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By Antonio Laguna

During the past few years, synthetic efforts have been addressed to the synthesis of polymeric materials with optical or semiconducting properties or even with capabilities to act as sensors for volatile organic compounds (1). The most recent studies have been concerned with the synthesis of heterometallic systems with short metal-metal interactions and the determination of their optical properties. These complexes are undoubtly interesting from a theoretical viewpoint and include an emerging class of luminescent materials, in which the observed luminescence results mainly from the interactions among the different metal centers, as well as the environments of these atoms. The understanding of the photophysics and photochemistry of these products could permit the design of complexes with appropriate metals and ligands chosen for individual applications. Following a synthetic strategy consisting on reactions between acid heterometal complexes and basic gold precursors we have succeded in synthesizing supramolecular assemblies formed via acid-base stacking, which display tunable luminescence or selective and reversible sensitivity to Vapour Organic Compounds (VOC?s) (2-5). In this sense, in accord with previous Mössbauer studies carried out in the gold precursor complex [AuR2]- (R = C6F5), the basic properties of this and related materials have been employed as building blocks of supramolecular assemblies in their reactions with complexes in wich the metallic centers act as lewis acids as, for instance, Tl(I) or Ag(I) (6). For instance, in the case of silver, by reacting equimolecular quantities of [NBu4][Au(C6F5)2] with AgClO4, in acetone, a solid of stoichiometry [Au2Ag2(C6F5)4(OCMe2)2]n is obtained. The polymeric nature of this material in solid state is confirmed through X-ray analyses (figure 1). It consists of polymeric chains formed by repetition of Au2Ag2 moieties linked through short gold-gold interactions. Nevertheless, in solution, the nature of this polymeric materials was still a matter of controversy and, in this case, the optical properties have been shown as useful tools in order to obtain information. Thus, while dilute acetone solutions of this complex give a emission coming from pentafluorphenyl localized ??* excited states, in accord with the presence of isolated tetranuclear Au2Ag2 units, when the measurements are done at different and higher concentrations, a band that does not obey the Lambert-Beer law appears. This deviation is consistent with molecular aggregation in solution of these units through gold-gold interactions, and a clear correlation between the emssion wavelength and the structure in the solid state and in solution is shown (figure 2). DFT calculations accord with the observed experimental behaviour and show the nature of the orbitals involved in each transition.

Oct 1, 2003

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

"11.1. IntroductionThe recovery of platinum-group elements (POE) from ores is a subject which has received almost no mention in the literature. Edwards (1975) refers to the process used for refining of the POE, throughout the Western World, as a so-called ""conventional"" process .... ""not because of the simplicity or convenience of the operations, but more probably because of the inertia of established processes and the aura of secrecy with which the major platinum refiners have surrounded this process."" There is no doubt in this writer's mind that the latter is also applicable to the dearth of knowledge of the mineralogy, geochemistry and ore deposits of PGE and that the poor recoveries, mainly attributed to the mineral beneficiation stages of concentration, are also affected by this traditional secrecy. Fortunately, this attitude is changing, due no doubt to the advantages that accrue from more open research which may be critically assessed in the literature in the traditional manner. Examples of this more open approach to recoveries and recovery problems are represented by Newman (1973), who gave some typical recovery percentages for Merensky Reef ores, and the recent encouragement and cooperation on mill samples from the Sudbury area by lnco Metals Company (cf. Cabri, 1981a).In general, platinum-group elements are recovered from an ore by the use of a physical concentration method, such as gravity separation or flotation, followed by further upgrading using further physical, wet chemical or pyrometallurgical techniques. The final process of refining in which the individual platinum-group elements are produced in pure form is outside the scope of this chapter.Platinum-group element deposits naturally fall into different categories according to the recovery process best suited for them, viz. those amenable to gravity separation, those amenable to flotation, and those where platinum-group elements are by-products of base metal sulphide, chromite and miscellaneous other deposits."

