. In this research work, a stir casting system was designed for the improved manufacturing Al-SiC composites, The effect of some production variables such as the addition of SiC particles to the aluminum melt on wettability, was also studied. The results showed that the manual addition of particles would not be successful in manufacturing and that a system of adding silicon carbide particles through controlled temperature, atmosphere and improved mixing was needed.

Jan 1, 2005

By H. W. Smith, C. L. Lewis

"A process control computer has been installed in the Lake Dufault concentrator to: (a) control the on-stream X-ray analyzer and convert chart readings to elemental percentages, (b) calculate the flow rates required for the most important flotation reagents, using the amount of material entering the process, the analyses and the slurry pH, and (c) set the reagent feeder to these flow rates automatically. Although this project was largely experimental, to gain knowledge and experience in flotation process control, the objectives have been met and fully automatic computer control is now the normal mode of mill operation.This paper describes project planning and defines the system with respect to both control design and functional design. System operation -as seen by the mill operator -is detailed. Implementation of the system is described and the system is discussed in terms of its success, economic justification and future plans."

Jan 1, 1969