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By William Petruk, J. H. Gilles Laflamme, Jean Robitaille, Louis J. Cabri

"A quantitative mineralogical study using ore microscopy, electron microscopy, proton-microprobe, image analysis, and material balances was done on samples from the circuit of a concentrator in Quebec, with particular emphasis on the Cu concentrate. The ore contains many different minerals, of which the principal ones, in decreasing order of abundance, are pyrite, sphalerite, chalcopyrite, bornite, galena, tennantite, and pyrrhotite. Minor to trace amounts of covellite, chalcocite, stannoidite, mawsonite, colusite, wittichenite, miharaite, hessite, petzite, electrum, and an unidentified Cu-Pb-Bi-sulfide also occur.Liberation of pyrite is very high in all size fractions for all samples (ranging from 80-91 %). Liberation of chalcopyrite, bomite, sphalerite, and tennantite is relatively high, on average, in the head .sample and Cu concentrate (55-78% and 66-88%, respectively). Most of the chalcopyrite in the flotation tails is not liberated, whereas about one half of the tennantite and sphalerite are liberated in both the flotation and :final tails. Recoveries calculated for the Cu concentrate (on the basis of assays, mineralogy, and image analysis) are chalcopyrite 72. 5%, bornite 73. 7%, sphalerite 41.0%, tennantite 70.9 %, and galena (together with some trace minerals) 34.2%. It was also calculated that the Cu concentrate contains 10.0 % of the pyrrhotite and i.4 % of the pyrite.Materials balance calculations were done on the five major sulfide minerals to determine the mineralogical distribution of 13 major, minor, and trace elements (as determined by protonmicroprobe analyses). It was determined that tennantite is the principal carrier of Bi (67%), As (90%), and Te (86%) in the Cu concentrate. Therefore, removal oftennantite, which is mostly liberated in the Cu concentrate would significantly reduce these three contaminant elements, but at a loss of9% of the Cu, 2.0% of the Zn, and 0.7% of the Ag. The precious metals (Au, Ag) occur as discrete minerals (electrum, petzite, hessite). Some of the Ag also occurs in solid solution in bornite (23.1% of Ag in Cu concentrate), tennantite, and sphalerite. Four of the major sulfides (chalcopyrite, bomite, sphalerite, tennantite) in the ore also contain measurable concentrations of the following trace elements: Se, Cd, In, Sn, and Sb, occurring mostly as solid solutions. Some of these elements are also concentrated (up to about 18%) in minor and trace minerals such as colusite, stannoidite, and mawsonite."

Jan 1, 1999

By Sergei Decterov, Peter Hayes, Evgueni Jak, Taufiq Hidayat, Denis Shishin

Copper smelter operations around the world are under sustained pressure to reduce costs and increase output. Through the provision of reliable data on fundamental properties of the chemical systems the opportunities for improvements of industrial copper production can be identified. Experimental and modelling studies on phase equilibria, thermodynamics of copper slag/matte/metal/gas systems have been combined into an integrated research program undertaken at PYROSEARCH. Experimental phase equilibria studies involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of compositions of equilibrium phases with electron probe X-ray microanalysis (EPMA). Thermodynamic databases development and modelling is undertaken using the computer package FactSage in conjunction with advanced models used for complex solution phases. Progressive development of these research methodologies has brought significant advances in characterisation of these complex systems, including a new optimised thermodynamic database for the copper-containing slag system Cu2O-Al2O3-CaO-FeO-Fe2O3-MgO-S-SiO2.The new data and models can now be applied to assist in improvements of the processes. The effects of changes to chemistry and process conditions within the smelting reactor can be examined. Several examples of new descriptions of the phase chemistry of the Cu2O-CaO-SiO2 and Cu2O-FeO-Fe2O3-SiO2 systems in equilibrium with metallic copper showing calculated and experimental data are presented.

