Search Documents

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012

By J. Keith Haddock

"IntroductionThe Bienfait Mine is operated by Bienfait Coal Company Ltd., one of the Luscar Limited group of companies. Situated 5 km southeast of the town of Bienfait, Saskatchewan, it can produce 2.0 million tonnes of lignite annually in addition to 158,000 tonnes of char from a carbonization plant located on the property. Geology The economically mineable coal seams of the Estevan area are found in the Ravenscrag Formation. The lignite-bearing sands, silts and clays were deposited in Early Tertiary age, in an inland sea centred in the Williston Basin of North Dakota. The top of the Ravenscrag is an erosional surface, overlain by Tertiary or Quarternary sands and gravels or glacial till. The regional structure is a gently plunging syncline which dips to the southeast at about 0.3 degrees. There are minor undulations in the Bienfait area which are due to differential subsidence during deposition. Sporadic faulting is probably a result of glacial pressures, and preglacial and glacial channels are responsible for washout zones and the abrupt irregular subcrop found in the area. There are two economic coal seams in the Bienfait area, an uppe; seam locally known as the Roche Percee, and a lower seam, the Estevan. Both seams have been extensively mined since lignite mining began in the area in the late 1800s. The Roche Percee remains only in a small portion of the Bienfait Mine and comprises a very minor portion of the reserves. It averages 1.74 m thick under 8.1 m of overburden. The till rests on top of the Roche Percee and due to weathering the seam is generally of poorer quality. The Estevan seam comprises the majority of reserves at Bienfait. The main seam which is being worked on consists of an upper bench averaging 2.75 m, a carbonaceous parting of 0.21 m, and a lower bench of 0.92 m. Overburden depth above this seam varies from 21.0 m to 38.0 m."

Jan 1, 1985

By David Berberick

"Hecla Limited’s No. 4 Shaft at the Lucky Friday Mine is the largest capital expenditure in the corporation’s 128-year history and is considered the deepest shaft in the United States. This paper will discuss the project’s history and lessons learned from the initial conceptual design work in 2007 through project commissioning in 2017. Change management was key for the owner, contractors, and vendors in delivering the operational and organizational success on the project. The No. 4 Shaft has extended the life of the Lucky Friday Mine by 21 years to 2039. INTRODUCTION The Lucky Friday Mine of Hecla Mining Company (Figure 1) is the oldest active (77 years) and deepest mine in the Coeur d’Alene mining district, producing approximately 725 tonnes (800 tons) per day from narrow, vertical, silver, lead, and zinc veins. Primary access into the mine is via the Silver Shaft, a 5.5-m (18-ft) diameter, concrete lined shaft sunk to an original depth of 1,890-m (6,200-ft). Current production is from the Gold Hunter vein system, approximately 1,525-m (5,000-ft) northwest of the Silver Shaft.Cut and fill stoping is currently employed at depths to 2.3 km (7,500 ft) below ground surface, making it one of the deepest mines in the western hemisphere. No. 4 Shaft is a 5.5-metre (18-foot) diameter, concrete lined circular shaft, constructed as a 1.2 km (3,860 feet) deep winze in the Lucky Friday Mine. The 2.4 m (8 ft.) diameter, double drum, double clutch, Siemag hoist and associated headworks are situated at the 4760 level, top station at 4940 and shaft stations at 5900, 6500, 6580, 7500, 7580, 8300, 8380, 8500, and 8620. Shaft stations reference depth below Silver Shaft top station. The 4 Shaft was designed, constructed and commissioned over ten years, between 2007 and 2017. Basic design work was completed by Nordmin Engineering, followed by detailed design completed by Cementation Canada. Shaft construction was awarded to Cementation USA and lateral development was initiated in early 2008. Over the course of the next nine years, the project was suspended and restarted twice, dealt with the loss of a miner, added scope including shaft depth and mine infrastructure facilities, experienced squeezing ground that required liner replacement, changed excavation section, and dealt with a final alignment that was not within design requirement for verticality. Hecla and Cementation were successful in delivering a facility that provides fully functional access from collar at 4940 level to shaft bottom at the 8620 level. Two active mining levels below the collar, 5900 and 6500 are accessed. In addition, the shaft provides access to the future mining level at 7500, skip loading facility at 7580 level, station and loading pocket cutouts at 8300 and 8380 levels, spill pocket at 8500 level, and shaft bottom pumping facility at 8620 level (Figure 2)."

