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This modern plant was installed with the object of treating all oxide ore and payable dump material by the cyanide process.The plant is located on a ridge on the eastern side of Linda Gully. The mill -site has a slope to the south of 1 in 4.The new plant is of steel and concrete construction and was specially designed to suit the climatic conditions which exist at Mount Morgan.THE COARSE CRUSHING PLANTThe ore received from the, mine is dumped into a 600-ton steel bin which is commanded by a 3 ft. 6 in. gauge railway,The mine ore is conveyed by steam locomotives in rakes of five self-dumping 7-ton railroad cars. The dump material is mostly loaded by bull-dozers and conveyed to the binsin large motor lorries. Located on the top of the bin is a heavy railroad grizzly having 12-in openings through which all ore must pass.The flow of ore from this steel bin is controlled by a No. 7D 3-speed Ross chain feeder. It should be mentioned here that, although the bottom of the steel bin is inclined at an angle of 45°, it has been found, owing to the clayey nature of the oxide ore, that the live capacity of the bin is only about 50% of the total capacity.

Jan 1, 1939

By Lam. E. K., J. W. Jarvi, B. P. Bharadwaj

"The Rabbit Lake Operation is located in Northern Saskatchewan on the western shore of Wollaston Lake approximately 800 km north of Saskatoon, Saskatchewan.The Operation is owned by a joint venture of Cameco Corporation and Uranerz Exploration and Mining Limited. Cameco is the operator.The Mill started production in June 1975 under the ownership of Gulf Minerals Canada Limited and over the past twenty years has increased the rated production capacity to over twice the original design.The Mill was originally designed to process 485,000 tonnes per year of ore with an annual production of 2.0 million kg of U308 (yellowcake). During the past ten years changes in ore sources and process modifications have led to increased milling capacity and production targets. The Mill has treated a total of 8.6 million tonnes of ore and produced over 40 million kg of U308 in the twenty year period, despite the shutdown and cutbacks in operating time since 1989.The 1995 tonnage throughput was 206,000 tonnes per year. Annual production though has risen to 3.6 million kg of yellowcake despite the departure from full-time to half-time operation in 1991 (7 up-7 down). The forecast for the coming years will see tonnage rising from 300,000 to 570,000 tonnes, production of 4.5 to 5.4 million kg of yellowcake and an anticipated return in the year 1998 to full time operation.This paper will give a brief history of the Mill and focus on the present flowsheet and recent improvements to the process."

Jan 1, 1996

By S. Caron, P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. However, over the last decade, Discrete Element Method (DEM) modelling has shown an interesting potential in describing the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics, and in developing solutions to industrial practice. With the objective of bringing this modelling technology into the concentrator control room to assist operators, this paper aims to describe the main elements needed to apply this emerging and developing technology to on-line mill performance monitoring.

Jan 1, 2004

By X-F Zhao, J-W Li, L-P Zeng

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The formation of Kiruna-type deposits has been ascribed to either immiscible iron phosphate melt separated from silicic magma or precipitation from magmatic-hydrothermal fluids. The early Cretaceous Ningwu volcanic basin in Eastern China contains tens of Kiruna-type iron deposits. The orebodies are mainly hosted within the top zones of subvolcanic dioritic intrusions and along the contacts between these intrusions and adjacent volcanic rocks/strata.The orebodies are commonly associated with widespread brecciation and wall rock replacement. Magnetite formation was closely associated with extensive hydrothermal alteration that may extend kilometres, with both vertical and horizontal zonation. Field and textural data indicate that magnetite formed slightly later than albitisation but coeval with apatite and actinolite. Elemental analysis of magnetite and apatite from ores shows distinct features to those as igneous accessary minerals in the host dioritic intrusions, suggesting a genetic relationship to magmatic-hydrothermal processes. Magnetites have elevated TiO2 (up to 5 wt per cent) and V2O3 (up to 0.7 wt per cent), which implies that they are derived from incipient high-temperature magmatic fluids. It is concluded that the Kiruna-type deposits in the Ningwu basin most likely formed from high-temperature magmatic-hydrothermal fluids. The emplacement of dioritic intrusions into a subvolcanic setting likely plays a critical role in the development of Kiruna-type deposits.CITATION:Zhao, X-F, Zeng, L-P and Li, J-W, 2015. Kiruna-type iron deposits in the Mesozoic Ningwu volcanic basin, Eastern China – origin and relationship to subvolcanic dioritic intrusions, in Proceedings PACRIM 2015 Congress, pp 657–662 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By J. P. Theron