Jan 1, 1979

By A. T. Jakubick, A. MacG. Robertson

This paper reviews key issues related to the placement of dry (soil) covers on extremely weak, compressible fine tailings. The design and construction of soil covers on such tailings often presents a formidable challenge to the geotechnical as well as the environmental engineer due to the low shear strength, poor traffic ability, and high settlement of under consolidated tailings at the time of reclamation. The geotechnical issues to be considered include: (1) consolidation of near-surface tailings to achieve strength gains, improve traffic ability, and allow safe placement of initial cover layer; (2) stability of tailings slopes during dewatering of tailings ponds and/or cover placement; and (3) long-term settlement of tailings and its impact on cover integrity and final surface shaping. The environmental issues to be considered include: (1) management of contaminated (free) pond water; (2) management of contaminated pore water expelled during tailings consolidation; and (3) management of (uncontaminated) surface water on top of the cover. This paper summarizes recent experiences gained in a large uranium tailings reclamation project. It is concluded that a careful consideration of both geotechnical and environmental issues during the planning stages greatly reduces the costs and environmental risks associated with fine tailings reclamation.

Jan 1, 2000

By R. Lasmanis

"Washington State's diverse geological setting is reflected by its several types of porphyry Cu-Mo deposits. All are associated with calc-alkaline intrusions, and they range in age from Jurassic to Miocene.The largest is the Mount Tolman Mo-Cu deposit located in the Omineca Belt. It contains 2.18 billion tonnes of material averaging 0.093% MoS2 and 0.09% Cu. There are intermediate-size Mesozoic deposits in the Intermontane Belt. The Cascade volcanic arc hosts small- to medium-Tertiary deposits. Among these, of particular interest is the Sunrise breccia pipe, which has been explored over a vertical distance of 1000 m. It contains reserves of 64.6 million tonnes averaging 0.319% Cu and 0.071% MoS2 with significant tungsten values. The Glacier Peak deposits have potential resources of 1.7 billion tonnes averaging 0.334% Cu and more than 0.015% MoS2 and also contain tungsten. The Margaret deposit can be classified as a porphyry Cu-Au type; it has reserves of 200 million tonnes averaging 0.434% Cu, 0.0175% MoS2> 0.27 g!t Au and 1.92 g!t Ag. Drill intercepts of the North Fork deposit also show significant gold values.Mineralization and hydrothermal alteration of these deposits are typical of porphyry deposits, although some differences can be noted. The Mount Tolman molybdenum deposit contains topaz alteration zones and is transitional between a plutonic type and a Climax-type molybdenum system. Other deposits, such as the Kelsey, Mazama, North Fork, and Margaret, are low-sulphide systems that contain significant amounts of magnetite."

Jan 1, 1995

By N. R. Andrade-Gonzalez

The present work was performed on four alloys containing Al-6 2 wt pct Si-3 5 wt pet Cu, with magnesium in the range of 0.02-0 40 wt pct, and strontium in the range of 0-165 p p m Tensile bars were cast in a permanent mold (ASTM B108-160) and heat treated at 495°C for 4 hours, followed by quenching in hot water. Two different artificial aging temperatures were applied at 180 °C and 220 °C for times from 0 5 h up to 8 h Tests were conducted with the intent of determining how the mechanical properties of an aluminum-based 319 alloy are affected when aging time and temperatures are varied In general, it is seen that the alloy does not exhibit the common peak-overaged aging condition due to the presence of several coexisting phases, indicating that they form through complex eutectic reactions late in solidification.

