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By Robert K. Koch, Henry E. Blake

Laboratory tests were made to determine if aluminum fluoride of commercial grade could be synthesized by reacting alumina hydrate with dilute ( 25 to 75 grams per liter of fluorine ) aqueous fluoride solutions . • Products containing up to 90 percent aluminum fluoride ( A1F ) were synthesized by reaction of alumina trihydrate ( A120 3H2O) with either dilute hydrofluoric acid ( HF ) or ammonium fluoride ( NHF) solutions , the ammonium fluoride solution resulting from ammonia ( NH ) desilication of a hydrofluoricfluosilicic acid ( HF - H₂ SiF ) solution . Fluorine recoveries of over 80 percent were obtained with either type of solution . The hydrated precipitates of AlF, and ( NH4 ) , A1F ( ammonium aluminum fluoride ) obtained by reacting hydrated alumina with these solutions were subsequently converted to anhydrous AlF, by controlled heating .

Jan 1, 1964

By T

THE Sulphide Corporation's works for the smelting of ores containing lead, gold, and silver are situated close to the Cockle Creek railway station, on the main Northern railway line, and are about 95 miles from Sydney and 10 miles from Newcastle. A branch line runs to the works, and siding accommodation and bins are provided for expeditiously handling all ores sent for treatment. The Corporation also possesses wharfage facilities at the port of Newcastle, where consignments of ores arriving by sea can be handled direct into railway trucks for conveyance to the works.The greater portion of the ore treated at Cockle Creek comes from the Corporation's mine at Broken Hill, but a large quantity of other grades is also purchased and treated.

Jan 1, 1918

By Ronald M. Hays

The White Pine Copper Division of Copper Range Company is a large copper producer operating an underground mine, mill, and smelter on Michigan's Upper Peninsula. Principal water discharges are from the tailings basin where these discharges are high in dissolved solids because of mine water pumped into the basin. Principal air emissions are from the smelter where SO2 emissions are uncontrolled. Although water discharges and air emissions have not had significant environmental impacts, environmental regulations could require additional control procedures. Because of low copper prices and poor profitability, cost of compliance with possible new environmental regulations could have serious impact on White Pine with no apparent significant beneficial environmental impacts.

Jan 1, 1979

By John C. Feeley

This paper is the result of a field study of prospect drilling in the Florida phosphate fields. The objective is to describe the drilling methods employed . . Since the general policies of the operating companies in the land - pebble area do not permit the dissemination of prospecting information and costs thereof , the writer has carefully avoided mentioning names and locations except by reference to existing publications ,

May 1, 1949

By Armin D. Ebner

A hetero-f1occulation model is developed to calculate the net force exerted on a paramagnetic nanoparticle that is moving in the proximity of a magnetite particle that is fixed or supported within an open flow and magnetically energized packed bed. Important variables investigated include the size and surface charge of the particles, the magnetic field, the ,flow velocity, the electrolyte concentration and the magnetic susceptibility of ,the nanoparticle. The ?influence: of other naturally occurring forces, such as hydrodynamic and DLVO(Le., van der Waals and electrostatic) forces on the magnetic attractive forces between the magnetite particle and the nanoparticle are also examined. This model reveals the feasibility of using magnetite particles instead, of stainless steel as the energizable element for high gradient magnetic separation.

