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By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

By A. R. Laplante

"In this paper, the performance of the Knelson Concentrator and of the batch and continuous Falcon Concentrators are compared. The units are based on different operating principles, and as such they perform quite differently. The Knelson yields very high free gold recoveries over a wide size range of both the recovered and rejected species. It is ineffective in recovering very fine ( <15 µm) or flaky gold, as encountered in flotation feeds, concentrates or tails. It is the: preferred unit for gold recovery from grinding circuits. The batch Falcon is effective in the fine range, typically less than 37 µm for gold. Its recovery zone is quickly saturated when there is significant heavies in the feed. It works best as a pre-concentration unit. The continuous Falcon is a versatile unit which is capable of recovering fine heavies (density down to 5 g/cm3 ), especially from coarser gangue. INTRODUCTIONThe purpose of this presentation is to describe the mode of operation of two Canadian centrifugal concentrators, the Knelson and Falcon. It is hoped that it will prove informative to prospective users in the selection, testing and optimization for applications of either machine. The work is based on testwork both in Canadian mills and at McGill. I am indebted to many colleagues at these locations. Appropriate references will be made to articles further describing the work, either already in the open literature or in preparation.Although this work is meant to be more practical than scholarly, it is appropriate to begin by considering how the two units achieve selective recovery. This will become useful in establishing a suitable testing methodology, which will then be described, and interpreting typical results. In the last section I will attempt to define appropriate applications for the two units. This is a thankless task, as I am likely to miss some applications or to make projections based on partial results, as much of the work is still in progress. In deference to the reader and both manufacturers, areas where reasonable doubt still remains will be identified."

Jan 1, 1993

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By ANNE FUZESY

Soluble potassium salts in bedded underground salt deposits supply most of The world demand for potassium f or agricultural and industrial use. The potassium salts, sylvite and carnallite, were f irs, noted in drillcores in southern Saskatchewan during The search for oil and gas in ihe early /940s. Problems in shafi sinking beset pioneering potash companies, however, and cominuous production did no, begin uniil 1962. Powsh deposits in southern Saskatchewan occur within ihe uppermost 60 111 of the Middle Devonian Prairie Evaporite a, depths in excess of 900 m. Four groups of po/ash-bearing haliie beds have been distinguished: the Esierha-::,y, White Bear, Belle Plaine and Paiience Lake members. Powsh deposiis extend a jell' kilomeires into Manitoba and south imo orth Dakoia and non heasiern Moniana. Individual potash-rich beds are extensive and consistent in grade and Th ickness. Local th ickening occurs where carnallite is the dominani poiash mineral. Th e preferred ore, sy lviniie, is a clean mixiure of sylvite and haliie. Carnalliie and insolubles are avoided wherever possible because of Their detrimenwl effects on mine stability, grade and refining. Sy lvin ite is exTracted by underground mining or brought TO swjace as brine in solution mining. Poiash is separaiedfrom halite byfloiation or sequential crystallization. The refined produci, potassium chloride, is employed as a fertilizer ingredient as well as in chemical and other industrial capaciiies. The ten poiash mines of Wesiern Canada all are in Saskatchewan and account for aboui 25 per cem of world production. Faciliiies are being expanded, and a new mine and refinery was planned for ihe Breden bury area. Deposiis in Manitoba also were being evaluaied.

Jan 1, 1984

By I Wilkomirsky

The neutralization of S02 from copper smelter gases to produce calcium sulphate (anhydrite) is considered an attractive alternative to sulphuric acid production. To develop the required technology for the process, a three-stages fluidized bed reactor prototype was designed and operated using both high and low grade limestone and gases with 2, 8 and 12 vol -% S02. The results obtained shows that at 800°C and up to 8 vol-% S02 in the gases, the capture of S02 reaches near 99% with limestone conversion to anhydrite of 45 to 48%. A larger pilot plant is presently being built at the Codelco El Teniente-Caletones Smelter to demostrate the technology and to evaluate the economics of the process. Cu2007

