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By Rod Maclean, George Stewart

"This paper covers the planning, development, and mining of an underground pillar complex using a bulk mining method. To achieve the long-term goal of continually improving our operating processes, all cut-and-fill and undercut-and-fill workplaces at Thompson Mine have been evaluated for their conversion potential to the bulk method referred to as VerticalBlock Mining (V.B.M.).Since December 1979, conversion has occurred to the extent where 80% of the ore hoisted is mined using Vertical Block Mining (V.B.M.).Productivity and profitability have been substantially improved by converting to this bulk method, especially in pillar areas.IntroductionThompson Mine is a 6000 ton per day underground nickel mine located 3 miles outside the City of Thompson, 400 air miles north of Winnipeg . The mine has two shafts, T-l and T-3 (Fig. 1). The T-l shaft is 4427 feet deep with the deepest mining taking place on 4000 level. The T-3 shaft, which is the area of this presentation, extends to a depth of 2607 ft with the deepest operating level at 2400 ft. The two shafts, some 10 000 ft apart, are connected underground on numerous levels. The ore mined at T-3 is trammed on 2400 level to the T-I main ore pass and hoisted through the T-l shaft. Eight hundred and fifty thousand cubic feet of fresh air per minute ventilates the mine.The 1400 level 310 pillar complex is located in the T-3 mine area. There are six rib pillars, two crown pillars and one main pillar (boundary pillar between cut-and-fill stopes) within the complex (Fig. 2). The majority of the ore in this area has been mined using mechanized cut-and-fill techniques .Undercut-and-fill mining was the method originally planned to recover these pillars. It is slow, labour-intensive, and requires extensive use of timber during the mining cycle. The extraction drifts in the area are heavily timbered due to their proximity to the ore and the age of the facilities. Increasing drift maintenance costs and the successful mining of two main pillars with V.8.M. techniques provided the stimulus to review the mining plans for this area."

Jan 1, 1988

By R. Blazej

Machinery Systems Division (MSD) in the Institute of Mining Engineering at Wroclaw University of Technology specializes in belt conveying systems analyzing, calculating and design. Within the division operates the certified Laboratory of Belt Transportation (LTT) and Laboratory of Rollers. Since few years, a group of several people have begun work on developing a comprehensive system for the automatic evaluation of condition of conveyor belts working in the mines. Group uses both magnetic devices developed by specialized companies servicing belts and its own machine vision system developed for assessment of belts covers and edges during belt movement (up to 7 m / s) on the specially designed for this purpose the test conveyor. Recently they have got the research grant funded by the National Centre for Research and Development (NCBiR) for development of the system for automatic diagnosing of conveyor belts? condition and aiding of rational belt management. On the basis of previously created diagnostic tool called ABCDE (Automatic Belt Condition Diagnostic Equipment) the five modules: vision-A magnetic-B, preventive-C, forecasting?D, and determining safety factor-E will be developed. They will automatically interpret data about conveyor belts? condition to indicate the extent and timing of repairs, to prevent failures and to select the optimum moments for their replacements. The system will use results of ongoing research & development and planned research concerning modeling of belt wear using evolutionary genetic algorithms. The reached stage of research can not yet allow to start the implementation work by potential users. It is therefore necessary to pursuit research in real scale, the development of new modules (C-E) and intensive testing of the system in working condition with system calibration to optimize the economic effects.

Aug 1, 2013

By Linda Dufour

"Autoclaves have been in commercial use in the mining industry since the early 1950's the initial applications included tin, uranium, cobalt, nickel and copper extraction under both acidic and alkaline conditions. These circuits varied in batch or continuous operation. The geometry has been spherical, vertical, and horizontal type with up to six agitators, with throughput as high as 1000 stpd.Presently autoclaves are a good process selection for many refractory sulphide gold bearing ores. The first application of pressure oxidation in the gold industry was at the Homestake Mcglaughlin's Mine which was commissioned in 1985. This was an acidic pressure oxidation process treating 3000 stpd in three four compartment horizontal autoclaves 14' diameter and 53' long. Since the initiation of autoclaves for the treatment of gold bearing sulphides, there are presently 16 gold autoclaves operating worldwide varying in size up to 18'4"" inside diameter. There are seven autoclaves for the treatment of refractory sulphide gold bearing ores to be commissioned in 1997 and 1998.Autoclave technology has progressed extensively since the mid-eighties. Operational experience has made rapid progress and the result is much smoother and safer autoclave operation. There have been many advances in autoclave technology design. For example, the use of exotic materials for corrosion resistance to reduce down time for maintenance. The instrumentation involved in autoclave operation is very sophisticated which allows for many safety features. The advanced design has allowed for greater availability and as a result operating costs and maintenance costs have decreased. These technological advancements have made autoclave technology more safe and this has resulted in a greater acceptance of this type of operation. Many of the gold autoclave facilities operate up to 9 months continuously without shutdowns. The advancement of autoclave technology has inspired many new applications.Because of the outstanding operation of autoclaves in the gold industry, many other applications for autoclave technology are being considered. The following is a list of autoclave applications:"

