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By B Shi, Y Li, L Ma, F Zhou

Subsurface fires are a common threat to coal mining, as spontaneous combustion of coal can potentially result in gas combustion and explosion. Fire-proof techniques, such as grouting, foam, or colloid injection, are not in a position to function ideally, due to the limited coverage and stopping the extinguishment substance from reaching the fire location. Liquid nitrogen, as a kind of all-submerged fire prevention or extinguishing method, can rapidly extinguish fires, thus preventing gas explosion and minimising extinguishment time. Injecting liquid nitrogen through boreholes is an important way during the period of mine catastrophe. But liquid nitrogen is not effective enough in infusion; technical issues restrict the development and utilisation of liquid nitrogen fire prevention and extinguishing technology. Immediate infusion of liquid nitrogen is usually associated with ‘air slug’ (the balloons and bubbles in the pipeline which hinder the flow of low-temperature liquid), which blocks pipelines for liquid nitrogen injecting. Another issue is that the pipeline tends to be damaged due to freezing, which undermines the injecting efficiency of liquid nitrogen and its application result. In order to solve the problems of the low efficiency and some other related field issues in liquid nitrogen perfusion, the ground–underground high efficiency liquid nitrogen injection technology were developed. Implementation of liquid nitrogen infusion techniques in Chinese coalmines achieved the goals of fire prevention and air-cooling. The technique presented in this paper is efficient in absorbing heat, and consequently, displacing oxygen and combustible gases. Field tests at Rujigou and Yangchangwan Coalmine justified the efficiency of the technique. By using this technique, there was no waste left behind, which may impede the subsequent production. The presented technique is of great benefit to the social, economic, and environmental aspects of mining operations, and will have broad applications in fire prevention for large-scale coalmines.CITATION:Zhou, F, Shi, B, Li, Y and Ma, L, 2015. Key techniques and engineering applications of stereoscopic liquid nitrogen infusion for coalmine fire prevention, in Proceedings The Australian Mine Ventilation Conference, pp 291–298 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

The paper gives details of the performance of a 6-ft. by 6-ft. grate discharge ball mill which was converted into a rod mill of the overflow type and then into a grate discharge rod mill. Proposals for further alterations are outlined.INTRODUCTIONThe mill of King Island Scheelite (1947) Limited recovers scheelite by gravity methods.Crushed ore at the rate of 34 tons per hour is divided between two mills. (6 ft. by 6 ft. and 8 ft. by 6 ft. respectively), the mill discharges being pumped to a common distributor which feeds seven Hummer Screens. Each screen has three 4-ft. by 2-ft. Ton-cap sections and repulping compartments are provided. The screen oversize is returned to the mills whilst the screen undersize is finished grinding section product. A third (6 ft. by 6 ft.) mill regrinding the coarser table tailings also discharges into the common Hummer Screen Distributor.The screen undersize is pumped to a bowl classifier which separates at 200 mesh. The bowl classifier sands are treated on tables whilst the bowl classifier overflow, after thickening, is treated in the slime plant by flotation. The flotation concentrate is further concentrated on vanners and slime tables.A recovery of 80 per cent. is possible by tabling whereas only 50 per cent can be recovered in the slime section. The object of comminution is, therefore, to reduce all the new feed to less than a certain mesh (22 mesh Tyler) with the production of a minimum quantity of minus 200 mesh material. cheelite is, a very friable heavy mineral (Sp.Gr. 6'0) and is therefore susceptible to overgrinding. For the evaluation of grinding performance it is hence advisable...

