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By R. G. Haire

Studies of the f-elements under pressure provide important insights into their solid state chemistry and physics. From such studies, of the elements and their alloys, it has been established that the normally localized f- electrons of several of these elements can become, involved in bonding under pressure. The electronic behavior of f-element compounds under pressure tend to be more difficult to interpret, due to the variety and the nature of electronic orbitals that are present. The 4f-elements and some 60% of the 5f-elements have been studied under The systematic comparisons that have been established for these materials are discussed.

Jan 1, 1992

By R. J. Nankee

Coal is our most abundant, low cost energy resource. Expansion of its use is being challenged due to "SO2 emission" regulation with even more restrictive legislation pending. High quality coal reserves are becoming more limited due to greater use in recent years. Aids to allow more use of coal in today's environment include beneficiation of coal before combustion and scrubbing the emissions from coal during combustion. Dow's efforts to help meet these challenges by beneficiating coal include true heavy media gravity separations with chlorinated solvents and liquid/liquid partitioning processes and "Dow Solvent Recovery Technology" to recover the solvent from product (or floats) and rejects (sinks), The objectives of the efforts to clean coal are to reduce sulfur and ash. In this paper, the solvents will be described; a general flow diagram presented; some of the results on upgrading various coals will be described, and projected costs of full-scale plants using chlorinated solvents will be compared to conventional cleaning plants.

Jan 1, 1985

By J. R. Pennington

The town of Green River, Wyoming, is located along the Green River on an arid plateau at a elevation of 6,300 feet. Green River has become the center of a booming soda ash industry. The rapid development of coal, oil, and gas resources, coupled with the soda ash boom, have created growth pains for the area. Green River and Rock Springs have experienced a 20-25% population increase in 1973 alone. However, public officials, business leaders, and local citizens are taking positive steps to ease the problems relating to housing, schools, medical services, and recreational facilities. What Is Soda Ash? Soda ash is one of the most widely used chemicals in the world. It is an important raw material in the manufacture of glass, paper, soap, petroleum products, metals, chemicals, pharmaceuticals, plastics, and a host of other items essential to every day living. In ancient times, soda ash was obtained from water solutions of various desert earths. Later, it was produced by leaching the ashes of wood and seaweed. For the past 100 years, it has been manufactured by the ammonia-soda process, which employs large quantities of salt, limestone, and coal as raw materials.

Jan 1, 1974

By J. Hamisch

Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely economic consequences of different climate policy options. In our study we first compare atmospheric observations to the available estimates of PFC emissions for the baseline years 1990 and 1995. We then present projections for regional emissions of PFCs from the aluminum industry using the MIT Emissions Projection and Policy Analysis model under different policy scenarios. Abatement costs for emissions of PFCs and C02 are compared in the context of the Kyoto Protocol.

Jan 1, 1999

By Bo Liang, Hongmin Zhu, Kai Huang, Shafiq Alam

A new approach of recovering platinum and palladium from electronic wastes by hydrochloric acid leaching followed by selective adsorption on low-cost and environmentally benign biomass sorbent prepared from easily available agriculture waste is suggested. The obtained adsorbents were prepared by a combination of chemical modification and hydrothermal carbonization process with (NH4)2C2O4. It was found that the maximum adsorption capacity of hydrothermal carbonized garlic peel for Pt( ) and Pd( ) was 1.64 and 0.42 mol/kg respectively. The Langmuir adsorption isotherm was applied to describe the adsorption process. Kinetics of the Pt( ) and Pd( ) ions adsorption was found to follow pseudo-second-order rate equation. The adsorbents were examined by scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). Based on the characterization results, a possible mechanism of Pt( ) and Pd( ) ions adsorption with the hydrothermal carbonized garlic peel was proposed. This study provides a promising adsorbent with efficient adsorption property for platinum and palladium recovery from the leach solution of electronic wastes.

Jan 1, 2016

By Ronald B. Stotelmeyer

This report summarizes studies of 55 Idaho national forest roadless areas completed by the U.S. Bureau of Mines (USBM) in the period 1966-1992. These roadless areas have been recommended for addition to the National Wilderness Preservation System, proposed as special management areas, or otherwise recommended for study by the U.S. Forest Service or the Idaho congressional delegation. The Bureau of Mines' studies indicate which parts of the roadless areas contain mineral resources. They also show where mining and prospecting are likely to occur in the future, where mineral production has occurred in the past, and where abandoned mine workings (possible hazards) would be encountered. The number of mine and prospect workings found are a measure not only of surface disturbance, but of areas not wilderness in character.

