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By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By W. Evans, T. Steis

"Sulphide ores under certain circumstances will react with explosives to generate an autocatalytic chemical reaction. This reaction is exothermic and results in the production of large volumes of poisonous gases and creates an unsafe, unstable condition with the possibility of a low energy deflagration or even a detonation of the loaded hole. This paper outlines the conditions that need to exist for such a reaction to take place and the precautions necessary to minimize or eliminate the problem in areas of reactive ore. A special case study involving a northern Ontario mine will be detailed.IntroductionOne of North America's leading underground gold producer's processes over 6500 tonnes of ore per day from an orebody containing high concentrations of sulphides. After six years of problem free operation, the mine experienced two serious reactions in two months between the sulphides and AMEX II, the ammonium nitrate and fuel oil explosive it uses."

Jan 1, 1995

By G. Girard, A. Larouche, J. Colbert, G. Doyer

"The Direct Chill (DC) casting process uses water to extract heat from molten aluminium and helps to control the solidification process. Many factors such as the water flowrate, water distribution around the mould and water impingement angle have significant impacts on the solidification process. It has been noted that the chemistry variation of the cooling water is also an important factor that has a major impact on the presence of defects on the ingot. A significant change in the water quality can produce defects on the ingots such as cracks, bleedouts, or runouts. Understanding the impact of water quality variation on ingots is therefore essential to ensure good ingot production and reduce defects. This paper aims at describing a new approach to follow the variations of process water quality over time. It is an original and innovative method, which is still under progress. A water quality and stability index (WQSI) is under development to evaluate changes in the water composition based on water physico-chemical parameters. The index is calculated by comparing each of the actual parameters with historical values previously modeled by a statistical law. It is a dimensionless number having an adjustable weight factor for each parameter. The positive or negative contribution of each parameter, with respect to the water cooling capacity, is taken into account to calculate the WQSI. The current selection of parameters is based on knowledge from the literature as well as on empirical experience. When the developed tool will be mature, it could be used to track water variations upon time and anticipate problems, enabling proactive actions to ensure good ingot production.INTRODUCTIONFor many years, the impact of water chemistry on heat transfer, during DC casting, has been of great interest in the aluminum industry. Several papers have been published to demonstrate the correlation between water chemistry and heat transfer (Yu, 1985), (Gildemeister, 2014). Although numerous studies do present the effects of water parameters (i. e. hardness, conductivity, oil, and grease…) on cooling capacity under controlled experimental conditions, they do not reflect the strong interactions between the parameters and variations present in a casting center. Wells and Cockcroft also demonstrated that laboratory based studies are not fully representative of real heat transfer in an industrial casthouse, there are too many factors involved (Wells, Li, & Cockcroft, 2001). In this context, it becomes very difficult to obtain a quantifiable relationship between the capacity of water to cool the ingot and ultimately the performance of the cast."

Jan 1, 2016

By Terence M. Gordon, Mati Raudsepp, Gregory M. Dipple

Four methods of measuring mineral abundance in a rock are examined for their potential in assaying for high-tech industrial minerals. One method uses X-ray powder-diffraction data and the other three rely on whole rock chemical data and information on mineral assemblages and mineral compositions. All four methods were employed to estimate wollastonite content in diamond drill core of skarn collected as part of an exploration program and are compared to visual estimates of wollastonite content from core logs. These techniques for assaying wollastonite span a considerable range ofaccuracy and expense, and combined, define a non-linear relationship between these variables. Accuracy increases rapidly relative lo expense up to total costs of about $50 per analysis. Assay methods in the $50-100 per analysis range have associated errors of 5-10% relative and probably suffice for most exploration programs. Improvements in accuracy above this level require a much larger investment. The most expensive assay technique (-$300 per analysis) yields the most accurate measurement of grade (relative error -1%). Its application may best be limited to periodic checks on other assay techniques and for fine-tuning ofmineral separation procedures.

Jan 1, 2001

By S. Fox, Y. Fujita

Increasing demand for rare earth elements (REE) is expected to lead to new development and expansion in industries processing and or recycling REE. For some industrial operators, sending aqueous waste streams to a municipal wastewater treatment plant, or publicly owned treatment works (POTW), may be a cost effective disposal option. However, wastewaters that adversely affect the performance of biological wastewater treatment at the POTW will not be accepted. The objective of our research is to assess the effects of wastewaters that might be generated by new rare earth element (REE) beneficiation or recycling processes on biological wastewater treatment systems. We have been investigating the impact of yttrium and europium on the biological activity of activated sludge collected from an operating municipal wastewater treatment plant. We have also examined the effect of an organic complexant that is commonly used in REE extraction and separations; similar compounds may be a component of newly developed REE recycling processes. Our preliminary results indicate that in the presence of Eu, respiration rates for the activated sludge decrease relative to the no-Eu controls, at Eu concentrations ranging from <10 to 660 µM. Yttrium appears to inhibit respiration as well, although negative impacts have been observed only at the highest Y amendment level tested (660 µM). The organic complexant appears to have a negative impact on activated sludge activity as well, although results are variable. Ultimately the intent of this research is to help REE industries to develop environmentally friendly and economically sustainable beneficiation and recycling processes.

