Search Documents

By M Stewart

Alluvial gold deposits in the area studied are preserved on the valley floor and elevated terraces due to a sequence of glacial/interglacial events during Pleistocene and Recent times. Continued regional uplift has overprinted these events. Prospecting by drilling and bulk sampling has demonstrated a complex alluvial gold resource which is now being mined.

Jan 1, 1989

Selective Recovery of Platinum from Cobalt-Rich Crust

Sep 13, 2010

By J R. Lang, J K. Mortensen

The Canadian Cordillera contains numerous classic porphyry deposits and several unusual subtypes, including the alkaline suite of porphyry Cu-Au deposits and the Tombstone magmatic suite and associated Au¦W deposits. The alkaline suite formed in collisional settings in island arcs whereas the Tombstone suite was emplaced in an active fold and thrust belt in a continental arc. In addition to different regional settings, these suites differ in the type of underlying basement, metallogeny, and the styles of mineralization. Both magmatic suites were emplaced over short intervals, probably in response to specific tectonic events. In the case of the alkaline suite, the tectonic event promoted magmatic processes suitable for the formation of porphyry Cu-Au deposits. The tectonic environment is less well constrained for the Tombstone suite, but the result was the formation of distinctive porphyry and intrusion-related Au¦W deposits.

Jan 1, 1995

The material presented in this paper describes experimental work to determine the effect of variations in suction nozzle design upon inlet flow conditions. Four entrance profile shapes were examined under controlled conditions of slurry flow and it was found that the straight ended nozzles had consistently higher entrance losses than the straight taper or the ellipse, and that the circular arc profile nozzles were the most efficient. Subordinate considerations were the measurement of the quantities and the forces involved.As the work progressed, three distinct phases in the pattern of flow were apparent and the static pressures in each were carefully examined. An inlet zone was found to be unstable in changing boundary conditions, a transition zone was largely independent of slurry density and in a zone of stability the pressures were found to be directly related to the characteristics of the flowing pulp. In this zone pressure measurements were reproducible within ± 2 per cent regardless of changing boundary conditions.The effect of varying the "1" parameter of nozzles with a part circular entrance profile was examined and it was found that flow conditions approaching the ideal were obtained when the radius of curvature was between 0·40 and 0·550.

Jan 1, 1966

By W. H. Tomlinson

This publication presents the basic text for a 20-hour accident-prevention training course developed for supervisors by the Federal Bureau of Mines. During the past 2 years, the course has been used by the Bureau in teaching more than 300 groups of coal-mine supervisors-men whose responsibility is twofold: To manage in production and maintenance phases of coal mining and to guide their men along paths of safety. This is a handbook for teaching teachers. In this handbook will be found references to safety practices followed by companies that consistently have low accident records. These companies credit their outstanding performance to the adoption and faithful observance of accident prevention by supervisors and workers alike on a wholesome, cooperative basis. Teaching safety to workers involves both on-the-job and classroom-type instruction. If such training is to be permanently effective, it must be reinforced consistently on the job by the immediate supervisor of the worker. This publication is intended to provide such a supervisor with the motivation to provide such follow-up and shows how he can accomplish it effectively.

Jan 1, 1962

By Tom George

"INTRODUCTIONNo. 1 Queens Rd was an existing 10-storey office building founded on large pad footings. This project involved the construction of a 6-level, 15m (50-ft.) deep basement excavated immediately adjacent to the existing building and also beneath the existing footprint of the Southern end of the building. The total perimeter of the new basement was to be approximately 200m (656 ft.) all with a retained height of 15m (50 ft.). It was also proposed to add a further 5 storeys to the building. Approximately 18 of the existing columns supporting the 10-storey building were to have the applied column load diverted from the existing foundations at ground level onto the new piles or basement raft 15m (50 ft.) below.The geotechnical profile consisted of fill for the top 1.5m predominately comprising of clayey sand with a high gravel content from 1.5m to 9m (5 to 30 ft.), a medium dense to dense clayey sand and then below was a sandy clay extending to 15m (50 ft.) ranging from stiff to very stiff. From 15m on completely to extremely weathered siltstone was encountered. The groundwater was measured at 9.5m (31 ft.) below the natural ground surface.DESIGN BRIEFThe existing building columns were founded on large pad foundations up to 4.4m (14.5 ft.) square, founded on the dense clayey sand. These pads would require temporary support to enable the excavation to proceed beneath them. Upon completion of the excavation under the pads new columns were to be constructed joining into the existing columns to transfer the load onto the new raft slab, 15m (50 ft.) below. The existing 10 floors were to be refurbished. It was planned to undertake all the temporary support and transferring of loads while the structure above was only able to provide a dead load. It was decided that any movement of the building would have minimum impact on a skeleton structure. During the temporary support of the columns, movements due to construction activities had to be monitored to understand any potential stresses in the structure above.The original design required beams to be installed under the pads and supported at either end by temporary piles that were to be founded below the level of the proposed excavation. (Refer to sketch 1). Wagstaff Piling considered that this methodology had difficulties in construction at all stages and did not provide facility for transfer of the load without significant movement of the structure above. Wagstaff Piling revised the design to attach beams to the columns above the pads using shear collars. (Refer to sketch 2). These beams supported on the temporary piles could then be jacked upwards to remove loads off the pads. This would enable removal of the pads with minimal movement of the 10-storey building above. (Refer to photo 1 and back cover photo)."