Jan 1, 1994

By H. M. Cooper, R. F. Abernethy

Determination of the fusibility of coal ash consists in melting a pyramid of the ash to fluid under prescribed conditions . The conditions of the test are specified by the American Society for Testing Materials4/ and must be adhered to strictly if comparable results are to be obtained . The Society formerly specified a particular type of furnace , but with improvements in design of both electric and gas furnaces , it was decided by the Society to specify only essential details of the test . The Chairman of Committee D - 5 , Coal and Coke , of the American Society for Testing Materials suggested that the Coal Analysis Section of the Bureau of Mines conduct a cooperative investigation on the effect of furnace type and atmosphere upon fusibility of coal ash . The Coal Analysis Section enlisted the aid of a number of laboratories using the more common furnaces to cooperate in the investigation . Four types of gas furnaces burning natural and manufactured gases and two types of electric furnaces with different methods of maintaining a reducing atmosphere were employed . The results from the survey are tabulated herein , and some comparisons are made . There were not enough data from any particular furnace and atmosphere to make a reliable statistical analysis . However , definite tendencies are evident , and attention is called to them by direct comparison. in tables .

Oct 1, 1943

By N. Dahata

Earlier research has indicated that an addition of titanium master alloy to aluminum alloys, results in improved fillability, grain refinement and finer pores. B206 alloy differs from other alloys used in automotive industry, with lower titanium level. This paper examines the effect of alloy chemistry (copper and titanium levels) and grain refinement (A1-5`)oTi- 1%B grain refiner) on grain size, microstructure and microporosity in B206 aluminum alloy. In this study, characterization of grain size, microstructure and microporosity was carried out using light optical microscopy (LOM) and scanning electron microscopy (SEM). Results have shown that the addition of 0.05 wt % titanium resulted in grain refinement of B206 alloy. With an increase in titanium to 0.25 wt further grain refinement, much reduced pore size and uniform distribution of pores resulted. These results suggest that B206 with proper addition of titanium has a promise as an alloy for automotive casting.

Jan 1, 2007

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

A new analytical approach for characterizing and improving the performance of ball milling is presented. Individual ball mill circuit design and operating variables can be related to overall circuit performance through two distinct parameters for classification and breakage. The ball mill circuit functional performance equation is presented. Applications in the industrial plant and in the research field are discussed.

Jan 1, 1990

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By Walter Kawa

The hydrogenation of phenyl ether, benzyl ether, and phenyl sulfide in the presence of iron catalysts was studied by the Bureau of Mines to gain a better understanding of the role of iron catalysts in the hydrogenation of coal. The carbon-oxygen and carbon-sulfur bonds in these compounds may be similar to some of the carbon-oxygen and carbon-sulfur bonds in coal which react during the early stages of liquefaction by hydrogenation. Experiments were made in batch autoclaves for 4 hours; hydrogen was at a pressure of about 540 atmospheres. In the hydrogenation of phenyl ether at 400° C, metallic iron catalyzed both hydrogenolysis (splitting-hydrogenation) and nuclear hydrogenation (addition of hydrogen to aromatic rings) reactions, Products were principally benzene and cyclohexane. The activity of metallic iron was decreased by adding carbon monoxide or a reactive sulfur-containing organic compound. Ferrous sulfide catalyzed the conversion of phenyl ether to benzene, phenol, and small amounts of cyclohexane. Hydrogenolysis of benzyl ether was catalyzed by metallic iron and to a lesser extent, by ferrous sulfide at 250° C. No nuclear hydrogenation was observed with either catalyst. Conversion of phenyl sulfide to benzene was nearly quantitative in experiments made at 250° C with equimolar quantities of phenyl sulfide and metallic iron or iron as ferric oxide. Conversions of metallic iron and ferric oxide to ferrous sulfide were nearly stoichiometric. No reaction of phenyl sulfide occurred in the presence of ferric oxide and water, and very little occurred in the presence of metallic iron and water. Ferrous sulfide also catalyzed the hydrogenolysis of phenyl sulfide to benzene, but conversion was lower than in experiments with metallic iron or ferric oxide. The activity of ferrous sulfide was increased by adding water and decreased by adding hydrogen sulfide. The results of this study suggest that ferrous sulfide is an active form of iron when iron is used as a catalyst for the hydrogenation of coal.