Jan 1, 2016

By C. F. Hews, P. N. Calder

"MIROC and The Mining Industry The Mining Industry Research Organization of Canada (MIROC), incorporated in 1975, is a non-profit organization sponsored by member companies from within the Canadian mining industry. The Canadian mining industry is a world leader in technological development and in organizational and human resources development. A prime objective within the industry is to retain this leadership and also improve its competitive position worldwide.MIROC is dedicated to support the objectives of its member companies and their common interest, and the objectives of the industry. In this context: MIROC&apos;s mission is to encourage the formulation of ideas to improve mining technology and methods by any source, and to foster the development and testing of promising initiatives in progressive steps from the early stages of conceptual and feasibility research through manufacture to delivery of new technology to the mining industry. In so doing MIROC plays an important role in the development of individuals skilled in mining research. Management ApproachMIROC&apos;s research program is driven by member companies who have interests throughout Canada. The board of directors approve projects that are acceptable to its members. While MIROC&apos;s basic research funding is provided by its member companies, about 30% of its annual research budget is now derived from royalties generated from previous research activities."

Jan 1, 1994

By M. Phylli Bray

"Mining has the reputation of being a very ""macho"" industry. Recently, wider educational opportunities for women in nontraditional occupations and changes in mine technology have combined to make mining a viable career choice for women also. To benefit from this new resource, the mining industry faces the challenge of developing a different work environment from the one now burdened with sexism. Management supported initiatives are needed to facilitate such a transformation. The same rethinking of gender attitudes might also be extended to mining women in their traditional role as ""wife of"". The assumption that the male worker&apos;s wife is an unpaid adjunct is being questioned. It is suggested that women&apos;s separate concerns both as helpmate and as part of the mining workforce should be considered when planning for mining into the 21st century.IntroductionI must confess that, during the preparation of this paper, there have been many moments when I questioned my temerity. After all, I am not male, I am not an engineer, and I have never had a position in mine management. But as the wife of a mining engineer and a long-time resident of Northern Ontario mining towns, I do have an interest in the mining industry. This interest has had little to do with the technical and management aspects of the industry. Instead my research has been concerned with the impact the mining industry has on the people involved, particularly women, whether directly as employees or indirectly as wives. As I look toward the 21st century, I believe that the whole question of gender relations in the mining industry is one of the critical management issues smouldering below the surface."

Jan 1, 1995

By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By M. Bourassa, R. del Villar, S. St. Arnaud, J. Valenzuela

"Autogenous grinding is used quite frequently for mineral comminution as a result of its lower capital and operating costs. However, it is more difficult to control than conventional grinding, particularly when the autogenous or semiautogenous mill is the only comminution stage (i.e. no secondary grinding is available). Analysis of the control strategy used then becomes extremely important, a task that is greatly simplified by the use of an empirical dynamic simulator:This paper presents the methodology used in the development and the calibration of such a simulator for the autogenous grinding circuit of an iron are concentrator: The various steps are described: industrial data acquisition, preliminary treatment of the gathered information. and empirical modelling of the process. Finally, both the actual and the proposed control strategies are compared using simulation results.This exercise has shown that the variability of some of the controlled variables could be reduced through a better handling of the water addition and the use of filters on some of the signals used for control purposes. The reduction in variability of critical variables, such as power draw, would allow their average value to be increased without the risk of exceeding their safety values. Some advanced control techniques were also tested, with interesting results."

Jan 1, 1995

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977

By Dallas Bienhoff

Boeing Study Team Participants Andrew Daga & Associates American Aerospace Advisors Hamilton Sundstrand Harris Honeywell ILC Dover Lunar Transportation Systems Oceaneering Orion Propulsion SICSA Thin Red Line USA LSSCA BAA Topic 2: MFHE Definition Minimum Functionality Habitation Element Deployable Habitat DHE Update The Path to Growth

May 1, 2013

By Lawrence Devon Smith

What is a Failed Project? For mining projects, some key indicators of a ?failed? project are: ? Cost is more than it should be (particularly capital) ? Schedule ? It takes longer to build than expected ? It takes longer to ramp-up than expected ? It does not do what it is supposed to do ? Poor performance; output, product specifications; ? Low revenue ? High costs ? No one is happy about it: Management, Shareholders, Bankers ? Does a project fail if it does not meet expectations that were unrealistic and unattainable? ? Caution: Failure may not become evident until years later