Jan 1, 2004

Spatial information Critical to a project since it underpins: ?Discovery of mineral resources ?Orebodydefinition and technical assessment ?Mine design and planning ?Profitability and project value Data ?Single most import asset. ?Good interpretation of quality data underpins project growth and success. TEAMWORK

May 1, 2002

By R. E. Johnson

Seventy years after the start of the Industrial Revolution in Great Britain, as reckoned from Arkwright's water frame patented in 1769, there was a significant development of the metallurgical industry in Virginia. In Britain, crucible steel had been rediscovered by Benjamin Huntsman in 17~0, and this made spring and tool steel more generally available. The metal-turning, screw-cutting lathe, including the basic principles recognized in today's engine lathe, was developed by Henry Maudslay about 1797. Wrought iron, as manufactured by Henry Cort's process patented in 1784, was readily available. Richard Trevithick's highpressure steam locomotive had met its test on the Pennydarren tramroad in 1804, and George Stephenson had built his famous Rocket, along with several other locomotives, at Newcastle around 1828. Puddling furnaces and a rolling mill had been placed in operation at the Tredegar Iron Works in Glyn Sirhowy, Monmouthshire, Wales, in 1807. In the United States, expanding commerce and a growing population resulted in continuing development from the Chesapeake to Virginia's Blue Ridge, and this demanded improved means of transportation. Ore deposits rich in hematite had been found in Virginia's Piedmont during the Colonial period, and a number of blast furnaces now dotted that area. The products of these operations were mostly pots, kettles, stove parts and like items for local trade. The James River and Kanawha Canal was incorporated in January 1785. Its eastern leg, winding along the slope of the high bluffs overlooking the river, was completed about 1800. About two dozen railroads were chartered in Virginia between 1830 and 1837. With expanding population and steady industrial development came a need for metallurgical products. Throughout the eastern United States, numerous metallurgical enterprises sprang up, and many of these flourished. The purpose of this article is to outline the development of one Southern metallurgical company, the Tredegar Iron Works, which was to have a significant impact on the industrial development of Virginia and the fighting of the American Civil War. Although the Tredegar Iron Works no longer exists, remnants of the early operations have been restored, and the current status of the site is also presented.

Jan 1, 1999

By Michael T. G. Brown

Syncrude Canada Ltd. has recently completed construction of its ambitious tar-sand mining and processing facilities at Mildred Lake, Alberta. The Syncrude site is approximately 48 km (30 miles) north of Fort McMurray near the west shore of the Athabasca River. The Syncrude operation involves the open-pit mining of approximately 270,000 tonnes (300,000 tons) of tar sand daily using draglines and a conveyor system. Bitumen is extracted from the tar sand, upgraded to oil-gas and transported to refineries in Edmonton and other locations for final processing . The Beaver Creek Dam forms part of the mining facilities for the Syncrude tar-sand mining operation. Water from Beaver Creek is diverted from the open-pit mine site south to the Athabasca River via Ruth Lake and the Poplar Creek Dam. General site layout is shown on Figure I . Design of the dam was completed by R. M. Hardy and Associates Ltd. of Edmonton, Alberta (now Hardy Associates (1978) Ltd) . Construction was undertaken during the summers of 1974 and 1975 under the direction of Canadian Bechtel Limited, managing contractors for Syncrude Canada Ltd. Total length of the dam is approximately 2.8 km (1.7 miles), with a maximum height in the order of 16 m (50 ft) The Beaver Creek Dam is located in a broad, flat, poorly drained valley. About 50 per cent of the site is covered with treeless peat deposits, which ranged in thickness from in excess of 5 m (15 ft) at the east end of the dam to less than 1 m (3 ft) at the central portion. The peat deposits overlie Pleistocene meltwater sediments on top of clay/clay shales of the Clearwater Formation and the tar sands of the McMurray Formation. The peat deposits and high groundwater levels at the site combine to make the excavation and construction of a conventional rolled clay cutoff impractical. For these reasons, the slurry cutoff trench technique was utilized to produce an efficient and effective seepage cutoff under various sections of the Beaver Creek Dam .

