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By Hiroaki Kawamura, Takeshi Yoshikawa, Kazuki Morita, Yutaka Yanaba

"To develop an alternative metallurgical process for phosphorus removal in the production of solar-grade silicon (SOG-Si), slag treatment of metallurgical-grade silicon (MG-Si) was conducted, followed by acid leaching. Phosphorus-doped silicon alloy or MG-Si containing certain amounts of phosphorus and calcium was reacted at 1723 K and 1773 K with CaO--CaF2 of several compositions. Phosphorus removal from the molten silicon into the slag phase was confirmed by reduction to phosphide ions, P3-, and phosphate ions, P3-. These ions were separately determined using a wet chemical analysis method developed by ourselves. The highest phosphorus distribution ratio obtained was 2. 7 after reaction for 18 h with 17.5 mass% CaO--CaF2 slag. We then conducted acid leaching of the silicon and achieved removal of a large fraction (over 90 % ) of the phosphorus, which was much higher than that obtained by ordinary oxidizing slag treatment.IntroductionIn recent years, the production of solar cells has been increasing rapidly. Because of this, the demand for solar-grade silicon (SOG-Si) has also been growing rapidly. The development of lower-cost mass production processes is therefore needed to provide silicon feedstock. Phosphorus is one of the impurities in metallurgical-grade silicon (MG-Si). Because of its large segregation coefficient (kp = 0.35) [l ], it is difficult to remove phosphorus using a solidification refining process. Vacuum melting is considered to be a promising method for removing phosphorous from MG-Si [2], but the issues of high cost and large energy consumption have still to be resolved.Slag treatment is often used to remove impurity elements by oxidizing reactions during general oxidation refining processes. For example, phosphorus in molten steel is removed into a slag phase as phosphate ions, PO4 3-l-, by the following reaction:"

Jan 1, 2013

By M J. Shearer

An investigation into the reliability of the data being collected at the Mount Isa Mines site operated by Glencore in Queensland allowed on-site ventilation personnel to scrutinise pressure and volume measurements collected from the primary surface fans. The investigation effectively identified discrepancies being reported to the on-site remote monitoring system. The difference between the real-time and static measurements on the P63 RAR shaft identified that the in situ differential pressure transducer and piezo annubar system was not operating correctly. This indicated a deficiency of approximately 30 per cent reporting back to the remote monitoring software versus the live readings measured with the Pitot tube bomb and ALNOR AXD610 pressure micro-manometer.Constant monitoring of an operations ventilation network is imperative to ensuring that the underground atmosphere provides a safe and healthy workplace. Further benefits to real-time monitoring allows for the early indication of network failures and promotes increased availability. An innovative approach to out engineer and improve the existing measuring equipment from the 1970s was sought.The use of ultrasonics in the mining industry is not new with ventilation management systems (VMS) equipment available within the marketplace. The introduction and implementation of a reliable product for real-time monitoring was a challenge to overcome due to limited access and suitable measuring points within the mine. The available equipment on the market through mainstream suppliers was not suitable for the unique application required due to the in situ installation of the surface fans. A solution was identified in the oil and gas industry through collaboration and innovative thinking. This paper describes the sustainable approach to implement a reliable air flow monitoring system on-site.CITATION:Shearer, M J, 2017. Case study – an analysis of reliability and efficiency: ultrasonic versus annubar technologies, in Proceedings Australian Mine Vent Conference 2017, pp 51–56 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

An Ammonia Leaching-Solvent Extraction-Electrowinning-Flotation Process for Copper Oxidised Ore Treatment

Sep 13, 2010

By Orlando Ramírez

El presente trabajo describe el sistema integrado de seguridad a través de la norma OSHAS 18001 - 1999 y calidad ISO 9001 – 200m, donde la aplicación de la integración controla las desviaciones de los procesos oportunamente. Es decir, que a través de la procalsedad se reúnen tres elementos: productividad, seguridad y calidad,logrando una ventaja competitiva en el mundo globalizado.

