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By Xiaoqiong Wang, Daobing Wang, Fanbao Meng, Jianbo Wang, Hongkui Ge

"Shale gas has become an important unconventional oil and gas resources. Its effective development relies on comprehensive and accurate understanding of shale gas reservoirs. Rock mechanical properties is one of the important components of reservoir evaluation. Two adjacent black shale samples, which are cored from the depth of 1145 meters in Chongqing, southwest China, are subjected to acoustic emission(AE) test under uniaxial stress and compared with coarse grained granite. The results of synchronous AE, stress-strain and ultrasonic velocity experiments show that shale has weak anisotropy. Compared with granite sample, two shale samples are similar, but their strength, velocity and brittleness are quite different, indicating that shale has strong microscopic heterogeneity. TOC, XRD, SEM microstructure analysis show that total organic content, mineral composition and natural fractures are the main impacting factors for mechanical heterogeneity. INTRODUCTIONShale gas is a typical low-grade marginal resource, which is characterized by ultra-low matrix permeability and small single well control volume. In order to enable commerical development, complex hydraulic-fracture networks must be created in the shale to allow gas to escape from the micro/nano-pores and natural fractures where it is trapped in the rock (C. Clark et al.,2013; Ge et al., 2013). The development of shale gas requires accurate evaluation methodologies to evaluate shale reservoir properties and predict production. (Jarvie et al., 2007). Rock mechanical properties are an important part of the reservoir evaluation. It is significant for efficient drilling, completion and hydraulic fracturing to understand mechanical behavior of shale gas play (John, 2011; Wei, 2013).Rock mechanical properties mainly include heterogeneity, anisotropy, brittleness and acoustic emission activity (Lockner et al., 1992; Jerome et al., 2009; He et al., 2010; Liang et al., 2012). Shale mechanical properties are evaluated from laboratory tests following a complex workflow that covers tasks from sampling to testing (Md. Aminul Islam et al., 2013). It is common to include various experimental methods such as stress-strain curves, ultrasonic velocity and acoustic emission when evaluating the mechanical properties (Rao et al., 2006). Because of the presence of organic-rich matter, mineral composition orientation and natural fractures, shale tends to have strong anisotropy and heterogeneity (Deng et al., 2004; Wang et al., 2013; Hathon et al., 2013)."

Jan 1, 2015

By James A. Morgan

FIELD MEASUREMENTS OF NOISE WERE MADE ON THE PERIPHERY OF ENCLOSURES DESIGNED, MANUFACTURED AND INSTALLED BY INDUSTRIAL ACOUSTICS COMPANY, INC. ON THE SECONDARY TACONITE CRUSHER AT THE JACKSON COUNTY IRON COMPANY PLANT IN BLACK RIVER FALLS, WISCONSIN. NOISE REDUCTION ACHIEVED BY THE ENCLOSURES WAS SUFPICIENT TO PERMIT REDUCTION OF CRUSHER ROOM NOISE TO 90 DBA, PROVIDED THAT OTHER SOURCES ARE APPROPRIATELY TREATED AND ACOUSTICAL ABSORPTION IS PROVIDED IN THE CRUSHER ROOM. SECONDARY CRUSHER NOISE WAS REDUCED 10 TO 15 DBA BY THE ENCLOSURES.

Jan 1, 1980

By A. Warczok

The oxidation and smelting of chalcopyrite, bomite, chalcozine and pyrite has been studied under simulated flash smelting conditions. The results of copper sulphide oxidation show that under constant oxidation conditions, the degree of oxidation drops sharply when the particle size is increased above a given range. This critical size range varies typically between 200 and 500 pm depending on the oxygen content in the gas phase. For bomite, chalcopyrite and pyrite, the critical size range increases with increasing iron content in the mineral and with increasing oxygen content in the gas phase. The extreme case is observed for pyrite in pure oxygen, where there is no effect of the particle size on the degree of oxidization. Microscopical observations of the oxidized products show the influence of different factors on the mechanism of oxidation and fragmentation of the sulphide particles. Based on microscopical analysis and phase identification of the oxidized products, a model has been proposed for the oxidation and smelting of copper sulphide particles in suspended state. The mathematical model describing the sulphide particle oxidation is supported by the obtained results. Using this model, it is possible to describe the role of particular factors in the sulphide minerals oxidation.