Jan 1, 1999

By M. Sagisaka

The purpose of this study is to obtain carbon dioxide emissions by copper production systems and quantitative merit to use copper scraps in Japan. Electrolytic copper and sulphuric acid originating from the refining gas are produced in the system. In this study, the inventories such as the fuel consumption of the unit processes and the in-house electricity generation were obtained from published papers and public statistical data. The following observations were made based on the Life Cycle Assessment (LCA) method: (1) Carbon dioxide emissions from the production of electrolytic copper and sulphuric acid in the system are about 1.0 kg and 0.4 kg/kg-product respectively. The carbon dioxide emissions attributable to the transportation of copper concentrate correspond to 20% of the total emission. This emission is higher than that of zinc because the metal content in the concentrate is lower than zinc. (2) The carbon dioxide emissions from the system decrease with the recycling of copper scrap to the converting process because the consumption of copper concentrate is reduced. The reduction is estimated to be 0.18 kg-CO2/kg-Cu at the point of 0.1 kg-scrap/kg-blister Cu. This corresponds to 9% reduction for the present system. However, this recycling leads to the decrease of sulphuric acid by 450x103 tonne at the point. The recycling of scrap should be evaluated not only from the reduction of carbon dioxide emissions, but also in terms of sulphuric acid demands as well as advantage of waste management.

Jan 1, 2003

By Boyd GL

Backfill applied to highwall mining is foreseen as a means to increase recovery of mineable coal to levels comparable with underground longwall mining. This paper describes the progress of research to demonstrate the role required of backfill to achieve real increases in coal rCCOvCrCd h\ hi'eh ss-all mining methods.

Jan 1, 1998

By Louis A. Panek

The practice of roof bolting, now recognized as an effective method of support, is based largely on rule of thumb. Among the various applications of bolting, the support of stratified mine roof is by far the most common. The general principles relating to this type of reinforcement are presented in two companion reports; the first describes the function of the bolts, the bolting pattern, and the behavior of bolted roof (1), 2/ and the second describes the design of the models and the theory of the experimental method (2). This report presents a rational method for designing systems of vertical bolts to reinforce horizontally bedded mine roof, developed from model tests. The structure treated herein may be described as follows: The immediate roof, consisting of beds of like material and equal thickness with no bond between them, is reinforced by vertical bolts installed in straight lines across the opening; the case of suspension is excluded because the bolts are assumed not to extend above the immediate roof. The assumption is made that the behavior of the lowest bed approximates that of a rectangular plate clamped along two opposite sides (the ribs). These specifications represent approximately the roof conditions encountered in mining bedded deposits of all kinds - coal, potash, iron ore, etc. Thus, for the design of a roof-bolting system a quantitative solution to the following problem is required: For a roof composed of beds of given thickness and physical properties, how does the support depend upon the length, spacing, and tightness of the bolts?

Jan 1, 1956

Gravity gold recovery has been practiced for thousands of years, making it one of the oldest forms of mineral processing. Gold is 19 times heavier than water although the barren rock is generally only 2.7 times heavier. Any potential gold ore needs to be characterised to assess its amenability to a gravity recoverable gold (GRG) process based on well planned and executed test work. Scale up considerations need to be considered in designing a gravity circuit. The economic impact of a gravity circuit should be justified based on the installed cost and likely benefits. Maximising gravity gold recovery results in a faster cash flow, lower operating cost per ounce and higher overall gold recoveries compared to the several weeks required to recover gold adsorbed onto carbon. The advent of centrifugal concentrators such as the Knelson and Falcon, coupled with intensive leaching of concentrates (ILR), has revolutionised gravity gold circuit designs. Considerations associated with the sizing of the centrifugal machines and the percentage of the circulating load (bleed) that should be processed is discussed in this paper. The trends with gravity circuit layout, engineering, as well as optimum dumping cycles, are important areas which require close consideration. Key aspects of these are presented in this paper. There are a number of circuit configurations to be considered, including the integration of different gravity concentrators. Other gravity process design considerations such as fewer modules, the effect of equipment size and enhancement of process efficiency using preconcentration, together with factors that affect OPEX and CAPEX are addressed. Practical considerations of maintenance, security from theft, minimisation of risk and water balance considerations are discussed using different equipment and circuit configurations. The trend towards using gravity recovery in flotation plants is also reviewed. A number of examples are cited and good design aspects highlighted.