Jan 1, 2014

By R. L. Virta

Four companies mined ball clay in four states during 2005. They included H.C. Spinks Clay (owned by Franklin Minerals), Kentucky-Tennessee Clay (owned by Imerys), Old Hickory Clay and Unimin. Production was estimated to be 1.32 Mt (1.45 million st) valued at $53.3 million, based on the results of a preliminary survey of the ball clay industry. Production in 2004 was 1.22 Mt (1.34 million st) valued at $54.1 million. Tennessee was the leading ball clay producer state with 61 percent of domestic production, followed by Texas, Mississippi and Kentucky.

Jan 1, 2006

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies were determined calorimetrically for Na2Cr04, A reversible transition was found at 700° K with an isothermal heat of transition of 2,263 cal/mole. High-temperature X-ray diffraction analysis showed that the transition was a crystal change from the low-temperature orthorhombic form to the high-temperature hexagonal form. At 795° K the hexagonal form had the parameters a, = 5.691 and co = 7.478 A. Powder diffraction data for the high-temperature form are given and possible structures discussed. The melting point was determined to be 1,065° K with a heat of fusion of 5,810 cal/mole. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate enthalpies of formation, free energies of formation, and equilibrium constants of formation from 298° to 1,400° K. Equations that represent enthalpies above 298° K are given.

Jan 1, 1972

By R. H. Grau, A. Sainato, S. J. Schatzel, T. M. Kohler, A. T. Iannacchione

This Bureau of Mines research study found gas emission rates from an advancing face, and flows and pressure of gas from an exploration drill hole were dependent upon the geology of salt encountered in a domal salt mine. Normal production-grade "pure" salt adjacent to an anomalous' zone was found to have a methane emission rate of less than 5 ft3/ ton (0.1 m3/t) of mined salt from a room advanced by a continuous miner. Extremely low gas flows [less the 4 ft3/h (0.1 m3/h)] and lack of pressure buildup were also observed from this normal salt in a 154-ft (47-m) exploration drill hole. These data indicate that methane emissions should not be a problem when mining in this type of salt. In the adjacent anomalous zone, methane emission rates ranged from 15 to 70 ft3/ton (0.4 to 1.8 m3/t) of mined salt from an advancing face. Gas flows of approximately 42 ft3/h (1.2 m3/h), and pressures in excess of 900 psig (6,200 kPa) were observed in an exploration drill hole when the anomalous zone was encountered. This information suggests a greater methane emission hazard from the anomalous zone than from the associated normal salt. If this trend of increasing emissions problems associated with anomalous zones of salt is common with similar anomalous zones encountered or observed in other domal salt mines, then special control strategies should be employed to minimize this potential mining hazard.

Jan 1, 1984

By Jonathan E. Ludlow

A field test was conducted to demonstrate and quantify the relationship between deep cutting and the creation of airborne respirable dust for longwall mining With a double-ended ranging drum shearer. The testing program was carried out on the 3 North longwall of North American Coal Company's Quarto No. y mine in Claringten, Ohio. Continuous recordings of the dust levels were made at both the midface and tail ate areas. Data were collected during 27 shifts during which time 81 complete mining, cycles took place. Both drum speed and the number of picks per line were varied systematically during the testing program to alter the depth of cut while the production rate was held constant by maintaining a constant haulage speed. The test results indicated that at the midface position, airborne respirable dust was strongly dependent upon the depth of cut as influenced by both the drum speed and number of picks. Drum speed had a much stronger effect than number of picks over the experimental range, since a halving of drum speed reduced dust levels by approximately 60 percent while removal of every other vane pick resulted in only a 2.1 percent reduction at constant production. At the tailgate position, however, neither effect was strongly apparent. A tendency for the slower drum speeds to he associated with reduced power consumption and higher haulage speeds (and therefore production rates) was also noted. It is recommended that longwall operators oper¬ate at the lowest available drum speed wherever possible.