Paper written on project work carried out in partial fulfilment of Phd.(Process Engineering) degree Process modelling is an essential element in the development of advanced (model-based) process control systems, accounting for up to 80% of the cost of development. Often, models based on historic process data are the only viable option when dealing with processes that cannot be modeled cost-effectively from first principles. Despite major advances that have recently been made in the field of nonlinear process modeling, some basic idea of the dynamic behaviour of a process system is important prior to system identification. While many process systems seem unlikely to be linear, the possible nonlinear aspects of their dynamics are not necessarily supported by the data. This may have significant implications for subsequent system identification or interpretation of the data. For example, it is quite possible that an underlying nonlinear deterministic signal may be obscured by a high degree of measurement or process noise, to the extent that it may be critical in the choice of model to fit to the data. The method of surrogate data analysis has recently been proposed as a means to classify the underlying dynamics of complex systems, and in this paper the use of Fourier transform surrogates to classify process systems is explored. Keywords: modelling, process control, simulation, surrogate data analysis, nonlinear systems.

Jan 1, 2004

By R L. Brathwaite

The gold-scheelite-quartz lodes of the Wakamarina valley were the most productive of the mesothermal gold-bearing areas in the Marlborough Schist. Most of the production came from the Empire City and Golden Bar mines which worked the Golden Bar lode. Only 134 m of its 1800 m strike length are accessible, in the No.2 level of the Golden Bar Mine. A fault has downthrown the Golden Bar Mine section by = 47 m and displaced it left-laterally by 18 m. The lode is a typical ribbon-banded mesothermal vein, averaging c. 1.75 m wide, and enclosing narrow horses of schist country rock. It is composed of bands of milky æbuckÆ quartz with thin laminae of schist. Scheelite occurs in short strings of grains within quartz on the footwall side of the lode and also in small quartz-carbonate veinlets in the foot wall and hanging wall schist. The lode quartz contains only localised traces of pyrite and arsenopyrite. They are more abundant in the wall-rock schist.   The Golden Bar lode lies within a steeply dipping normal fault, which, on its footwall side, is adjacent to a 40 m-wide, shallow-dipping mylonite shear zone. Within 1 m of the lode, the shear foliation has been dragged down to nearly parallel the lode footwall. Wall rock alteration is manifested by a marked increase in K and Rb, which correlate with abundant illite/muscovite and K-feldspar within 2 m of the footwall of the lode. Amphibole, stilpnomelane, and pumpellyite show a progressive decrease towards the lode. As and Sb increase close to the lode, but are at background levels within the lode itself. Enhanced Cr (150-430 ppm) in the quartz, relative to the schists (~40 ppm), suggests that the source hydrothermal fluids passed through and leached mafic rocks, such as the metabasites from the hanging wall of the lode (~400 ppm Cr).

Jan 1, 1995

By F. T. Cawood

This article is a continuation of a series of publications by the authors on the international debate on resource nationalism, with specific reference to South Africa. Previous outcomes have shown that mine nationalization is not a solution for South Africa, and that maintaining stability of the current mineral and tax regimes is fundamental. It will not be wise to replace existing law and policy instruments until there is a better understanding of the distinction between fact and public perception about the impact of the current system. The new scheme of state custodianship linked to a mining royalty that effectively targets economic rents provides for effective resource use. The methodology in this article is to consider how South Africa's mineral tax regime can be tweaked to achieve optimal management and benefit from mineral extraction and associated rents by avoiding changes feared by investors. The major finding is that the current suite of instruments can be considered a suitable platform for optimal management of resource rents. However, it will be necessary to first investigate ways of improving the mineral beneficiation intent of the royalty structure, and secondly investigate whether the mineral rent portion of the royalty formula can be ring-fenced for the purpose of establishing a sovereign wealth fund.