Jan 1, 1979

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By E. L. Chanturiya

The research and characterisation for compositional, physicochemical, structural, electrical and flotation properties of various pyrite samples for a copper-zinc sulfide ore was carried out. Various methods were used during the research, such as optical microscopy, X-ray diffraction, electron probe micro-analysis (EPMA), phase emission analysis, routine chemical analysis, auger electron spectroscopy (AES), scanning electron microscopy (SEM), back-scattered electron images (BSE), potentiometry, and instrumental neutron-activation analysis, flotation. Analysis of obtained results established the interrelation between impurity structures and concentration of electric charge carriers in minerals, Butyl xanthate sorption and flotation yield of pyrite. The research concluded that pyrite samples differ by morphology, micro defects of structure, concentration of donor and acceptor impurities (Co, As, Sb, etc.) and conductivity parameters (thermo-electrical force, specific resistance and concentration of charge carriers The peculiarity of pentagon-dodecahedral pyrite is the high concentration of electric charge carriers (electrons) and the more negative surface potential (by 25–75 mV) in comparison to cubic pyrite. The surface of cubic varieties is more active, therefore it is oxidized in alkaline lime medium much faster, than the surface of pentagon-dodecahedral varieties. This phenomenon is caused by high reaction ability, irregular jointing and defects of cubic pyrite. This promotes the increase of calcium ion sorption on its surface and the decrease of Butyl xanthate sorption. According to this, an increase in alkalinity (lime medium) from a pH of 10.0–11.5 leads to an increase of gold content reporting to the tail of bulk flotation. Gold content is increased from 0.58 g/t (?? 9.5) to 1.9 g/t (?? 11.6), which represents an increase in gold recovery of 24.68 to 79%, respectively.

Jan 1, 2016

By Bryan Wilson

Background ?Nickel Rim South Mine started production ramp-up in Q2, 2009. ?The main dewatering pumps were put into use in August 2009. ?3 Feluwa?multisafe?positive displacement pumps ?1700m single lift pumping ?Reliability has been an issue due to the amount of slimes and fibers (from shotcrete) at the pumps. ?Critiqued internal dewatering system to solve some issues we were having with our sumps Findings 1.Much of the final dewatering system was not in place. a)Temporary pain. Difficult to say something is not working when the system was not yet in place as per design. b)Not enough capacity to handle slimes within the system. 2.Need to address issues with the final design: a)Ongoing costs: The end design has operating costs of $2.5 million b)Scoops in Sumps: The end design relies on scoops to be used for cleaning the sumps c)Slimes Recovery: The system mixes 3 different products in the sumps along with the fibers d)Pump repair costs: The existing Tsurumi pumps are too light duty for our slimes

Nov 1, 2011

By Tom Brady

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate weak rock masses (such as are associated with operations in the Carlin Trend in Nevada) into existing design relationships. The original database that led to most of the empirical design relationships presently employed in hard-rock mining was derived from fair-to-good-quality rock. In this study, the relationship between weak rock quality and opening design (nonentry/entry methods) is being investigated. The common factor in all mines is a weak back or wall. This work attempts to provide tools that will enable a mine operator to make economic decisions that will also ensure a safe working environment.

