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Aspects of the formation, decomposition and acid solubility of zinc ferrite were examined to find potential ways of increasing the recovery of zinc from a calcination process of mineral concentrates. Ferrite can begin to form within 2 hours at 450¦C. while complete reaction can occur after 35 minutes at 700¦C. The nature of the starting materials has a pronounced effect on the rate of formation and below 700¦C. ZnSO4 and Fe2O3 proved to be the least reactive of the materials investigated. It is possible that iron in a mineral admixed h sphalerite can be converted to a relatively inactive form, however, it does not seem possible to prevent zince f formation when iron is in the sphalerite lattice. At the two temperatures examined, 650¦C. and 700¦C, the presence of SO2 in the atmosphere accelerate .e formation of ferrite. Prolonged exposure to such atmospheres, however, caused the ferrite to decompose to ZnSO4 and Fe203. The optimum temperature for decomposition was 650¦C. and it was virtually complete within 2 hours in an atmosphere of 10% SO2 in air. Zinc ferrite was also decomposed by CO at low concentrations, and by heating with limestone at 1000¦C. for at least 2 hours. The solubility of zinc ferrite in acid was influenced by the starting materials used. As both the reaction temperature and the time at temperature increased the acid solubility decreased. The acid solubility was a minimum when the ___i_.. n - I -r~...................c -..... F, fe..i+e --A frn... A01- +^ Z(lo/

Jan 1, 1970

The development of the SECV brown coal open cut at Loy Yang will require depressurisation of aquifers both within and below the coal seam sequence in order to maintain open cut stability. Prediction of future open cut dewatering requirements at Loy Yang Open Cut and evaluation of the regional consequences of dewatering has required development of a detailed hydrogeological model of the Loy Yang area. The complex stratigraphy of the coal seam and aquifer/aquitard sequences at Loy Yang have been analysed and integrated with the hydrogeological concepts developed from regional groundwater studies to formulate a realistic hydrogeological model as a basis for finite-element flow modelling.

Jan 1, 1988

The Taupo Volcanic Zone (TVZ) is the largest active volcanic belt in New Zealand. It is

Jan 1, 1987

It is recognised by the current JORC (1999) code that resource classification involves the interaction of numerous qualitative and quantitative criteria such as data quality, geological continuity and grade continuity. No prescribed criteria and rules will work for all situations or even between different ore types within the same deposit. Also these criteria and rules are sometimes applied without a clear understanding of their appropriateness, accuracy or correct implementation. For these reasons case studies are useful to evaluate and compare criteria commonly used to assist in resource classification. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody are used as the basis of a case study for the above-mentioned purposes. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce a random sample grid, a semi-random sample grid and a regular sample grid. Using nearest neighbour, inverse distance squared, ordinary kriging and sequential gaussian simulation, block iron grades are estimated using these three blasthole data subsets as inputs. This provides four groups of estimates with the ordinary kriging estimate based on the complete blasthole dataset being considered to represent the true estimate of iron grades. Also generated during this process are estimates of the error for each block. These error estimates range from the simple, such as drill spacing, through to more advanced methodologies such as kriging efficiency and simulation. These estimates of grade and grade estimation error are then compared to the true estimate using graphs and statistics. In order of increasing accuracy the block grade estimation and simulation methods were nearest neighbour, inverse distance weighting, ordinary kriging and finally conditional simulation. The simulation in some instances doubled the accuracy of individual block grade estimates when compared to nearest neighbour and inverse distance weighting estimates. It was found that many methodologies for estimating the error of individual blocks performed equally well with only methods such as average drill hole spacing and classification by search ellipse pass number performing poorly. An approach on how to convert the abovementioned error estimates of individual blocks into a meaningful JORC classification is also discussed. Although advanced non-linear resource estimates are applicable, most iron ore mines are still using relatively straightforward methods. The use of blasthole data and some simple linear interpolation methods and simple linear based error estimates makes this study repeatable for most iron ore sites and their resource geologists. This style of investigation is recommended as a useful approach for the Competent Person to apply to their deposit and thus better select, implement and understand the criteria used for resource classification and provide more consistency and confidence in the resource classification process.