Jan 1, 1981

By Tony A. Rorke, Joe R. Brinkmann

The application of instrumentation to better understand and improve production blasting is one of the most fruitful areas of explosives and blasting research. The majority of instrumented studies of production blasting have relied on the extrapolation of far field measurements to postulate blast performance in regions of interest closer to the charge where rock breaking takes place. However, the nonlinear and dissipative nature of the quantities being measured raises serious questions as to the accuracy and validity of such extrapolations.

Jan 1, 1991

By P. Ashayer, J. Curran

Introduction Rockfalls occur when rocks or boulders detach from mountains or hills and tumble down. They can pose significant hazards to infrastructure such as highways, buildings, and mine open pits, and they sometimes result in personal injury or death. Prediction of rockfalls is a difficult task. Slopes that are at risk of rockfall have highly variable geometries. The location, mass, and shape of the rocks that might dislodge and fall are uncertain. Moreover, the materials that make up a slope can vary considerably from one section to another. Furthermore, the relevant material properties are usually not well known. Performing probabilistic simulations of rockfalls, combined with proper statistical analyses, has proven to be an effective and acceptable method for dealing with these difficulties [1, 2, 3]. The movements of a falling rock can be classified as freefall, bouncing, sliding, toppling, or rolling. The falling trajectory is controlled mainly by the geometry of the slope, the block shape, and the energy dissipated at each contact of the block with the slope. A rockfall model is evaluated based on its ability to efficiently predict the velocity, frequency, height of bounce, and run-out distance of falling rocks. With this information, the engineer can design remedial measures such as restraining nets and ditches. Most of the existing rockfall simulators are based on particle models that consider the falling rock as an infinitesimal particle with a mass, called the lumped mass or stereomechanical models [1, 2, 3, 4]. Other models involve hybrid methods relying on simplified assumptions. The most common hybrid methods are based on contact searching for the movement of a dimensionless object and incorporate some aspects of rigid body impact for bouncing [5, 6, 7]. There are also some rigid body models in the literature that employ simplified versions of rigid body models [8, 9]. This study applies a more sophisticated rigid body theory based on rigid body impact mechanics (RBIM), which was developed by Stronge [10, 11, 12]. The new theory captures all modes of rigid body movement. Due to the importance of the rock geometry, single impacts of ellipsoidal and prismatic rocks with rectangular cross sections are investigated. The effect of rock slenderness on rebound velocities and energies is also investigated for ellipsoidal rocks. The correspondence between the model parameters and the data from the rockfall literature data will be discussed.

Jan 1, 2007

By David A. Larson

Preliminary laboratory experiments have been conducted by the Bureau of Mines to define the influence of bit geometry on methane ignitions as a step toward establishing safer mining-machine operating parameters. The experimental system was designed to simulate the operation of a continuous mining machine, using a drum-type cutterhead of normal diameter with a narrow cross section, permitting full-diameter drum cutting tests to be run on material representative of sandstone lenses (or inclusions) in coal seams. Two conical bit types were tested at shallow depths of cut with three drum speeds. Bits that rotated in the mounting block during testing did not produce ignitions. The ignition frequency for used bits was three to four times greater than for new bits at the same kerf depth.

Jan 1, 1983

By D. L. Sawyer

The Bureau of Mines studied alumina extraction from uncalcined, kao-linitic clay at temperatures from 1000 to 2500 C using 20-or 27-wt-pct-HCI concentrations and with an acid-to-clay ratio of from 0.8 to 1.4 times stoichiometric. Autogenous digestion pressures ranged from atmospheric pressure to about 900 psia. Extraction of 96 pct of the alumina was obtained by HCI leaching at temperatures and leaching times that varied from 1000 C for 120 h to 2000 C for 15 min. Hydrochloric acid stoichiometry of the reaction A1203'2Si02'2H20 + 6HCI + 2AICl3 + 2Si02 + 5H20 was studied at different temperatures and leaching times in a 750-mL tetrafluoroethylene-polymer-lined autoclave. A combination of high temperature and 20 wt pct excess HCI promoted rapid and almost quantitative extraction of alumina (99 pct in some tests). Additional Bureau data obtained with 35-mL tantalum bombs and leach-ing tests with added fluoride are also provided. At high temperatures, the addition of fluoride did not result in a significant improvement over HCI alone and was deleterious to the filtering properties of the digest residue.