May 1, 2003

By W. G. Jewitt

THE Box mine, situated in Saskatchewan on the north shore of lake Athabasca, is unique in two respects. It is the first and, so far, the only gold mine in Saskatchewan, and it is the only gold mine in Canada to employ a large-scale forced caving system as the main mining method. Discovered in 1934 by Tom Box, an Edmonton prospector, its subsequent history, while breaking no records for speed, has been one of steady and more or less normal development. Camp and plant are situated close to the shore of Beaverlodge bay, sorne 50 miles east of the Saskatchewan-Alberta boundary and 35 miles south of the north boundary of the Province. The railhead at Waterways, Alberta, is about 220 miles to the southwest. Prince Albert lies some 450 miles to the south. The surrounding country presents a rather rugged variation of the usual Precambrian topography, with hills rising five to six hundred feet above lake Athabasca. The numerous lakes and islands, together with the wide expanse of lake Athabasca, compose an attractive scene, at least in the not over-long 'open water' season. The winters are long but not extremely cold, judged by prairie standards. The small lakes break-up around May 20th and the 'freeze-up' stops navigation early in October. Though apparently remote, the Box mine is fortunate in having reason-ably cheap transportation from Edmonton. The 300-mile railway from Edmonton to Waterways is the most expensive section, the rate for 1st class freight being $1.70 per hundred pounds and for 5th class freight $0.77 per hundred. Freight from Waterways to the mine, approximately 140 miles down the Athabasca river and 90 miles along lake Athabasca, is delivered by barges and tugs for 50 cents per hundred pounds. All freight is delivered during the 'open water' shipping season, which lasts from about .Tune 7th to October 7th. In normal years, barges are loaded to 3 to 3 1/2feet draught up to September 1st. After that date, and earlier in dry years, shallow water at Waterways reduces the barge loads. Barges of 100 to 200 tons capacity handle all mining freight, including pieces up to 15 tons in weight, without undue difficulty.

Jan 1, 1940

By Y. Guglielmi, C. Gout, P. Henry, P. Dick

The key questions about fault reactivation in shales concern the potential enhanced fluid displacement through a previously low-permeability aseismic shale formation. Here we selected a critically-stressed fault cross-cutting the underground research facility of Tournemire (France) which is located in Toarcian shales. Several inclined boreholes were drilled across the 8.5 m thick fault zone characterized by a fractured damage zone (FDZ) and a central 2.4 m thick complex core (FC) made of multiple shear bands with gouge intercalated with highly fractured lenses. The fault was pressurized using a straddle packer system defining a 2.4m long injection chamber normal to the fault surface. Three fault zone intervals were tested, two in the fault damage zone and one in the fault core. A three-dimensional displacement sensor set in the chamber allowed continuous synchronous coupled monitoring of fault movements, injection pressure and flow rate. An anticlockwise 0.22-to-0.05 mm fault slip was captured associated with a 10-to-100 hydraulic aperture increase of the fault. Preliminary analyses of the experiments show that leakage in the fault zone is controlled by strength and stress magnitude contrasts between the fault core and the fault damage zone. Fault damage zone discontinuities display a much higher peak static friction angle than the fault core shear zones, respectively of 34 and 22° that could be related to complex interactions between healing and sealing processes. Fault core leakage is much more dependent on strain than on effective stress variations. Discontinuous, pulse-like leakage, develops following complex failure processes that may simultaneously take place in the gouge zones and along the large pre-existing discontinuities. Such results may be of importance in evaluating fault seal integrity in oil and gas exploration, production or CO2 storage or underground excavations monitoring.

Jan 1, 2015

By Dan Zou, Ji Chen, Deqian Li

"Bayan Obo mixed RE concentrate is the largest RE source in the world. RE elements occur dominantly in bastnaesite and monazite. This paper describes a clean and green technique for processing Bayan Obo mixed rare earth (RE) concentrate. A two-step oxidation method can lead to the effective recovery of REs, thorium (Th), fluorine (F) and phosphorus (P). Ce has a property of valency change, enabling the separation of it from other RE(III) elements. Making use of the interactions of cerium (IV) (Ce(IV)), F and P, a new extraction system was created to separate Ce(IV) effectively from other RE(III) while recovering F, P and Th by complexing F and P following the oxidation of Ce(III) to Ce(IV). The method includes two parts. Firstly, bastnaesite is oxidized by air roasting and sulfuric acid leaching. And then a first leach liquor containing Ce(IV), F and P is obtained. Secondly, monazite was converted into REhydroxide through alkaline attack and then Ce(III) in the RE-hydroxide was oxidized into Ce(IV) by wetair oxidation. After sulfuric acid leaching the oxidized RE-hydroxide, a second leach liquor is obtained. The two parts of leach liquor containing Ce(IV), F and P are then extracted by Cyanex923 to obtain CeO2, CeF3 and CePO4 based on the complex of Ce(IV) with F and P. The raffinate was further extracted by the primary amine N1923, and Th-product was recovered as ThO2. The RE elements recovery yield during the whole process is greater than 92%. The new technique not only provides a new way for Bayan Obo RE ore utilization, but also avoids resource waste and environment pollution.INTRODUCTIONRare Earths (REs) refer to lanthanides, including scandium and yttrium. Owing to the similar structure and property of RE(III), it is difficult to separate them from each other, especially for the adjacent elements. According to the United States Geological Survey, in 2010, the whole world has about 142 million tonnes of rare earth reserves. In that, China ranks the second with 22% following Brazil which ranks first with 32% (Cheng, 2011). There are three main RE ore types in China with about 80% mixed ores in Bayan Obo, 10% bastnaesite ores in SiChuan and ShanDong province and 2.9% ion adsorption ores in Southern China. Bayan Obo mixed RE concentrate consists of bastnaesite and monazite. The concentrate contains CeO2/_REO of 50% and there are 7–8% F, 4-6% P and 0.2–0.3% Th."

