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By M. Maldonado

This work details the application of a decentralized control strategy to a pilot flotation column working with a two-phase system (water-air). The process is represented by a multivariable system composed of three inputs and three outputs. The selected control variables are the froth depth, the air hold-up and the bias rate, whereas the corresponding manipulated variables are the set-points of the local flow controllers of tailings, air and wash water. All controlled variables are estimated using electrical conductivity based techniques. In particular, the results of a new method for estimating the bias rate, based on the measurement of the volumetric fraction of wash water under the interface, is presented. This method reduces the coupling problem associated to the bias estimation as a difference between feed and tailing water rates. Moreover, the nominal system transfer matrix can be represented by an upper triangular matrix, in such a way that the closed-loop system stability reduces to the stability of the independent control loops. The experimental results show that the closed-loop system performance, particularly that of the bias rate loop, is strongly dependent on the air flow rate, reaching in some cases the saturation point of the controller.

Jan 1, 2007

By T. L. McCall

CHANGES in mining practices have evolved so quietly and unobtrusively that perhaps we scarcely appreciate how truly startling these changes are unless we cast our minds back so as to compare the past with the present. Such retrospection is, indeed, necessary when attempting to forecast the future, for it is only by carefully reviewing the past that we can hope to obtain an indication of what the future may hold in store. In this instance, it is not necessary to delve into the very early history of . coal mining, as our purpose will be served if the last three or four decades are reviewed, a period that is still fresh within the memory of many of us. These earlier days might be termed the selective period of mining, for at that time the coal resources of the world had not been tapped to anything like the extent they are at present and this condition enabled the owners and operators to exercise selective powers and only mine such seams of coal as could be most easily reached an worked at the lowest possible cost and which, at the same time, would suit the requirements of the market. Carrying this thought of selective mining still further, the miner, who was then an artisan skilled in all the branches of his calling, was able to select or discard such parts of the seam he was working that the co al sent out of the mine was acceptable to the consumer with just the barest minimum of preparation. Compare these conditions with the? conditions prevailing today, when coal seams of medium height, good quality, and readily accessible have been largely depleted and the operator has been compelled either to carry on his operations under much greater depths of cover where the coal is more costly to win, or else to work seams of lesser height or of poorer quality.

Jan 1, 1938

By P. V. Amosov, V. A. Masloboev, D. V. Makarov, S. G. Seleznev, A. A. Baklanov

"The development of industry and intensive use of natural resources leads to a significant decrease in the share of reserves of rich ores, deposits of which have nearly all been exploited. Large amounts of displaced rock mass are accumulated, significant emissions of gas and dust from mining, dust from dumps and tailing pits, ingress of chemicals and toxic elements in surface and groundwater all can have negative effects on existing ecosystems and human health. Especially dangerous is the impact in Arctic regions with extreme climate conditions. The maintenance of overburden dumps and tailings dams requires significant capital and material costs. In this paper, some mining enterprises of the Murmansk region, in the Russian Federation, consider the environmental problems of the industry and propose some solutions.INTRODUCTIONThe safety of environment during the extraction and processing of minerals is a very acute problem throughout the whole world. The problem acquires a specific character in the Russian Federation. There, rather poor minerals, often existing in unconventional forms and including several mineral components are processed. The Russian mineral base has a specific geographical location; most of the deposits under operation are located in the Subarctic or Arctic regions, as well as in Siberia and in the Far East. Vast amounts of rock waste and tailings pose serious economic and ecological problems in mining regions. The operation of overburden heaps and tailings requires considerable capital and material costs. The dumps withdraw vast lands from potential commercial use. Large amounts of mined rock disturb the existing geological balance; emissions of gas and dust which accompany the mining operations, dusting of waste heaps and tailings, emissions of reagents and heavy metals into natural surface and ground waters all can produce negative effects on existing ecosystems and human health."

Jan 1, 2016

By G. K. Lee, E. R. Mitchell

Designers of combustion processes may select aerodynamic conditions which produce only superfine fly ash. Although it is not usually anticipated that this will create a problem, such as has been found to agglomerate in high-velocity gas streams, to plug mechanical dust separators in a short time, and to contribute to atmospheric pollution. The problem is a fundamental one, and may be approached in several ways. The authors, in the course of their combustion research program, had occasion to examine the agglomeration of ash, ranging from sub-micron to 17 microns in size, produced in a (coal and oil) dual-fuel-fired steam generator. Several theories, supported by extensive laboratory studies, have provided some understanding of a probable mechanism of agglomeration. As a result, certain precautions are suggested in the design and selection of combustion processes and equipment.