Jan 1, 1955

By S Hapugoda, J R. Manuel, M J. Peterson, A Poliakov, E Donskoi

The occurrence and deportment of manganese in a number of ferromanganese and Mn-bearing iron ore samples from supergene-upgraded deposits, as well as from magnetite banded iron formation (BIF) and magnetite skarn deposits, was characterised in order to provide a basis for improved understanding of the processing characteristics of different ore types and investigate the potential for development of a robust geometallurgical classification for Mn-oxide ores. An understanding of the Mn mineralogy in mixed Fe-Mn deposits is necessary to inform any attempt to separate the Fe and Mn during beneficiation and to understand and predict the behaviour of lump and fine ore products during processing.A suite of analytical techniques was utilised, including hand sorting of lump ore particles, optical microscopy, X-ray fluorescence (XRF)/inductively-coupled plasma mass spectrometry (ICP-MS) chemistry, X-ray diffraction (XRD), scanning electron microscopy (SEM)/electron probe microanalysis (EPMA) and gas and solid phase pycnometry, in order to elucidate manganese mineralogy, mineral chemistry and mineral textures. Manganomelane group minerals (eg cryptomelane, hollandite), pyrolusite and lithiophorite were the most common manganese oxides in the samples examined. From the microprobe work, there was evidence of probable substitution of Mn, as well as Al and Si, into the structures of goethite and hematite. Manganomelane minerals were often intimately associated with goethite, in particular, and a clarification of this association and the associated Si and Al impurities is fundamental for improved understanding of beneficiation and sintering behaviour of Mn-oxide ores. Due to the poor or very fine crystallinity of some supergene manganese deposits and of some Mn oxide minerals, in particular the extent of overlapping peaks and their variable mineral chemistry, XRD was a problematic technique to equivocally determine Mn mineralogy.For lower-grade, earthy, poorly microcrystalline ores the mineralogical and textural association between mixed Mn, Fe and Al (¦ Si) phases was also critical. The deportment and potential separation of these elements in these deposits, especially Al, was complex, as they were characterised by forms of æhydrousÆ cryptomelane with higher levels of Fe-Al-Si substitution, as well as intimate intergrowths of ochreous-earthy goethite (probably aluminous in part) with cryptomelane, lithiophorite and/or kaolinite.Trace amounts of alkali elements in ferromanganese deposits were considered likely to be preferentially structurally associated with Mn oxides, while lateritic deposits with significant amounts of lithiophorite could contain elevated levels of deleterious impurities; Co and Ni in particular.A combination of solid and gas phase pycnometry proved to be a useful technique for broadly discriminating hematitic, goethitic and mixed Mn oxide-goethite lump particles based upon differences in their envelope and apparent densities. Based upon these preliminary results and ongoing Raman spectroscopy work on manganese deposits sensu stricto, Raman spectroscopy is a technique considered to have promise during targeted research to better link the optical and compositional properties of ferromanganese ore particles. CT-scan (computed tomography scan) analysis could also be combined with Raman spectroscopy and pycnometry to link mineral composition, mineral texture, ore particle textures and particle porosity/permeability to the high-temperature processing behaviour of lump and fines products.CITATION:Peterson, M J, Hapugoda, S, Manuel, J R, Donskoi, E and Poliakov, A, 2013. Textural characterisation of manganese minerals to improve the geometallurgical characterisation of ferromanganese and iron ores, in Proceedings Iron Ore 2013 , pp 281-300 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By D J. Williams, G W. Wilson, S, A B. Tran

A comprehensive field program was implemented to evaluate the internal structure and hydrology of two full-scale waste rock piles. The excavation of waste rock dumps for in-pit disposal at the two mine sites provided an opportunity to characterise the in situ properties of the dumps given contrasting geologic and climatic settings. The internal structure and materials within the dumps were observed and sampled as the waste rock piles were being excavated and placed in the open pits for permanent closure. The field program was designed to fully characterise the structure and material properties of the waste rock. The alteration of the material by physical and chemical weathering was also observed. Samples were analysed for paste pH, water content, grain size distribution and geochemistry. In situ density and matric suction were also measured. Soil water characteristic curves and saturated hydraulic conductivity were measured for representative materials. These properties were used to predict seepage pathways through the waste rock and the resulting outflow geochemistry using the finite element model SEEP/W. The materials in the dump at Site 1 were predominantly fine-grained in texture and highly weathered. The presence of dipping beds with alternating coarse and fine materials was evident throughout the profile of the dump. The structure of the waste rock appears to have an impact on the hydrologic pathways within the waste rock pile. The material in the dump at Site 2 was found to be competent and resistant to particle size breakdown. The particles range in size from clay size to large boulders with the median particle size being approximately 125 mm in diameter. The coarse-grained texture of the waste rock resulted in a loosely packed arrangement of coarse particles with little matrix material infilling the pore spaces between the coarse-grained particles. Seepage modelling for Site 1 was completed to predict seepage paths based on observed structure and hydraulic properties measured in the laboratory. The modelling showed that materials with a fine grain size distribution become the dominant pathways for flow through the waste rock pile. The modelling also showed that layers with high silt and sand contents are subject to the highest flow rates. Finer grained clay rich layers have a low hydraulic conductivity and do not convey large volumes of water. Alternately, coarse gravel and cobble materials are unsaturated under values of matric suction that approach the residual water content of the material and do not transmit liquid water. The seepage modelling together with the results of the geochemical analysis show that the dominant particle size that receives the most fluid flow and flushing ranges from fine sand to silt, corresponding to materials with air entry values ranging between 5 kPa to 50 kPa.