Jan 1, 2016

By Chris M. Healey

"Abstract- The Jasper Gold mine in northern Saskatchewan produced a total mill feed of 140 127 tonnes at an average grade of 19.0 g/t Au. Both diamond drilling and chip samples from under­ ground workings returned extremely high values, up to 12 851 g/t (375 oz/I) Au over 0.10 meter from a chip sample. In the presence of such extremely high grades, the accurate estimation of reserves is a major problem.ln the first part of this study, production data from the mine were used to evaluate the results of a variety of reserve estimation techniques in this environment. In two out of three cases studied, indicator kriging with assays cut to 342.9 g/t (10 oz/I) gave extremely good results. In the third case, however , indicator kriging gave unacceptable results. Instead, lognormal kriging of uncut data gave the best results.Secondly, from the same database, a number of drill-hole spacings were simulated, and reserves estimated from the simulations. As may be expected, the results of this analysis show increasingly better results with tighter drill-hole spacing. However, even with a 5 m by 5 m spacing the variation from actual grade was quite large. This is not a systematic under- or over-estimation of grade, rather a random scatter of results .The results of this study show very clearly the problems of deriving good estimates of reserves when extremely high-grade samples are encountered. There is a high degree of randomness to this database, so reserve estimation in this situation will remain a high-risk operation."

Jan 1, 1993

By Ju-hyung Ha

New automated curing system for mass concrete has been developed to improve the quality of concrete structure and to save construction time and cost. The principle of this system is the automated water circulation system of heated curing water. Applied curing water on the surface of mass concrete keeps the temperature difference between center and surface of the structure below the threshold of specification. Mock-up test and field application have been conducted to investigate the performance of this system. In the results, new automated curing system reduced the chance of thermal crack occurrence and improved quality of the concrete structure as well.

Aug 1, 2013

By G. H. K. Pearse, R. P. Taylor

The Big Whopper, one of only four giant economic rare metal pegmatites worldwide, is set to become a producer of the highly valued lithium mineral petalite (LiAlSi4O10) used in glass, ceramics and the specialty glass-ceramics familiar as Corningware® and the new ceramic stovetops. The deposit has a strike length of 1.5 km, a width of up to 80 m and a resource, open in all directions, of 11.6 Mt, grading 25% petalite. It is amenable to open pit mining and Avalon Ventures Ltd. holds a patent on a flotation process that produces an exceptional quality petalite product. The project will also produce: superb quality Na-feldspar which, too, finds use in glass and ceramics; the unusual Rb- K-feldspar for high voltage porcelain insulators; tantalum, in high demand for electronics; lepidolite, an ore of rubidium; and mica and tin. A positive prefeasibility study has been completed and it remains only to undertake bulk sampling and a full feasibility study.

Jan 1, 2001

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007