Jan 1, 2002

By G Davies, D Dunn, C Mawdesley, O Bertoli

The coal industry in Australia has been actively working in recent years towards the (re)integration of geostatistical techniques to the process of coal resource estimation. The benefits of using geostatistical techniques, over the current interpolation algorithms in use in coal modelling packages used to generate the grid estimates, need to be illustrated for the methodology to gain a broader acceptance in the coal industry. This paper focuses on the benefits gained at BHP Billiton Mitsubishi AllianceÆs Saraji mine for the estimation of the total product yield value at a 9.7 per cent product ash cut-off of a particular seam of the Saraji deposit. In order to perform this comparison, the results of the alternative estimation methodologies need to be benchmarked, which in most situations is achieved through the reconciliation of the estimates against production and/or process plant reconciliation data. Unfortunately, this benchmarking was not possible as no reconciliation data for the area of interest in the chosen seam was available, as it has not been mined at the time of the study. Where no reconciliation data is available, an alternative method is to use conditional simulations as the benchmark for comparison. The simulated values can be regarded as ærealityÆ, and the alternative estimation methodologies, based on a sampling of the underlying ærealityÆ, can then be compared using the simulated ærealityÆ as the benchmark for comparison.

Jan 1, 2009

By Woodcock J. T, Rummel P. H, Sparrow G. J, MacRae C. M

A rapid automated search method, developed for the location of native gold grains in polished sections with a scanning electron microscope (SEM), has been extended to locate platinum group elements (PGE), in particular platinum and palladium, and their minerals down to 1 ¦m in size. Problems associated with the search for PGE minerals are discussed and examples of PGE minerals located with the facility in drill core sections, crushed ores, and metallurgical test products are given.

Jan 1, 1991

By Toomey P. T

In many open cut coal mines, rivers and large creeks can cause planning and operating difficulties, both in the terms of the more obvious location of the current watercourse, but, and sometimes more importantly, past meandering of the watercourse. Prevent and past flow regimes may have deposited large alluvial sequences within the current mining areas. The presence of groundwater within the alluvium further complicates the planning and operating practices.A situation exists at Saraji Mine in which alluvial sediments overlie a massive sandstone sequence which in turn lies at about one metre above the coal seam. The problems encountered include high levels of groundwater ingress to the pit, highwall instability, and an unacceptably high rate of blast hole collapse (prior to charging with explosives). Other aspects of the dragline stripping operation were also affected.

Jan 1, 1992

By K Saito, M Hasegawa

Removing sulfur and phosphorus from molten iron can be expressed by the following reactions, respectively. [S]Fe + (O2-)slag = (S2-)slag + [O]Fe [P]Fe + (3/2) (O2-)slag + (5/2) (FeO)slag = (PO43-)slag + (5/2) Fe(liquid) These equations indicate that desulfurisation and dephosphorisation have opposite oxygen potential conditions. If a small amount of desulfurisation slag not removed is carried over to dephosphorisation process, the reaction of sulfur mentioned above proceeds toward left hand resulting in increasing sulfur content in molten iron. For better understanding of such re-sulfurisation reaction in hot metal pre-treatments, the present study aimed at evaluating the effect of iron oxide on the sulfur distribution ratio between slag and hot metal. To measure sulfide capacities and FeO activities simultaneously at temperatures below the melting point of pure iron, CaO-SiO2-FeO and CaO-Al2O3-FeO ternary molten slags were brought into equilibria with copper-iron-sulfur liquid alloys, and the equilibrium oxygen partial pressures were determined with an electrochemical technique involving the stabilised zirconia solid electrolyte. The experimental results showed that the sulfide capacity increased with an increase in FeO content, and this trend was consistent with the fact that FeO was basic. Although the addition of FeO raised the FeO activity and oxygen potential, the calculated value for sulfur distribution ratio between slag and hot metal increased with increasing FeO content.