Jan 1, 1992

By R. M. Tyson

Sulfides present in the troctolitic and footwall rocks are placed into one of three major zones (hornfels, cloud, and basal) on the basis of their stratigraphic position and mineralogy. Hornfels sulfides, enriched in Fe, represent remobilized sedimentary sulfide. Sulfides from the Cloud Zone are probably magmatic and are enriched in PGE, Cu, Ni, and Ag. The basal sulfides, composing most of the ore, resulted from contamination of the magma by remobilized sedimentary sulfide. The basal sulfides exhibit a differentiation trend in their mineralogy and chemistry. PGE, Cu, and Ag are enriched with increasing differentiation which is attributed to fractionation within an immiscible sulfide liquid.

Jan 1, 1986

By R. G. Warncke, D. Harrington

"INTRODUCTION The use of black blasting powder as an explosive in coal mines has long been recognized as hazardous and has been responsible for many of the worst disasters in American coal mines. One of the most pressing of the numerous problems confronting the Bureau of Mines, upon its creation in 1910 was to determine methods that would lessen the hazards created by the use of explosives in coal mines. The Bureau continued the study begun by the Technologic Branch of the Geological Survey as to the nature of explosives and made numerous tests to determine types of explosives suitable for blasting in coal mines. The Bureau has tested and approved hundreds of types of explosives and has disseminated information on methods and conditions for use underground to make them permissible as to safety. The Bureau of Mines has encouraged the use of permissible explosives for coal-mine blasting, and its experts both in the laboratory and in the field believe that the use of black blasting powder in any form (granular or pellet) is hazardous in any underground coal mine. Despite the information published at various times and innumerous ways and the general knowledge of the hazards that the use of black blasting powder in any form creates in the blasting of coal, the coal mines in the United States, during 1947 used approximately 34 million pounds of black blasting powder (granular or pellet), or approximately 11.8 percent of the total quantity of explosives used by the coal-mining industry.Many coal mines of the United States, for various and sundry reasons, probably will continue the use of black blasting powder, and this circular has been written for the benefit of such users, not that any suggested method or methods will make the use of this explosive safe, but it has been found that methods and conditions of use of black blasting powder can be improved so as to lessen, though not eliminate, the hazards created by its use."

Mar 1, 1949

By Cheng Pan, Xuewei Lv, Guibao Qiu, Chenguang Bai, Meilong Hu

"Physic-chemical properties of slag at high temperature play an important role in the pyrometallurgical process of production of ferronickel alloy. It determines the operation efficiency, metal recovery ratio, energy consumption and the distribution of elements like S and P between the slag and metals. In the present work, the effect of MgO content in the slag on melting features and viscosity of the slag was investigated. The MgO content in the SiO2-CaO-MgO-Al2O3 -FeO in the quinary slag system varied from 14.5% to 22.5%. The results shown that all slag samples begin to softening at the same temperature, the softening temperature, melting temperature, flowing temperature decrease with the increase of MgO content when the MgO content is in range of 14.5 and 20.5 pct mass, and when MgO content up to 22.5 percent, the temperatures increase sharply. Besides the inflection point temperature of viscosity-temperature curve increase with the increase of MgO when the MgO content is in range 16 and 22.5 pct mass.IntroductionNickel is very important to modern society, without it, we would not be able to share many things in our daily life, such as airplanes, computers and many stainless steel appliances in our homes and workplaces1.. It is the essential element of the stainless steel making, and about 65% of the nickel consumed in the world is used to make stainless steel2., so with the increase of stainless steel, the nickel production and demand has continued to increase3.Nickel is produced from two distinct ore types: nickel sulfide deposits and oxide nickel laterite deposits. The great majority of world’s known nickel resources are contained in laterite deposits3.. The laterite ores are normal classified into two groups: the high-iron laterite ore and high-magnesia laterite ore1. Typical composition of high-magnesia laterite ore is in the range 1-3%, and these ores are suitable for pyrometallurgical process to produce ferronickel4."