Jan 1, 1962

By M. S. Badollet

Introduction The manufacture of some asbestos products involves the use of asbestos in combination with water, cement and granular fillers. This type of production is often called the wet or semi-wet process and requires the use of either pressure or vacuum to eliminate the excess water in the fibrous blend so that the product may develop the proper strength during the curing stage. Asbestos - cement products available today are numerous and are a valuable contribution to the building industry. Their production in quantity depends upon the type of equipment employed, the speed at which it can be operated, and the factors involving the? blending of asbestos, cement, water, and fillers. Assuming that all mechanical troubles at a plant have been eliminated or are under control it is still advisable to study the basic properties of the raw materials used in the asbestos-cement products. The type of cement used is an important factor, but usually the manufacturer of the cement is willing to work with the asbestos development engineer and recommend the proper type to be used for the product. The source of the water should not be overlooked as a general factor involved in the production cycle. Waters containing a high percentage of contamination such as silts, humus, or soluble salts may adversely affect the setting of the cement or cause a slowing down of the production rate in the factory. Asbestos in combination with cement is an ideal material fo1 building products. It is inorganic, will not deteriorate, and can be handled by mechanical equipment with a minimum reduction of fibre length. The many physical properties peculiar to asbestos fibres should be well understood by the manufacturer. They may be briefly enumerated as follows: fibre strength, fibre composition, sliminess, length, harshness, softness, and filterability or porosity. This last named property is important and it is the purpose of this paper to present some basic studies on filtration as applied to production problems.

Jan 1, 1949

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012

By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By I. Stefanou, J. Sulem

"In the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface. Multiphysics couplings play a major role in earthquake nucleation and seismic slip. The effect of shear heating and thermal pressurization may be of prime importance in the control of the stability of shear deformation inside the slipping zone. Other mechanisms in relation with thermal decomposition of minerals affect the pore pressure and the temperature evolution of the system, and can play a significant role in the extreme strain localization observed in field. The actual width of the localized zone is a key parameter for understanding fault weakening mechanisms. On the basis of field observations, laboratory experiments and recent advanced modeling, these phenomena are analyzed and discussed in order to bring some new insights in the understanding of earthquakes nucleation.INTRODUCTIONIn the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface (Scholz, 1998; Sykes, 1978). The conceptual model of spring slider system is commonly used to represent the interaction between an elastic crustal block and a fault zone. Stick-slip instability is possible if the softening rate of the shear resistance of the fault zone is high enough as compared to the stiffness of the crustal block. Therefore, weakening mechanisms that can explain how the frictional resistance of a fault decreases with slip and/or slip rate is of prime importance to understand how an earthquake nucleates. In recent years, several drilling programs in active faults (e.g. the Nojima fault in Japan, Boullier, 2011; the Aigion Fault in Greece, Cornet et al. 2004, the Chelungpu fault in Taiwan, Ma et al. 2006, and the San Andreas fault in the U.S.A. Ellsworth et al. 2000) as well as high velocity friction experiments (e.g. Tanikawa et al 2012a; Tanikawa et al. 2012b) have highlighted the physico-chemical processes involved in the nucleation of seismic slip (see for the example the review paper of Niemeijer et al. 2012)."

