Search Documents

By S. Huang, K. Xia

"During crushing, rock particle is subjected to complicated loading and the particle shape influences the fragmentation outcome. Thus, a highly controlled laboratory test is desired to establish the relation between the loading and the fragmentation parameters for better understanding the rock crushing mechanism. In this work, a split Hopkinson pressure bar system in combination with high speed cameras is utilized to carry out a dynamic ball compression test, in which the spherical rock sample is adopted to avoid the shape effect. Using the elasticity theory, the history of the axial symmetric tensile stress perpendicular to the diametrical direction along the loading axis is determined, from which the loading rate and the dynamic indirect tensile strength are calculated. With the aid of the moment-trap technique, the total energy absorbed by samples is accurately determined from the one-dimensional wave analysis. Furthermore by considering the kinetic energy of the sample fragments using the high speed camera snapshots, the surface energy is determined for each sample. The relations between the loading rate and the fragmentation parameters, i.e., the number of fragments and the surface energy are established. The application of this method to a granitic rock shows that it is flexible and can be applied to the crushing study of generic brittle solids. INTRODUCTIONCrushers are widely used to break rocks to extract specific minerals in the mining industry, and to obtain rock fragments with desired size distribution in construction industry. During crushing, the breakage of particles can be in either the single-layer mode or the multi-layer mode. In the single-layer mode, the particle breakage can be assumed to be isolated, in which the interaction between particles can be ignored. It is thus suggested by many researchers that highly controlled single particle test should be performed to establish the relation between the input mechanical energy and size reduction for better understanding the crushing mechanism (Yashima et al., 1987; Tavares, 2007; Pitchumani et al., 2004)."

Jan 1, 2015

By Narasimha Mangadoddy, Teja Reddy Vakamalla

"Vertical hydrocyclones are very common in most of the comminution circuits. Inclined cyclones are also found for specific mineral processing applications. In this work, Computational Fluid Dynamics (CFD) technique and experiments are used to find the reasons behind the inclinations effect on hydrocyclone performance characteristics. The water and silica slurry experiments are conducted with 75 mm hydrocyclone at different inclined positions (0-600) to the vertical plane. Corresponding two-phase numerical simulations are performed with Volume of Fluid (VOF) model coupled with Large Eddy Simulation (LES) turbulence model. Multiphase simulations are carried out with Algebraic Slip Mixture model modified with lift, drag forces and Newtonian rheology model corrected with fines for various feed solids concentration. A raise in the under flow solids percentage, cut diameter and a reduction in the water split is observed with the inclination. Electrical Resistance Tomography (ERT) and High Speed Video (HSV) data is used to cross validate the inclined cyclone’s CFD air-core and solids concentration data. Predicted efficiency curves are found in a close agreement with experiments for all the inclinations. Comparison of experimental and predicted flow data clearly follows trend with the literature. Key words: Hydrocyclone, CFD, ERT, inclination, water splitINTRODUCTIONHydrocyclones are devices used to separate or classify particles based on particle size difference in the water medium. Their usage is very wide in chemical, petroleum, mineral and bio industries due to its structural simplicity, high throughput, small volume, low cost and maintenance. Cyclone mainly consists of a cylindrical section followed by a conical section attached to a single feed inlet and two product outlets named vortex finder and spigot. It works on the principle of centrifugal sedimentation. The slurry is fed tangentially to the hydrocyclone, in which larger particles are moved towards the wall and separated by centrifugal forces to the underflow. Smaller size particles follow liquid due to drag forces to the overflow. With its simple structure, the flow behavior inside the hydrocyclone is quite complex. Vertical cyclones are common in practice in most of the comminution circuits. Horizontal cyclones can be found in extreme cases which are for installation convenience rather than for process reasons. Inclined cyclones are also present for specific mineral processing applications. In coal preparation plants, dense medium cyclones are operated near to horizontal inclination of 20 degrees to allow large spigot sizes for sinks removal, self-drain of contents during shutdown. In the phosphate removal, dense medium cyclones are inclined with an angle between 0-90 degrees for better separation of ore and tailings (Liu Feng et al., 2006). Even in the clusters, hydrocyclones are mounted with an inclination around the feed distributor for uniform distribution of slurry and under flow collection. It is believed in mineral processing industry that inclined cyclones would fetch the benefit in number of ways while classifying the material by size. Gravity influences the cyclone performance through the air core size and position variations in large cyclones. It also favours the cyclone operation at coarser cut points without varying any other design and operating parameters. Minimizing fines misplacement to underflow can be achieved with inclination."