Jan 1, 1985

By A. M. Tunstall, N. Djordjevic, H. A. Villalobos

The damage zone behind a typical smooth-wall blast in the open pit was assessed by visually examining diamond drill core to identify blast-induced cracking, mapping core rock quality designations to identify changes in fracture frequency and conducting uphole seismic testing to determine changes in rock mass characteristics. The results from the three techniques show reasonable correlation. They suggest that major damage, in the form of fracturing of intact rock, occurs at least 7 m behind the smooth-wall blast and significant damage, in the form of opening and extension of calcite-filled fractures, at least 12 m from the blast. At greater distances the dominant damage mechanism is the loosening of existent joints within the rock mass. In the trachytes at El Soldado these damage mechanisms correspond to peak particle velocities of 2 000, 900 and 500 mm/s respectively

Jun 19, 1905

By D C. McPhail, S L. Rogers, J Brugger

Using iron- and sulfur-oxidising bacteria to catalyse the breakdown of sulfides that host the gold is an important biological method for the pretreatment of refractory gold ores. Following this biological treatment a combination of chemical and physical methods are used for leaching (such as the cyanide process) and concentration (such as carbon-in-pulp or electrowinning) of gold. Although these methods are well accepted by industry, they harbour limitations in the processing of low-grade refractory ores, and regulatory agency/public acceptance of cyanide use. Thus, it is beneficial to industry to develop environmentally friendly, cost-efficient leaching and concentration techniques that are based on micro-organisms. This may soon be possible by adapting the results of recent regolith geoscience research, which has shown that micro- organisms are capable of driving a biogeochemical cycle of gold dispersion, transport and reconcentration in the supergene environment. The indigenous microbiota in biologically active soil microcosms from a number of Australian sites are capable of solubilising up to 80 wt per cent of the gold contained in these materials during 50 days of incubation. Studies using molecular microbial techniques have shown that a metallophilic bacterium, Ralstonia metallidurans, is present in biofilms on gold grains from a number of Australian sites. R metallidurans is capable of actively accumulating gold from solution, suggesting that the bacterium may contribute to the formation of secondary gold grains and nuggets. Identifying the biochemical and physiological pathways that lead to the dispersion and accumulation of gold in regolith, and quantifying the reaction kinetics of these processes may thus lead to the development of industrial bio-processing capacities for gold-containing ores.

Jan 1, 2007

The Bayswater seam of the Singleton Coal Measures is discussed in relation to its field occurrence and related li~hotype profiles. The seam is correlated throughout widely separated areas of the Hunter Valley with the Farrells Creek seam at Howick, Broke seam at Broke, and Saddlers Creek seam at Mt. Arthur. The unusual features of composition of the seam in relation to adjacent seams is dealt with in terms of the seam environment, particular attention being given to the sandstone at the base of .the seam. Petrographic and other data are used to support the arguments submitted.