Jan 1, 2013

By F. D. Ford, Z. Dai

"Vale’s Ontario Operations re-introduced Cu/Ni separation at Clarabelle Mill in 2006. The mill processes ores from a number of mines in the Sudbury basin. A saleable Cu concentrate is produced at 30-60% Cu recovery from mill feed, which has to meet the quality specification. In particular, Ni content in Cu concentrate must be less than 0.6%, otherwise, penalties will apply and diminish the value of Cu concentrate, in addition to the lost Ni value. Generally, a Ni grade of less than 0.4% is obtained in Cu concentrate. More recently, while processing Cu-rich ore, Cu concentrate contained more than 0.6% Ni which is abnormally high. Detailed mineralogical investigation shows that Cu-rich ore contains more millerite in comparison to typical Sudbury Ni sulphide ore. Millerite is found to be more floatable than pentlandite and is much more difficult to depress using high-lime aeration conditioning, which is the standard practice in Cu/Ni separation to float chalcopyrite while depressing pentlandite. The current operation uses sodium cyanide at 20 g/t to depress pentlandite and pyrrhotite. However, it is found that a high dosage is required to depress millerite. It is also shown that starch and dextrin are promising in millerite depression.INTRODUCTIONPrior to bulk smelting in 1991, Cu/Ni separation was carried out at Vale’s Copper Cliff Mill, Ontario Operation. The typical Cu concentrate grade was around 30% Cu and 1% Ni. This is very high in comparison to today’s value of 0.4% Ni and would not be acceptable for external processing. However, the Cu concentrate was processed internally at the Copper Cliff smelter/refinery, so the Ni contained in Cu concentrate was not lost and no actual penalties applied. During the SO2 abatement initiative, bulk smelting was chosen because of the perceived simplicity and consequently, Cu/Ni separation was eliminated (Agar, 1991) and the Copper Cliff mill was subsequently demolished. In 2005 and after more than one decade of bulk smelting, business changes required the removal of some Cu concentrate from Clarabelle Mill bulk concentrate to provide smelter capacity for Voisey’s Bay concentrate in the Copper Cliff smelter. In essence, this strategy calls for Cu removal at Clarabelle Mill (Lawson, 2006). In this case, Cu concentrate is sold externally and it must meet the quality requirement of less than 0.6% Ni."

Jan 1, 2011

By C. Sun

The Leeville underground mine has been in operation since 2006 and currently produces 3,500 tons of ore per day with an average gold grade of 0.34 opt. The mine has a large horizontal extent of 2,500 feet by 500 feet and a vertical extent of 20 to 200 feet. Based on the characteristics of the ore bodies, a long-hole stope and cut-and-fill mining methods are used at the deposits which are divided into several mining zones. Cemented rock fill (CRF) is used as the backfill in the open stope. CRF design includes the aggregate design, the ratio of cement and fly ash design, and strengths for the long-hole stope and cut-and-fill. In the aggregate design, the particle size distribution is one of the most influential aggregate characteristics in determining how it will perform as a basic backfill material. Gradation helps determine durability, porosity, cement and water requirements, strength, and shrinkage. To cut the backfill cost, fly ash usually is added into the binder to replace some part of cement. However, adding fly ash can affect the strength of the backfill. The reasonable percentage of fly ash is also important for making a good and low cost backfill. Based on the different mining method, the different backfill with different strength is designed. A systematic quality control procedure for aggregate and backfill is followed. After four yeas application, CRF system in Leeville achieved very good results.

Jan 1, 2011

By Lance Rasband, Richard Hanke, John Starcevich

"Mining on Seattle’s SR99 tunnel began in July of 2013. Initial mining progressed slowly through a 4.5 m (14.9-ft) thick fiber-reinforced concrete headwall before immediately entering the first of three planned safe havens. Once through the headwall and safe haven the machine would move through roughly 122 lineal m (400 ft) of jet grout improved soil at a rate of slightly more than 1.6 m/d (5.3 ftpd). It was anticipated that once mining has passed through the improved area, “Bertha” – now the world’s second largest tunnel boring machine (TBM), would be moving at a rate of almost 11 m/d (36 ftpd). By the end of October 2013, Bertha had mined roughly 131 m (430 ft), averaging 1.4 m/d (4.7 ftpd), and had begun mining within native soils. By the start of December 2013, tunneling had reached the 244 m (800 ft) mark and Bertha was averaging 3.6 m/d (11.9 ftpd), achieving as much as 12.8 m (42 ft) of progress on given days. Unfortunately, on Dec. 6th, 2013, Bertha began to stumble and all progress quickly came to a halt.Initial reports stated an obstruction had stopped Bertha in her tracks. The preliminary investigation involved installation of 10 deep dewatering wells to reduce the hydrostatic pressure within the ground around the TBM, to allow the contractor’s personnel to inspect the cutter head from within and also to investigate for the presence of obstructions at the face of the cutter head. During inspection, the contractor’s crews found fragments of steel pipe entangled in the cutter head. The steel was apparently from an abandoned 254 mm (0.9 in.) diameter monitoring well casing, previously installed by the Washington State Department of Transportation (WSDOT) to monitor groundwater conditions for the design and planning of this tunnel project. After the steel was removed from the cutter head and cleared from Bertha’s path, she attempted to move forward but was only able to generate a slow crawl."