Jan 1, 2012

By Mike de Wit

Of the approximately 6,500 kimberlites known to date, less than 3% are diamondiferous and less than half of those are economically viable. Admittedly, this is a global figure and varies from area to area much depending on geological, logistical, and political circumstances. The number of diamond-bearing kimberlites is an important geobarometer, and an age-frequency profile has been compiled in order to identify diamond metallogenic epochs and provinces. Four primary diamond clusters have been recognized: Siberia (332-370Ma), Kaapvaal South(114-144Ma), Kaapvaal Southwest(84-95Ma), and Slave (52-55Ma). In addition, three secondary clusters are the Kaapvaal Central (S06-S38Ma), the Man Craton (139-lS3Ma) and the Kasai Craton (120-130Ma). The Kaapvaal is the only area where kimberlites with diamonds were discovered between 1870 and 1925, except for the Prairie Creek discovery in North America in 1906 and Colossus in Zimbabwe in 1907. Between 1906 and 1940 no major diamondiferous kimberlites were discovered, but many of Africa's alluvial deposits were found and exploited in that period. Advances in scientific prospecting in the 1940's rapidly accelerated the discovery rate that peaked in the 1990's; 39 diamondiferous occurrences were found in the 1980's, of which 8 became mines and 5 are in feasibility, and nearly 450ha of kimberlite was added to the global resource base. Despite the accelerated exploration expenditure, the last decade (e.g. 2000-2009) has been the leanest since the 1940's. The most important reason for this decline in exploration success is that any undiscovered deposits are largely buried by younger cover. Understanding complex and geophysical noisy basement geology, as well as decomposition of path-finder minerals are major challenges to further exploration success. Major investments in basic geological expertise and field research will have to be made in order to secure future diamond resources. Integrated geophysical studies, geochemistry diamond forensics, and improved imaging of Earth's upper mantle are perhaps foremost in this requirement, but the costs of these activities are such that government support will be required if countries are to sustain their diamond mining industry.

Jan 1, 2010

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of quartz with oleic acid as collector and barium, calcium, aluminum, iron, and tin as activators were studied using a simple vacuum-flotation technique in glass-stoppered graduates. The detailed study of barium activation led to an interpretation based on ideal Langmuirian chemisorption.

Jan 1, 1950

By W. G. Davenport

The offgas from flash furnaces inadvertently contains dust. The dust contains 25 to 30% Cu so it must be treated for Cu recovery. This is almost always done by recycling it back through the flash furnace*. This chapter shows how dust production/recycle is included in our matrix calculations. It then discusses the effects of dust production/recycle on flash furnace industrial oxygen and oil requirements. It concludes that re-smelting of dust requires considerable industrial oxygen and fuel, so that dust production should be minimized. Recycled dust also takes the place of new concentrate in the flash furnace feed system, decreasing Smelter productivity -another reason to minimize dust production. Compositions of industrial dusts are given in Appendix VII and Table 18.3. Industrial quantities are given in Tables 2.1, 3.1, 19.1,20.1' and Appendix VI.

Jan 1, 2001

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By Webber. G. R.