Jan 1, 2019

By S. X. Shi, M. Tan, Y. Q. Li, D. F. Han, Z. B. Han

Bauxite resources in China are mainly diaspore ore with the characteristics of low ratio silicon to aluminum. In order to obtain high quality of alumina product, flotation process is generally used to extract the aluminum from diaspore ore. Small aeration rate is needed for bauxite flotation, which requires air to be controlled accuracy. In addition, productive froth from bauxite flotation is too sticky to effects froth transportation. Air-forced XCF/KYF flotation machines are helpful for aeration control, while self-suction GF flotation machines benefits froth transportation. Zhongzhou aluminum plant of China Aluminum Group (Chinalco) uses 7 series of XCF/KYF /GF combined flotation machines to process bauxite. Air distribution, suspension characteristics, froth flow velocity and Al2O3 recovery were investigated, to evaluate the performance of flotation machines in one series and determine recovery contribution of each cell to the entire flotation circuit.The air distribution degree varies from 3 to 4, which is enough for bauxite floatation process. Froth in the tank could flow smoothly with a flow velocity of 2.4m/min. The recovery of the first KYF-40 flotation cell is the largest. Flotation concentrate of Al2O3 is up to 64.29%, the total recovery is about 75%, and the ratio of Al/Si has reached 10.4.

Jan 1, 2015

Phelps Dodge has recently operated a commercial scale, super fine grinding circuit of copper concentrates for use in a medium-temperature pressure leaching process. Two 355 kW vertical stirred mills were installed in series, targeting a grind of 80% passing 7.5 µm and 98% passing 15 µm as outlined in Phelps Dodge's concentrate leaching patent portfolio. This paper details the operation and results of the test program at Bag dad, as well as some of the operating challenges encountered.

Jan 1, 2007

By Rosie Moore, Harvey Keats, Kerry Sparkes, A. J. Naldrett

"Abstract-The Voisey’s Bay Ni-Cu-Co deposit was discovered in late 1994 as the result of prospecting initiated in the summer of 1993. By July 1995, proven mineable reserves were 31.7 x 106 tonnes grading 2.83% Ni, 1.68% Cu and 0.12% Co, and current total resources in all categories are quoted to be in the order of 150 X 106 tonnes. The deposit is associated with a body of troctolite belonging to the Nain Anorthosite (1.35 Ga - 1.29 Ga) suite, which was emplaced across the boundary between the Proterozoic "Rae" Province to the west and Archean "Nain" Province to the east.The deposit can be described in terms of three geological settings. The "Ovoid" is a 600 m long by 350 m wide by 100 m deep lens of massive sulfide, covered by 10 m to 20 m of glacial overburden, and separated from the underlying country rock quartz-plagioclase-biotite gneiss by a breccia of gneissic fragments in troctolite known as the Basal Breccia Sequence. To the west of the Ovoid lies the "Western Extension", comprising disseminated and massive sulfides in a north-dipping sheet of troctolite which ranges from upper unmineralized troctolite down through troctolite with increasing amounts of sulfide (up to 50%), to massive sulfide (in some places only), and then to Basal Breccia Sequence. East of the Ovoid, the troctolite sheet broadens out into a troctolite intrusion, within which occurs the "Eastern Deeps", a zone of massive and disseminated sulfide up to 100 m thick that is currently being explored. The mineralization of the Eastern Deeps lies along the line of intersection of a feeder sheet with the base of the intrusion. The current interpretation is that the three geological environments represent different erosional levels through a single mineralized intrusion. In this model, the deepest erosional level lies to the west and exposes the feeder to surface, whereas the Ovoid represents the base of the intrusion at surface, and the Eastern Deeps the base of the intrusion overlain by 600 m to 900 m of troctolite. Sulfides and gneissic fragments were brought up by magma flowing quickly through the feeder, and settled out where the flow rate decreased as the sulfide-bearing magma mixed with magma already emplaced in the intrusive body."