Aug 1, 2010

By CorrOa de Araujo A, Salum MJG

The treatment of mining and metallurgical liquid effluents is becoming, everyday, a necessity felt by these industries. Physical-chemical and chemical methods for treating such effluents are generally necessary whenever heavy-metals and other toxic compounds such as cyanide are present. The present paper discusses the use of precipitate flotation as an alternative physical- chemical method that can be applied for the treatment of effluents containing heavy-metals (mainly zinc and cadmium) and cyanide. Examples of laboratorial scale applications on real effluents are given. In both cases precipitate flotation was able to reduce the concentration of toxic components of the effluents at a very high removal rate, generating a solid waste that can either be disposed, re-used or recycled. A cationic collector - dodecylamine hydrochloride - demonstrated to be the best choice of surfactant for the two systems investigated. Sodium sulphide and dithizone were selected for the precipitation of the zinc bearing effluent whereas a copper salt was preferentially used for precipitating cyanide in a form adequate for its recycling envisaging the use of an AVR (acidification - volatilisation - regeneration) technique.

Jan 1, 1993

By H. C. Carpenter

Lignite tar made by low-temperature Lurgi-Spülgas carbonization of North Dakota lignite was hydrocracked in single-pass, fixed-bed operation at 3,000 pounds per square inch over cobalt molybdate catalyst to produce gasoline, and at the same pressure, over zinc chromite catalyst to crack the high-boiling phenolic compounds to low-boiling phenolics. Hydrocracking the raw tar or the creosote-oil fraction from the tar over cobalt molybdate removed most of the oxygen, sulfur, and nitrogen in the forms of water, hydrogen sulfide, and ammonia, and produced gasoline yields from 31 to 59 volume-percent. The gasoline fractions contained from 0.1 to 7.7 volume-percent tar acids, but tar-base percentages were too low for reliable measurement; removal of these materials with dilute caustic and acid solutions also reduced the sulfur and nitrogen to 0.01 weight-percent or less.

Jan 1, 1963

By V. Fiedler, H. Lachmund, R. Bruckhaus

"After producing some 50 million tonnes of crude steel the two BOF vessels at Dillinger Hüitte steel plant had to be replaced in 2000/01 due to large deformations. The new vessel design was optimised after a number of theoretical evaluations.Refractory investigations were carried out as well as temperature measurements of the shell to provide a basis for selecting a suitable steel grade. This was found in a DH-GTS development - P420M HT - with high strength at elevated temperatures and excellent weldability and made it also possible to build the vessel without any cooling system.After putting the first vessel into operation the metallurgical results showed no remarkable improvement compared to the old vessel, and were therefore not satisfying. With the help of cold model investigations the arrangement of the tuyeres was modified to improve the flow conditions and the interactions between oxygen jet and the heterogeneous plume of the bottom stirring gas. Further optimisations were obtained by a variation of lance tips and a newly developed lime addition model."

Jan 1, 2004

By A Minchinton

With blasting, all far-field phenomena including, but not limited to, stress wave propagation, fracture, vibration and muck pile formation are intrinsically and irrevocably dependent upon near-field phenomena or mechanisms that we describe using physics-based mathematics typically transcribed into computer codes. The energetics involved in such near- to far-field transitions are not fundamentally relevant as they are simply progenitors of these processes.The notion of explosive energy as a descriptor for explosive or blasting performance is a case in point. These energies, which are generally used in blasting tables, are almost exclusively based on ideal detonation theory alone and do not include the influence of the rock, charge diameter, blasthole length and the late-time dynamic expansion that can be predicted using codes based on non-ideal detonation theory.With decoupled charges in presplits for example, the pressure drop between the charge and the blasthole wall can be simply described to first order using the energy relationship associated with adiabatic expansion. However, a more realistic mechanistic solution involves interacting fluids and turbulence leading to dynamic processes such as the channel effect.CITATION:Minchinton, A, 2015. On the influence of fundamental detonics on blasting practice, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 41–54 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By H. Yin, T. Emi