Jun 19, 2024

Papua New Guinea is geologically prospective for large, medium and small mineral discoveries. All profitable developments to date have been very large mines but for every large mine there should be many small mines which could be developed under appropriate circumstances.The Papua New Guinea Government should, with appropriate changes to fiscal, legislative and policy regimes, create a favourable exploration envir-onment to encourage a major increase in exploration by small exploration companies and subsequent discoveries and mine development.

Jan 1, 1994

By McKee DJ

Future mineral processing developments will be of two types. There will be a continuation of the advances of the last 20 years including major increases in equipment capacities, the development of reliable on-line instrumenta- tion, the use of digital computers for automatic control, and the greatly expanded use of in-situ leaching techniques. However, there will also be a need for innovations as the industry faces a different set of problems to those involved in cost and extraction efficiency considerations. These new problems include those relating to energy usage, environmental pressures, and the further development of large low grade deposits and small, high grade metallurgic- ally complex deposits. Present technology does not appear adequate to solve many of these new demands. New treat- ment concepts will be required, and the immediate outlook in this regard is not encouraging. A major research and development task in mineral processing over the next 20 years will be to seek out new ideas and develop them, and this must be pursued with imagination and determination. Both the continuation of the present research pro- grammes and the development of new methods will require a steady supply of highly qualified technical personnel. These people are not being produced in the numbers required, and this situation must be urgently rectified.

Jan 1, 1981

By Zharinov SE

Geonechanical modelling of island arc sys- tems and their analogs is investigated. Slow seismotectonic movements along the inclined deep fault zone under the compressive horizontal stress conditions are proposed to be the princi- pal mechanism controlling the structures and processes in the active continental margins. A model of shearing surface crack in an elastic half-plane is used for simulation. The main ele- ment of the model is viscous interaction bet- ween the crack sides, the viscosity varying with depth. To describe the stress-strain state of the medium an integro-differential singular equation is derived and solved numerically. The results of simulation are in good agreement with geological and geophysical data on the ac- tive continental margins.

Jan 1, 1987

With production at Olympic Dam scheduled to commence in June 1988, it has been necessary to install a complete underground ore handling system capable of removing two million tonnes of material annually from the mine. The system comprises mucking from stope drawpoints, truck haulage to underground storage, primary crushing, conveying and hoisting. On the surface, material is conveyed to stockpiles at the Metallurgical Plant. Mining of the numerous special excavations within the system was incorporated into the mine's ongoing development program prior to the underground construction phase. Utilisation of a decline from the surface enabled versatile construction equipment to operate at the underground sites as well as simplifying the transportation and delivery of construction Materials.

Jan 1, 1988

By J Q. Cooper

The New Zealand rail authority, Kiwi Rail and Auckland Regional Transport Authority (ARTA), are jointly planning a new mainline rail link between Auckland’s downtown Britomart Station and the existing Western Line at Mt Eden. In 2009, APB&B, a consortia of Aecom, Beca, Parsons Brinkerhoff and Hassell Architects where commissioned to develop the conceptual design, Assessment of Environmental Effects (AEE) and business case for the new 3 km rail line towards preparing a Notice of Requirement to protect the route through Auckland’s central business district.This paper describes the engineering challenges in the development of the conceptual design for the three proposed underground stations, the running tunnels and connections to the existing network. Feasible alignment and station location options were developed and evaluated using multi-criteria analysis based on key client functional requirements, constraint mapping and environmental impacts. The resulting preferred scheme was then developed to a conceptual design suffi cient for assessment of environmental effects, risks, and the development of a robust construction methodology to allow high level capital cost estimates.The paper describes some of the major challenges overcome to develop the concept, including steep gradients, narrow street envelopes with existing buildings and structures, the need for large platform spaces with low ECBF rock cover and complex connections at Britomart and the main line near Mt Eden.The development of the conceptual design of the underground stations in particular demonstrates the need for a holistic value engineering approach to satisfying the architectural and functional requirements, in a highly constrained dense urban environment and at lowest practical cost. The construction methodology was a key input to the conceptual design development throughout.The conceptual design will be used as the fundamental basis for the development of the AEE and business case for the project in the future.