May 1, 2010

By Robert B. Parsons

"It is generally acknowledged that Canadian and foreign-based mining companies are spending relatively fewer dollars in Canada and more dollars abroad than was the case not many years ago. It is common to see the Canadian tax system being fingered as one of the causes in this shift in direction. However, if one takes the time to peel away the surface of our tax system, and to probe a little deeper into its substance, it will be found that the Canadian taxation of mining is generally quite competitive. IntroductionCross-border shopping in the mining industry? - Absolutely! Economics 100 teaches that dollars are votes in the capitalist system, and mining companies are going to cast their limited number of votes where they can achieve the highest return at the least risk. The Canadian consumer knows that taxes are a major factor in cross-border shopping, and mining company executives know that the same tenet holds true in their industry. Unfortunately, mining operations are subject to such a bewildering array of tax rules that making an intelligent decision is not always an easy matter.Statutory Tax RatesConsider, for example, the ""statutory"" tax rates shown in Table 1. (Statutory tax rate in this table refers to the simple sum of federal and provincial tax rates on profits as specified in the tax legislation.) Looking only at the total statutory tax rates (such as 66070 for Manitoba) , one might quickly observe that the Canadian mining industry is subject to a truly onerous tax regime, especially as compared to the United States where statutory tax rates can be in the 34% range."

Jan 1, 1992

By E. D. Fox

Introduction The financial statement of the hypothetical Gold Mining Company, which forms the background of this survey, was designed for the Institute with the express abject of having it assessed in respect to Profits by the several taxing bodies representing the Federal and Provincial Governments, which comprise the Dominion of Canada. On the completion of the figures, copies were sent to the several Ministers of Mines, accompanied by a request that they be submitted to their taxing authorities and assessed accordingly. The response, while it was not general, was very favourable, and at all times we were treated with the utmost courtesy and patience, and what has been set forth in the compilation bears the authentication of the various government officials who are immediately concerned with taxation. The data itself constitutes a fairly comprehensive digest of taxation as it directly applies to gold mining profits in Canada. The Hypothetical Balance-Sheet (See Exhibit A) In the balance-sheet schedules 1 and 2 (Exhibit A), income is divided between taxable and non-taxable classifications, and here it should be noted that the division contemplates only the assessment for Dominion income tax. The same applies to the factors of exchange and depletion. Therefore, in making comparisons, it is to be borne in mind that the set-up for assessment to the Provinces, that is, Manitoba and Alberta, will stand as if the gross non-operating income is taxable, with the reservations as shown in the notes below the schedules.

Jan 1, 1934

By S. Konetschnik, Lux Degel, R. Degel, T. Haslinger

UrbanGold and its partners from Mettop and SMS group have developed a novel technology for the recovery of valuables from all non-ferrous metals’ fractions of WEEE (Waste Electrical and Electronic Equipment), with a special focus on low qualities which are commonly landfilled or incinerated. The technology is marketed under the brand name “UrbanGold Flex” to illustrate the high flexibility in respect of plant design and raw material portfolio, allowing also the processing of low grade material and materials with high caloric values. The process of the technology’s centrepiece, a modified and enhanced bath smelting furnace called “HENRI”, was investigated in numerous pyrometallurgical trials as basis for a scale-up towards a capacity of up to 100,000 tons of WEEE-concentrates per year. All relevant facility components have been evaluated in respect of references, fall-back options, as well as exit strategies (alternatives) to minimize risks when establishing a novel technology. A spin-off within the development is the “UrbanGold Compact” technology which can be seen as optimization of state-of-the-art smelters by using an optimized TBRC as primary processing unit. As an UrbanGold Compact plant will be the first industrial scale reference of UrbanGold’s technologies, it is also explained in the publication. As precious metals recovery is of major (economical) importance when recycling WEEE, major attention has been given to minimize the losses of these valuables. These measures, as well as a sophisticated way of utilizing waste heat as far as possible, result in interesting business cases with gross profits of up to 20% or even more. INTRODUCTION Over the past years, the demand of electrical and electronic equipment has increased dramatically with technological progress. Innovations on the technology of electronic devices led to a shorter usage and lifespan and thus boosted the generation of Waste Electrical and Electronic Equipment (WEEE). WEEE is one of the fastest growing waste streams, growing at 3 to 4% per year worldwide and is expected to reach more than 52 million tons per year by 2021. Currently, about 45 Mt of these wastes are estimated to arise worldwide, and the trend is rising (Baldé et al., 2017).