"Advantages of gas/flux injection technology as materialized in the main stay unit processes for steelmaking are depicted covering hot metal pretreatment through secondary refining. Current status of micro-kinetic issues involved in the injection technology are reviewed including gas-in- metal, gas-in-slag, flux-in-metal, metal-in-flux and three-phase dispersion systems with reference to macro-kinetics. Key problems are briefly addressed to further develop injection technology for steelmaking processes.1. FROM PAST TO PRESENTApplication of gas injection to steel industry started in early 1950's when inert gas bubbling via stopper rod, lance, or porous refractory plug was practiced to make the temperature of steel melt in ladle uniform The gas bubbling in ladle was then extended to slightly removing hydrogen ti'om the steel melt tapped from Electric Arc Furnace (EAF) and Basic Open Hearth Furnace (BOH) when vacuum processing facilities were not popular. Later, oxygen gas injection via calorized steel pipe into molten steel bath in BOH Furnace was also put into operation to promote the decarburization to increase the productivity of the process. This line of development has been made in parallel with more profound processes, i.e, top blowing Basic Oxygen Furnace (BOF) for primary steelmaking and side blowing Argon Oxygen Oecarburization (AOD) vessel for decarburizing stainless steels.On the other hand, injection of fluxes into steel bath was first industrialized in Germany in 1960's, Primary objective was to desulfurize steel melt in ladle by injecting CaC2 or CaCrCaO mixture via lance under neutral slag cover with good success. Difficulties in injecting fluxes without clogging and rippling at a desired flux/gas ratio, and durability of injection lance were resolved in due time to bring forth many injection facilities to flourish for versatile refining operation. Top injection of fluxes from main oxygen lance to BOF was also industrialized as LDAC to promote early slag formation. A new process then emerged which injects oxygen gas and fluxes together through concentric annular tuyere, installed at the bottom of the BOE into steel melt. This process, developed in Germany [Oxygen Bottom Maxhutte (OBM)] and brought into maturity in USA (Q-BOP) and Japan in a large scale operation, became the predecessor of the combined blowing (top and bottom blown) BOF which dominates modern steelmaking."

Jan 1, 1996

By G. Mahieu, L. Perez-Barnuevo, P. Barbeau-Verreault, O. Gravel

Raglan mine is a copper-nickel mining operation, part of Glencore, and located at the northern border of the province of Quebec, in Canada. The concentrator is fed by a mix of four different underground mines, thus it must accommodate periodic variations in run-of-mine mineralisation and composition. In order to concentrate nickel and copper sulphides, the flotation circuit also includes a regrind step at the cleaner stage. This leads to challenges in maintaining optimal recoveries and in diagnosing potential disturbances. This paper advocates for the combination of automated mineralogical analyses, reconciliated mass balances from diagnostic sampling campaigns and innovative multidimensional visualisation to assist in tackling these challenges. Through this approach, it has been possible to quantify the regrind step influence on the liberation of valuable mineral particles in the final flotation concentrate. The methodology also allows for virtual sieving of the products in order to track unit loss in the flotation process. The proposed analysis scheme presents an opportunity to easily diagnose flotation circuit performance based on mineralogical information. Keywords: Flotation diagnostics, multi-dimensional visualisation, mineral liberation analysis

Jan 1, 2020

By A. Ordoñez

El presente estudio refiere la metodología y los cálculos para resolver el problema del transporte del fluído en el sistema de bombeo, de forma que ayude al diseñador en la selección de números de plantas de bombeo, sistema de la tubería y los diámetros adecuados, así también se describe las características idóneas para las posibilidades de su operación. Las características técnicas y económicas son programadas en FORTRAN IV y se obtienen para cada alternativa los costos de inversión anual dol proyecto con los que se determina la solución óptima. Una vez obtenida la solución óptima para el sistema de bombeo, el diseñador evaluará un programa donde se determine los anclajes y la ubicación de válvulas de aire, considerando ciertas simplificaciones en la estructura que mejoren el análisis del sistema.