Sep 12, 2005

Eco-Efficient Gravity Separation Solutions in India Sustainable development and social responsibility issues are a principal aspect of mineral processing operations around the world. With the need for more environmentally effective technologies, some gravity separation systems have provided eco-efficient mineral processing solutions in places where it is not otherwise viable because of lack of fresh water or for other environmental reasons. Advanced spiral separation technologies developed in Australia offer a cost effective and environmentally viable way to process minerals. In particular, we review recent case studies of spiral plants commissioned in India where environmentally sustainable solutions to design problems included the use of spirals operated with sea water and the use of high capacity (HC) spirals to provide low consumption of energy and materials and a reduced plant footprint. This paper evaluates the performance of various spiral plants in India and how critical environmental issues which affect the overall viability of wet concentrating processes where resolved.

Sep 13, 2010

By Dave Minney

The South African mines health and safety regulations require that mine management establish a quality management system for rock support material. Quality control of resin capsules used as a support medium in South Africa is specified under SA National Standards No 1534. Experience has shown that this specification, while addressing the chemical and physical aspects of the products, but does not address the required performance criteria. In order to address this shortcoming, the industry has put a lot of emphasis on short encapsulation pull tests, performed insitu, in the underground workings of the mine. This is also fraught with many shortcomings, particularly as regards site availability, cost and repeatability of results. To try and address these issues, the Department of Mechanical and Aeronautical Engineering at Pretoria University were approached to develop equipment and machinery that could produce reliable, repeatable results in a laboratory environment which reasonably simulates installation practice underground. The test method is based on the ASTM F432-95 Strength Index test, but modified to use push test rather than pull tests. The paper describes development of the test method and the preliminary results and findings of the work.

Jan 1, 2007

By Ludger Suarez-Burgoa

At the Porce III Underground Powerhouse Complex in Colombia, the observational method (Peck, 1969), was used to provide information to an underground wedge and a 2D Finite Element Method numerical models, both used to estimate the mechanical behavior of the hoisting rock mass. The observation process consisted in collecting fault events in the field and in interpreting Multiple Point Borehole Extensometers and Surface Convergence Displacement Points readings. The calibrated models were employed to predict the behavior of the pillars formed between the machine and transformer caverns. The observational method is an important activity during excavation of large openings and provides arguments to understand the rock mass mechanical behavior.

Jan 1, 2008

By D Craw, P Whigham, C Rufaut

Geographic Information Systems (GIS) are computerised management systems for spatial data, offering improved data management, extensive data manipulation techniques and greater understanding of data. At the Wangaloa Coal Mine, South-East Otago, ArcGIS is being used to manage, integrate, analyse and visualise the diverse range of datasets being generated from an interdisciplinary research team. GIS will assist with identifying spatial and temporal patterns associated with the current site rehabilitation strategy. This paper will present an overview of how GIS can be a useful tool for understanding ecological recovery during mine site rehabilitation.   The Wangaloa opencast coal mine, owned by Solid Energy NZ Ltd, was closed in 1989 after more than 40 years of operation. Rehabilitation efforts involving more than 60 000 native plants began in October 2001. At Wangaloa sample points were randomly selected at 100 m intervals and recorded using a differential GPS. Plant, soil and invertebrate data have been collected at each sample point. Plots of 8 - 9 plants have been established within approximately 5 m of each sample point. Since September 2003 seasonal monitoring of plant growth and survival has been carried out. Chemical and physical datasets have been generated from soil collected in June and December 2003 for each sample point. A more restricted dataset is being generated for soil collected on a seasonal basis from March 2004. Plant and soil characteristics from these datasets have been attached to each sample point and GIS layers have been created. Relationships between data layers can be explored based on their spatial patterns. Examples presented from Wangaloa include distribution of planting success and temporal variation; temporal change in pH; interpolated pH map; digital elevation model; relationships between planting success and growth with pH and organic matter. GIS is proving to be a valuable tool on the integrated project at Wangaloa.