Jan 1, 1973

By Jesse R. Jacobson

A large casino complex in Cherokee, North Carolina recently underwent a $633 million expansion that involved substantial foundation challenges. The site is located in a valley on the southern edge of the Great Smoky Mountains National Park, where subsurface conditions typically consist of varying thicknesses of fill overlying alluvium, residuum, partially weathered rock and rock. The fill and alluvium contain cobbles and boulders as large as several feet in diameter. The residuum and partially weathered rock are very thick in some areas, and the depth at which consistently high quality rock is encountered is highly variable. To reduce the foundation costs for the expansion, continuous flight auger (CFA) piles were proposed in lieu of micropiles. CFA piles are not generally used in this geologic environment and concerns regarding their selection included: (1) an uncertainty that CFA piles could be successfully constructed given the difficult conditions and (2) a lack of regional data regarding unit resistance values and load transfer characteristics. To address these concerns, a design-phase test program was undertaken to evaluate pile constructability, develop an understanding of the load transfer behavior, and establish the required pile lengths. The program included soil test borings, shear wave velocity measurements, timed auger probes, instrumented pile load tests and observation of exhumed piles. It was demonstrated that CFA piles could be advanced through the fill, cobble/boulder-laden alluvium, residuum and into the partially weathered rock, albeit with some limitations. Under axial loading, the pile response was very stiff and relatively high unit resistance values were measured. Pile instrumentation allowed for the evaluation and use of design pile lengths shorter than that tested, and the overall reduction in pile lengths yielded a 40 percent reduction in foundation cost. In general, CFA piles were determined to be a suitable, economical foundation alternative.

Jan 1, 2011

By C. Birch

"A ‘geologically constrained’ orebody model has long been hailed as vital for a Mineral Resource statement that is compliant with the South African Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (SAMREC Code). In this paper, the requirements for geological modelling as contained in the outline for the SAMREC Code are considered, and whether the new modelling software available on the market is a ‘black box’ or is better for modelling than traditional methods of wireframe creation.Implicit geological modelling is a technique that uses a radial basis function to establish and update geological models relatively quickly and efficiently from borehole data, outcrop data, manually interpreted vertical or horizontal sections, and structural data. Assays and any coded drill-hole data, such as lithology and alteration, can be interpolated.Leapfrog Geo software is an example of this new approach to geological modelling. A case study of a short training course in geological modelling for non-geologists at the University of Witwatersrand, as part of the Higher Certificate in Mineral Resource Management, is presented. The benefits of this type of geological modelling software are considered for this type of assignment as well as for mining industry applications.The use of geological models in mine planning is reviewed and a case study is presented comparing the variations in mine plan design and financial output of 13 final-year Mine Design projects from the University of the Witwatersrand School of Mining Engineering. These designs were all based on the same geological model created in the traditional way, and yet the resultant mine designs were significantly different, with very different resulting financial outlooks for the project. This raises questions as to how significant a very detailed model in the pre-feasibility and feasibility phases of projects really is, considering the huge costs involved in gathering the required data to build a SAMREC-compliant geological model."

Jan 1, 2014

By Daniel H. McClain

A unique partnership between the Colorado Mine Safety and Training Program (CMSTP), the Colorado Rock Products Association (CRPA) and the Higher Education and Advanced Technology (HEAT)Center resulted in a video CD-ROM training program for new miners entering the aggregate industry. Cooperation from everyone involved, including the U.S. Mine Safety and Health Administration (MSHA),made this the product against which other training materials in the mining industry will be measured in the 21stcentury. This product’s versatility and wide application make it a tool that is as critical to a mine’s success as any earthmoving machine. The state and federal grant money involved allows this product to be affordable to small operators and independent contractors. The quality of this two CD-ROM set rivals any commercially made CD-ROM training.