Jan 1, 1997

By G. Ellie, D. F. Coates

"The mining of coal in thick and inclined seams is difficult, and there are only a few countries in the world that are really interested in the problems associated with their exploitation. In France a considerable amount of investment has been made in the mechanization of systems appropriate for such conditions.For seams inclined up to 50 degrees, of normal thickness, a new system was introduced in 1967. It consists of a longwall advancing to the rise with walking props, a shearer and hydraulic backfill. During the first two years the panel productivity was an average of 25 TN/MS, and they foresee the possibility of reaching an average of 30 TN/MS.A system for thick beds, both horizontal and inclined, is in p•rocess of being mechanized. In 1969 they started with a method consisting of a longwall in a footwall slice, or sub-level drifts with walking props, and caving and drawing up to a height of 20 m of coal. Recent experiments with a shearer have produced panel productivities between 9 and 11 TN /MS, and there is hope that with experience an average of 16 TN/MS will be obtained.In 1964 a method was initiated for beds inclined from 60 to 90 degrees, based on a mechanical cutter designed by the collieries in Lorraine. An overhand slice of 4.2 m in height is taken with a drum cutter mounted on the end of a boom. Hydraulic fill is placed at the completion of a slice. The face productivity, which has been from 13-20 TN /MS, can be perhaps increased to an average of 22 TN/MS. For those companies with important reserves in inclined and thick seams, these French systems may be worth the trouble of examining in some detail."

Jan 1, 1972

By Gennaro Delisle

"Les Services TMG (Niobec) currently treat a niobium ore in the Chicoutimi area of Quebec. The mineral pyrochlore is present in a carbonatite deposit which assays 5% to 7% apatite.The ore is ground to minus 65 mesh and deslimed at 10 micrometres. Part of the carbonates are floated with a fatty acid emulsion and rejected to the tailings as a first step to ensure the proper conditions for the flotation of the pyrochlore concentrate. The carbonate concentrate is 65% minus 44 micrometres and is composed of dolomite, calcite, 22% apatite and a minor amount of silicates.A laboratory investigation was undertaken to determine the feasibility of extracting apatite from the carbonate concentrate. This led to the development of an economic flowsheet to produce high-grade apatite concentrate. The apatite is depressed with phosphoric acid, and the pH is adjusted at 4.8-5.0 with sulphuric acid. An additional amount of fatty acid is added to permit efficient flotation of the carbonates. 1n a second stage, the silicates left behind with the apatite concentrate can be removed by depressing the apatite with AIC3 while floating the silicates with a secondary amine.The results of the laboratory tests indicate the possibility of producing an apatite concentrate assaying 38.3% P2O5 (83.7% BPL) with a recovery of 66.2%. Pilot-plant tests undertaken at the concentrator yielded a concentrate of 34% P205 and recovery of 76%."

Jan 1, 1981

By Mohammad Mehdi Salarirad

Fouling of activated carbon by different organic species is a great concern in carbon in pulp and carbon in leach circuits. The rate of gold adsorption onto activated carbon from synthetic gold solutions which contained different amounts of potassium ethyl xanthate (PEX), potassium isobutyl xanthate (PIBX), and methyl isobutyl carbinol (MIBC) were evaluated through batch adsorption tests. The results of these experiments showed that the gold sorption rate rapidly decreases by increasing the concentration of collectors including PIBX and PEX up to 20 mg/L and at higher concentrations, the kinetic rate constant (i.e., k value) gradually leveled off to 53 h-1 for PIBX, which is 46% lower than the 99 h-1 for PEX. At low concentrations of up to 15 mg/L of MIBC, a gradual decrease of the rate constant was observed, while at higher concentrations, the decrease was found to be more pronounced. The gold loading capacity and the rate of gold adsorption onto activated carbon from a gold cyanidation pulp in the presence of flotation reagents were also evaluated. The results of these experiments showed that the flotation reagents have no significant effect on the gold loading capacity of activated carbon at prolong adsorption period, meanwhile the rate of gold adsorption continuously decreases by increasing the concentration of flotation reagents in the leaching solution.