Jan 1, 2003

The Racecourse Orebodies at Mount Isa consist of a series of parallel steeply dipping lead/zinc/silver orebodies with a strike length of up to 1000 metres. Production from these orebodies between 13 Level to 9 Level has been by a series of cut and fill stopes in two level stages, leaving a crown pillar at 11 level. Development of the 15 level to 13 level extraction stage has recently been completed. The layout consists of a series of parallel stopes over a strike length of 1200 metres. Access to the stopes is by two declines connecting the stopes with a series of crosscuts This paper describes the basic layout with development and production methods employed.

Jan 1, 1977

By Le V, Nguyen Ngoc Quynh, R H. Murfitt

The Truong Son Fold belt in Indochina hosts the significant Sepon gold-copper district (Laos) and the similar gold-basemetal districts of Phuoc Son and Bong Mieu (Vietnam). With over seven years of exploration, Toronto-listed Olympus Pacific Minerals Inc, is one of few foreign companies that have to date made a substantial investment in mineral exploration in Vietnam.Much of this work has been conducted along the Phuoc Son û Tam Ky Suture, on the south-eastern limb of the Truong Son Fold belt on the Vietnamese side of the border with Laos. These programs have produced a significant number of gold prospects at varying stages of exploration development. The Phuoc Son û Tam Ky Suture is a major Paleozoic subduction zone that extends from northern Laos, through Central Vietnam and out into the South China Sea.It represents a Lower Mesozoic collision zone between the Paleozoic-age Truong Son fold-belt terrain to the north, with the crystalline terrain of the Pre-Cambrian Kontum Block to the south. Since its formation, it has been a locus of deep faulting, continental accretion, intensive intrusive activity and mineralisation. This paper briefly discusses the geological setting, structure, metamorphism, mineralisation, exploration history, and proposed mining development of the Olympus Phuoc Son Gold Project, with particular reference to the Phuoc Son û Tam Ky suture.

Jan 1, 2004

By S J. Neethling and, S J. R Simons

In this paper the effect of humic substances (natural surfactants), electrolytes and solid particles on bubble coalescence, and as a consequence on froth stability, have been investigated. In this study two bubbles of equal size were formed and forced to collide using a novel experimental apparatus. The interactions were recorded by a high-speed camera, the images of which helped to determine the coalescence frequency and the coalescence time, as well as the mechanisms of the interactions. Two types of humic substances were used, along with three different electrolytes. Humic substances appeared to have a considerable effect on bubble coalescence, while the effect of electrolytes was minimal. Moderate and high hydrophobic glass spheres were used between two bubbles. Very hydrophobic spheres promoted fast bubble coalescence, while moderate hydrophobic spheres had no effect. Data of coalescence frequency and time is presented, as well as images of the coalescence events. The coalescence frequency was used to validate a parameter, Pf, known as the film failure frequency, used in a simulation model to predict foam height in a gas-sparged vessel. Predictions determined using Pf were then validated by experimentation.

Jan 1, 2005

Over the past seven years, a combination of New Zealand-, Australian- and German-led research voyages using the research vessels Tangaroa, Southern Surveyor, and Sonne respectively, have revolutionised our understanding of the Kermadec-Tonga arc-backarc systems. This convergent margin is the most seismically-active subduction zone system on Earth with convergence rates steadily increasing northwards from the Hikurangi Trench to ~250 mm/year at northern Tonga. In combination with the intra-oceanic setting, factors potentially producing magmatic, tectonic, and hydrothermal variability in this system include an increase in potentially subductable sediment northwards along-strike, intersection of the Louisville Ridge (hot-spot chain) and Osbourn Trough (paleo-spreading centre) with the arc at ~25¦S, and the possibility of Samoan (hot-spot) plume ingression in the northern Lau Basin. The bulk of the magmatism is submarine; whereas only a few emergent (some transient) volcanic islands exist, about 80 submarine volcanic centres of significant size (>1000 m above surrounding sea floor) are present between White Island in the south to north of Tafahi in Tonga. About 35 per cent of these centres are hydrothermally active. Important petrogenetic features of the volcanic rocks along this arc system are the abundance of rhyolite (some quartz-amphibole-bearing), and the outcrop of primitive olivine-clinopyroxene-phyric basalts in satellite cones of the major edifices. Many of the edifices consist of complex caldera systems. Eruptions from and degradation of these edifices were probably tsunamigenic. Many of the hydrothermal systems developed within the edifices are likely destroyed during the sector collapses which are the characteristic edifice degradation mode. There are three backarc spreading systems along this margin: the Havre Trough, Valu Fa-Eastern Lau Spreading Centre, and the nascent Fonualei Rifts. The latter are particularly notable in having captured the entire suprasubduction zone magmatic flux for a distance of about 150 km, shutting down the adjacent volcanic front arc volcanoes.