Jan 1, 2007

By Mike McKevitt

We are trying to promote a concept and a change in management?s approach to the iterative process of grade control. This is important as grade control must routinely try and achieve the long term objectives set by the mine plan ??BackgroundBackground ??Factors contributing to variation from planFactors plan ??Basis of OptimisationBasis Optimisation ??Ore Block Optimisation processOre process ??Operating mine examplesOperating examples ??Chain of Mining. ??Intention is to highlight the need for repeatable and consistent materialand material-type classification to remain consistent with the Life of Mine Plan ??We can drill another hole or reWe re-optimise a plan, but once excavated, the final decision has been made ??The grade control decision is the last decision made in the resource exploitation sequence.

May 1, 2009

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

By Paul Hughes

Purpose of Research ? What are the loading mechanics of paste against barricades? ? What is the capacity of the composite paste fill fences? ? Based on the loading mechanics of the paste, do the fill fences pose a risk of failure? Outline ? Glossary of Terms ? General Introduction ? Research Methodology ? Site Description ? Instrumentation Program ? Results ? Analysis ? Conclusions ? Recommendation for Future Work

May 1, 2008

By K. Duckworth

"AbstractA new electromagnetic depth sounding technique was applied to the measurement of salt thickness above the workings in the Central Canada Potash Mine at Colonsay, Saskatchewan. The initial tests indicate that this new technique can measure salt thickness and that the technique possesses operational feature s which make it possible to monitor trends in salt thickness throughout the mine. The technique can be applied using existing equipment, but the tests do indicate the desirability of developing equipment with features specially suited to the mine environment.IntroductionTESTS were conducted in the Central Canada Potash Mine at Colonsay, Saskatchewan during 1974 and 1975 to determine if a new technique in electromagnetic depth sounding could provide a convenient means of measuring salt thickness above the workings. This new technique, which was described by Duckworth (1975), offers operational features which appear to be advantageous in this particular situation.The problem requires that soundings be made upward from the mine workings to the base of the second red shale. This shale forms an impermeable seal on top of the Prairie Evaporite. A knowledge of this salt thickness is of interest due to the need to avoid any possibility of the workings rising to cut the red shale. Another desirable objective is the detection of any disruptions of the red shale. Ideally, this should be done ahead of the workings in order that such areas of disruption may be avoided."

Jan 1, 1977

By Zhao-shu Sun, Mao-lin Li, Rui Cui

"Fankou Mine produced pyrite concentrate (PC) from the tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34%. The economic value of PC increases with its purity. When the S grade of PC feed to sulfuric acid plant is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the PC with S grade of 47% as target.The direct way to reach that goal was to clean the rough PC Lots of cleaner flotation tests were conducted and the balanced strategy was to produce two ranks PC with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of PC, gravity separation was introduced into the flowsheet. The numerical simulation and tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rough PC. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to PC with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough PC, single PC with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality PC at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry."

Jan 1, 2016

By C. S. Simons, D. A. Dahlstrom

"Growing interest in the developing technique of improving the dewatering of filter cakes by the direct application of steam has been apparent during the past year. A number of applications to iron and base-metal concentrates are under study, and intensive work continues on applications to coal cleaning.This paper presents and discusses the data presently available. The effects of material characteristics and operating variables on final cake moisture are examined. Although it is not yet possible to answer all questions regarding the applicability of the technique to specific problems from general data correlations, it is found that the use of these in con-junction with empirical data derived from properly conducted laboratory tests does yield reliable conclusions.Emphasis is placed on the basic economics of the process, and on de-sign criteria for ""steam drying"" filter stations, as applied particularly to metallurgical concentrates. Examples of the use of laboratory tests to solve application problems are given."