Mar 8, 2011

The paper discusses the characteristics of Be-zymianny activity during the last 2500 years. Three periods of increased activity have been identified which are the eruptive cycles lasting for 100-400 yrs. The periods of high activity fall on the fol-lowing time intervals: 2400-1700 yrs ago, 1350-1000 yrs ago and from 1955 ixp to the present time. The 1955-1956 catastrophic eruption after a long period of repose (about 900-1000 yrs) opened a new cycle of activity of the volcano which is continuing to-day. Several decades are distinguished in activity which differ in character and intensity of eruptions.

Jan 1, 1990

By J Bang, I-H Jung

Ti is an important constituent for steels and superalloys. During the continuous casting process and ElectroSlag Remelting process (ESR), Ti in molten steel and superalloy can have chemical reactions with casting flux and ESR slag containing CaO and CaF2. In order to investigate such exchange reactions, the understanding of the (Ca,Ti//O,F) reciprocal slag system is prerequisite. In the present study, a coupled phase diagram experiment and thermodynamic modelling of the (Ca,Ti//O,F) reciprocal system was performed. In particular, the phase diagram of the CaF2-TiO2 system was experimentally investigated by Differential Thermal Analysis (DTA) experiment and quenching experiments followed by Electron Probe MicroAnalysis (EPMA) phase analysis. The Gibbs energy functions of all solid and liquid phases in the (Ca,Ti//O,F) reciprocal system were optimised to reproduce the present data and all available reliable experimental data in literature.

Jun 19, 2024

By R G Warren

Most orebodies have cross-sections of less than 1 km2 and hence do not offer a particularly large target for exploration. Fortunately, although in the geological record ore deposits are small and rare and result from the exceptional coincidence of certain geological processes, these processes are mappable on a much larger, district to regional scale and constitute a mineral system in which the ore deposit is the central feature. A mineral system can therefore be defined as `all geological factors that control the generation and preservation of mineral deposits, and stress the processes that are involved in mobilising ore components from a source, transporting and accumulating them in more concentrated fonn and then preserving them throughout the subsequent geological history'. The mineral system concept emphasises that for many ore deposit types, although economically viable mineralisation may only occur on a scale of say, hundreds of metres, the total system of fluid-rock interactions that led to ore formation can extend over a distance of tens to hundreds of kilometres around the deposit. When mapped out, the total mineral system provides a far larger exploration target than the actual ore deposit itself. Important geological factors defining the characteristics of any mineralising system include: 1. sources of the mineralising fluids and transporting ligands; 2. sources of the metals and other ore components; 3. migration pathway; 4. thermal gradient; 5. energy source; 6. a mechanical and structural focusing mechanism at the trap site; 7. chemical and/or physical traps for ore precipitation. Many of these factors individually are common throughout time and space and are mappable on a regional scale. The delineation and empirical prediction of mineral systems can thus be approached by combining two components of metallogenic research. Firstly, the development of maps of regional geoscientific data and data sets of the distribution of factors significant for mineral systems in general. Secondly, the determination of the essential ingredients of particular styles or types of deposits in terms of mappable elements that any exploration program could focus on.

Jan 1, 1994

By Kuganathan V

The processing of black coal in Australia segregates waste in the form of coarse reject and fine tailings. The coarse reject is relatively easy to handle, while the tailings can be problematic. Conventionally, the two waste materials are disposed of separately, the coarse reject in dumps, and the tailings in man-made containments. Aqueous tailings slurry is pumped to a 'wet' tailings storage, where the fine particle size of the tailings limits dewatering. Their low bearing capacity and high compressibility result in tailings deposits being difficult to rehabilitate. Disposing of the waste streams separately moves away from the heterogeneous mixture in the undisturbed ground, and concentrates potential problems with each waste stream. The feasibility and desirability of the co-disposal of tailings and coarse reject by combined pumping is demonstrated. This technique is in operation at Jeebropilly Mine and is proposed for a number of other coal mines.