Nov 20, 1972

By P. Massacci

The modelling of phenomena by nonlinear dynamic Systems Theory representations require the specification and identification of suitable models of the phenomenon and the availability of good optimization algorithms to determine the optimal controls. Stochastic disturbances and difficulties of monitoring the process lead invariably, otherwise, to suboptimal performance. It will be shown that an algorithm can be formulated which will simultaneously identify and optimize such a system. The properties of the algorithm will be derived and its convergence to an optimal control proved. Some results of actual applications will be presented and it will be shown how this approach generalizes easily to optimal control of the actual processing system. These results generalize those of optimal learning and input conditioning.

Jan 1, 1991

By L. B. Pankratz

Heat contents, measured above 298.15° K, and derived entropy increments are presented in tabular and equation form for the two crystalline forms of zinc sulfide (sphalerite and wurtzite) and for four solid solutions of iron and zinc sulfides having the compositions Zno.,,6Fe0.302S, Zno.750Fe0.250S, Zno.650Fe0.3505, and Zno.498Feo.502S.

Jan 1, 1965

By Paul C. Ragland, P. Geoffrey Feiss

The Piedmont province of the southern Appalachians is the focus of interest for many exploration geologists. In the past, only those deposits with significant surface exposure were exploited. Thus, few deposits have been found and relatively little exploration has been conducted in recent years. Modern geochemical and geophysical techniques can alleviate this problem of concentrating on exposed ore bodies by allowing us to "look through" the soil and saprolite to detect the presence of significant mineralization at depth. This paper will attempt to evaluate the feasibility and effectiveness of several geochemical exploration techniques in the Piedmont province of Cabarrus and Stanly counties, N.C. The area chosen for study is shown in [Fig. 1], lying almost wholly within the Mt. Pleasant quadrangle, N.C. The area is on the eastern boundary between the Charlotte belt, a zone of plutonic and intermediate grade metamorphic rocks, and the Carolina Slate belt, a series of complexly interbedded volcanic and sedimentary rocks of predominantly low metamorphic grade. The area is considered to be an early Paleozoic active, continental margin. l As is typical of most of the piedmont, outcrop is sparse. [Figure 2] is a sketch map of the general geology of the area under study, showing the Charlotte belt rocks in the northwestern quadrant and slate belt rocks to the east. Within the area are a number of old mines and prospects, the most famous of which are the Furniss and Phoenix mines in Cabarrus County. All are reported to have contained Au and Cu. Ag and Pb were reported from some. A summary of the deposits is given in [Table 1]. Data used in this study are from three Master's theses completed at the University of North Carolina at Chapel Hi11. 3, 5, 6 In separate studies, well waters, 5 B-zone soils,3 and vein and float from the area were sampled and analyzed. Each study concluded separately that geochemical anomalies in the vicinity of the ores justify use of that specific sampling technique in a geochemical exploration program. However, no comparative study of the methods has been made. It is our intention

Jan 1, 1980

By V. Jokovic

Hydrocyclones are the most commonly used classifiers in the mining industry. The reason for this is their low operating cost and a small footprint. Data from plant trials where screens replaced hydrocyclones indicated that lower bypass of fines and sharper separation could improve breakage rates, with a positive effect on flotation circuit performance throughput. Despite the importance of classification, hydrocyclones have not received as much attention as more expensive comminution units, and their technological progress has been incremental. Noticeable water split (Rf) reductions of a semi-inverted hydrocyclone have been reported in the past. According to theory, the hydrocyclone with reduced Rf will improve classification of fines. A classification study using semi-inverted hydrocyclones was conducted to determine if a hydrocyclone could be operated in a way that would minimise misclassified fines. The classification performance of a semi-inverted hydrocyclone will be presented in this paper and other potential applications will be discussed. Keywords: Semi-inverted hydrocyclone, water split, misclassification of fines

Jan 1, 2020