Jun 1, 2016

By Robson W. D, Irwin D. A

In November, 1932, an investigation of silicosis was undertaken at the, McIntyre Porcupine Mine, Schumacher, Ont., atfer a discussion of the problem with Sir Frederick Banting and his, staff. As a result it was decided to carry on dusting experiments with animals at the mine in a manner that would duplicate as far as possible actual industrial conditions.At that time 50, guinea pigs were placed in the crusher nouse tunnel of the mill where a considerable quantity of fine dust, containing approximately 35 per cent., of free silica, was being constantly produced. These animals lived in this atmosphere for periods up to one year, and, while on autopsy large amounts of dust were found in the lungs, not a single case of silicosis had developed. These negative results suggested, among other things, that the mine gases might be a predisposing factor in the production of silicosis, and the results of this investigation led us to undertake the study of the hydrogen-ion concentration of the condensate of the atmosphere, both in the mine and in various sections of the mill.The C02 combining power of blood serum on a series of 400 miners was also studied at this time. While these results were inconclusive, the variation in the hydrogen-ion concentration of the condensate between the surface and underground atmospheres encouraged us to investigate the effect of neutral, weak acid and alkaline solutions on the solubility of silicious materials. Gye and Purdy were the first to point out that the chemical reaction and not the physical presence of silicious material was responsible for the production of the fibrosis in silicosis. This work was investigated by Gardner and Cummings who showed that the tissue reaction to quartz was definitely proportional to the size of the particle. They found that 1-3 micron particles of quartz produced an acute proliferative fibrotic response while the 10-12 micron particles produced only a foreign body reaction up to a period of three years. It is accepted that the dangerous silica particles retained by the lung are under 5 microns in diameter. We assumed that if the solubility of the silicious material retained in the lung could be reduced sufficiently by the addition of some non-toxic element or compound the usual fibrotic respohse would be modified. We found that the addition of certain compounds to silica would reduce its solubility in the beaker to a slight extent. But these compounds, when mixed with quartz...

Jan 1, 1945

By Shawn Healey, Ray Norcross

"Site IdentificationNew Britannia MineA 50/50 WX Gold Inc. - High River Gold Mines Ltd. Joint VentureTVX Gold Inc. is the OperatorLocationThe New Britannia Mine is located in the town of Snow Lake, Manitoba, which is situated between Flin Flon and Thompson, 420 miles north of Winnipeg.Brief Description of OperationNew Britannia Mine processes 2000 tonnes per day at an average grade of 4.5 g/t. Mill recoveries are currently 91 YO, accounting for forecast of 98,000 ounces for 1998.New Britannia Mine's mill complex incorporates conventional crushing, grinding and carbon-in-pulp technology. The design capacity of the New Britannia Mine mill is 1850 tonnes per day. The mill has processed upwards of 2300 tonnes per day, with no required upgrades.Gold recovery averaged 89.8% for 1997 compared to the planned 87% recovery expected from projected metallurgical test work. Year to date recovery mid December 1998 stands at 91.1 %Cash costs for the 1998 year to date were down to U.S. $221.49 per ounce, down 12% from the 3rd quarter of 1997. Milling costs for 1998 YTD were at Cdn. $9.38 per tonne and Cdn. $73.50 per ounce.Geology - (Orebody Description)The Snow Lake gold deposit is located within the Aphebian Flin Flon / Snow Lake Greenstone belt. This belt is composed of an assemblage of poly-deformed volcanosedimentary supercrustal sequences intruded by pre and sin tectonic ultra mafic and mafic intrusions and sin to post tectonic granitoid.The principal gold bearing rock at the New Britannia Mine is made up of quartzcarbonate material in sequence of basic and acidic volcanic rocks contained within a shear zone. The ore itself is gold associated with the sulphide mineral arsenopyrite and contains some pyrite, pyrotite, plus chalcopyrite. Proven and probable reserves at December 31, 1997 were at 4.04 million tonnes at 4.6 g/t and underground exploration continues to confirm the extension of the ore zones to depth."