Jan 1, 2016

By Carrasco .. P. J. A., R. Parada, I. Saavedra, F. Parada, R. Parra, E. Balladares

In most of the smelters, the management of flue dust has a double objective: the control of minor elements in the anodes and the management of volatiles compounds that can cause contamination due to fugitive gas emissions. This is a special concern when high content of Va elements (As, Sb & Bi) are present in concentrates. We present the results of the experimental study to prove the principle of a novel process that recovers, via volatilization, the As, Sb and Bi in the flue dust as gaseous sulfides, due to a previous sulfidization. In the case of as control any further classical treatment for its stabilization is possible from the gas. The clean calcine can be returned to the smelter avoiding any concentration of these minor elements in the circuit. This process is now tested at pilot scale and shows better indices on carbon footprint than the classical hydrometallurgical process for flue dust.

Jan 1, 2011

By A. Tohn, K. Adham, R. Lu, D. Lemieux

"To remove sulphur, carbon and arsenic from the gold concentrates of Dundee Sustainable Technologies (DST), Hatch has designed a demonstration plant roaster using the fluid bed technology. The fluid bed was selected for its ability to maintain stable temperatures and uniform reaction conditions. Data points from a small pilot plant (operated by DST) were used for setting the parameters of the demo plant roaster.The DST demonstration plant is being built to further prove their patented gold extraction process at an industrial scale. Their gold extraction process is based on halogenation at atmospheric pressure and relatively low temperatures. Before the halogen leaching, most of the sulphur, carbon and arsenic should be roasted out of the feed concentrate.The Hatch fluid bed roaster design includes a moist feed introduction system, simple bed cooling for temperature control, and cyclone fines recirculation. The demonstration plant roaster is planned for construction in 2014, and the performance results will be presented in a future paper."

Jan 1, 2014

ABSTRACT Based on mineralogical characteristics and processing techniques required, gold ores can be classified into 12 types: gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper-gold ores, porphyry copper-gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores, and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type differs and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ore and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2013

By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By Juergen Antrekowitsch, Stefan Steinlechner

"Waelz oxide from steel mill dust recycling is usually sold to the primary zinc industry, where it is first charged to the roasters to eliminate the remaining fluorides and chlorides. This limits the overall amount of secondary materials which can be used because of different operating problems in the roasters. Another option, in the case where the halides are low, would be direct leaching with low or medium concentrated sulphuric acid. Unfortunately, because of the carryover of some steel mill dust, iron is also present in the Waelz oxide, reaching contents up to 5 wt.%. Since the objective is to treat the solution more or less directly by electrowinning, with only a few simple preliminary purification steps, iron in the solution is a very important factor. Various trials have been done to investigate the dissolution behavior of the iron contained in the Waelz oxide. Although the zinc extraction should reach a maximum, all other elements, especially iron, should be low. This paper describes the results of our research in this area and offers possible options for Waelz oxide utilization. There is also a focus on how other elements, present in the material, influence the dissolution behaviour of zinc and iron, and whether a loss of zinc is unavoidable, if low iron dissolution is required.INTRODUCTION One of the most important secondary zinc resources is the zinc oxide originating from steel mill dust recycling. For the treatment of high zinc containing steel mill dusts, the Waelz kiln process is the so called “best available technology” and it dominates the industry, with roughly a 90% market share. The product Waelz oxide contains mostly zinc oxide, but it also contains lead compounds and halides due to evaporation with the zinc. In addition, it contains iron and some slag compounds due to mechanical carry-over. The presence of halides limits the use of the material as an alternative concentrate for primary zinc electrowinning. Such halides can be reduced to a certain extent by washing and/or solvent extraction (see following chapter). Although lead is not troublesome and theoretically represents a second recoverable valuable metal, iron is unwanted and causes additional problems during leaching. Even though Waelz oxide is generally a highly welcome input material in primary zinc metallurgy, due to its high zinc content, it still contains halides, and in the majority of cases, the oxide must first be treated in a roasting process. Different circumstances, like accretion formation because of the lead and halogen compounds as well as unwanted cooling effects in the roaster, limit the amount of Waelz oxide which can be substituted for the primary concentrate. Another, even more limiting factor, is the allowable concentrations of chlorides and fluorides in zinc electrowinning, the last step in the primary zinc processing route (Ruetten, 2011)."