Oct 1, 2011

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By L. Li

To accommodate the large payloads and harsh operating conditions associated with heavy vehicles in the mining industry, off-the-road (OTR) tires are typically used with heavy mining vehicles. These tires have increased abrasion and wear resistance due to their thicker tread, sidewall and bead thicknesses. Given these features, OTR tires are much stiffer than conventional passenger vehicle tires and cannot be mounted to a single-piece rim without damaging the structural integrity of the tire during the mounting process. Therefore, multi-piece wheels are used with OTR tires to facilitate mounting. While these assemblies are necessary, several instances of their failure have been reported to result in injuries or fatalities within the mining workplace. Many of these failures were specifically reported to be caused by the disengagement of the wheel lock ring - a component used to securely engage the assembly during operation. In this study, a threaded-connection locking mechanism has been proposed in place of the traditional lock ring design. The performance of this threaded-connection was numerically evaluated in a pull-out test against a conventional five-piece wheel assembly. The pull-out test was devised as a means of quantifying the engagement ability of each wheel?s locking mechanism. A high degree of modelling accuracy was maintained throughout the analysis by validating the vertical and horizontal static loaddeflection behaviour of the rim model of the five-piece wheel assembly against experimental data. Through validation, the model data were found to be within 10.5 and 4.80 %, for vertical and lateral loaddeflection behaviour, respectively. Results from the pull-out analysis found that the threaded-connection demonstrated a 113 % increase in the force required for disengagement to occur relative to the conventional five-piece design - a force of 9,550 kN in total.

Aug 1, 2013

By Tracey Bodnarchuk, Philipp Mirzoev

Sulfate balance control is a common problem for zinc plants. Roast-leach-electrowin plants are mostly concerned with the over-generation of sulfates while for the HudBay direct leach plant both extremes are possible including potential necessity to buy sulfuric acid to replenish a sulfate-depleted circuit, which makes the problem doubly important. Quantitative methods were applied at the HudBay plant to analyze sulfate generation/depletion based on a local sulfur balance and sulfate extraction calculation in the leach circuit, using a Pb-tie method. Main factors were established influencing sulfate generation/depletion, including the critical role of Pb and pyrite. Regression analysis proved to be effective and allowed the quantitative prediction of Pb concentrations necessary to reach the equilibrium for the sulfate balance. This in turn provided a firm basis for a sulfate-control strategy realized through concentrate blend correction, which allowed the plant to fine-tune sulfate generation/depletion effectively reducing economic consequences of excessive/deficient sulfate generation.

Jan 1, 2015

By Mauro Chiesa

A. New Dictionary, Since 2007/8 Traditional concept of ?cycle? is dead A dearth of projects AND good metal prices suggests otherwise In a depletion-business, good times for any greenfields in 2-3 yrs! ?Balance? sheet means quality assets = quality capital So, de-risk the assets, and ration the capital ?Replacement costs > historical costs ?Discounted assets depleting; replacement costs need self-financing (FCF) ?Public-sector slows permits, avoids assets and wants more of FCF ?Capital ?markets? are now ?market fragments? ..and? ??Shareholder? has changed from ?growth? to ?income + performance? ?Higher search costs, higher capital costs and higher cost of capital

May 1, 2013

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By D. Chakravarty, D. Dutta, B. Samanta, S. Patteti

"This paper presents the mixed spectral behaviour of iron ores from deposits in Gua, India. Spectral signatures of powder samples and their two-component mixtures were generated by spectro - radiometry. Spectra were divided into continuum and absorption components. A modified Gaussian model was used to extract subtle features from the absorption components of the spectra. A linear unmixing model (LUM) applied to estimate minerals from the spectra of mixed powder samples indicated that this model achieved an R2 value of 0.88. The LUM was then applied to estimate the abundance of ores from a hyperspectral satellite image of the deposit area.RÉSUMÉ Le présent article montre le comportement spectral mixte de minerais de fer de gisements à Gua, en Inde. Les signatures spectrales d’échantillons de poudres et leurs mélanges à deux composantes ont été générés par spectroradiométrie. Les spectres ont été divisés en composantes de continuum et d’absorption. Un modèle gaussien modifié a été utilisé pour extraire des caractéristiques subtiles des composantes d’absorption des spectres. Un modèle de démélange linéaire, appliqué pour estimer les minéraux dans le spectre des échantillons de poudres mixtes, indique que ce modèle a atteint une valeur R2 de 0,88. Le modèle de démélange linéaire a ensuite été appliqué pour estimer la quantité de minerai à partir d’une image satellite hyperspectrale du secteur du gisement."