Jan 1, 1966

By Carol Odell

This paper was prepared as a brief for Prospectors and Developers Association of Canada (PDAC) to guide input at a series of round tables carried out by the Federal Government in response to the 38th Standing Committee on Foreign Affairs and International Trade (SCFAIT) report, on ?Mining in Developing Countries and Corporate Social Responsibility?. This document mandate is to provide background information, analysis and recommendations on the practice of Canadian exploration and mining companies abroad. This research was based on 11 case studies of Canadian companies which have experienced conflicts or controversies overseas. All case studies were assembled through an extensive literature review of publicly available documentation and communications with representatives of the mining companies to assist in deepening the insights into the drivers of the conflicts and the needs of Canadian companies in similar situations. The case studies include both exploration and mining operations. Our analysis begins with the identification of general and case specific drivers of conflict/controversy in each case study. Company names are kept confidential and only anonymous results are presented. We make ample use of simple flow charts and schematic diagrams to explain how contextual drivers and aggravators and company drivers and mitigators play varied and interrelated roles in conflicts. The diagrams also illustrate the cumulative analysis of drivers including the linkages among drivers/aggravators/mitigators across different domains (social, governance, NGO/media and company). Finally, we discuss needs of companies and propose recommendations for addressing social responsibility and human rights concerns.

May 1, 2007

By Y. Jin, H. You, H. Pang, B. Lin

Successful application of steam assisted gravity drainage (SAGD) on the recovery of land facies ultra-heavy oil in Xinjiang oilfield depends largely on shortening the preheating period with the aid of the micro-fracturing technology, which is conducted through controlled water injection to a pair of horizontal wells to create homogenously distributed microcracks in the zone between the two wells. The numerical simulation of this mechanical process is yet to be investigated. Up to date, there has been research work on rock mechanics during the SAGD production period of marine deposited ultra-heavy oilsands, but the counterpart research on land facies ultra-heavy oilsands of Xinjiang oilfield is left undone. In this regard, this study is attempted to perform numerical simulation of the fracturing process on land facies unconsolidated oilsands. With this objective, the study first investigates geological and physical identification of the field collected cores, then carries out mechanical analysis on laboratory triaixal test results, based on which numerical simulation of the fractured zone is performed. The simulation is applied through a finite element platform adopting extended Drucker-Prager constitutive model, with the parameters determined by experimental work. It is verified that hydraulic fracturing of unconsolidated oilsands generates a microcrack feature in terms of a dilative zone instead of linear apertures. The extent to which the fractured zone propagates is visually demonstrated based on the magnitude distribution of equivalent plastic strain or volumetric dilation. Evaluation of the connection of injection and production wells can possibly be determined by the expansion of the saturated region around each well. Finally, the implications on the efficiency of hydraulic fracturing in stimulation of the pay zone are investigated.

Jan 1, 2015

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016

By L. D. Smith

Net Present Value Impact of Discount Rate The Discounted Cash Flow (DCF) method of valuations is universally used and accepted. The main criticism of the method is that it does not recognize the value of projects long life projects. This can be seen in the preceding graph where the present value of cash flows in later years are small for discount rates over about 10%. This graph covers a project that has a 25 year operating life. It is clear from the low height of the NPV bars at 10% and 15% in the last years of the project that an additional 25 years would add almost no value to total project NPV. As an example of this effect, an colleague undertook the evaluation of a pulp and paper project. The plant could be justified, but it was not possible to justify planting the trees as they took too long to grow and so had not appreciable NPV. The plant had to purchase wood to feed the plant.