Jan 1, 1963

By Sailesh S. Author

The current design method for soil-cement (SC) columns improved soft clayey ground under the highway embankments assumes a slip circle failure surface shearing through the columns and the soils using a weighted average shear strength. However, the results from the laboratory centrifuge model test and numerical analysis indicate that in many cases, the SC columns fail by bending. Some researchers have proposed methods for estimating the maximum embankment loading for bending failure of SC columns, but those methods have limitations in correctly considering the internal shear stresses or not applicable for the group SC column improvement. Numerous model embankments on SC columns have been simulated by three-dimensional (3D) finite element analysis (FEA) and the mechanism of bending failure and the magnitude of the bending moment in the SC columns under embankment load has been investigated. Based on the simulated results, the design method for the estimation of the bending failure of floating SC columns has been proposed. The predicted results from the proposed method agreed with the existing field condition of one embankment in Saga, Japan reported in the literature in terms of the stability of columns. Hence the proposed method can be used for the design of floating SC columns in the soft ground.

By Richard F. Hewlett

This report describes how a limited number of preliminary exploration drill-hole assays from a mineral deposit can be used to design grid spacing that is both economic and efficient for subsequent evaluation drilling of that deposit. Relationships between desired precision of the estimate of grade of ore and drilling cost are used to determine the economic drill-hole spacing. The statistical concept of precision in estimating grade of ore is used to determine the efficient drill-hole spacing. Assay data from approximately 50 known copper deposits were studied, and the relationships of the statistical parameters of these deposits were computed. Drilling requirements for various precisions of the estimates of grade of ore were computed for some of these known deposits to serve as guides for drilling future copper deposits. The effect of various geologic factors on the trend in grade of ore and, therefore, on the drilling requirements is shown for certain deposits.

Jan 1, 1965

By SANJIT KUMAR PAL, Sarvesh Kumar, Arindam Guha

The integrated geophysical study around pipe 1 and pipe 2 in Wjarakarur Kimberlite Field (WKF) assisted in comprehending the response of pipes. In the present study, we have attempted a combined analysis of very low-frequency electromagnetic (VLF-EM), electrical resistivity tomography (ERT), and magnetic methods to analyze the response from pipe 1 and pipe 2. A comparative analysis along all the profiles revealed the extension, depth, and geometry of the pipes. The results of VLF data and ERT data have been compared for two profiles of pipe 1 and pipe 2. Fraser-filtered grid map generated from all profiles of pipe 1 proficiently demarcated the trend of kimberlite pipe extension with high Fraser filter value associated with kimberlite. The ground-based magnetic data around pipe 1, pipe 2, and pipe 6 have been processed to analyze the magnetic behavior and subsurface structure based on the susceptibility contrasts. Analytical signal (AS) map revealed the extension of pipes, which was validated with the Fraser-filtered grid map. Analytical signal anomaly pattern reveals that pipe 1, pipe 2, and pipe 6 are trending in SW-NE, NE-SW, and NE-SW, respectively. Based on this study, the results indicate the conducting nature of pipe 1, whereas pipe 2 is resistive in nature. Further, the Euler deconvolution technique has been applied to calculate the possible depth of pipes from magnetic data. The comparisons of calculated depth ranges obtained from all geophysical techniques correlate well and validate the result (Table 1). The geological borehole data at pipe 1 and pipe 2 reported by the Geological Survey of India are well corroborated with our combined geophysical study.

Jan 17, 2024

By Antônio Augusto Gorni, Fabio Adriano da Silva, Emanuelle Garcia Reis, Afrânio Márcio Costa

Gerdau Ouro Branco´s plate mill started the operation in 2016 with high level technology. Stands out the capacity to produce different thicknesses in a same plate, therefore allowing special service for sectors such as building structures, bridges, shipbuilding and mechanical applications. The purpose of this study is to present the first results obtained in this innovative product in Brazil. Some slabs of EN10025-2 S355JR+AR steel were rolled and were evaluated the dimensional tolerances, mechanical properties uniformity, grain size, surface and internal qualities. In addition, a correlation was observed between slab and plate thickness reduction and internal plate quality. The results show that this technology can be used with adequate performance for these steel grades in the current market.