Jan 1, 1999

By T. Yegulalp, R. Farrauto, A. Belova, M. Castaldi

Calcium oxide, with its ability to capture and store carbon dioxide, is emerging to become an important tool in carbon management. Calcium oxide can be used reversibly to capture carbon dioxide in situ and then be regenerated to produce a pure stream of carbon dioxide ready for sequestration; the Zero Emission Coal Alliance technology utilizes this property of calcium oxide to generate emissions-free electric power from coal. The reaction of calcium oxide with carbon dioxide resulting in thermodynamically stable carbonate is well understood; however, the efficiency of this reaction is limited by the diffusion of gases through bulk calcium oxide and through a layer of carbonate formed on the surface. In addition, the regeneration of calcium oxide is an endothermic reaction and is favored at high temperatures. The purpose of this paper is twofold: first, to address the diffusion limitation, a thin layer of calcium oxide, supported on a high surface area material, is studied thermogravimetrically to demonstrate the physical adsorption of carbon dioxide on calcium oxide. The adsorption is to take place at temperatures lower than required to form calcium carbonate.

Jan 1, 2007

By D. W. Nel

Nanofiltration (NF) has attracted much attention over the past few years due to the reduced energy consumption compared to reverse osmosis (RO) and better separation performance compared to ultrafiltration (UF). Although research has been done in the area of NF of nickel ions, sodium ions, and acid separation, not much attention has been given to the separation of high nickel concen¬trations from sulphuric acid streams. The use of NF for the separation of nickel and acid from a spent nickel electrolyte is an innovative process alternative for future industrial application within a base metal refinery. In this study, the separation performance of a composite polyamide NF membrane on a spent nickel electrolyte was investigated by varying the sodium sulphate concentration in the feed (50-150 g/l), the trans-membrane pressure (35-55 bar), and cross-flow velocity (1.5-3.5 m/s), and measuring quantities such as total permeate flux, acid rejection, nickel rejection, and sodium rejection. The nickel and acid concentration in the feed were kept constant with variations between 40-60 g/l and 25-40 g/l respectively, while the temperature of the experiments was kept constant at 50°C. The membrane was found to be very selective for nickel ions, with the rejection of nickel ions varying between 54.4% and 98.2%. The rejection of acid ions varied between -5.9% and 21.8%. The rejection of sodium ions varied between 16.6% and 72.4% at a cross-flow velocity of 2.5 m/s and sodium sulphate concentration of 50 g/l in the feed solution. An increase in trans-membrane pressure increased the rejection of nickel, sodium, and acid ions, while an increase in sodium sulphate concentration decreased the rejection of nickel and acid ions. The total permeate flux was found to increase with an increase in trans-membrane pressure and decrease with an increase in sodium sulphate concentration. The cross-flow velocity had an insignificant effect on the total permeate flux and the rejection of nickel, sodium and acid ions.

Jan 1, 2013

Taking the Presidential chair of the Australasian Institute of Mining Engineers, my first duty is to thank you for the high honour and position you have conferred on me. A position entailing the highest compliment the Institute could bestow on any of its members, and one which I feel my inability to properly fulfil, inasmuch, as you have men in your ranks of the highest scientific training residing on that great continent where the head quarters of the Institute is established, while my engagements here will not permit me leaving this colony but for a very limited period.About six years ago, during the time the mining boom was at its height, there came to this colony from England, Germany, and South Africa, several mining engineers, who in conjunction with the mining engineers here, formed an Institute which we soon found we were not able to maintain. The mining boom gradually died away, and many engineers have left the colony to find employment in other parts of the world. We made overtures to your Iqstitute to take us under your wing, which you were kind enough to do, and the outcome is that you have come over 1200 miles to hold a meeting in New Zealand. The paucity of members residing in this colony does not admit of a large attendance; but we heartily welcome you to our shores and hope you will enjoy a holiday visiting some of the principal mining centres and exchanging ideas, which not only improves our minds, and widens our field research, but also tends to lead to further economic improvements in the extraction of metals the earth contains...