Jan 1, 1996

By J. M. Mwase

The platinum group metal (PGM) industry is currently reliant on the crush-mill-float-smelt-refine route to process PGM ores. However, there are many instances where this route would not be feasible. An alternative process route has been developed which involves heap bioleaching to extract base metals followed by heap reclamation and a water wash step, leading into heap cyanide leaching to extract precious metals. This process was evaluated through test work on samples of Platreef ore using laboratory scale columns. After 304 days 75% Ni and 93% Cu were extracted in the bioleach experiment at 65°C, and after 60 days 58% Pt, 99% Pd and 90% Au in the follow-up cyanide leach experiment at 50°C. A preliminary process flow sheet has been developed around this. Analysis via a mineral liberation analyser showed that the remaining Pt was in the form of the mineral sperrylite, which appeared to be slow leaching in cyanide in comparison to the other mineral types. Analysis of cyanide effluent solution showed high levels of thiocyanate, which present an environmental risk for disposal and high consumption of cyanide. Further studies to develop the process for commercial application in the South African PGM industry are outlined.

Jan 1, 2014

By G. W. Toop

"The Cominco smeller in Trail, British Columbia, is a large integrated lead-zinc production facility. In the plant description, emphasis is given to the pyrometallurgical operations including zinc concentrate roasting, lead singer-blast furnace processing and silver refining. Production figures for the main metal products - zinc, lead, silver and gold - are provided.IntroductionIncorporated in 1906, Cominco Ltd. is an integrated natural resource company with principal activities in mining, smelting and refining, mineral exploration, fertilizer production and electrical power generation.Cominco is one of the world's largest producers of zinc and lead, accoW1ting for about 10070 of mine production in the western world. The company also produces and sells copper concentrate, copper sulphate, copper arsenate, sodium antirnonate, silver, gold, cadmium, bismuth, indium, and germanium dioxide and a range of fertilizers and sulphur products.Zinc OperationsRoastingThe roasters currently treat about 1400 t/d of zinc concentrates. Over half of the total concentrate treated originates from the Red Dog Mine in Alaska. During the summer, concentrate is shipped from Alaska to Vancouver where it is loaded into rail cars and hauled inland, transferred to trucks and delivered to Trail. The remainder of the roaster feed is made up of Sullivan concentrate and various custom concentrates. These arrive either by train or by truck.There are three roasters available for roasting the concentrate. The two major roasters are Lurgi fluid bed units. Each Lurgi roaster can process concentrate at about 1:7 tonnes per hour (tlb). A smaller Cominco suspension roaster with a capacity of 10 tlb is also used. The flowsheet for the high temperature section of the fluid bed circuit is shown in Figure 1.Concentrates fed to fluid bed roasting are conditioned with 7 1/min water to give 8% moisture in feed. Two slinger belts throw the mixture into the fluidized bed. The fluid bed roasters are 10.4 m in diameter with a bed depth of 1 m. Grate area is 84 m2• Normal operating conditions include bed temperatures of 930°C to 950°C, fluidizing air at 750 Nm3/min and a wind box pressure of 2000 mm H2O."

Jan 1, 1994

By E. Essadiqi, P. Poruks, D. Boyd, D. Emadi, I. Yakubtsov, T. Turi

This paper reviews the results of an extensive study of microstructures and mechanical properties in bainitic linepipe steels. The research was carried out as a collaborative project between Queen's, Stelco and CANMET. Basic studies of phase transformations and mechanical properties in these steels established important relationships between processing schedule and microstructure evolution, and between final microstructure and mechanical properties. The best combination of strength and toughness properties is obtained with a microstructure comprising a matrix of intragranularly-nucleated bainite (`acicular ferrite - AF') and small (~ 0.5 µm) dispersed particles of martensite (`M/A'). We describe this as a dual-phase AF+M/A microstructure. An experimental study on 15-mm thick plate determined the window of steel composition and processing parameters which gives the dual phase AF+M/A microstructure. The minimum strength and toughness properties for Grade 621 (X90) linepipe steel can be achieved by either a lean steel composition (0.04C-1.77Mn-0.04Cr¬0.32Mo-0.31Ni-0.29Cu-0.08Nb) with extreme processing parameters, or by a higher alloy composition (0.04C-2.07Mn-0.50Cr-0.51Mo-0.04Nb) with a more industrially realistic processing schedule. It is proposed how this approach could be extended to obtain higher strength linepipe grades.