Jan 1, 2005

By J. Böhlke, B. Friedrich, E. Hecker

The legislation for the disposal of heavy metals contaminated substances is still going to be tightened up in the future. The main criteria for the utilization or deposition of these residues are the content and the water solubility of these metals. Through this, the use of slags from the lead-and zinc-industry in road building may become limited or even not possible at all. From an economic point of view this would lead to Pb/Zn losses and costs for safe dumping. This paper investigates the feeding of the reducing agent via hollow electrode DC smelting and the yield of metal reduction. After carrying out thermodynamic calculations, the process window conditions for electric-arc furnace tests were determined. Doing this, the zinc could be reduced, evaporated and recovered as an oxidic intermediate product flue dust, while the lead was present either in flue dust or in metallic form. The zinc content in the final slag could be reduced by up to 90%. The slag product has undergone an eluation test which allows it to be used as building materials. Keywords: zinc reduction, lead reduction, hollow electrode, slag treatment, electric arc furnace

This publication summarizes, for potential contractors and other interested parties, the research, development, and demonstration contract projects programed by the Bureau of Mines for fiscal year 1982 (October 1, 1980 -September 30, 1981) under its Minerals Health and Safety Technology program. Contingencies may require that a significant port ion of the program be deferred into fiscal year 1983. The objective of these projects is to provide an ordered and sequenced series of advances toward the Bureau's overall goal of providing the systems technology required to create a healthier and safer working environment for the Nation's mining and minerals processing workers.

Jan 1, 1981

By Vu Van Dong

Resource estimation is the science of determining the amount and quality of a given material in the ground that has the potential to be mined at a profit. This is because during this time computers have become more widely available and more powerful and software packages have become more comprehensive and user friendly. Over the past three years The Mining Geology Company with the support from Vinacomin Group has developed the Coal Geological Modelling and Reserve Estimation ? VMG system. The VMG system enables the geological and mining engineer to start at the reserve estimation for the mine design and planning. The VMG system enables the national and international standards (NI43-101, CIM-Canada; SAMREC Code, Africa, and JORC Code, Australia) and user friendly with menu driven thereby permitting the engineer with minimal computer training to rapidly learn and utilize the system. Geological and mining data input through digitized map files and drill-holes information files stored in the database that is an integral part of the VMG system with the main function for collection, validation, and recording, storing and processing of data will include both ?primary? (observation and measurement) and ?interpreted? data. It is recommend that data be stored digitally, using a documented, standard format and a reliable storage medium that allows for easy and complete retrieval of the data. The coal reserve estimation through standard polygon methods with the increased use of these mathematical techniques (geometrical modelling, geostatistical method, least square method, ?) over the last ten years corresponds, to some degree, to a decrease in both the amount of the coal deposit mapping and, in particular, coal seam structural interpretation and modelling, and permit rapidly evaluation of coal seam and overburden quality and quantity. The understanding of the relationship between the coal mineralization of interest and the likely related complicate geological processes and structure that govern its emplacement and geometry within the geological framework is essential to the establishment of the geological controls for coal mineralization. System outputs includes: drillholes summary reports, stratigraphy, cross-sections, isopach maps, structure, contour maps, premining and post mining topography maps, and 3D perspective view on coal seam structure.

