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By P. H. Jennings

Commercial tellurium commonly contains heavy basemetal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities (~ 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too s low to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Feb 1, 1966

By P. H. Jennings, J. C. T. Farge

Commercial tellurium commonly contains heavy base-metal impurities such as lead, copper, iron, etc., as well as selenium and oxygen. The base metals may be removed by vacuum distillation or by zone melting. Vacuum distillation is a convenient method for treating moderate quantities ( 100 kg.) for the production of a material having a total content of heavy metals in the 10-30 ppm range. By zone melting, it is possible to lower all the heavy metal impurities tm below the limits of spectrographie detection. Neither vacuum distillation nor zone melting is effective for the removal of selenium, but treatment of molten tellurium with hydrogen converts selenium to hydrogen selenide. This procedure is too slow to be considered except as an adjunct to zone melting. In the course of air-melting, many of the more easily oxidized impurities form a dross and may thus be readily removed. Substantial refinement with respect to iron, tin, chromium, aluminum, sodium, silicon, magnesium, calcium and manganese can be achieved in this way. Although tellurium can be electrodeposited from either acid or alkaline solutions of the dioxide, various factors militate against successful electro-refining, amongst which may be mentioned the brittleness of cast tellurium anodes and the tendency for the metal to be deposited in dendritic form, even at low current densities.

Jan 1, 1966

By John J. Stetler

The Companhia Vale do Rio Doce in Brazil operates one of the most extensive systems in the world for the mining, transportation, processing, pelletizing and shipping of high grade hematite iron ore and pellets. Current shipping of unbeneficiated, sized, high grade ore from its ports at Tubarão and Vitória is now at the rate of 17,500,000 metric tons annually. An increase in this annual rate is now under study. Using the technology and facilities of Lurgi (1) and Arthur G. McKee company CVRD undertook a program to process and pelletize two types of fines - "Blue Dust" and ?Itabira Fines?. Blue Dust is a high grade fine ore which was bypassed while mining the direct shipping ores and which, also, exists as a very large ore body called the Conceição Mine. Itabira Fines is a lower grade of fine ore which is comprised of in-situ fines and, also fines which are generated in sizing the direct shipping ores for a rigid specification market.

Jan 1, 1970

By Gerald W. Elger

The Federal Bureau of Mines developed a modification in the conventional Kroll process for preparing high - purity hafnium metal . This modification involved the partial replacement of magnesium by sodium in the batch reduction of purified hafnium tetrachloride to sponge metal . The raw tetrachloride was purified either by thermal degassing of the volatile contaminants to the atmosphere or by fused- salt treatment . In the fused- salt treatment , the tetrachloride was contacted with molten alkali chlorides to remove the impurities . The reaction byproducts were removed from the metal by heat treatment in an evacuated furnace . The metal sponge was consolidated by melting into buttons or ingots , which were analyzed for impurities . The purity of the metal prepared by the modified process is superior to that of the metal produced by the conventional method . The hafnium metal was comparable to crystal - bar hafnium except for the oxygen content , despite the abnormally high impurity concentrations in the raw tetrachloride . Several ingots were successfully cold - rolled to sheet .

Jul 1, 1960

By W. O. Vanderburg

This paper describing the methods of concentrating tungsten pros at the mills of the Atolia Mining Co. is one of a series of similar papers being prepared by the United States Bureau of Mines. The writer acknowledges the assistance and cooperation of A. V. Udell, president, Louis Warnken, bookkeeper, and C. K. Dennis, superintendent, of the Atolia Mining Co. in the preparation of this paper.