Oct 1, 2019

By D. Ling, Santos. R. M., T. Van Gerven, M. Guo

The valorization of alkaline waste materials from thermal processes utilizing intensified mineral carbonation routes is investigated. The principal advantages of this approach are the chemical stability and storage safety of mineral carbonates, the opportunities for process integration presented by the technology, and the potential for conversion of low-value materials into useful products. Treatment and disposal of steel slags are a costly burden on steel plants. Sustainable solutions for Argon Oxygen Decarbonisation (AOD) and Continuous Casting (CC) stainless steel slags and Basic Oxygen Furnace (BOF) steel slag are desired. An integrated on-site mineral carbonation approach is envisaged as a favourable solution.

Jan 1, 2011

By W. C. Taylor

The present fuel situation indicates that, at least for the next 20 to 30 years, the burning of coal will be a main source of energy. All coal contains sulfur, which is converted to sulfur dioxide during combustion. The concentration of sulfur dioxide (SO2) in the resulting flue gas, for most coals, would exceed the limits established by the Environmental Protection Agency (EPA). Therefore, the sulfur must either be removed from the coal prior to its burning, or be collected from the stack gas before it reaches the atmosphere. There is currently a large amount of research devoted to methods of removing the sulfur from the coal before burning, or during combustion in fluidized beds with materials which trap the sulfur in the solid residue. The commercialization of these processes, however, is not expected in the near future. Flue gas desulfurization appears to be the best near term prospect of fulfilling current air quality control regulations. The lime/limestone wet-scrubbing methods are the most advanced flue gas desulfurization processes and will account for the majority of sulfur removal systems in electric power generation. There are currently at least 23 full-scale systems existing or under construction and 17 of these will use the lime or limestone wet-scrubbing process. (1)

Jan 1, 1974

By C. T. Harper, B. J. Fryer, R. P. Taylor

"IntroductionThe Maurice Bay deposit is one of a number of uranium deposits that have been found in recent years in the Athabasca Basin of northern Saskatchewan (Tremblay, 1982). This deposit, along with the others, belongs to the unconformity type deposits (Beck, 1977). They are, for the most part, polymetallic, being characterized by a suite of metals which include U, Ni, Co, Cu, Pb, Zn, Mn, V, Ag, Au, Pt-group elements, S, As, Bi, Se, Te, and Mo, some of which, besides U, are present in economic concentrations (Amok, 1974; Ruzicka, 1975; Tapaninen, 1976; Hoeve and Sibbald, 1978; Dahlkamp, 1978). The Maurice Bay deposit was known to be a small low grade deposit in which the ore was essentially monomineralic, consisting mainly of pitchblende (Harper, 1978). However, the occurrence of trace amounts of some of the elements common in the larger polymetallic ore bodies (e.g. Key Lake, Cluff Lake D) was anticipated. Thus a lithogeochemical sampling project was undertaken in 1979 across part of the Maurice Bay deposit (Harper, 1979). Major oxides (SiO2, Al2O3, FeO, Fe2O, MgO, CaO, K2O, Na2O, MnO, P2O5, and TiO2) and a group of the most common trace metals (U, Ni, Co, Cu, Pb, As, Au, V, and Se) were analyzed to determine whether any elemental patterns (halos or depletions) could be detected which would reduce the number of pathfinder elements needed for exploration purposes. In addition to the above metals, Th was also checked because some conglomerate strata in the Maurice Bay area are known to be thorium-enriched (Harper, 1978). Only the trace metal distributions will be discussed in detail in this report.General GeologyThe Maurice Bay area is underlain by three major groups of rocks, the White Lake metamorphic complex, an unnamed granodiorite complex, and the Athabasca Group, described previously (Fig. 1; Harper, 1979). Table 1 summarizes the stratigraphic features as deduced by geological mapping and the examination of drill cores."

Jan 1, 1986

By Russell A. Carter

Alaska is a land of immense proportions and resources. Its very name, derived from an Aleut term, means "The Great Land." Yet, in a state slightly larger than Texas, California, and Montana combined, there are presently only two-large scale mines in production, excluding dredge operations. Once referred to by its territorial governor as "a storehouse of minerals," Alaska is, in the opinion of many industry observers, at least 20 years away from a healthy, productive mining industry. The mineral potential of the state is tremendous: coal deposits on the North Slope alone have been hypothetically pegged at 1.5 trillion tons. Copper-zinc deposits on the south flank of the Brooks Range are conservatively estimated to be worth $4 billion to $6 billion. However, the problems facing mineral development are of equal magnitude, and include:

Jan 11, 1976