Jan 1, 2004

By Dave Rose, David G. Meadows, Mike Westendorf

"Copper Mountain’s concentrator was commissioned in May 2011. The circuit consists of a 34’ x 20’ EGL SAG mill, a Raptor 900 pebble crusher and two 24’ x 39’6” ball mills. Each mill is equipped with a 2 x 8500 HP dual pinion drive system. The plant was designed to process 1585 mtph of SAG feed. From startup, the mill struggled to meet the required production rates. Over time, a major initiative that involved blasting and fragmentation, optimization of the SAG mill in terms of discharge grates, ball size and slurry density, and operation of up to three mobile pre-crushing plants resulted in significant increases in throughput. In parallel, a number of modeling tools, including JK SimMet, were run based on plant benchmarking exercises. Samples collected at the mine site during ramp up confirmed the very competent nature of the ore with drop weight - A*b values of less than 24 being recorded on a variety of plant feeds and lithologies. After due consideration including demonstration of proof of concept, a new pre-crushing circuit incorporating an XL2000 cone crusher and associated screening equipment was designed, constructed and commissioned at the site in August 2014. This paper reviews the history of the original circuit design, the various optimization steps taken and impacts, together with the final pre-crushing circuit and net results.IntroductionThe Copper Mountain Mine is located approximately 20 km south of Princeton, British Columbia, Canada (refer to Figure 1). The region has a long history of copper mining dating back to 1923. The Copper Mountain camp occurs in the 'eastern volcanic belt' of the Nicola Group (Monger, 1989). It is an alkali copper-gold deposit in which the volcanic strata are intruded by early Jurassic dykes, sills, irregular plugs and zoned plutons (Woodsworth et al., 1992). The stratified rocks are relatively fresh with slight metamorphism in the local contact regions."

Jan 1, 2016

By J Parnell, B Manson

Bitumen occurs in the basins in reservoir sandstones, in veinlets close to hydrocarbon source rocks, in veins through lava beds and in sulphide-mineralised veins where it is closely associated with, but predates, the sulphides. The role of organic matter was probably in enhancing metal reduction by creating a low-Eh environment rather than in metal transport. Coeval euhedral quartz crystals or albite in sulphide-bearing carbonate veins provide evidence of an aqueous component to the hydrocarbon fluid

Aug 1, 1995

By D Craw, L C. Kerr, P Wopereis

Gold placers in the Nokomai and Nevis valleys are dominantly Quaternary in age. They occur mainly in western tributaries of the upper Nevis, eastern tributaries of the middle and upper Nokomai, and in the trunk valleys themselves. Placer gold in both valleys is dominantly a-phase Au-Ag-Hg alloy. Au-Ag alloy is absent or rare in most of the deposits, except in the lower Nokomai. Alpha-Au-Ag-Hg alloy is typically coarse-grained (up to 2 cm), angular, and rarely flattened or folded. Crystalline texture, quartz intergrowths, and psuedo-hexagonal crystal-pluck cavities are common. Fluvial transport distance predicted from the maximum Flatness Index ofAu-Ag-Hg alloy particles is typically less than 10-20 km. Coarse (up to 2 cm) cinnabar is commonly associated with the Au-Ag-Hg alloy, and both were probably derived from hydrothermal sources in western tributaries ofthe upper Nevis and eastern tributaries of the upper Nokomai. Minor secondary Au-Ag-Hg alloy occurs locally in the lower Nokomai, where it coats or cements detrital a-phase Au-Ag-Hg and Au-Ag alloy particles. Au-Ag alloy dominates over Au-Ag-Hg alloy in the lower half of the lower Nokomai alluvial plain and gravel of a raised channel incised into semischist basement adjacent to the plain. The Au-Ag alloy is rounded and commonly flattened and folded. Crystalline texture, quartz intergrowths, and pluck cavities are rare, and a fluvial transport distance of 25-40 km is estimated from maximum Flatness Index ofAu-Ag alloy particles. The Au-Ag alloy, three types of gamet, magnetite, clinozoisite and well foliated schist boulders in the abandoned channel are not found in the pumpellyite-actinolite facies bedrock in the Nokomai. These components were derived from greenschist facies schist and sedimentary sources in Otago, many tens of kilometers north of the Nokomai catchment. They were transported to the Nokomai either in Wakatipu Glacier till or fluvio-glacial outwash that entered the valley via Nokomai Saddle, the confluence with the Mataura, or both.