Jan 1, 2015

By Unknown

We are indebted to the Consolidated Mining and Smelting Company of Canada Limited for the several pictures in this issue showing the progress made in new construction at Tadanac and at Bonnington Falls, B.C. Plate No. 1 shows the down-stream side of the No. 1 hydro-electric station of the West Kootenay Power and Light Co. Limited at Bonnington Falls, on the Kootenay river, at which 17,500 k.v.a. will be developed to meet the requirements of the enlarged zinc and lead refineries at Tadanac. The generators, exciters and switch apparatus were supplied by the Canadian General Electric Company and the step-up transformers by the Canadian Westinghouse Company Limited. The plant throughout was designed, manufactured and erected by Canadians. Plate No. 2 shows the casting room of the new lead-plant and plate No. 3 the new tank-room of the electrolytic lead refinery at Tadanac. These additions will increase the capacity of the lead refinery by some 150 tons daily. The extensions also include practically doubling the zinc plant, and the gold and silver refineries. With the exception of the new stack, all designing construction and installation of the various plants is being done by the Company's own employees at Tadanac. Plate No. 4 shows the progress made in the construction of the new reinforced concrete stack at Tadanac. This stack, of 21 feet inside diameter at the top, will be brick lined and when completed will rise 400 feet above its foundations: the tallest of its kind in the world. The construction is in charge of the Rust Engineering Company of Pittsburgh, Pa. Plate No. 5 is a panorama of the Tadanac smelters and refineries. The photograph was taken from the roof of the lead smelter and gives an excellent idea of the size of the plant and its surroundings. Tadanac produces electrolytic lead, zinc and copper and fine gold and silver. During 1924 the company treated 1,333,523 tons of ore and produced: 161,400,- 769 pounds of lead; 92,197,824 pounds of zinc; l,382,750pounds of copper; 4,074,044 ounces of silver, and 26,976 ounces of gold.

Jan 1, 1925

By W. Holdsworth

The flotation mill of Dentonia Mines, Limited, at Greenwood, B.C., went into operation on April 20th, 1934, and by October 11th a total of 15,000 tons of ore had been treated. It is intended in this paper to describe briefly the operation and to give some of the operating data which have been gathered. The metallic minerals in the Dentonia ore are pyrite, chalcopyrite, galena, and, occasionally, native gold, and the gangue includes chloritic material, vein quartz, and calcite. Pyrite makes up about 90 per cent of the metallic content of the ore, in which it is disseminated as irregular grains and well-formed cubes. An average analysis of the ore is: gold, 0.27 oz. per ton; silver, 1.73 oz. per ton; copper, 0.12 per cent; lead, 0.31 per cent; and zinc, trace. From the mine ore-bin, situated near the portal of the tunnel at the mine, the ore is hauled by motor truck to the mill, a distance of three-quarters of a mile, and there dumped into the receiving bin, which has a capacity of fifty tons. The hauling is done during one eight-hour shift, commencing at 7 a.m. The maximum size of the ore fed to the mill-bin is ten inches. Lumps larger than this are broken by sledge hammer to pass through grizzly bars, spaced ten inches apart, installed above the bin. The ore is drawn from the bin by a 30-inch, 6-ply conveyor belt, 18 feet 6 inches long. In the near future, when the cross-cut tunnel is completed, the ore will be trammed to the receiving bin. This will effect a considerable saving in cost. At the same time, the bin will be set back several feet, so that the length of the conveyor belt may be doubled. This will make efficient ore-sorting possible, and so ensure a minimum of waste rock in the mill feed.

Jan 1, 1935

By P. R. A. Andrews

"Areas of bubble contact were delineated for cassiterite in the presence of chloride, fluoride, sulphate, phosphate, oxalate and citrate ions using dodecylamine hydrochloride collector. The limits of pH, and the minimum collector concentration were established using the bubble pick-up technique.Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 4.7, in the presence of chloride ion, and fluoride ion showed only a weak response in the same pH range. These anions are considered to act as indifferent electrolytes. Activation at pH values below the p.z.c. was obtained with sulphate, phosphate, oxalate and citrate ions; the greatest response was by oxalate and phosphate ions extending pick-up to between pH 2.0 and 2.5.Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to the formation of very stable metal ion species, thought to be formed on the surface of cassiterite, between exposed stannic ions and modifying anions; dodecylammonium ions being absorbed on the surface so modified."