Jan 1, 2015

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017

By Ali Bunjaku, Lauri Pesonen, Hannu Johto

It is well known that there are many ways to process copper concentrates into copper anodes using the pyrometallurgical route. All modern copper smelting technologies are fundamentally energy efficient and environmentally safe options, and therefore choosing one depends on the desired capacity range, feed impurity levels, plant location, flexibility needs, overall energy use, and of course smelter economics in both the short and long term. This paper focuses on comparing different solutions which have potentially the lowest variable opex (operational expense), meaning in practice finding out which technology offers the best chances for profit maximization under certain scenarios. For the comparison, we chose to have a closer look at Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC), Outotec Flash Smelting (FSF) – Outotec- Kennecott Flash Converting (FCF), Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC), Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF), Mitsubishi Smelting Process (MIT), Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC), and Side Blowing Furnace (SBF) - Top Blowing Converting (TBC) since these seem to be the main state-of-art technologies now being applied in many recent copper smelter projects around the world. The work was carried out by modelling each smelting route by using the new HSC SIM 9 simulation software and applying operation time, energy, and consumables consumption numbers for each unit process and stream. Combined with cost data, the exercise produced a rich set of information which will be shown in detail for each area per scenario. The authors’ goal here was to provide a fair comparison where each technology can be evaluated from various perspectives such as electricity use or refractory consumption. INTRODUCTION Copper can be produced either pyrometallurgically or hydrometallurgically. The hydrometallurgical route is used only for a limited amount of the world’s copper production (~20%) and is normally only considered in connection with in-situ leaching of copper ores. On the other hand, most of the copper extraction from Cu-Fe-S minerals is pyrometallurgical (~80%) (Schlesinger 2011, ICSG 2017). Thus, several different processes can be applied for copper production, including the following state-of-the-art technologies: Outotec Flash Smelting (FSF) – Outotec-Kennecott Flash Converting (FCF) Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF) Mitsubishi Smelting Process (MIT) Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC) Side Blowing Furnace (SBF) - Top Blowing Converting (TBC)

Jan 1, 2019

By D J. Murray

This paper outlines the principles of friction hoisting and the components involved, and gives a description of a specific mine hoist. Friction hoisting is compared with conventional drum hoisting, and the depth of shaft at which friction hoists become more economical than drum hoists, with respect to power consumption, is determined. Introduction T HE purpose of this paper is to outline the principles of friction hoisting, to describe the components and to show the advantages of multi-rope friction hoisting. Some calculations are made to show that the power requirements and the initial costs of friction hoists are less than those of conventional drum hoists, once a certain depth of shaft has been reached. The use of multi-rope friction hoists is gradually superseding the employment of the conventional drum hoist in many parts of the world. It results in heavier payloads from deeper levels, an increase in shaft safe-ty and a more compact installation for protection against adverse weather conditions. It was observed that where drums and friction sheaves exceeded 30 feet in diameter, a number of mechanical disadvantages were being experienced;

Jan 1, 1965

The control of AG mills fed by ores with harder and softer components can be challenging due to the sensitivity of the mill to the ratio of hard to soft components. The mills at LKAB?s iron ore operations are generally well controlled, but there are periods when the throughput falls off dramatically, due to a loss of mill filling. As the ore is upgraded in the sorting plant through magnetic separation prior to milling, this presents an opportunity to manipulate the feed blend in advance. In order to assess this opportunity, a fullscale mill charge was dumped and assayed by size to quantify the build-up of competent waste in the mills. This was supplemented by pilot and locked-cycle laboratory tests at a wide range of feed blends in order to facilitate the development of an appropriate multi-component AG mill model. This paper reports the experimental campaign requirements and methodologies, as well as the major outcomes from analysis and modelling exercises using the industrial, pilot and laboratory multi-component data.

Jan 1, 2012

By G. Ergin

The interactions taking place between Al-Mg alloys and the bed media during aluminum filtration are not yet well understood. These interactions were studied using the infiltration technique. The reaction interface was analyzed using different techniques such as SEM and TEM. Only spinel formation was observed at the interface regardless of the type of alumina and contact time. This paper discusses the results of the study.

Jan 1, 2004

By A. A. Brant

ONE of the reasons advanced for the decline in prospecting and discovery is that, as regards surficial examination, the law of diminishing returns is becoming applicable. Fewer surficially unprospected fields remain; therefore, fewer discoveries by such means result. Much in the nature of mineral resources remains to be unearthed, but even now, and more so in the future, will discovery depend on painstaking petrographic and structural mapping, aided, where necessary, by judicious applications of all the complementary scientific knowledge and devices (e.g., thin section microscopy, geophysics, and drilling) that experience proves effective in localizing a mineral deposit even beneath drift, lake, or muskeg. It is to be expected, then, that the rate of discovery will decrease, that the cost per discovery will greatly increase, and that the work of discovery will become more and more the careful, methodical assembling of field data, conscientiously interpreted on the basis of scientific knowledge by trained, experienced operatives. In view of these trends, the status of applied geophysics to Canadian mining exploration and development work might well be reviewed. The niche which geophysics may occupy relative to geological surveying and drilling has been clarified by the last twenty years' experience. The cloud of somewhat justifiable scepticism that followed the 'geophysical promotion' period of the late 1920's has lifted. Mining, exploration, and finance companies, in open-minded fashion, are seeking sound advice as to what are the scope and limitations of the geophysical methods at present practised. The purpose of this paper and the following one is, therefore, as far as lies within the author's power, to review briefly the geophysical methods at present in practice in Canada, and, at greater length, to joint out impartially and critically their scope, merits, shortcomings, an possible future development. The treatment will be non-technical, the hope being that an accurate statement of the present status of geophysics in Canada may do much to result in a sounder, saner growth of what, in the future, shall undoubted} y prove an increasingly useful tool in exploration and development work. ?