Jan 1, 2000

By Thomas F. Joyce

N L Industries, Inc., MacIntyre Development produces ilmenite and magnetite concentrates from its own open pit operation at Tahawus in New York's Adirondack Mountain region. The ilmenite concentrate is used within the company for the production of titanium dioxide pigments and the magnetite concentrate is sold to heavy media processors. Current production is from South Extension mine, loading by by six-yard Marion electric shovels into 85 ton Lectra Haul trucks. Bench heights are 44' and are drilled with a Robbins Rotary 9 7/8" diameter hole on 25' spacing for a yearly production of 3.4 million total tons of rock. The ore deposit occurs in veins dipping on the average at 40 degrees to the west. The ore body, which is divided into three zones, outcrops at surface and continues to depths of 800'. Zone 1 is a high grade band of thickness 150-200' with an Fe/Tio2 ratio of 2. Below this band is Zone 2, a low grade band of thickness 50-100' with an Fe/Tio2 ratio of 2 and beneath that seperated by a band of anorthosite is Zone 3, a high grade band of irregular thickness 50-450' with an Fe/Tio2 ratio of 1.6.

Jan 1, 1973

By John Gamble

This paper summarizes the weight of epidemiological evidence to evaluate the hypothesis that asbestos exposure is causally associated with increased risk of gastrointestinal (GI) cancers as suggested by Selikoff in an early study of insulation workers. This review looks at populations that develop GI cancers, namely stomach, colorectal, colon and rectal. Guidelines for assessing causality are strength of association, biological gradient and consistency of the associations. Exposure?response (E?R) was evaluated using three methods to estimate exposure. Rate Ratios (RRs) for lung cancer and percent of mesothelioma are used as surrogate measures of asbestos exposure for all the cohorts of exposed workers. Quantitative or semi-quantitative estimates of cumulative exposure to asbestos were also used to assess E?R trends and were compared to E?R trends for lung cancer and mesothelioma in individual studies. Surrogate measures are important since there are few individual studies that have assessed E?R. None of the various methods to estimate asbestos exposure yielded consistent E?R trends and the strength of the associations were consistently weak or non-existent for the four types of GI cancers. The epidemiological evidence detracts from the hypothesis that occupational asbestos exposure increases the risk of stomach, colorectal, colon, and rectal cancer. Findings are briefly summarized below. © 2007 Elsevier Inc. All rights reserved. Keywords: Asbestos; Colon cancer; Colorectal cancer; Gastrointestinal cancers; Ingestion; Lung cancer; Mesothelioma; Rectal cancer; Review; Stomach cancer

Jan 1, 2007

By P. A. Laxen, P. J. van Staden

In situ leaching tests with thiourea as the lixiviant were caried out in two worked-out stopes at the No. 6 shaft at Rand Leases Gold Mining Company. Dissolution rates of 0,9 and 0,7 9 of gold per week per 100 m2 of footwal area were achieved. A major disadvantage of the method seems to be the slow rate of dissolution of the gold, which is probably caused by poor contact and slow mass transfer between the lixiviant and the gold surfaces. Under full-scale application, the loss of lixiviant by leakage could also be a very important factor. Furthermore, the oxidation products of thiourea may 'poison' the activated carbon that is used for the recovery of the gold. The method may therefore be economically viable only in stopes that contain high values of residual gold.