May 1, 2013

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By Sunil S. Gandhi

"The Mountain Lake deposit is a tabular sandstone-type uranium deposit, hosted by the basal unit of Middle Proterozoic Dismal Lakes Group. Uranium occurs mainly as sooty pitchblende disseminated in stratiform lenses within gently dipping quartzose sandstone. It is associated with copper sulphides, pyrite, hematite, and traces of nickel and cobalt arsenides and of silver.Exploration HistoryUranium showings on the PEC claim group were discovered during 1969 by an airborne radiometric survey carried out over the Dismal Lakes-Great Bear Lake area by Aquitaine of Canada Limited (Bizard and Salat, 1969). Some drilling was done in the vicinity of the showings in 1975 by the company under a joint venture with Eldorado Nuclear Limited but the results were not encouraging (Hassard and Woollett, 1975). During 1972, Trigg, Woollett and Associates Limited conducting surveys for Imperial Oil Limited, discovered numerous high-grade radioactive boulders scattered over a distance of several kilometres north and west of the showings, and the area north of the PEC claims was staked as the YUK claims (Ahuja, 1974). A systematic study of the boulder distribution and Pleistocene geology suggested a source additional to the showings. More intensive exploration followed, and in 1976 drilling just north of the PEC claim group boundary intersected the main deposit at a depth of 75 m to 150 m, beneath overburden up to 60 m thick. Part of the deposit extends into the PEC claim group which is under exploration by the Aquitaine-Cominco Joint Venture.The following brief description is based on the presentations in 1978 by F. Hassard of Trigg, Woollett and Associates Limited at the Geoscience Forum in Yellowknife, and by S.S. Gandhi of the Geological Survey of Canada at the Mineralogical Association of Canada Uranium Short Course in Toronto."

Jan 1, 1986

By Finley A. Campbell

"Nickel-copper sulphide deposits associated with basic rocks in the Quill Greek area and the White River area in the Yukon Territory have been studied and compared from the view-point of their general geology, structural geology, and the mineralogy of the ores. The relative amounts of the major constituents, magnesium, iron and calcium, and the minor constituents, nickel, cobalt and chromium have been determined spectrographically for two cross sections of the basic rocks at Quill Creek and one at White River. These data, along with petrologic and field evidence, were used to determine the sill and dyke-like character and nature of the basic intrusions. Loss on ignition is employed as a measure of the degree of serpentinization. The distribution determined shows that the serpentinization does not appear to have greatly influenced the inferred original distribution and lithophile associations of magnesium and nickel. The cobalt content may have been altered.The nickel content of the serpentinized peridotites ranges from an average of 0.36 per cent in one section to an average of 0.24 per cent in each of the other two sections studied. The cobalt averages 0.0038 per cent in the samples from the two Quill Creek sections and averages 0.0042 per cent at White River. These results have been compared with other available data.The sulphide ores are later than both the peridotite and gabbroic rocks and may be co-magmatic with them. There is no evidence in these areas to support an origin by lateral secretion; on the contrary, the alteration associated with the ores, the mineralogy and spatial relationship to basic and ultrabasic rocks, indicate the ores are derived from a basic magma."

Jan 1, 1960

By S. M. Bulataovic, D. M. Wyslouzil

"The Martison Lake phosphate-niobium deposit is composed of unconsolidated residuum containing clay and silt-size particles of phosphate, niobium, iron and clay minerals. This paper deals with the laboratory and pilot plant development of the flowsheet and the reagent scheme to treat the Martison Lake ore. The ore, in addition to the complex gangue composition, contained several phosphate minerals including fluorapatite, francolite and florencite. The detailed laboratory and pilot plant evaluation resulted in the development of an effective flowsheet and reagent scheme for the selective flotation of phosphate minerals using a fatty acid circuit, followed by niobium flotation using amine collectors at acid pH. The developed flowsheet included des liming of ore, magnetic separation, and selective P 2 O 5 -Nb 2Os flotation. The main aspects discussed include characterization of the ore, step by step development of flowsheet and evaluation of dfferent modifiers and collectors for P20s and Nb20s flotation.INTRODUCTIONMartison Lake phosphate-niobium ore deposit, located 75 km north of Hearst, Ontario was discovered in the early 70's and has been the subject of extensive technical-economic evaluation in the late 70's and early 80's.The deposit is covered completely by 30 m to 90 m of glacial overburden and is composed entirely of unconso1idated material called residuum, that lies on top of a precambrian age carbonatite intrusive from which the residuum was derived by weathering and natural leaching in situ. The residuum is and irregularly-shaped horizontal lens, 2 km by 3 km in area, and up to 100 m thick, composed mostly of unconsolidated clay and silt-size particles of phosphate, niobium, iron, mica and clay minerals."

Jan 1, 1986