Jan 1, 2016

By Magnus Evertsson, Johannes Quist

HPGRs have since introduced in the 1980s (Kellerwessel, 1993; Schönert, 1988), now become integral comminution units at several minerals processing plants around the world. Even though a lot of the initial issues concerning performance, availability and wear have been addressed and solved there are still phenomena and aspects which can be improved and understood further. Schönert and Sander (2002) presented experimental results and a mechanistic model including the internal force dynamics between the rollers and the compacted bed. They derived expressions for the pressure distribution involving most of the influencing terms and effects. However, in order to solve the differential equations several of the terms vanish by assumptions. The Schönert and Sander model reflects the experimental data in many aspects but the predicted shear force distinctly deviates from the experimental results at the angular position of the peak pressure level. This finding suggests that the particle to particle interaction and breakage process in the different zones seen in Figure 1 are complex and difficult to model using analytical models. A numerical modelling approach using DEM does not require the same amount of assumptions and simplifications of boundary conditions. Hence such modelling may provide further knowledge and vital understanding. In this paper the breakage process is simulated in order to investigate the shear slip behaviour and how it relates to different operating variables. A laboratory scale HPGR corresponding to the experimental setup used by Schönert (2002) have been modelled in EDEM (DEM-Solutions). The bonded particle model (BPM) is used for modelling quartz particles (Potyondy, 2004). The breakage model strength parameters are calibrated against interparticle breakage experiments in an Instron 400RD compression device. The contact model parameters are calibrated using calibration methods developed by Quist (2015). The floating roller dynamics are modelled using a spring-damper system. Results present insights regarding the interparticle slip behaviour as well as the frictional tangential force distribution on the rollers. The simulated roller pressure distribution shows good correspondence with previously reported findings in the literature.

Jan 1, 2016

By W. Petruk

A study was undertaken to determine whether interrelations between mineral grains affect ore breakage during grinding, and to establish a correlation between ore breakage and mineral liberation. A base metal ore from the Brunswick No. 12 deposit in New Brunswick was ground for different periods of time in a laboratory ball mill, and both the unbroken ore and the ground products were analysed by image analysis. The results show that the mode of breakage is strongly influenced by the behaviour of pyrite. Similar size distributions were obtained for material from the 15 minute grind in a laboratory ball mill, for the grinding circuit discharge from a commercial mill, and for pyrite grains in the unbroken ore. This similarity indicates that a 15 minute grind breaks poorly bonded pyrite grains along grain boundaries, and represents the limit of easy breakage for the ore. Such a grind liberates both large separate grains of ore minerals and poorly bonded mineral grains that occur in interstices among pyrite. On the other hand the 15 minute grind does not separate moderately bonded mineral grains nor release moderately bonded interstitial minerals from pyrite; a 45 minute grind in a laboratory ball mill is required. It is assumed that, for Brunswick No. 12 ore, a 45 minute grind in a laboratory ball mill is equivalent to regrinding in a commercial mill. Grinding beyond 45 minutes in a laboratory ball mill breaks the ore by fracturing pyrite across grain boundaries and by chipping grain edges. Such intense grinding does not markedly increase sphalerite liberation from Brunswick No. 12 ore, because most of the sphalerite that can be released was liberated at the 45 minute grind. In contrast the intense grinding increases galena liberation because a significant proportion of the galena occurs as minute inclusions in pyrite. These findings show that ore breakage and coincident liberation depend upon size distributions, intergrowths, and mode of occurrence of the minerals in an ore.