Jan 1, 1942

By T. Macpherson

ABSTRACT: Drawing on past research experience with sprayable polymer mine support agents (TSLs), Spray On Plastics Ltd. has developed a TSL ground support system called RockWeb. Using a relatively new polyurea polymer technology, RockWeb has been engineered to solve problems encountered underground with polyurethane liners by incorporating rapid curing, moisture insensitivity and superior physical performance. RockWeb possesses a unique, patented ability to be sprayed in a ?cobweb? like consistency allowing the applicator to span fissures in the rock, ensuring no initial defects in the liner, and maintaining design thickness over highly irregular surfaces. This ability, coupled with the high strength and elasticity of polyurea, allows RockWeb to mitigate rock movement through yielding, while maintaining intimate surface confinement. RockWeb provides reduction in logistics through the transport of 1/25 of the material quantities required for shotcrete, rapid deployment rates of as little as 30 minutes per round, and immediate return to the work area. This paper will discuss the technology and advantages of RockWeb as well as opportunities for overall mining cycle cost reduction. The safety benefits, as well as health and environmental considerations regarding application of isocyanate-based liners will also be discussed.

May 1, 2009

By J. W. Choung, T. Fu, Z. A. Zhou

An on-line visualization technique and methodology was developed to investigate the role of fine sphalerite (< 10 um) aggregation in flotation. The images of particle aggregates under different operating conditions were recorded and analyzed. The effect of impeller design on particle aggregation was demonstrated. This difference was not mainly due to the energy input into the system, but due to the resultant hydrodynamic conditions created by the impeller and their effect on particle interactions. The recorded image showed that adding fine silica (- 5 um) did not interfere with fine sphalerite aggregation, thereby showing no effect on the sphalerite recovery. Effect of the enlarged aggregate size on increasing flotation recovery was confirmed. Although Malvern Mastersizer produced consistently lower estimates of aggregate size than those by the image analysis, both methods responded to the changes in operating conditions in the similar trend. It was shown from this study that on-line visualization technique is a powerful tool for studying fine particle aggregation and morphology in the context of diagnosis for the flotation separation.

Jan 1, 2004

By K. J. R. Ford, Botz. M. M.

Porphyry copper ores are frequently a source of low-grade gold ore, but gold in these ores is often associated with significant levels of cyanide-soluble copper. Cyanide leaching of such ores increases flowsheet complexity and operating costs, and requires thorough planning to satisfy environmental requirements for tailings disposal and mine closure. This paper presents a review of the chemistry of cyanide leaching of gold-copper porphyry ores, carbon adsorption phenomena and means of removing base metals from leach solution. The primary economic drivers behind the processing of such complex ores are also analyzed.

Jan 1, 2011

By M. Mohammadijoo, J. B. Wiskel, D. G. Ivey, S. Kenny, H. Henein

Cold-wire tandem submerged arc welding (CWTSAW) has recently been developed as a novel welding technique to replace the conventional tandem submerged arc welding (TSAW) process and improve the productivity of pipeline manufacturing. The process involves two electrodes with arcs and one electrically cold electrode. Since heat-input of the welding process is a key factor affecting the properties of the weld metal (WM) and the heat-affected zone (HAZ), and the additional cold-wire affects the heat introduced to the weldment, it is of interest to investigate property and geometry changes in the WM and HAZ when a cold-wire is added to the welding process. In the current research, the CWTSAW process is investigated and optimized by correlating the main welding parameters with the micro-hardness of the WM and HAZ and the geometry of the weld, i.e., the bead width (BW), penetration depth (PD), reinforcement area (RA) and coarse grained heat-affected zone (CGHAZ) area. Three statistical and mathematical methods are employed to optimize the CWTSAW process in terms of the mechanical properties and WM and HAZ geometry of a typical microalloyed steel used for pipeline manufacturing.

Jan 1, 2015

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016