Jan 1, 1931

By Yuji Yamashita, Kazuyoshi Kamimura, Tsuyoshi Takahashi, Naoya Matayoshi

"The CDM-LODIC method (cement deep mixing - low displacement and control) method enables ground displacement to be reduced by removing an amount of soil equivalent to that of injected cement slurry and the volume of the plunged mixing tool, which causes a certain degree of ground displacement. Since the CDM-LODIC method was developed in 1985, it has been applied to over 930 sites and the accumulated volume of stabilized soil has now reached 7.6 million cubic meters.In the CDM method, the number of blade rotations per unit depth in the ground when the mixing blades are withdrawn is considered a construction item. The blade rotation number depends on the degree of mixing between the cement slurry and the ground Some field tests were performed based on the degree of mixing between the cement slurry and the ground. In these tests, a new concept of evaluating the blade rotation number when the screw rod penetrates to a given depth without injecting cement slurry has contributed to the degree of mixing. Furthermore, a correlation exists between the coefficient of efficiency of soil removal and the cement slurry admixture rate. In this paper, we discus the data collected in those field tests and present some application examples.OUTLINE OF CDM-LODIC METHODThe injection of cement slurry may cause some ground displacement during Cement Deep Mixing (CDM). In recent years, due to an increased demand for ground improvement work in urban areas, there is increased concern that buildings near any CDM site may be adversely affected. The deep mixing method which reduces displacement due to mixing (CDM-LODIC method) enables ground displacement to be minimized by removing an amount of soil equivalent to the injected cement slurry and the volume of the mixing tool, which itself causes some ground displacement. When the construction site is near other structures, regardless of whether on or under the ground, the CDM-LODIC method can be used in order to minimize any ground displacement. There are considered to be two main causes of ground displacement as shown in Figure 1. Displacement A indicates ground displacement caused by the volume of the inserted mixing tool during the penetration stage and displacement B indicates ground displacement caused by the volume of the injected stabilizing agent. Thus, by removing soil equivalent to the volume of the inserted mixing tool and the injected stabilizing agent, ground displacement can theoretically be minimized. Figure 2 shows the amount of observed ground displacement in the cases of CDM and CDM-LODIC at an actual site. These case studies indicate that ground displacement can be reduced by removing the soil."

Jan 1, 2015

By Alton B. Cook

The practice of using partly depleted oil reservoirs for gas-storage operations is proving successful. Moreover, this practice provides a method of secondary oil recovery when gas is cycled at full-storage reservoir pressure. Because of the relative newness of this operation, a study was undertaken to assist engineers in developing improved gas-injection and production procedures and in calculating the amount of gas needed for completely repressuring reservoirs. This paper is the third in a series reporting the progress of a study by the Federal Bureau of Mines of reservoir performance during complete gas repressuring and gas cycling. A procedure for estimating secondary oil recovery by this method is also under study. One report (7)3/ describes the laboratory equipment. The other report (8) gives (1) data on the New York City field, Clay County, Tex., which has been converted to gas-storage operations; (2) laboratory data from research with a model oil reservoir, in which primary production, complete gas repressuring, and gas cycling for the New York City field were simulated; and (3) theory to explain reservoir performance during gas repressuring.

Jan 1, 1961

By Andrew Budek

"Analytical and experimental work has shown that achieving the full inelastic lateral capacity of a pile may require the formation of a plastic hinge below ground level, in the pile shaft. The confining action of soil about the pile shaft was further been shown to greatly enhance the ductility capacity of the pile. An experimental program was therefore undertaken to build in the effect of external confinement through the addition of a GFRP jacket to the subgrade plastic hinge region. Two piles were thus modified, and compared to an unjacketed pile in a test rig which simulated a subgrade moment pattern and soil confinement. The ductility achieved by the jacketed piles was found to be substantially lower than an unjacketed control specimen. Failure mode of the jacketed specimens was also undesirable, involving complete tendon rupture and sudden loss in capacity IntroductionSeismic loading of concrete pile shafts can result in a demand for inelastic response. In the case of a superstructure supported by a single pile (i.e., a pile-column forming a single-column bridge pier, in which there is no rotational restraint at the top of the pile}, a plastic hinge will form below grade, at a depth which varies with soil properties and above-grade height of the center of seismic mass.In the case of a superstructure supported by multiple piles, there is rotational restraint, and the connection will experience inelastic action first. However, development of the full lateral inelastic capacity of the pile may call for the formation of a second, subgrade plastic hinge (fig. 1 )."

Jan 1, 2005

By M. M. Oosterveld

"In South West Africa diamonds are mined from ancient beach deposits by the Consolidated Diamond Mines of South West Africa, Limited.To improve the control of mining production, a computer is used for the calculation of statistically more accurate and homogeneous ore blocks. Geological and sampling information has been digitized and stored on magnetic files.The figures derived for each block entail the calculation of the diamond size frequency distribution, the diamond density distribution and the ore reserve by using the density distribution.The diamond size frequency distribution is used for estimating the revenue in an ore block.A description is given of how a linear programming system can be used for production planning."

Jan 1, 2014

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By Wern-Ping Nick Chen

Durability risks for underground facilities can be underestimated during design phase as compared to well-known geological risks. However, unclear durability requirements can result in construction schedule delay and change orders. Unlike bridges or buildings, a unified underground durability code or standard does not exist. This paper will provide a durability approach for underground facilities, including degradation modes, mitigations, and compliance measures during construction. In addition, this paper will address how to clearly specify durability requirements in a contract document to reduce disputes during construction and discuss key durability tests that are time consuming and will impact construction schedule if not timely planned.