Jan 1, 2005

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By M. Nejati, A. Paluszny, R. W. Zimmerman

A numerical method is proposed to propagate multiple discrete fractures leading to primary fragmentation in a mine that is being worked using block caving. Deformation is computed using the finite element method, fractures are represented explicitly, and the mine domain is discretized by an unstructured mesh. Bedding planes are represented by systematically varying the elastic modulus of the rock and by defining horizontal weakness planes. Fractures and matrix are represented using parametric surfaces, and tips are defined by their boundary curves. Tip advance is controlled by a failure criterion, and a criterion for propagation direction and magnitude, based on the evaluation of the modal stress intensity factors. A novel domain integral approach is applied to accurately compute stress intensity factors (K) ahead of fracture tips in three dimensions. The method does not require a structured volumetric mesh structure around the crack tip, as integration is performed over a series of virtual surface domains along the crack front. The method is efficient, as it makes direct use of automatically generated, arbitrary tetrahedral meshes, and approximates stress intensity factors (KI, KII, KIII) along each crack front using Interaction-integrals. As opposed to the JIntegral, the method does not decompose K a-posteriori, but instead uses an auxiliary field to directly compute modal K. When using this method, numerical approximations of K do not exhibit dependence on the mesh layout, and require meshes that can generally be ten times coarser than are required by displacement- and stress-based methods. Volumetric meshing requires only, on average, 17% of each computation step. Thus, cracks do not follow any pre-existing mesh structure, and the method is well suited for high-density fracture datasets. The method is demonstrated for primary fragmentation of a mine area covering 110 initial draw points, immediately beneath a 2m high undercut. Displacement is constrained at all boundaries except the surface of the undercut. The growth of the fractures is investigated at the onset of the undercut. Ninety initial disc-shaped fractures are taken into account, each having an initial radius of 10 m. Fractures grow around the undercut, intersect the bedding plane boundaries, and the domain is fragmented as a result.

Jan 1, 2015

By M. S. Greenfield, E. Cocchiarella, S. Chubbs

"At Dofasco sNo.4furnace a variation of the basic oxygen steelmaking process, Klockner Oxygen Bottom Maxhutte (K-OBM), is used to produce steel. Large amounts of hot gases and particulate are evolved during the oxygen blowing phase. A quencher and a venturi scrubber are used to collect over 99.5% of the particulate. In 1990, the authors investigated the effect of foamy slag on the particulate emissions from the furnace. The amount of lime added early in the oxygen blowing cycle was reduced, making the slag more viscous and foamy for a six minute period. Instantaneous particulate emissions were monitored throughout the blow by analyzing quencher and venturi scrubber water samples. Particulate emissions were reduced up to 59% during the foamy slag period.IntroductionThe reduction of the amount of waste generated or control of emissions at source is at the top of the ""3R"" hierarchy of waste management (Reduce, Reuse, Recycle). Process and operating practice changes are often the most economical ways to control emissions. At Dofasco, they investigated the effect of operating practice changes, specifically the formation of a foamy slag, on particulate emissions from steelmaking furnaces. They wanted to determine if a foamy slag changed the quantity and nature of the fume evolved from the K-OBM furnace over the oxygen blowing phase.The Basic Oxygen Steelmaking ProcessesThe basic oxygen steelmaking process (BOP) generates large quantities of very fine metal oxide fume during the production of steel. In this process, scrap steel and molten iron (hot metal) from blast furnaces are charged into a steelmaking furnace. Then pure oxygen is injected and a lime flux added . The oxygen reacts with carbon dissolved in the molten iron to form carbon monoxide. Oxygen lances can have secondary nozzles which introduce oxygen above the bath. This secondary oxygen, known as post-combustion, bums some of the carbon monoxide radiating the heat back to the bath. Particulate and gases rich in carbon monoxide are ejected from the furnace during the oxygen blowing phase and are collected by a gas cleaning system. Typically, more than 99.5010 of the particulate is scrubbed from the gases by high energy venturi scrubbers or electrostatic precipitators. The oxide sludge or dust collected may have elevated zinc and lead which is unsuitable for recycle to blast furnaces. Due to the presence of these undesirable elements, treatment and disposal of steelmaking oxide dust is difficult and costly."