Jan 1, 1988

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By Louise Corriveau

A Targeted Geoscience Initiative transect in the eastern Grenville Province reveals an extensive VHMS-style cupriferous hydrothermal system among rhyolitic pyroclastic rocks of the Wakeham Group at La Romaine, Québec. The volcanic rocks outcrop sporadically along a < 10 km-wide by about 100 km-long belt correlated with the south-eastern extension of the Wakeham Group. This belt occurs among voluminous, magnetite-bearing, granitic gneiss. At Lake Musquaro, 1.51 Ga metarhyolitic to dacitic lapillistones and flows, locally with aluminous nodules and veins, are intruded by 1.49 Ga feldspar porphyries. This volcanic package was deposited on typical Wakeham Group arenite (< 1.52 Ga) interbedded with nodular, muscovite- and fibrolite-bearing gneiss, and minor marble hosting finely layered garnetiferous hornblendite, garnetite and magnetite-bearing coticule. The latter are interpreted as meta-exhalite and with the associated albitite (sodic alteration), aluminous veins (hydrothermal leaching) and magnetite-rich granitoids, they are key elements in the search for concealed mineral deposits in this area. At La Romaine, to the south, 1.5 Ga lapillistones outcrop structurally above metasediments and below a composite amphibolite unit of uncertain origin (lava or sills) with magnetite-rich (BIF?) units. An extensive zone of aluminous gneiss, with lapilli textures, provide evidences for severe hydrothermal leaching of the volcanic rocks prior to metamorphism. An adjacent siliceous vein-textured unit likely represent a zone of intense silicification (74 wt.% SiO2), while aluminous, hematite to magnetite-bearing veins in adjacent felsic gneiss (tuff?) preserve evidences for the sequence of alteration events. Despite granulite-facies metamorphism, the main characteristics of the amphibolite unit persist along the entire belt. This competent unit likely served as a cap rock; the garnetite, diopsidite and hornblendite it hosts provide effective guides to the sites of fluid discharge and mineralization. A number of Cu showings, modest in size, were discovered in this unit. Their systematic occurrence, in a structural-stratigraphic sense, indicates that this setting is attractive for mineral exploration despite high-grade metamorphism and deformation. Late-stage veins laden with fluorite crosscut these alteration zones, and are themselves metamorphosed, indicating that hydrothermal activity was polyphased. SHRIMP U-Pb ages obtained on detrital zircons (1 arenite) and on igneous zircons (5 volcanic rocks, 1 porphyry and 6 granitoids), pervasive arc-type geochemical signatures and presence of in situ rafts of barium-rich garnetite in the granitoids indicate that sedimentation and volcanism occurred between 1.52 and 1.49 Ga coevally with hydrothermal activity and emplacement of a sub-volcanic 1.5 Ga granitic batholith with early, 1.53 Ga tonalite intrusion. Such a geological context can sustain large-scale hydrothermal cells and development of VHMS, Cu-Fe oxides or SEDEX deposits.

May 1, 2003

"THE CONCEPT of energy as a commodity, while not entirely new, is not as widespread as the importance of the idea to this modern world would lead one to expect. The growth in the supply and use of energy over the past years has been tremendous, but our very closeness and familiarity have somewhat distorted the viewpoint, particularly of the younger generation. To many of us who remember the wonderful satisfaction of our first responsibility for directing two horsepower hitched to a farm cart or hay wagon, there still arises a feeling of some awe at the casual flick of the switch with which our sons and daughters summon to their convenience the service of some one hundred or more horsepower.Energy is the vital component of our existence and, no matter what contempt our day-to-day familiarity may •breed, it is wise to .pause from time to time and consider our national energy standing. Have we still capital in the bank? Are our expenditures wisely •conceived and well directed? Is provision being made for the years •ahead for the needs of our children and our children's children?"

Jan 1, 1953

By Y. M. Shneerson, I. V. Fomenko, M. A. Pleshkov, E. A. Ospanov, A. A. Shakhalov, S. S. Naboychenko

Low-grade copper concentrates (with copper content less than 20%) often contain impurities such as arsenic, zinc, lead, mercury, antimony and bismuth. The pyrometallurgical treatment of such concentrates is associated with several problems, which will ultimately affect the cost and the quality of copper cathodes as well as by-products. SRC Hydrometallurgy proposed a complex hydrometallurgical technology which allows the removal of impurities and the enrichment of low-grade copper concentrates to a quality which will be more suitable for pyrometallurgical processing. Laboratory batch tests and pilot plant results for the pressure leaching steps are shown in this paper. The key parameters of the leaching steps were determined and optimized. The quality of possible by-products were also determined. The developed flowsheet includes two pressure leaching steps: pressure oxidation (POX) and hydrothermal alteration (HTA). Both operations are carried out at 170°C with subsequent flotation of POX and HTA residues and recovery of copper, zinc and lead into separate concentrates for further processing. The development of the flowsheet was based on the Balkhash Zinc Plant (Balkhash, Kazakhstan), which had been non-operational since 2009. The developed flowsheet for processing of low-grade concentrates will utilize 80% of the existing equipment of the Balkhash Zinc Plant, thus leading to a significant reduction in required capital expenditure. INTRODUCTION As the age of copper mining operations advance, copper grades continue to diminish and impurity levels increase. Therefore, copper producers are forced to look for new innovative hydrometallurgical technologies which are able to handle low-grade raw materials and solve problems associated with impurities in an economically justifiable way. New technologies allow to extract valuable components selectively and to process low-grade concentrates which had previously been marked as non-technological and economically unviable. Hydrometallurgical technologies for processing of copper-containing materials can be divided into two main categories: chloride and sulfate (atmospheric, autoclave and bacterial) based technologies. Since the 1970s, many autoclave techniques for the processing of copper-containing materials have been developed and implemented (Naboichenko, 2002; Dreisinger, 2005; Habashi, 2009; Shneerson, 2011). The mineralogical composition of the ore (or concentrates), geographical location of the deposit, distance from industrial areas, availability of existing treatment facilities, availability of skilled labor, cost of electricity and cost of neutralization are some of the factors which are usually considered when the appropriate technology is selected (Halbe, 2002).