Oct 1, 2009

SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg in June 1969, may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal, at the reduced price of R5.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). "The world sulphur position," by W. C. J. van Rensburg (Member). "The South African sulphur position," by D. L. Taylor (Member). "The recovery of pyrite at Government Gold Mining Areas Limited," by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. P. Carlisle (Member). "Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment," by W. A. Gilbert (Visitor) and E. A. Nugent (Member). "The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process," by D. J. Tutt (Associate Member). "Pyrite recovery by jigs at Durban Roodepoort Deep Limited," by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). "The storage of pyrite concentrates," by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). "The flotation plants of the Anglo-Transvaal Group," by L. A. Bushell (Member). "Pyrite flotation with amines and cyanidation of the products," by E. H. D. Carman (Member). "Gold recovery by cyanidation from mill products obtained after pyrite flotation," by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). "The influence of sulphydryl and cationic flotation reagents on cyanidation of native gold," by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). "Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector," by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy). INCOME TAX: POST-GRADUATE STUDY COURSE CONCESSION As a result of representations made by the Associated Scientific and Technical Societies of S.A. and the Suid-Afrikaanse Akademie vir Wetenskap en Kuns, engineers and scientists will now be allowed to deduct expenses incurred on post-graduate study courses from their taxable income. The conditions of this concession are set out in section 16 of the Income Tax Act, 1969, which reads as follows: 16. (1) The following section is hereby substituted for section 16 of the principal Act: 16. "Notwithstanding the provisions of section 23(a) and (b), there shall be allowed to be deducted from the income of any person who is a dentist or medical practitioner or practises any profession referred to in paragraph (a), so much as the Secretary may allow of any expenditure incurred by such person in the circumstances contemplated in paragraph (c), if the Dental Association of South Africa in the case of a dentist, or the Medical Association of South Africa in the case of a medical practitioner, or the "Suid-Afrikaanse Akademie vir Wetenskap en Kuns" or the Associated Scientific and Technical Societies of South Africa in any other case, certifies in such form as the Secretary may prescribe that such person- (a) if he is not a dentist or medical practitioner, is the holder of a degree in engineering or allied technology or natural sciences awarded by a recognized university on completion of a prescribed minimum period of study of not less than four academic years or the equivalent thereof and enabling the holder thereof to practise the profession of an engineer or a profession for which advanced and specialised scientific knowledge is required which relates directly to- (i) the development or exploitation of natural resources; (ii) mining or prospecting for minerals; (iii) the production of pastoral, agricultural or forest produce ; (iv) the breeding or care of farm animals; (v) any industrial process; or (vi) the training of specialists in any branch of science or technology connected with any aforementioned profession; (b) has practised his profession for not less than three years; and (c) has incurred such expenditure during the year of assessment in respect of the attendance by him of any postgraduate study course approved by such body to improve his qualifications for carrying on his profession in the Republic". (2) The amendments effected by subsection (1) shall first take effect in respect of assessments for the year of assessment ending on the twenty-eighth day of February, 1970. From this section it is clear that the concession will only be granted if the application is accompanied by a certificate, which certificate must be either signed by the Chairman of Die Akademie or the President of the Associated Societies. In terms of the authority granted such certificates must certify that: (i) the taxpayer concerned has practised his profession for not less than three years; (ii) the expenditure was incurred by the taxpayer during the year of assessment indicated in the certificate; (iii) the expenditure was incurred by the taxpayer in respect of the attendance by him of a post-graduate study course approved by the Associated Scientific and Technical Societies of South Africa or Die Suid-Afrikaanse Akademie vir Wetenskap en Kuns, as the case may be, to improve his qualifications for carrying on his profession in South Africa; (iv) the taxpayer is the holder of a degree in engineering or allied technology or natural sciences, which degree was awarded by a recognized university,

Talvivaara deposits, Kuusilampi and Kolmisoppi, comprise one of the largest sulfide nickel resources in the world with 642 Mt in Measured and Indicated Resource categories. TalvivaaraÆs preferred extraction technology is bioheapleaching, which is already widely used for other metals, notably copper and gold. The company has demonstrated the viability of bioheapleaching technology for the extraction of nickel using the Talvivaara ore. The leaching process is heat generating and therefore suitable for the subarctic climatic conditions. The planned annual metal production is 33 000 t of nickel, 60 000 t of zinc, 10 000 t of copper and 1200 t of cobalt. Talvivaara deposits are well-suited for open pit mining due to a thin overburden, favourable resource geometry and a low waste to ore ratio. The ore is relatively low-grade, but well suited to bioheapleaching due to its high sulfide content. Bioheapleaching is a process whereby metals are leached from ore as a result of bacterial action. The bacteria used in the Talvivaara bioheapleaching process are endemic to the area and therefore well adjusted to the prevailing environmental conditions. The solution is collected at the bottom of the heaps and either re-circulated through the heap or fed to metal recovery. In metal recovery, nickel, copper, zinc and cobalt are precipitated from the pregnant leach solution and filtered to produce saleable metal products. After the metals are removed, the solution is further purified and returned to irrigate the heaps. Mining, bioheapleaching and metal recovery techniques for the Talvivaara mine have been tested in a 17 000 t on-site demonstration trial during 2005 and 2006. Subsequent construction of the mine started in 2007 and commercial production in the fourth quarter of 2008.