Jan 1, 2005

By Y Gu

Based on the mode of occurrence, gold is classified into three categories: microscopic gold, submicroscopic gold and surface-bound gold. Microscopic gold, or visible gold, refers to gold minerals in which Au occurs in a substantial amount, such as native gold and electrum. Submicroscopic gold, ie invisible gold, refers to gold contained in the structure of other minerals (mainly sulfides) in minor to trace amounts. Surface gold is the gold that was adsorbed onto the surface of other minerals during mineralisation and subsequent oxidation or metallurgical processing. Gold mineralogy has a significant impact on its extractive metallurgy. Gold process mineralogy helps address problems related to gold ore processing. It is widely used as a predictive and troubleshooting tool in gold ore processing, and provides useful information on process selection, flow sheet development, recovery improvement and reagent consumption optimisation. This paper will begin with the classification of gold ores, and will focus on gold mineralogy and how it impacts extractive metallurgy through case studies.

Jan 1, 2008

By T Lancaster

The Mount Gordon operation, consisting of the Esperanza open cut mine and the unique Mount Gordon Ferric Leach processing plant, is operated by Western Metals Copper Ltd at Mount Gordon, 125 km north east of Mt Isa. The processing plant treats predominantly the secondary copper sulphide minerals, chalcocite and covellite. The gangue consists of massive pyrite and a range of silicified siltstones. The processing plant utilises a conventional single stage SAG/cyclone milling circuit, followed by low-temperature/low-pressure autoclave oxidation to produce copper in solution. The pregnant leach solution is treated via conventional SX/EW technology to produce copper cathode. Currently the plant is operating at a nominal production rate of 48 500 tpa copper. The Mount Gordon Ferric Leach technology is the worlds first integrated pressure leach/SX/EW process to be used to treat copper sulphides on a full plant scale. In the last six months, July to December 2001, the plant has emerged from a two-year postcommissioning phase to achieve steady state operation. This has been characterised by high plant availability and consistent production performance in excess of the name plate capacity of 45 000 tonnes. Production rates will continue to increase over the next 12 months to over 50 000 tpa via a planned process of incremental improvements. The pressure leach circuit has consistently achieved availabilities exceeding 95 per cent over the past 18 months. Notwithstanding this, the leach circuit still has a much greater requirement for planned maintenance than SX/EW. For much of the Mount Gordon processing plantÆs operating life, the leaching process has constrained production. Recent developments arising from detailed mass and energy balance modelling have now significantly improved leach capability, resulting in the plant bottleneck being shifted to electrowinning. In order to balance the capabilities of the two circuits however, the surge capacity between leach and SX/EW was increased substantially. This effectively de-coupled the higher capability but lower availability leach circuit from the lower capability but higher availability SX/EW circuit. As a result, electrowinning utilisation has increased to in excess of 98 per cent, which is reflected in a higher overall plant throughput.

Jan 1, 2002

Largely inherited from the past and from strictly internal laboratory use, the certification of reference material using round-robin assaying is often insufficient for the use made today for external assay laboratory control by client parties. Certification often needs to be revisited on the basis of existing round-robin data, especially to derive reproducibility parameters to the end of establishing probabilistic performance gates for operational error detection on a batch per batch basis (ie batch-ærejectionÆ). The most common difficulty arises when only a few certification samples have been analysed in one single batch by each laboratory, so that the round-robin data do not contain the full variability that needs to be quantified. Existing certification data sets from properly submitted round-robin samples were studied using analysis of variance to derive a remedial method, leading to the proposal of default correction factors to restore full variability estimates when no other avenue is available.