Jan 1, 2019

By M. Jiang, X. Fan, W. X. Chen, Z. K. Guo, H. H. Zou

"Some improvements are carried out for elasto-plastic model by taking the shear dilation effects and relaxation effects of deep rocks into accounted. The high pressure equations of states with Mie-Grüneisen form are also introduced to describe the relation of pressure-volumetric strain. Numerical simulations of free field responses for deep underground explosions are conducted by using the user subroutines which compiled by means of the secondary development functions of LS-DYNA9703D codes. It is indicated that the dynamic responses of free field are well simulated based on this improved elasto-plastic model, and the analytical results are in good agreement with the data of U.S. Hardhat nuclear test.INTRODUCTIONDynamic behaviors of deep rocks for underground explosions are obviously different from that of shallow underground explosions and have aroused great attentions of international experts who work for rock engineering. The dynamic models of deep rocks could be roughly divided into classic elasto-plastic model and fracture damage model according to different theoretical foundation. M. E.Kipp and D. E.Grady et al. are the outstanding representatives who engaged in the researches of fracture damage mechanics. Researches of dynamic problems for geomaterials were carried out by C.C.Grigorian and the conclusion that incompressible elasto-plastic medium model could not be used to solve the problems of closed underground explosion was derived, and therefore C.C.Grigorian model was proposed. In this model, C.C.Grigorian assumed that the average hydrostatic pressures and the densities of medium had one to one relationship, and the path of loading or unloading is different from each other. For shear deformations, analytical solutions of the problems were derived according to the model which was slightly different from Prandtl-Reuss model, the constitutive equations were closed by Mises-Schleiher constitutive model. However, the analysis showed that there were two inadequacies in C.C.Grigorian model. Firstly, the shear dilation effects of fractured medium after wave front could not be considered. Secondly, the relaxation characteristics of the rocks in fractured region were not taken into account."

Jan 1, 2015

By Xianglin Yang, Hong Zhong, Jingjing Xiao, Guangyi Liu

"The selective adsorption of a flotation collector to a mineral plays a crucial role in enhancing the hydrophobicity of targeted mineral particles for attaching air bubbles in pulp. The recent progress of the structure-reactivity relationship of flotation collectors, the characterization methods for mineral surfaces with adsorbed collectors and their commercial application are reviewed in this paper. Particular emphasis is placed on the density functional theory (DFT) for understanding the reactivity of new collectors, the surface analysis techniques including time-of-flight secondary ion mass spectrometry (ToF-SIMS), in situ scanning electrochemical microscopy (SECM) and atomic force microscope (AFM) to characterize mineral/collector interface, and the flotation technologies for optimizing recovery of valuable minerals. Especially, the recently developing collectors such as Gemini, alkoxyalkylthiourea, dithiourea, amide-hydroxamate and oximido-thiol surfactants, and their specificity to given minerals are evaluated. Based on this crucial review, it is evident that the structural modification approaches for minerophilic or hydrophobic groups, and combined surface analysis approach for further understanding the adsorption mechanism of collectors on mineral surfaces will lay a solid foundation for the future development of flotation collectors. INTRODUCTIONIn mineral processing, flotation is the main process for separation and recovery of valuable minerals from the ores contained them (Fuerstenau et al., 2007). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by collector adsorption so that these mineral particles can preferably attach to air bubbles in a slurry or pulp (Fuerstenau et al., 2007). Flotation collector is a kind of functional surfactant, which is composed of polar and non-polar groups (Somasundaran, & Wang, 2006). Non-polar portion, commonly being linear, branch or ring hydrocarbon group, is termed hydrophobic group. The polar portion, exhibiting strong affinity to mineral surfaces, is known as minerophilic group (Nagaraj, 1988). According to mineral types including saline, oxide and sulfide minerals, flotation collector divides into sulfide and oxide mineral collectors. For efficient recovery of valuable minerals from the refractory complex ores, insights into the adsorption mechanism, hydrophobic model and subsequent flotation approach of flotation collectors have been regarded as an indispensable issue in mineral processing."

Jan 1, 2016

By Nicolas Gatelier, Sophie Laurent, Thierry You

Hard-rock caverns for hydrocarbon storage are a very particular type of underground facility controlled not only by local administrative and regulatory constraints that can be very specific, but also by the possible risks of geotechnical or geomechanical failure. Each such facility throughout the world is a prototype that needs to be adapted to very different site conditions. The straight forward application of design methodologies from relatively similar fields (mines, tunnels) can be very useful, but risks holding back the scientific and technical improvements needed by an engineering industry in full development. Here we look at various case histories and at problems that have been raised where recent attempts at standardization would appear to have been ill adapted, and where storage designers, through experience and judgment, may still provide innovative engineering solutions.

Jan 1, 2015

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014