Jun 23, 2024

By D. H. Magoon

The zinc smelter of Cominco Ltd. at Trail, B.C. Is the largest In the western world. A total of 550.000 tonnes of concentrate are proceed at the smelter annually. Approximately 80% of the zinc concentrate is roasted and the remainder Is treated by aqueous oxidation preaaure leaching. The zinc concentrate roasting and sulphur dioxide gas processing plants have undergone many changes over the years. This paper describes the processes and equipment currently used for concentrate roasting, S02 gas cooling and cleaning, mercury removal, sulphuric acid production liquid S02 production, and tall gas S02 scrubbing. The recent Installation of an advanced process control system for the operation of these Integrated processes Is also described.

Jan 1, 1990

By Yueyue Ding, Yuanhui Li, Zhengrong Li, Pengfei Yu, Kunmeng Li, Zhipeng Xiong

The stress evolution and failure characteristics of overburden were studied during multi-stope mining for a gently inclined thin orebody. Firstly, an indoor physical experiment was conducted on the excavation of a multi-stope mine with an orebody dip angle of 20°. The results show that the vertical stress concentration area gradually shifts to deep-buried rock mass with the mining from shallow to deep buried stopes, resulting in shear failure originating from high stress. On the contrary, the pressure relief zone presents an asymmetric distribution characteristic that is biased towards the upper part of the goaf, resulting in large subsidence and tensile failure of the stope #1 and #2 roofs. Secondly, the numerical simulation model under the same geological condition was established to measure the roof deformation at different stages of mining. The numerical simulation results are in good agreement with the physical test results; the roof displacement is largest in stope #2, second-largest in stope #1, and smallest in stope #3. Finally, the evolution of deviator stress concentration, displacement field and potential failure zone of overburden under different orebody dip angles were studied. As the dip angle of the orebody increase, the deep-buried stope roof changes from deviator stress release to deviator stress concentration in different stages of mining, and shear failure is most likely to be induced when the orebody dip angle is 30°. Meanwhile, the closure displacement of the stope roof decreases gradually, while the tangential displacement increases, so the anti-sliding ability of the support bodies in the stope should be improved. The potential tensile failure zone gradually shifts from the center of the goaf to the upper part, and the deep-buried stope roof evolves from tensile failure to shear failure. Results of this research expected to provide guiding significance for stope support design to control roof deformation and failure, to ensure the safety of the stope.

Mar 2, 2023

By W. G. Davenport

The flash furnace is used for smelting concentrate to (i) high-Cu matte and (ii) molten metallic copper. It is also used for converting solidified/crushed matte to molten metallic copper. This is flash converting. It consists (Table 20.1, Fig. 20.1) of: (a)tapping molten 65 to 72% Cu matte from a flash smelting furnace (b) granulating the molten matte to ?1/2 mm particles in a 103 m3/hour water torrent (c) crushing the granulated matte to 50 µm in a vertical roller mill (d)drying the crushed matte (e) feeding the dry particulate matte to a second flash furnace for oxidation converting to molten copper. In 2000, flash converting is being used by Kennecott Utah Copper (George, et al; 1995; Newman et al, 1998, 1999a,b). A second installation is being designed for the Chuquicamata smelter (www.outokumpu.com [October 12, 2000]), The potential uses of flash converting are: (a) as the second half of a flash smelting/flash converting coppermaking sequence (b) as a continuous converting alternative to batch submerged tuyere converting. This chapter uses our flash furnace matrix to determine the %O2-in-blast, industrial oxygen and oil requirements for converting solidified 65% and 72% Cu matte to molten copper. It then discusses choice of feed matte grade and other aspects of the process.

Jan 1, 2001

By Gwenaële Petit, Ulan Massimkhanov, Gilles Joubert

For its Zuuvch Ovoo uranium deposit in Mongolia, Badrakh Energy (partly owned by Orano Mining) is working on the prefeasibility study for exploitation by ISR (in situ recovery). As part of this project, Orano built a 2-cell (each cell is constituted of one producer well located in the center and surrounded by six injection wells in an hexagonal pattern) and a processing pilot plant that will be used to demonstrate the operability and economic viability of an ISR process. Another main objective of this pilot trial is to demonstrate the ability of Orano’s modeling tools to predict the ore behavior under given leaching conditions. To model uranium production by ISR, Orano uses HYTEC, a reactive transport computational software, which was adapted for its existing operation in Kazakhstan (Katco) to predict uranium recovery and reagent usage based on operating conditions. In order to perform similar simulations for this new deposit, Orano engaged in a comprehensive program including ore sampling, detailed characterization, and metallurgical testwork. The mineralogical conclusions were used to prepare a simplified geochemistry for the ore, in particular carbonate and reactive clay grades, uranium mineralization and penalizing elements such as pyrite. Then, bottle roll leach tests were used to characterize dissolution kinetics for smectite clays. Eventually, column leach test results such as pH, free acid, and uranium recovery were modeled on HYTEC to improve the fit of some of the dissolution kinetic parameters. Parameters fitted using metallurgical test work results will now be used as inputs for predictive model at the pilot scale, in order to anticipate operational results and help with operating decisions for production ramp up.