Jan 1, 1991

By W. A. Crosby, W. K. Smith, K. L. McDonald

"IntroductionThis paper describes how the introduction of two blasting techniques and the resuItant development of new dragline digging methods have increased the productivity of single- and double-seam dragline operations at the Rietspruit opencast mine.LocationRietspruit , one of South Africa's largest opencast strip mines, is situated some 11 5 kilometres east of Johannesburg in the Witbank coal field.BusinessRietspruit is a joint venture between Transvaal Consolidate d Land and Exploration Company (T.C.L.) and Shell, South Africa. Rietspruit is administered and managed by Rand Mines, the Mining division of Barlow Rand, transportation and marketing being the responsibility of Shell. The total saleable coal product, approximately 5,5 million tons per annum, is exported via Richards Bay.Presplitting and Throw BlastingPresplitting was initially introduced in September 1980, as a means of dewatering t he overburden and mid burden to facilitate the use of dry-mix explosives a s opposed to slurry explosives.The utilization of the throw blasting technique arose as a direct result of observed ground movement after the successful introduction of presplitting. The first trials commenced in March 1981 on the double-seam operation. The methods, economics and resulting advantages are fully described elsewhere. A brief description follows.Method of PresplittingAfter determining the desired presplit line, 250-mm holes are drilled to top of coal at 4-m to 6-m intervals, dependent on the competency of the rock overlying the coal. A single 60-kg charge of slurry explosives is located at the bottom of each hole, no tamping is used and all the holes are detonated simultaneously. The results are a competent, straight, vertical highwall. This enables accurate control of the first row of blast holes closest to the highwall, which is a prime requisite for successful throw blasting."

Jan 1, 1983

By Ron Jessulat

"IntroductionBrunswick Mining and Smelting Corp. Ltd. is a IO 500 tid base metal producer. Development is carried out by Jarvis Clark MJM-21 3-boom development jumbos, using Tamrock E400, 410 and 550 pneumatic drills. Typical drift size is 13 ft by 18 ft with a 12-ft advance per round. Blast holes are 1 ½ in. in diameter while reamed holes are 3 in. in diameter. AN/FO is the principal blasting agent, being loaded by C-I-L model60R intermediate loader. The detonators are NONELS and DETINELS. Sulphide dust explosions occur during blasting when dusts from certain minerals such as pyrite and pyrrhotite are ignited by name from the detonating shots. The result is a secondary unwanted explosion with a characteristic shock wave and name front that are very destructive to mine services such as ventilation ducting, electrical cable, and ventilation control doors.A typical reaction in the Brunswick orebody occurs according to the chemical formula:4FeS 2 + IIOs-2Fe2O3 + 8SO2 + 3458--(Enright , 1988)The hematite (FeO3) is deposited as a red dust in the blast area while the toxic sulphur dioxide gas (S00 contaminates the underground workings . The presence of S02 gas disrupts production until it is purged from the area by the mine ventilation system or dissipates slowly in those areas where the vent ducting has been melted by the name front or torn down by the shock wave.Sulphide dust explosions exact a high economic toll. Direct costs in damaged materials and wages are probably exceeded by the value of lost production and disruption to the mining cycle. In addition, the health and safety concerns associated with sulphide dust explosions cannot be ignored."

Jan 1, 1993

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By Weiren Lin

The Mw 9.0 Tohoku-Oki, Japan earthquake occurred on 11 March 2011 produced a maximum coseismic slip of >50 m near the Japan Trench. To investigate why the plate boundary fault between the subducting Pacific Plate and overriding North American Plate which caused the earthquake had such unprecedented large coseismic displacement and slipped to the trench, Integrated Ocean Drilling Program Expedition 343 called Japan Trench Fast Drilling Project (JFAST) drilled three boreholes at Site C0019 through the earthquake fault about one year after the earthquake. Borehole C0019B dedicated to loggingwhile- drilling (LWD) penetrated ~850 meters below seafloor (mbsf) at a water depth of approximately 6890 m. The plate boundary fault is located at ~820 mbsf in the borehole and has been identified as the slip zone during the Tohoku-Oki earthquake. Borehole wall resistivity images obtained from LWD show that drilling induced borehole breakouts are available in a wide depth range above the fault but are not available below the fault. Breakouts are reliable indicators of the orientations of current maximum and minimum horizontal stresses and can also be used to constrain the horizontal maximum and minimum stress magnitudes. As results of breakout analyses, the maximum horizontal stress orientation highly varied in the upper part of the borehole, but has a clear preferred orientation in a northwest – southeast direction in the deeper part just above the fault. This orientation is approximately parallel to the direction of the Pacific Plate subduction. Stress magnitude constraints indicate that the post-earthquake stress states in the hanging wall are either in or close to the normal faulting stress regime. By inferring the pre-earthquake stress state and comparing with the constrained post-earthquake stress state, a significant coseismic stress change was interpreted. The stress change suggests an active slip of the frontal plate-interface consistent with coseismic fault weakening and a nearly total stress drop.

Jan 1, 2015

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018