Jan 1, 1993

By L. E. Reed, I. G. L. Sinclair

An exploration program seeking kimberlite pipes, the common primary hosts for diamonds, Was' conducted during the years 1979 through 1982 in the James Bay Lowlands of Ontario by Selco Mining Corporation (now the Mining Division of BP Resources Canada) and Esso Minerals Canada. The area to be explored was selected on the basis of its regional geological setting, and because of the known presence of kimberlite indicator minerals in the region. The primary exploration technique was low level airborne magnetic surveying, followed by detailed ground geophysics. This work located many pipe-like bodies, with diameters of a few hundred metres, as well as several dykes. Targets located by these geophysical methods were drilled, intersecting a total of45 intrusions, consisting of34 alkaline diatremes containing tuffisitic breccias, 7 carbonatites, and 4 massive alnoites. K-Ar determinations indicated ages of 152 Ma and 180 Ma for two of the massive alnoites. The texture and general mineralogy of the tuffisitic breccias are similar to those of diatreme facies kimberlites, but detailed examination of their mineralogy and chemistry demonstrated that they lie within the alnoitic rather than the kimberlitic compositional field. Although the exploration program did not lead to the discovery of true kimberlites, it did demonstrate the presence of a large, previously unknown province of alkaline volcanic activity, which has no surface expression.

Jan 1, 1991

By S. D. Normani

A Deep Geologic Repository (DGR) for Low and Intermediate Level radioactive waste has been proposed by Ontario Power Generation for the Bruce Nuclear site in Ontario, Canada. The DGR is to be constructed at a depth of about 680m below ground surface within the argillaceous Ordovician limestone of the Cobourg Formation. The objective of this paper is to apply paleoclimate boundary conditions to a regional-scale groundwater flow model for the DGR site and to describe the influence of glacial loading and unloading on flow system evolution using the FRAC3DVS-OPG flow and transport model. The regional-scale domain encompasses an area of 18,775km2 extending from Lake Huron to Georgian Bay in southwestern Ontario, Canada. From a hydrogeologic perspective, the domain can be subdivided into a shallow zone, an intermediate zone, and a deep zone comprised of the low-permeability units of Ordovician and the more permeable Cambrian where present. The deep groundwater zone is characterized by units containing stagnant water having high concentrations of total dissolved solids (TDS) that can exceed 300g=L. The high TDS values at depth require density-dependent coupled flow and transport calculations within FRAC3DVS-OPG. The computational sequence involves the calculation of steady-state density independent flow that is used as the initial condition for the determination of pseudo-equilibrium for a density-dependent flow system that has an initial TDS distribution. The 1,000,000 year pseudo-equilibrium heads and brine concentrations are used as the initial condition for the paleoclimate simulations. Over the past 900,000 years, the Canadian Shield has experienced approximately nine episodes of complete glaciation. During the glaciation cycles, the entire Canadian land mass has been covered by a series of continental ice-sheets whose maximum thickness reached 4 km and whose southern extents reached, in some cases, beyond the present-day Canada-U.S. border. The glaciation phase of a single glaciation-deglaciation episode is typically 90,000 years in duration, while the deglaciation portion proceeds relatively rapidly and has an average duration of approximately 10,000 years. Output from the University of Toronto Glacial Systems Model, a continental scale North American glacial reconstruction of the most recent 120,000 year glaciation event developed by W. R. Peltier, is used to supply the paleoclimate boundary conditions used in this paper. Permeabilty reductions due to the presence of permafrost are also considered in the paleoclimate simulations. This paper will demonstrate that the choice of rock properties can significantly affect residual pore water pressures within the rock matrix, as well as the migration of glacial meltwater.

May 1, 2009

By M. B. M. Monte, M. L. Torem, E. R. Pecanha, A. G. Merma

The recent literature has unveiled the potential use of microbial strains in mineral bioprocessing. This study presents the use of a Gram-positive bacterium (Bacillus subtilis) as bioreagent for hematite flotation. The bacterium presents the ability to modify the properties of mineral surface (electrophoretic mobility and hydrophobicity). It was studied the electrokinetic behavior of hematite particles, before and after the interaction with the bacterial cells. The results revealed a shift of the isoelectric point (IEP) of the hematite after interaction with bacterial cells, suggesting a chemical adsorption mechanism. Moreover, after bacterial conditioning, the zeta potential curve of hematite presented high values in the alkaline pH range. The hematite and the bacterial surfaces presented contact angle values around 27.4° and 41.0°, respectively. According to the results, the B. subtilis strain was capable of modifying the hematite surface, and after interaction the hematite surface presented a contact angle value around 46.0°. The flotation tests were carried out in a modified Hallimond tube. The experiments revealed a significant increase in hematite flotability using the Gram-positive strain as bioreagent. The tests pointed out a maximum recovery of hematite in the presence of 600 mg/L and pH 5. Therefore, the results from this study showed the potential use of the B. subtilis strain as a biocollector for hematite flotation, and its possible application in the mineral flotation industry.