Jan 1, 2020

By Jie Long, Zijie Liu, Pu Liu, Bo Li, Menghua Li, Qiang Wu

During coal mine operations, roadways may be located close to faults. When designing these roadways, it is important to determine the width of the rock mass between a roadway and a fault area to prevent water inrush. In this paper, the Xintian Coal Mine in the northern Guizhou Province of China is selected as a typical case. Through numerical simulation based on orthogonal tests, range analysis, and multiple linear regression (MLR) analysis, the process of water inrush from faults in excavation roadways is studied. The results show that the influencing factors of the safe width of a rock mass preventing water inrush (RMPWI) can be ranked according to the degree of influence from large to small as follows: the hydraulic pressure of the fault, the surrounding rock grade, the overburden depth of the roadway, the cross-section height, and the dip angle of the fault. Among them, the dip angle of the fault, the cross-section height, and the surrounding rock grade are negatively correlated with the safe width, while hydraulic pressure of fault and overburden depth of roadway are positively correlated with safety width. The predicted value for the safe width based on MLR is greater than the measured value of the width of the RMPWI when water inrush occurs, but less than the calculated value based on the empirical formula in the standard, which proves the accuracy and practicability of the prediction method. This research provides a certain basis and reference for the prevention and control of water inrushes in mines.

Jul 5, 2023

By Michael Wieland

The work principle from thermodynamics is used to model the shock and heave for explosives shot in rock or under water, with the latter compared to reported results. The work principle utilizes restrictions and constraints to yield a representative fit to the irreversible (natural) shooting process. The reduction of the internal energy of the reaction-zone yields the total expansion work (TXW), the resultant sum of the rock/water shock and heave. The restoration technique of forming a closed thermodynamic loop yields the reversible mechanical work (RMW) or the rock/water heave. The residual work that remains when RMW is subtracted from TXW yields the irreversible disorder work (IDW) or the un-dissipated (without loss) shock in the surrounding rock or water. The work principle renders an unequivocal relationship for the shock-loss factor, rather than the traditional roundabout formula for correcting the underwater gauge-shock of un-modeled explosives. There’s a novel heave-ratio factor that unquestionably rates the fit of results under comparison. Rock-shots are more complex in nature than underwater shots due to rock fracture and stratum rupture, though numerical resolution is worthwhile. The proposed rock-water-jelly (RWJ) model yields rough estimates, with rock-type results not wholly different from their underwater counterparts. Though reported underwater shots reveal shock and heave trends with respect to charge formulation ingredients, there are no such rock-shot results for comparison, since the relevant test measurements in rock remain difficult, if not intractable.

Jan 1, 2007

By Martti Hagfors, Mervi Hokkanen

The Finnish Defence Forces has destroyed obsolete and spoiled ammunition in open surface mass detonations at Hukkakero fell, in municipality of Kittilä, in Lapland since 1988. The de-struction method was learned from Sweden in 1987. The disposal camp is organized every au-tumn and it lasts four to six weeks. A gross weight of an average charge varies from 150 to 250 tons and the net weight of explosives from 15 to 25 tons. As a booster there have been used 2 to 3 tons of emulsion explosives. The explosives mainly consist of trinitrotoluene (TNT) containing smaller a mounts of amatol and hexotol. The Finnish Defence Forces Tech-nical Research Centre (PVTT) has studied the environmental effects of these mass detona-tions since they began in 1988.

Jan 1, 2011

By Diógenes Uceda Herrera

La refinería de cobre en Ilo, procesa el cobre ampolloso que proviene de la fundición de Southern Perú Cooper Corporation, la cual trata los concentrados cupríferos de las minas de Toquepala y Cuajone. En este proceso, el cobre ampolloso se vuelve pre-refinado a través del fuego para así eliminar algunas impurezas y moldear los ánodos de cobre. Posteriormente en la electrólisis, este cobre de ánodo se deposita en el cátodo, liberándose los demás elementos para constituirse en lodos anódicos y así luego ser lixiados con ácidos para recuperar el cobre y centrifugados completamente. En este sentido, el texto señala el método de tostación oxidante con Na2CO3 y en agua como uno de los que más se adecúa a la composición química particular de los lodos anódicos de esta refinería.

Nov 20, 1978

By Bill Paysse, Lyle Ruffle

My intention is to produce a video, pictorial, and oral presentation on utility blasting, primarily power pole holes and ditches. Included will be blasting for a take-off structure inside of Wanapum substation, jointly owned by BPA, PSE, and Seattle City Light, and blasting for 230kV steel tower foundations.

Jan 1, 2007