Jan 1, 1989

In, one stage of the purification sequence of the zinc sulphate electrolyte used at Risdon, cobalt is, precipitated as cobalt nitroso-,B-naphtholate, which is separated from the solution by filtration. Owing to the method of conducting the purification the filter cake contains much gypsum, unconsumed calcium hydroxide, basic zinc sulphate, and entrained zinc sulphate solution, Small amounts of iron and copper that have escaped previous purification steps are also precipitated with the cobalt as nitroso-,B-naphtholate. Thisprecipitate, normally carrying about 18% cobalt, is the raw material for the production of cobalt oxide, cobalt sulphate and cobalt metal.COBALT OXIDEThe main problem in the preparation of a reasonable grade of cobalt oxide from the filter cake is the economic separation ,of the cobalt nitroso-,B-naphtholate from the gypsum. This was solved by the application of flotation. It was discovered that the cobalt nitroso-,B-naphtholate, under correct conditions, would float without any addition agent, giving a relatively high grade concentrate. A plant, was built and has been in operation since 1936. The filter cake is pulped with water and pumped to one of two mechanically agitated tanks, eath capable of holding one day's output. Sulphuric acid is added until the free acid concentration reaches about 3 gm. per litre. Basic zinc sulphate is dissolved and calcium hydroxide converted to gypsum. The pulp, carrying about 2t lb. of solids per gallon, is pumped at a suitable rate to the first of a series of 10 flotation, boxes.. Each box is 3 ft. by 2 ft. 9 in. by 5 ft. deep, and, all have a common, pulp level, since the...

Jan 1, 1949

By S. Rivard

"This paper demonstrates the selection of grinding circuit technology for a number of recent projects including discussion of the key drivers and the role of energy efficiency. Decreasing head grades combined with a strong and sustained increase in operating costs has forced miners to examine increased project size, increased equipment capacity and efficiency improvements in order to reduce their unit operating costs and improve overall project economics. Comminution energy consumption, safety and capital cost considerations play a critical role in the success of projects. This paper presents some key guidelines for a successful and cost effective comminution circuit design and includes a case study on three projects, outlining the issues and the drivers which led to the ultimate circuit selection and the critical role that energy efficiency played.IntroductionComminution circuits for minerals processing are selected based on their suitability and efficiency in reducing run-of-mine ore to the desired feed size for the downstream process. The input material (ore) properties and downstream process requirements are the key determinants and there are standard approaches for each circumstance.The minerals processing industry has been a fast adaptor of efficiency improvements based on increasing capacity of equipment (e.g. trucks, crushers, mills, pumps) but less successful in adapting radically new technologies that disrupt incumbent flowsheets or processes.The installed power of grinding mills has increased linearly over the past 25 years (Meka & Lane, 2010) and pumps and classification equipment have kept pace. The autogenous grinding (AG) and semi- autogenous grinding (SAG) mills displaced stage crushing as a dominant method of coarse rock breakage in many applications causing crusher manufactures to increase the capacity of cone crushers to meet the competitive demand.Examples of new comminution technology in the 20th and 21st centuries are the development and adoption of cyclone classification in the 1940s (Newtech, 2016), AG milling in the late 1950s, vertical grinding mills in the 1980s, high pressure grinding rolls (HPGRs) also in the 1980s and ultrafine milling technology in the 1990s (Meka & Lane, 2010)."