Jan 1, 1992

Basic premises for evaluating special characteristics of gold-bearing porphyry metal systems stem from their contrasts with properties of the class as a whole. Included features are differences in geologic, thus tectonic, environments, subtle but real differences in the proportions of accessory metals Mo-Ag-Au that are regionally and within some regions, tempo-rally distinct, contrasts in the Ag:Au ratios, petrological-geo-chemical as well as isotopic differences between intrusive suites, the age and nature of host terranes, contrasts in alter-ation style, and zoning variations of mineralogical and physical properties of rocks. These properties are linked in various ways in different regions and suggest that in large gold-bearing systems where gold may be uniformly distributed, environ-ments of emplacement, and compositions or sources of igneous "progenitors" may dominate in importance over processes, and that systems in which gold is zoned are processes-dominant.

Jan 1, 1990

By J D. Lubben

Hibbing Taconite is a Lake Superior-type granular magnetite taconite deposit occurring within the Biwabik Iron Formation along Minnesota’s central Mesabi Iron Range. The deposit is situated on the northern margin of the Proterozoic Animikie Basin. The deposit strikes northeast, dips gently southeast, and occupies 10 km of strike length. Mining focuses on 50 m of granular cherty and laminated slaty taconite within the Lower Cherty member.Ores generally consist of a quartz, magnetite, siderite, ankerite, minnesotaite, stilpnomelane, and haematite mineral assemblage. Processing is optimised by exploiting the physical and chemical variations that exist between three major ore types. Taconite ore averages 20 per cent magnetic iron (MagFe), 27 per cent weight recovery (WtRec) and produces a final concentrate with 4.5 per cent silica (SiO2). Since 1976, production has totalled approximately 237 million long tons (Mlt) of pellets (8 Mlt per year rated capacity).Ore processing uses a simple fl ow sheet of autogenous grinding (<0.044 mm) followed by two phases of wet magnetic separation, fi ltering, limestone/bentonite addition, balling, and firing to create pellets averaging 66 per cent total iron. A Liberation Index (LIS) is used as a primary guide for ore grading and metallurgical control. Grind requirements, magnetite liberation and silica grade are closely monitored to ensure plant optimisation and product quality.A recent program of benefi ciation of low-grade ores by in-pit crushing and dry magnetic cobbing has demonstrated that low-grade ores (<17 per cent MagFe, <25 per cent WtRec) can achieve a signifi cant metallurgical upgrade (up to 25 per cent MagFe and 40 per cent WtRec). This operation recovers 60 per cent of the total crushed volume, and has a calculated effi ciency factor (magnetic iron recovery) of 79 per cent. This paper discusses the benefi ts of this upgrading and its effects on ore blending and processing.

Jul 11, 2011

Mining of the silver-lead-zinc orebodies at the George Fisher Mine officially started in 2000. A review of mining performance to date shows that many of the extracted primary stopes have experienced some degree of hangingwall dilution. The degree of hangingwall failure in the stopes became progressively more extensive throughout mining of the orebodies in 2001 and 2002, culminating in the unplanned catastrophic failure of the 744D stope in which the ore between 13C (2683RL) and 12L (2714RL) sublevels caved into the previously mined cavity between 13L (2654RL) and 13C sublevels. This was followed several months later by another unplanned caving event in a nearby stope, 740D. As a direct result of these unplanned failures it was decided to mine the stopes with a smaller span than had been previously planned and in a primary-secondary pyramidal stoping sequence. To limit the exposure of the stope hangingwall, a hangingwall drive is no longer developed and therefore geologists no longer have access to the detailed geological information that this provided. Geologists at George Fisher Mine have had to be adaptable and flexible in response to these proposed changes and rely more on data from drilling than mapping for their geological interpretation. The result is that the drilling cycle has become much more critical in the planning process.

Jan 1, 2003