Jan 1, 2003

By W. R. Hargrave

"Mining OperationsOre will be mined by open pit techniques. Because of the high grade of the deposit and the low strip ratio, mining rates are small relative to most other open pit operations.The ore deposit is located in the valley of the main fork of Red Dog Creek. The bulk of the deposit is located on the southwestern flank of the creek, but mineralization does traverse the creek in both the north and east directions.Erosion has exposed the orebody in a number of locations, and has resulted in oxidation of the mineralization closer to the surface. Although much of this oxide material is very high grade, it leaches readily and, at least in the initial phases of the operation, will be stockpiled and not treated in the concentrator.During construction, 2.3 million mt. (2.5 million st.) of overburden and waste will be stripped from the orebody to expose ore for initial operations. Competent non-mineralized waste will be used to build roads and waste dumps, but the bulk of material removed consists of oxide or ice-rich soils and weathered rock which is not suitable for construction.The annual ore mining rate will be 1.9 million mt. (21. million st.). The strip ratio will start off at 1.2 to 1, falling to 1.0 to 1 by year 5 and ultimately to 0.8 to 1.Bench heights are set at 7.6 m (25 ft). Pit slopes will vary depending on the material present in the wall. The slope, through competent waste and the sulphide package, was set at 45 degrees. This is flattened to 26 degrees (i.e. 2: 1) through overburden and Upper Kivalina shales. The Kivalina Shales are an ice-rich shale whose carbonate matrix has been leached out and which exhibits little or no strength as it thaws. In addition, a 100 ft containment berm will be left in the wall below overburden and Kivalina."

Jan 1, 1989

By J. W. Thompson

Be if enacted by the Senate and House of Representatives of the United States of America in Congress assembled, That deposits of coal, phosphate, sodium, oil, oil shale, or gas, and lands containing such deposits owned by the United States, including those in national forests, but excluding lands acquired under the Act known as the Appalachian Forest Act, approved March 1, 1911 (Thirty-sixth Statutes, page 9G1), and those in national parks, and in lands Withdrawn or reserved for military or naval uses or purposes, except as heroinafter provided, shall be subject to disposition in the form and manner provided by this Act to citizens of the United States, or to any association of such persons, or to any corporation organized under the laws of the United States, or of ;iny State or Territory thereof, and in the case of coal, oil, oil shale, or gas, to municipalities: Provided, That the United States reserves the right to extract helium from all gas produced from lands permitted, leased, or other- wise granted under the provisions of this Act, under such rules and regulations as shall be prescribed by the Secretary of the Interior: Provided further, That in the extraction of helium from gas produced from such lands, it shall be so extracted as to cause no substantial delay in the delivery of gas produced from the well to the purchaser thereof: And provided further, That citizens of another country, the laws, customs, or regulations of which, deny similar or like privileges to citizens or corporations of this country, shall not by stock ownership, stock holding, or stock control, own any interest in any lease acquired under the provisions of this Act.

Jan 1, 1921

By Oliver Bowles

[Simple systematic accounting that adequately records all transactions has long been regarded as essential to the welfare of any business enterprise. Some of the defects that detract from the prosperity of the slate industry are attributable to a lack of effectiveness in cost keeping. This condition has promoted the United States Bureau of Mines to make a detailed study of accounting methods for the slate industry, and to present for consideration a system of accounts, which it is believe would enable the industry to attain more economical management and operation if accepted by a fair proportion of its important units. The method of accounting presented herein has been worked out with the assistance of leading slate producers and the recommendations are tentative and are submitted in this form as a means of developing constructive criticism. Believing that cooperative effort in this, as in many ether problems will bring the most enduring benefits to the industry as a whole, the writer urges that the cost earnest consideration be given to this vital problem now facing the slate industry.]

Jan 1, 1929

By Y. P. Chugh

A novel dry and wet air dust filter concept was conceived and demonstrated successfully at two mines. A steel-wool and a fiberglass filter, suitable for underground use were identified through laboratory testing and demonstrated in the mine. The steel wool filter was operated with and without water sprays while the fiberglass filter was only operated in the dry mode. The dry steel wool filter provided a dust capture of 37% at a negligible pressure drop. When fine misting water sprays were used on the steel wool filter, the dust capture increased to 51% again with a negligible pressure drop. The filter screen also remained clean and no change in air flow characteristics was observed as a function of time. The dry fiberglass filter however did not perform as well achieving only 11% dust capture while introducing a significant resistance to air flow. This technology is seen to have several applications in underground coal mines.

Jan 1, 2009