Jan 1, 2016

By E. Asselin, G. K. Yue

"In the present study, electrochemical measurements, especially cathodic potentiodynamic polarization (CPC) and cyclic potentiodynamic polarization (CPP), have been employed to study the kinetics of ferric reduction on chalcopyrite in aqueous Fe(II)Fe( III)H2SO4 solution at 90 °C and 110 °C. Results from the calculation of speciation in the above solution reveal that, at both 90 °C and 110 °C, the real Fe3+/Fe2+ ratio is much lower than the nominal ratio, which leads to smaller VALUES (for the reversible potential of the ferric/ferrous couple. Exchange current densities of the ferric/ferrous couple were obtained and are on the order of 106 10 5 A/cm2 a t 9 0 °C and 1 07 10 6 A/cm2 at 110 °C, respectively. The Tafel slopes from the CPP method are higher than those from the CPC method at both 90 °C and 110 °C. The transfer coefficients were about 0.360.59 at 90 °C and 0.370.65 at 110 °C. Based on the exchange current densities obtained, the rate constant kc was calculated. It was found that kc at 90 °C was slightly larger than at 110 °C, especially for the results obtained by the CPC method. The average rate constants are 862.17 cm/s for CPC and 65.30 cm/s for CPP at 90 °C, and 477.69 cm/s for CPC and 63.53 cm/s for CPP at 110 °C for nominal Fe3+/Fe2+ ratios ranging from 1:1 to 1000:1. INTRODUCTIONChalcopyrite is one of the most abundant copper-bearing minerals, accounting for approximately 70% of the world’s known copper reserves (Wang, 2005). Most of the currently proposed leaching processes are based on sulfuric acid with ferric ions and/or dissolved oxygen as oxidants. Some of these processes have been piloted in attempts to implement these technologies on an industrial scale, such as Activox (U.S. 5,232,491, 1993), Nenatech (U.S. 5,993,635, 1999), Dynatec (U.S. 5,730,776, 1998), AAC/UBC (U.S. 6,503,293, 2003), Total Pressure Oxidation (U.S. 5,698,170, 1997), CESL (U.S. 5,874,055, 1999) and Galvanox (U.S. 7,846,233, 2010).To date, much effort has been devoted to understanding the kinetics and mechanisms of the oxidative processes (Biegler & Horne, 1985; Córdoba, Muñoz, Blázquez, González, & Ballester, 2008, 2009; Ghahremaninezhad, Asselin, & Dixon, 2010; Hirato, Majima, & Awakura, 1987; Hiroyoshi, Kuroiwa, Miki, Tsunekawa, & Hirajima, 2004; Warren, Wadsworth, & El-raghy, 1982) or the cathode reduction reactions of chalcopyrite itself (Arce & González, 2002; Biegler & Swift, 1976; Biegler, 1977; Nava, González, Leinen, & Ramos-Barrado, 2008), by chemical or electrochemical methods. However, as the most important cathodic processes in chalcopyrite leaching systems, the cathodic reductions of ferric ions or dissolved oxygen are worth measuring due to their effects on the overall leaching rate, as predicted by mixed potential theory."

Jan 1, 2012

By L. Fernandes

A factorial study was performed to investigate the relative effects of temperature, copper concentration and meso-2,3-dimercaptosuccinic acid (DMSA) concentration on the performance of thiosulfate leaching of gold. A total of 24 leaching experiments were performed representing eight unique combinations of high-low levels of the three factors performed in triplicate. All investigations were performed in an electrochemical cell with an electrolyte composed of 0.1 M sodium thiosulfate with a combination of copper (either 0 mM or 1 mM) and DMSA (either 0???or 1µM). All leaching investigations were conducted under open circuit while the electrolyte, which was open to the atmosphere and mechanically stirred, was maintained at either 25°C or 50°C. After 1.5h of leaching the amount of gold in solution was quantified using ICP-MS analysis from an aliquot of the electrolyte. Results indicate that DMSA addition improved gold leaching performance, most notably at 50°C and with addition of copper. Under this unique condition, the quantity of gold in solution was reproducibly and significantly above the average response of all other factors studied.