Jan 1, 1903

By Marc Arl

Failures of the face and roof above longwall shields have caused days and sometimes weeks of lost production. A common recovery method for these failures has been to pump light weight cementitious grout into the roof and face cavity to stabilize the area This approach while effective is very time consuming and costly. Mines in several coal producing nations have over the past few years been applying phenolic foam grouts in these situations in lieu of cementitious materials. Phenolic foam is a two-component injection product intended for cavity filling, air and gas sealing and the consolidation of highly fractured strata. The properties of phenolic foam; rapid application, quick setting, high expansion rate, high compressive strength and excellent anti-static properties, produce a fast, safe and cost effective cavity filing solution. The product is also classified as fire resistant and so is also suitable for sealing off underground heatings and for aiding fire fighting operations in deep mines. This paper will discuss the application and use of phenolic foam in various underground coal mines in the world over the past few years.

Jan 1, 2005

By Abraham Lindo

"Blasting plays a key role in hard rock underground mining. It is by nature a violent and destructiveextraction method designed to economically fragment the rock into a suitable size for it to be loaded and hauled as part of the specific mining process while controlling the amount of damage to the surrounding rock mass."

Jan 1, 2016

By Brown H. R, Wright E. A

The authors identify the workable coal seams, their distribution in relation to quality and economic occurrence and relate their analytical characteristics to industrial use. The development of established collieries is also discussed with regard to increased production demand.The authors also indicate the potential of the coal resources of the Southern District and postulate their ultimate development.INTRODUCTIONThe Southern Coalfield yields 30 per cent of the total production of bituminous coal in New South Wales. The economic potential of the coalfield was examined last by Harper (1915). Since that time additional knowledge has been gained by prospectors, mining companies and public authorities. Expansion in the steel industry and the building of power stations on the coalfields together with improvements in fuel technology, mining methops and road transport have resulted in production of coal from seams mice thoughtto have no economic value.DESCRIPTION OF THE COALFIELDFor the purpose of this paper the term Southern Coalfield includes also the South-Western Coalfield which together comprise the following Coal Districts:IllawarraDouglas ParkWollondilly-NattaiMoss Vale-Berrima (Hanlon, 1953).Geographically the coalfield is contained by the Illawarra Range in the east, the Shoalhaven River to the south, the Wollondilly River to the west, and in the north by a line...

Jan 1, 1958

By W. W. Adams

Lower accident rates were the outstanding feature. of the second annual sand and gravel safety competition conducted in 1930 by the United States Bureau of Mines in cooperation with the National Sand and Gravel Association. Both the frequency and, severity rates for accidents were greatly reduced as compared with those shown by the first year's contest, that for 1929. Three times as many plants were enrolled, and the number of man-hours of work represented wad more than doubled. Seventy-six sand-and-gravel plants, situated in 20 States, participated in the competition, as compared with 26 plants, located in 13 States, in the year before. The number of man-hours of employment, which indicated the amount of exposure to occupational hazards, was 4,915,592 an increase of more than 100 per cent over, the previous year's total of 2.259,572 hours. The frequents of accidents declined from 74.4 per million hours for all plants enrolled in the first year's contest to 42.7 per million man-hours for all plants enrolled in 1930. The accident-severity rate was reduced from 9.7 days of disability per thousand man-hours of exposure in 1929 to 5.9 days of disability per thousand man-hours of exposure in 1930.

Jan 1, 1931

By Thamiris Auxiliadora Gonçalves Martins, Karen Espina Gomes, Amilton Barbosa Botelho Junior

The present work aims at the synthesis of nanoparticles of copper by chemical reduction in microwave oven. The solution used comes from the selective copper precipitation of the lateritic nickel leachate. The copper solution (20mL) was placed in a beaker, and 2mL of 100g/L ascorbic acid and 20mL of 20g/L sodium citrate were added in that order and at room temperature. The pH of the mixture was corrected with 1M sulfuric acid or 2M sodium hydroxide. Then the mixture was placed in a microwave oven. The effect of pH, time and microwave power were evaluated. The morphology, composition and size of the particles were verified in Scanning Electron Microscopy with Energy Dispersion Spectroscopy (SEM/EDS). Results showed that the particles formed had no nanometric size. This may have occurred because the reducing action of ascorbic acid together with sodium citrate generates a very rapid reduction rate, which makes it impossible to form particles on a gauge scale. Particles synthesized at pH 4, after 4 minutes of reaction with 1000W of power presented particles with spherical morphology and only copper in the composition.

Oct 3, 2019