Jan 1, 2008

By R E. Conder

A major initial and ongoing cost component in many mining operations is that of transporting mined materials and processed ore from the point of extraction or processing to the next operation. For various reasons the transport distance can be significant or in some cases the route may be particularly challenging. The trend to higher production rates to gain economy of scale benefits and capitalise on sales opportunities means that optimisation of transport can play a significant part in profitability. Apart from the cost criteria, increasingly there are other criteria such as environmental restraints, land ownership and security of supply that can have a significant impact on determination of the optimum route and transport vehicle. The paper aims to briefly highlight the important selection criteria and the benefits and disadvantages of the most commonly utilised transport vehicles. It then moves on to looking in more depth at belt conveying, highlighting the unique capabilities of the Metso MRC Cable Belt Conveyor system.

Jan 1, 2004

This subject of paramount importance in many modern plants employed in the extraction of gold from ores by cyanidation, involves several considerations.With the old-type "slimes decantation" process, using several tanks of large dimension, installed at high capital cost, it was frequently possible to obtain good settlement over a protracted period, but the disability of indifferent response to subsequent filtration and washing of the residual pulp, after decantation of the supernatant pregnant solution, was often present.In modern cyanidation practice, the tendency is to reduce capital expenditure by continuous processing of the ore pulp in a plant of less volume, but capable of handling more tonnage through-put and yielding, coincidently, less residual dissolved gold in the final pulp residues.INHIBITORY FACTORS.These involve a study of the effect of the circuit water or solution employed in milling and treatment, the amount of "primary" slime occurring in the ore broken underground, the constitution of the "walls" underground, the inherent occurrence of colloidal slime in partially decomposed ore, and the presence of kaolinised and ferruginous clayey structures carrying payable infiltrations of gold values, to mention some of the troubles encountered in practice. Practically all the difficulties occurring are due to the presence of colloids (using the metallurgical as apart from the chemical definition of the term), either...

Jan 1, 1935

By S J Riley

The cover (cap) over the tailings pit at Nabarlek uranium mine must be structurally stable as it will act as a barrier to radon gas emission and have to contain other long-lived radionuclides. Structural stability is primarily an issue of erosional stability in the context of a design life of thousands of years. The primary agent of erosion is fluvial, dominated by rainwash, overland flow, filling and gullying in the local area. Other agents of erosion are of less concern although biogenic agents of erosion (eg termites and windthrow) may enhance fluvial activity. Several methods may be used to assess erosional stability. They fall into two main categories, namely erosion modelling and geomorphic modelling. The former is illustrated by the Universal Soil Loss Equation in which parameters describing aspects of the geotechnical and hydrological properties of the rehabilitated surface are used as input for the modelling of erosion rates. The latter is illustrated by estimates of gully and valley erosion using empirical models. Estimates of the erosion rates and stability of the Nabarlek cover are presented. The two main techniques are complementary and it is argued that rehabilitation design must make use of both approaches when estimating erosion and geomorphic stability. More recent developments in geomorphic modelling using numerical techniques incorporate both approaches.

Jan 1, 1994

Cores of pre-Tertiary basement from ten oil exploration wells are related petrologically to the "axial", "marginal" and "shelf" facies of the New Zealand Geosyncline.A NW. Nelson-type basement is inferred beneath peninsular Taranaki and the western continental shelf. The terms Taranaki Basin and Wanganui Basin are re-defined and the terms North Wanganui Basin, South Wanganui Basin, Pipiriki High, Taranaki Fault, and Turakina Fault are proposed. Major faults are interpreted as of mainly transcurrent type and appear to form the western part of a splay at the northern end of the Alpine Fault. Evidence for a major Cook Strait Fault is reviewed.

Jan 1, 1967

The Ida Valley in Central Otago is one of series of parallel basins filled with freshwater sediments. The basins are in fact tectonic depressions superimposed on NE trending grabenlike structures which occur in the area and are the result of block faulting possibly initiated in Cretaceous times and concluded in late Tertiary and early Quaternary. In Central Otago this tectonic event affected metamorphosed rocks belonging to the eastern facies of the New Zealand Geosyncline and collectively known as the Haast Schist Group. These rocks constitute the basement and the shoulders of the tectonic depressions. The Ida Valley occupies the depression wedged in between the Raggedy Range to the NW and the North Rough Ridge in the SE. The valley is approximately 38 km long, 3 to 7.5 km wide and is drained by the NE flowing Pool Burn, which meets the SW flowing Ida Burn. The resulting unified stream flows into the Manuherikia river which drains the next door depression to the NW. The present work deals with the Ida Valley basin and more specifically with the geology studied within two Prospecting Licence areas held by Gold Mines of NZ Ltd on the southeastern flank of the valley.