Jan 1, 2017

By Nawshad Haque, Leanne Smith, Hal Aral, Joseph Cho, Warren Bruckard

"Water availability is one of the principal parameters in determining the feasibility of mining projects in arid and semi-arid regions. The volumetric water footprint (VWF) of a conceptual model of a copper flotation plant was found to be 2.45 kL/t Cu ore, compared with an actual measurement reported in the literature of 2.72 kL/t Cu ore. The flowsheet considered included mineral processing stages such as crushing, screening, grinding, classification, separation, flotation, thickening and filtration. The effect of a number of variables on the VWF was evaluated, including solid/liquid ratio, feed mass flowrate, ore loss, water loss, moisture content of ore, ore grade and water recycling. The use of seawater with recycling provided the most environmental and economic advantage among several scenarios evaluated. The study assumed a price of $1/kL freshwater, $4/kL for transport over a 200 km distance at 2,000 m altitude and $4/kL for water treatment. The water related cost of the desalinated seawater use scenario was A$493/t Cu concentrate, while the water related costs of fresh water and blended water scenarios were A$308/t and A$268/t Cu concentrate, respectively. The water related cost (fresh water scenario) accounted for 44% to 49% of the entire mining and processing costs that included drilling, blasting, loading, hauling, crushing, grinding and concentrating. The total overall cost was A$435/t Cu concentrate for the seawater with recycling, compared to A$451/t Cu concentrate for the fresh water with recycling case.INTRODUCTIONReducing the water footprint (WFP) by utilising alternative water sources has been a focus of mining projects due to increasing concerns about water scarcity and growing energy costs. The global mining industry can expect to experience fresh water shortages in the future, and saline or hyper-saline water may be the only available water source to process minerals in arid regions. Extensive studies on alternative water sources (e.g. seawater, desalinated seawater, blended water) and the reuse of process water have recently been conducted (Moreno, Aral, Cuevas, Monardes, Adaro, Norgate & Bruckard, 2011; Aral, Mead, Cuevas, Davey & Bruckard, 2010). Such studies provide sustainable and economic strategies for mines and concentrators in the arid or semi-arid regions of the world such as in Chile, Peru, Indonesia, and Portugal. More work, however, is needed to confirm water consumption data for different base metal flowsheets and use this data to develop water models that can lead to reduced WFPs and more sustainable water usage in the mining industry."

Jan 1, 2016

By G. Włoch, E. Rudnik

The oxide fraction of industrial zinc ash was characterized in terms of chemical and phase composition, leaching behavior in sulfuric acid solutions, and leaching thermal effect. The waste product contained about 68 percent zinc (Zn), 7 percent chlorine (Cl), 2 percent aluminum (Al) and less than 1 percent other metals, such as iron (Fe), manganese (Mn), calcium (Ca) and silicon (Si). It consisted mainly of zinc oxide contaminated with metallic zinc and zinc hydroxide chloride. The dissolution of metals from the zinc ash was determined for solid-to-liquid ratios ranging from 100 to 500 kg/m3, acid concentrations of 10 and 20 percent, and temperatures of 20 and 40 °C. The best result — 130 g/dm3 Zn(II) at 95 percent zinc recovery — was obtained at a solid-to-liquid ratio of 200 kg/m3, sulfuric acid concentration RI SHUFHQWDQGLQLWLDOWHPSHUDWXUHRI ƒ& 7KH¿QDOVROXWLRQVZHUHFRQWDPLQDWHGPDLQO\E\0Q ,, DQG)H ,,, ions, but the presence of cadmium (Cd(II)) and lead (Pb(II)) ions enabled electrowinning of zinc of about 99 percent SXULW\DWKLJKFXUUHQWHI¿FLHQF\RI WR SHUFHQW /HDFKLQJRIWKHPDWHULDOZDVDQH[RWKHUPLFSURFHVVZLWKUHDFWLRQ heat of about 520 kJ/kg

By A. A. Bilgin

The prevention of acid mine drainage (AMD) in situ is more attractive than down-gradient treatment alternatives that do not involve source control. AMD source control can be achieved by shifting the microbial activity in the sulfidic rock from pyrite oxidation to anaerobic heterotrophic activity. This is achieved by adding biodegradable organic carbon amendments to the sulfidic rock. This technique was applied to an abandoned coal mine pool in Pennsylvania. The pool had a pH of 3.0 to 3.5. Following treatment, near-neutral pH and decreased effluent heavy metal concentrations were achieved. In situ bioremediation by the enhancement of bacterial iron and sulfate reduction is a promising technology for AMD prevention.

Jan 1, 2007

By J. Kretschmann

?We have constructed a world in which the potential for high-tech catastrophe is embedded in the fabric of day-to-day life.? (Malcolm Gladwell) The mining industry is a crucial provider for virtually every person?s needs and thus indispensable. Yet, mining is a complex and risky business: plenty of high risk factors can occur and severely affect nature and the miner?s life and health. Especially for small and medium enterprises (SME) risks may also threaten the economic existence of the company. The responsible and sustainable management of a company should thus be based upon the systematic finding and handling of risks or briefly upon an efficient risk management system. Why do we need risk management? Because nobody is perfect and we make mistakes in the normal course of operation.

Jan 1, 2011