Jan 1, 2014

By F. Parada Luna, F. Parada Torres, J. Salvo, A. Reghezza

In the pyrometallurgical processes of copper concentrates, arsenic is preferentially concentrated in the dusts carried by the gases as a result of their volatility and subsequent condensation in the gas cleaning train. In this work results obtained by alkaline leaching of the dusts from Ministro Hales roasting plant, belonging to Codelco, are presented. For the Ministro Hales plant the alkaline leaching would be an alternative to the recirculation of dusts to the roasting furnace. The experimental study considered NaOH and NaOH plus NaHS leaching of two samples of dusts, with 4.24 and 2.55% arsenic respectively. The results show that it is feasible to extract 90% of the arsenic and 50% of the antimony at room temperature using only NaOH, and when the temperature increases to 95ºC, the extractions of As and Sb increase. Copper remains in the solid residue with less than 1% dissolution, and the NaOH net consumption was approximately 140 kg/t of dust. In leaching tests with NaOH + NaHS, two types of methods were tested, baking plus leaching with water and direct leaching with a NaOH+NaHS solution. With the second method arsenic extraction increased to 95% and copper dissolution was less than 0.01% at 85ºC, NaOH 100 g/L, NaHS 90 g/L, 1.5 h and L/S ratio of 5/1 (L/kg). The bismuth remains stable in the solid in all cases. INTRODUCTION The presence of arsenic in copper concentrates has increased with time and the environmental regulations are becoming increasingly more stringent. In concentrate treatment pyrometallurgical plants, most of the arsenic is volatilized condensing in the gas train and is collected along with the entrained solids to form the flue dusts. Under these conditions, in smelters of copper concentrates with high arsenic content, the dusts are being treated in hydrometallurgical plants to extract and stabilize the arsenic, which also means that most of the copper contained in the dust is co-extracted with the arsenic. This affects the recovery of copper in the smelter and an alternative such as the selective alkaline leaching of arsenic, would allow the copper from flue dust to be recovered.

Jan 1, 2019

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

By Robert T. McKnight

"Traditional techniques for valuing resource projects companies have been primarily based on discounted cashflow methods (DCF) or by comparison to similar projects with an apparent market capitalization. Many resource projects are really forms of options to invest rather than a future cashflow stream. Employing the DCF method to value a resource project which is really an option to invest, can dramatically underestimate the real value of the project. The analytical tools required to evaluate options, while more complicated than the usual spreadsheets used for DCF, are becoming more easily available and usable by managers. This paper will discuss the background of options valuation and some of the tools which will make it easier for managers to estimate the value of projects and companies which have significant real option values.ResumeBob McKnight is a graduate of the University of British Columbia in Geological Engineering, supplemented by an MBA from Simon Fraser University. Following several years in the oil patch with Cities Service and Brascan, Bob returned to Vancouver in 1979 to work for Wright Engineers. He subsequently went on to work for Cassiar Mining, Getty Resources and Endeavour Financial before joining Pincock Allen & Holt Ltd. in 1998. His experience ranges from exploration to feasibility studies, financial evaluations of mining and oil & gas projects, due diligence, project finance, valuations and mergers and acquisitions. He has extensive international mining experience pertaining to such countries as Chile, Mexico, Uruguay, Thailand, Indonesia, Angola, Papua New Guinea, Kazakhstan.What are Options?Options have been around for centuries. They were familiar to Roman and Phoenician traders who were shipping cargoes from Mediterranean seaports. In the financial world, options are types of contracts that generally include the right, but not the obligation, to buy or sell a share, currency or commodity. The underlying commodity price or share price changes are assumed to be lognormally distributed. In this context, options are of two general types, ""call"" options and ""put"" options. Call options have the characteristic of having the right to buy a tradable commodity or currency at a predetermined price for a specified period of time. For the owner of call options, they become more valuable as the price of the underlying commodity increases. For the seller of call options, these options become an increasing liability as commodity prices rise, since there is the obligation to sell the commodity at a predetermined (perhaps lower-than-market) price. This characteristic of call options recently became high profile with the sharp rise in gold prices last year. The value of gold call options sold by certain producers increased their associated liabilities to the point where margin calls were made."

Jan 1, 2003