Jan 1, 1977

By M S. N Hadi, J Hossein

Numerical modelling is extensively used in civil and mining engineering applications because of cost and risk problems associated with different experimental studies. In this study, the effect of resin thickness was evaluated in bolt-grout-concrete interaction and bending behaviour of a fully grouted bolt installed across joints in post failure region. Tests were conducted in 20 and 40 MPa concretes, and modelling simulations were made, using ANSYS version 8.1, to include both with and without different pretension loads. It was found that in all resin thickness, both the strength of the concrete and bolt pretension had major influences on the shear resistance and shear displacement of the reinforced medium. Also it was found that the strength of the surrounding concrete is more important than that of the grout thickness in both the shear resistance and shear displacement when the bolt is pretensioned.

Jan 1, 2005

By M Colwell

The Coal Mine Roof Rating (CMRR) is a rock (roof) mass classification (RMC) system/index that was originally developed by the United States Bureau of Mines (USBM) for aspects of underground coalmine geotechnical design and was first introduced to Australia as a part of the original Analysis of Longwall Tailgate Serviceability (ALTS) project conducted in 1997/1998. In subsequent years further refinement to its calculation was undertaken, such that the CMRR is now an industry standard for quantifying the structural competence of the primary bolted roadway roof interval and has been routinely/widely used by Australian collieries over the last 25 years with great success for roof support/chain pillar design. There have been many publications discussing the use and calculation of RMC systems and this paper also provides an important update and recommendations in how best to calculate the CMRR. However, it is rare to find an explanation as to why and how a RMC system/index satisfactorily takes account of the mechanics and rock mass behavioural issues associated with ground reinforcement. This paper provides such an explanation and insight with respect to the CMRR so it is: 1) better understood, 2) to allay any concerns, and therefore 3) will continue to be confidently used by and for the collieries’ benefit.

Nov 29, 2022

By D Craw

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300 - 400 ¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size enhancement. During range uplift, a small number of relatively large axial streams and rivers have developed in structural lows between growing antiformal folds. Axial streams 'gather' their flow from consequent streams draining the folds, and flow parallel to a range axis for some distance before cutting across it in an antecedent gorge. The axial streams rework alluvial fan sediments along the range margins, and transport mainly fine-grained gold from the fans along the ranges. This gold is redeposited where the axial streams emerge from a range in the neighbouring structural basin. Axial streams drain relatively large areas of range surface, and thus reconcentrate significant quantities of gold in a small number of relatively large fans and fluvial deposits. The processes of gold collection and re-deposition by axial streams are essentially the same, regardless of stream size. Coarse-grained gold produced by chemical remobilization, is more difficult to transport in fluvial systems, and thus remains in close proximity to eluvial environment where it was formed.

Jan 1, 1995

By E Whiteman, L Reyneke, H Horsch

Heavy mineral sand deposits are a source for the economically important element titanium, which is contained in minerals such as ilmenite and rutile. In heavy mineral deposits ilmenite displays various degrees of alteration. Natural weathering of ilmenite involves the removal of Fe and thus results in an increase in the Ti-content. Minerals such as pseudorutile, ferropseudobrookite, anatase and the ill-defined mineral aggregate leucoxene, which consists mainly of various amounts of remnant ilmenite, pseudorutile, ferropseudobrookite and anatase, are typical replacement products of ilmenite. Ferropseudobrookite occurs as a recrystallised, optically and chemically distinct mineral phase. Textural relationships suggest a diversity of physicochemical conditions including weathering and metamorphism that led to the formation of complex mineral assemblages and textures. In the heavy minerals industry the alteration products of ilmenite are generally referred to as æaltered ilmeniteÆ and/or leucoxene. The distinction between æaltered ilmeniteÆ and leucoxene is not consequently defined and is very much dependent on economic factors and specific mining operations (ie determined by deposit specific mineral assemblages). Generally the term leucoxene is used in the heavy minerals industry as a collective description for ilmenite alteration products with TiO2-components ranging from 65 - 95 per cent. A detailed comparative mineralogical investigation including microscopic, SEM and QEMSCAN« techniques show that it is possible to identify and quantify the replacement products of ilmenite on a micron scale. QEMSCAN« generated particle maps were graphically compared with photomicrographs taken by applying reflective light microscopy. The resulting information can be integrated over the entire sample with respect to composition, absolute and relative mineral abundances, grain sizes, volumes, densities, textural relationships and liberation potentials. This provides a powerful tool for a first appraisal of the physicochemical behaviour of bulk samples and individual particles during metallurgical processing.

Jan 1, 2008