Jan 1, 2009

By E. S. Machlin

The wzodel of Blandin and Diplunt;, generalized to include a phase factor, is applied to the carbon-carbon interaction in iron. Darken&apos;s "energetic" model is generalized to include not only first neighbor interactions but further neighbor interactions as well. On the bases of these generalized models relations are derived for the activity of carbon in both austenite and ferrite in terms of the carbon-carbon Pair interaction energies. A single function then yields the pair interaction energies consistent with the experimental activities of carbon in both ferrite and austenite. Thus, a simple explanation is given for the observation that the nearest-neighbor interaction between carbon is repulsive in austenite and attractive in ferrite. Certain consequences of this approach are explored. OnE object of the present paper is to attempt to take into account the consequences of electrostatic contributions to the carbon-carbon pair interaction energy for carbon as a solute in iron. Friedel&apos; has shown that oscillations in electrostatic potential are to be expected about a solute atom in a metallic solution. Blandin and 6lant6&apos; have shown that such oscillations yield an interaction energy between pairs of solute atoms that obeys the relation: W{ = A cos(2ftFri + 4>)/(kFri)3 [l] where kF = Fermi wave vector, ri = distance between solute atoms comprising the pair7 <p = phase factor dependent only on electronic nature of solute and solvent, A = coefficient dependent only on electronic nature of solute and solvent. Machlin3 found that Eq. [I] accurately described the pair interaction energy derived from short-range order measurements based on field ion microscope observations of dilute alloys of platinum. He also found that the value of the phase factor $ derived from residual resistivity measurements agreed well with that obtained from the analysis of the short-range order data. Harrison and paskin4 were able to predict the long-range ordering energy of 0 brass using Relation [I] and residual resistivity values to predict the value of the phase factor $. Machlin5 has repeated their analysis and applied it to the prediction of the long-range ordering energy in AgZn and AgCd with excellent agreement between prediction and experiment. Both A and $ are independent of the crystal structure. The Fermi wave vector depends uniquely upon the conduction electron concentration per unit volume in the spherical approximation of the Fermi surface. Thus, Eq. [I] is expected to apply to both fer- rite and austenite with only one set of values of A and $. Mossbauer studies6 yield the result that iron has one 4s electron. We shall make an assumption found to hold previously for platinum3&apos;7 and nikel, which is that only the s electrons are involved in shielding the perturbing potential of carbon. With this assumption, kF = 1.35 A-l. Although A and $ may be obtained from certain mdels&apos;&apos;&apos; we shall take A and $ to be empirical constants in the spirit of Kohn and osko.&apos; Thus, Eq. [I] involves two adjustible parameters. Consequently, two independent relations in A and $I are required in order to evaluate them for carbon as a solute in iron. We may use a recent analysis of Aaronson, Domain, and poundg who showed that Darken&apos;s energetic model,1° as well as others, can be used to describe the activity-temperature data for carbon in iron in both the aus-tenitic and ferritic phases. Darken&apos;s model takes into account only first neighbor pair interactions. For our needs, all neighbor pairs need to be taken into account. It is convenient to generalize Darken&apos;s model. The result for the partition function for austenite is: over the temperature range 800" to 1200°C and where the uncertainty corresponds to one standard deviation. Eq. [4] effectively yields only one relation. Another relation is required to obtain unique values for A and $. One property of Eq. [4] is that it is independent of crystal structure. Hence, data for a iron can be used to obtain another relation. To arrive at this relation we must generalize Eqs. [2] and [3] so that they may be applied to the bcc a iron. The result is that:

Jan 1, 1969

By M. J. McLeod, D. R. Lux, R. P. Taylor

"The Mount Douglas Granite constitutes the eastern part of the Saint George Batholith and contains the youngest, most differentiated phases of the batholith. It also contains extensive endogranitic, low-grade. Sn- W-Mo-bearing sheeted vein systems. Early phases of the Mount Douglas Granite are coarse- to medium-grained, seriate granites that represent the slowly cooled carapace of the intrusion. Late phases are medium- to fine-grained, equigranular and porphyritic granites that were accompanied by repeated and widespread fracturing of the carapace and injection of mineralizing fluids. These granites represent a highly differentiated suite with ""A "" type affinities developed in a ""within plate"" transitional to ""syn-collision"" tectonic setting. 4oAr/ 39Ar dates for biotites from the various phases indicate emplacement circa 367 Ma.The linear distribution of some phases in the Mount Douglas Granite and the systematic orientations of sheeted veins along tensional fractures indicate structural control on granite emplacement and vein distribution. This type of relatively passive endogranitic mineralization is unique in the granites of southern New Brunswick and contrasts markedly with highly fluidized systems operative elsewhere in the area. IntroductionInvestigation of Sn-W-Mo occurrences in New Brunswick has shown that most of this mineralization is associated with late, highly differentiated phases of post-orogenic (Acadian) granitoid magmatism that occurred during Devonian and Early Carboniferous time (Ruitenberg and Fyffe, 1982; Taylor et al., 1988). The polymetallic Mount Pleasant Sn-W-Mo deposit (Ruitenberg, 1967, 1972; Kooiman et al., 1986)and the Burnt Hill W deposit are two orebodies of this type in New Brunswick. Numerous smaller deposits associated with these granitoid rocks in southwestern New Brunswick have been documented in previous investigations (Ruitenberg, 1967, 1968; Ruitenberg and Fyffe, 1982; Taylor et al., 1985; Lentz, 1985)."

Jan 1, 1988

By R. Mensah-Biney

The aqueous biphase separation process (ABS) has been used to separate ultrafine industrial minerals. The partition behavior ofTiO2, Al2O3, Fe2O3 and kaolin was not pH dependent. The partition behavior of SiO2 was, however, pH dependent. The partition coefficient of kaolin in PEG 3400/ Na2CO3 biphase system was 150 and that of the silica in the same system was 0.02, resulting in a separation factor of 8500 between kaolin and silica. The aqueous biphase separation system was used to separate free silica from kaolin in a raw clay sample from Mexico. The partition behavior of mica, feldspar and clay from North Carolina was also evaluated.

Jan 1, 1999

By Allan E. Martin

As part of a comprehensive investigation of tae mechanism of desulfurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of :lines, in cooperation with the Institute of Technology., University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope. Vogt5/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FeXCay)S and (MnxCay)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.

Jan 1, 1941

By P. H. Davenport

"The ore-element patterns in regional lake sediment geochemical survey data from four areas of Newfoundland containing granite-related mineralization reveal characteristics which can be used to identify mineralized granitoids. The St. Lawrence Granite with its fluorite deposits, the Ackley Granite with molybdenite mineralization, the Grey River tungsten lodes and the newly discovered Mo- W mineralization at Granite Lake, Central Newfoundland, have all been included in the regional lake sediment geochemical surveys, which now cover about 90,000 km2 of the Island of Newfoundland. The lake sediments over these mineralized granites show diagnostically high values of Mo, F, Pb, Zn and, in three of the four cases, U, together with locally high Ag and Cu values. Furthermore, these ore-metals display a distinctive zoning pattern about the intrusives, which can be related to the classical ore-metal zoning patterns developed about many types of mineralized granitoids.IntroductionGranitoids in Eastern Canada are receiving renewed interest as potential hosts of tin, tungsten, uranium and related mineralization. Although a number of mineral deposits and showings have been known from a few granites (sensu lato) in the region for many years, granites had generally received little attention as potential hosts of metallic mineralization until the recent resurgence in interest in the mineral potential of these rocks. In Newfoundland, where granitoid rocks underlie about 30070 of the land area, petrologic data are available from some granites, particularly those in eastern Newfoundland (Strong et al., 1974; Strong, 1980), but in southern and southwestern Newfoundland the data base is sparse, and indeed in many cases individual plutons are not delineated on the geological maps of the area . Most of the available data on Newfoundland graniotolds have been summarized by Strong (1980), who gives a general assessment of their mineral potential by comparing their physical, mineralogical and petrochemical attributes with mineralized granites elsewhere in the world."