Jan 1, 2019

By K. R. Brown, P. L. Krawchuk

In-situ recovery (ISR) is under increased investigation as a viable methodology for the extraction of minerals in ore bodies that may be uneconomic to mine by traditional methods or for resources situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash and uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. ISR allows for the extraction of metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in a process that produces very little to no waste rock or tailings. This paper aims to discuss the geological conditions that make ISR amenable to an ore body as well as the application of maturing technologies such as advanced directional drilling and the creation of artificial permeability that will help to access deep ore bodies and enhance or create favorable recovery conditions for ISR in the ore body. INTRODUCTION In-situ recovery (ISR), also referred to as in-situ leaching, is a potentially disruptive technology for the mining industry. ISR is under increased investigation as a viable methodology for the extraction of valuable minerals that may be uneconomic to mine by traditional methods or for deposits situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash mining, uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. Recently there has been increased interest in deploying ISR in hard rock applications due to a number of factors: the drive for environmental stewardship is stronger than ever, technological advances in drilling, blasting, and leaching are strengthening ISR economics, and a large inventory of ore bodies exists that are not feasible to mine or extract using conventional open pit or underground mining techniques. ISR allows for the extraction of valuable metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in solution via a recovery process that produces very little to no waste rock or tailings. Where the right conditions exist, the ISR process has a much smaller environmental footprint (Hiam-Galvez, 2018) and potentially much lower capital and operating costs than using conventional mining techniques.

Jan 1, 2019

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the &apos; centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, &apos;which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

By W. Beres, M. Bielawski

Recent research on the development of erosion resistant coatings has been directed to the finite element modelling of the behavior of coating and substrate, and their interface under the impact of eroding particles. The approach presented in this paper is based on advanced computer simulation techniques using ABAQUS/Explicit to investigate stress and strain at the surface and at the coating/substrate interface of multilayer coatings under single particle impact. It was found previously that solid particle erosion mechanisms are predominantly governed by the kinetic energy of the impacting particles. However, recent modelling efforts revealed that effects of various material models could be also significant. Therefore, different material models representing relevant coating and substrate properties were investigated and the effects of these models on the coating/substrate response were studied. Particularly, differences between elastic, elastic-plastic and brittle cracking model responses were assessed.

Jan 1, 2006

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By J. R. Welsh, D. J. Palmer, O. M. G. Newman

"The use of calcine for selective zinc precipitation requires specialist knowledge to achieve satisfactory flowsheet design. Calcine from the bed of a fluid roaster is preferred, and factors such as the size distribution of ground calcine, the stoichiometric ratio of the calcine precipitant to the initial dissolved zinc concentration and the moisture content of the resultant filter cake are parameters which require critical attention. Extensive testing in a fully-integrated electrolytic zinc plant pilot plant has demonstrated that properly designed selective zinc precipitation plants using calcine as the precipitant are reliable operating units.The advantages of using calcine instead of limestone for selective zinc precipitation include a decreased cost of reagents, as well as avoiding the formation of by-product gypsum.Process simulation modelling has demonstrated that the use of calcine in this context has widespread application in the design of zinc plants with superior impurity and water balance control characteristics. A particularly powerful approach involves closed circuit washing. In this mode, filtrate from the selective zinc precipitation step is used to wash a zinc plant residue such as jarosite, and the resulting filtrate is returned to the selective zinc precipitation section. IntroductionThe Selective Zinc Precipitation (SZP) Process, developed and patented by the Electrolytic Zinc Company of Australasia Limited (EZ) may be used to achieve simultaneously, water balance and impurity control in an electrolytic zinc plantO,2). Impurities which may be controlled by the SZP process include chlorine, magnesium, manganese, potassium and sodium.In the SZP process, basic zinc sulphate is precipitated from a zinc sulphate solution by either limestone, lime or a compound containing zinc oxide, usually calcined zinc sulphide concentrate (calcine) or alternatively zinc oxide fume .The solids containing basic zinc sulphate are separated, typically, by filtration and returned to the zinc plant circuit as a neutralizing agent. The zinc depleted solution can either be discarded, or used to wash residues, thereby achieving water balance and impurity control (Fig. I)."

Jan 1, 1988