Jan 1, 1982

By Bin Zhang

Drilled shafts are a popular type of foundation for transportation applications. They feature the advantages of providing high bearing capacity and generating low construction noise. Advancements in construction technology make it possible to construct drilled shaft with large diameters. In some transportation projects, the full structural loads are carried by a single large diameter drilled shaft; therefore accurately determining the bearing capacity of drilled shafts has important practical and safety implications. The increase of drilled shaft diameter combined with the structure properties of the surrounding soil play in an important role in their bearing capacity. The conventional methods for bearing capacity determination, which mostly come from experience with small diameter drilled shafts, may not work satisfactorily. This paper studies the influence of diameter on the bearing capacity of laterally loaded drilled shafts. Numerical simulations are conducted to investigate the effects of pile diameter on the lateral bearing capacity, especially the influence of shaft diameter and its structural contributions.

Jan 1, 2007

By C. J. Kirkland

For two thousand years and more, we insular Britons have been grateful for the existence of the narrow strip of water that separates us from mainland Europe. It has given us a sense of security against invaders, though it has been breached many times. The first recorded serious consideration of a fixed crossing of the English Channel was in around 1802, when it was suggested to Napoleon I. The motive was not entirely peaceable and the British Navy, who saw themselves as defenders of our shores, were decidedly unenthusiastic A whole series of imaginative schemes were proposed in the course of the nineteenth century, embracing viaducts, immersed tubes, artificial islands as resting places for the horses which were to draw carriages, as well as mechanically bored tunnels. The first Channel Tunnel Company was formed in 1872, and an application for permission to construct a tunnel was made to the British parliament. A Colonel Beaumont, of the Corps of Royal Engineers designed and constructed a machine which, in around 1882, bored over a mile of tunnel out to sea from Britain which exists to this day.

Jan 1, 1991

By C. Koopman

During the production of phosphoric acid from phosphate ore and sulfuric acid, large amounts of calcium sulfate are formed, in which impurities from the feedstock are incorporated. To use the calcium sulfate in, for example, the building industry, a lower concentration of impurities is desired. Mercury, copper, lead, and cadmium were extracted from clear industrial recrystallization acid (0.8-3.9 mol/kg H3PO4, 0.2-0:5 mol/kg H2SO4) by supported solvent extraction with the extracting agent Cyanex 302 in kerosene in a transverse flow hollow fiber module. The permeability for the mercury ion was 1.4.10-6 m/s, whereas that for the copper ion was calculated to be 1.5.10 m/s. Cadmium, lead, and copper were extracted during the recrystallization of calcium sulfate hemihydrate to dihydrate, an existing step within the ,phosphoric acid production process, by solvent extraction with the same extracting agent. The concentrations of cadmium and zinc in the newly formed calcium sulfate were proven to be decreased. Unfortunately, concentrations of mercury and lead were too low for analysis.

Jan 1, 1999

By Bernard H. Hertlein

Transportation system structures have come under very close scrutiny in the last couple of years, largely due to the damaging effects of disasters, both natural and man-made. In the Pacific northwest and California, earthquake risk is a major concern. In the central and eastern states barge impacts on bridge piers and docks are a big worry. In all cases of bridges over water and waterside structures, scour is a primary concern. Some of the results of this scrutiny have been changes in design and construction methods, and the introduction of more testing to supplement field inspection during construction, and throughout the service life of the structure. Future construction of bridges and docks will almost certainly see a continuing growth in these practices. Where foundations are concerned, particularly for bridges and waterside structures, many state and local authorities have started specifying drilled shafts rather than driven piles. Where the shafts must be constructed under water or slurry, visual inspection of most of the work is impossible, and one of several different Nondestructive Tests (NDT) is often specified. Contractors&apos; experiences with these methods have varied considerably, and there is a great deal of controversy in the deep foundation industry over the reliability of NDT methods for assessing the integrity of foundation shafts or piles. The author has had more than 15 years of practice with the various NDT methods for deep foundations, on projects all over the US, particularly foundations for bridges and dock structures, and has developed an understanding of the "NDT controversy" as it has become known. In particular, experiences in the Pacific Northwest, California, and Alabama have illustrated the reasons for the controversy. This paper reviews these experiences, and suggests some steps that owners and contractors can take to reduce the risk of inconclusive or downright inaccurate test results.

Jan 1, 1998