Variation in content of some of the major and minor elements in the Lake Dufault granodiorite near Noranda, Quebec has been studied. The element variation and specific gravity data show a pattern consistent with the concept of a concentrically zoned intrusive on the western side of Lake Dufault with a potassium-rich core and a calcium-rich inner zone. The part of the intrusive on the eastern side of Lake Dufault is of more problematical origin, but the suggestion is made that it has resulted from assimilation of volcanic rock by the intrusive. THE purpose of this investigation was to test the application of x-ray fluorescence analysis to the study of variation in chemical com-position of the Lake Dufault granodiorite. The Lake Dufault granodiorite is an intrusive body approximately six miles long by three miles wide located four miles north of Noranda, Quebec. This intrusive is of particular interest because of its -

Jan 1, 1962

By C. Gary Reiness

A safety glass eyepiece which had been repeatedly exposed to mine environment over a number of years was studied to determine some of its optical properties. In the regions from 385 to 400 mµ and from 625 to 760 mµ, the transmittance was less than the 89 percent required by the American Standard Safety Code for Head, Eye, and Respiratory Protection. From 200 to 320 mµ the relative transmittance of two parts of the eyepiece was found to vary widely, having a maximum of 38 percent difference at 315 mµ. Irradiation of the glass by ultraviolet light caused enhanced absorption in the range from 200 to 1,200 mµ. There was a time-dependent increase of 1016 color centers per cubic centimeter throughout this range after 36.5 hours of irradiation. The rate-of-growth curve for the optical density, at 243.5 mµ and 23° C, was resolved into linear and saturable components, indicating zero order and first order

Jan 1, 1968

By David M. Davidson

Seven intrusive phases have been mapped to date in the 1 b.y. Red Bluff Granite Complex (RBGC) near El Paso, Texas. This batholith is 20 km2 in area and intrudes older supracrustal units as well as a trachyte ignimbrite cap. Two early microgranite sills are spatially separated 6 km from a porphyritic, three-phase "ring complex" by a tin-bearing, biotite granite which cores the RBGC. These units are intruded, in turn, by a riebeckite granite which locally exhibits lineated and pegmatitic textures as well as exceptionally high light REE and Zr values (800 ppm La; 3,000 ppm Zr). The riebeckite granite is exposed in three separate occurrences within the Franklin Mountains. REE values in the RBGC are depleted in HREE and show distinct negative Eu anomalies. Typical La/Yb ratios are 5:1-2:1 with Eu values ranging from 10-80 ppm. The mineral source of the high REE values in the riebeckite granite has not yet been specifically identified, but is believed to be zircon.

Jan 1, 1988

By M. P. Dalton

This paper which describes the milling practice at the Morning concentrator of the Federal Mining and Smelting Co., Mullan, Idaho, is one of a series being prepared by the Bureau of Mines. ACKNOWLEDGMENT The author wishes to acknowledge the assistance given by H. G. Washburn, general manager of the Federal Mining and Smelting Co., and by C. S. Price, assistant mill superintendent, in the preparation of this paper.

Jan 1, 1932

By T. A. Sullivan

The use of sulfur combined with either sand or waste copper tailings was investigated by the Bureau of Mines as a substitute for a good graded aggregate in asphalt paving materials. The research was part of a utilization program to develop meaningful uses for a projected oversupply of sulfur. Many sections of the country lack good aggregate for paving but do have available sources of sands and sulfur. The development of paving mixtures of desert sands or tailings with sulfur and asphalt was accomplished in the laboratory and tested by laying small paving test sections. Three types of material were studied for use with the sulfur and asphalt. They were (1) a concrete sand similar in gradation to river or beach sands, (2) desert blow sand, and (3) waste copper tailings. Desert blow sand and waste copper tailings are much finer than concrete sand. Mix designs were established for the three types of materials, sulfur, and asphalt used in the paving materials. The best mix designs were as follows, in weight-percent: 80.5 concrete sand, 13.5 sulfur, and 6 asphalt; and 77 either blow sand or tailings, 17 sulfur, and 6 asphalt. Small-scale testing showed that these mixtures were suitable paving materials but would require specialized equipment for transporting and laying. The chemical modification of sulfur to obtain properties that would allow placement of these materials with normal asphalt paving equipment was studied. Results indicate that reacting sulfur with dicyclopentadiene before adding it to the paving mixture was effective in modifying the sand-sulfur-asphalt paving so it could be placed and rolled with conventional equipment.

Jan 1, 1975

By D. N. Tallman

The electrokinetic properties of MgO have been utilized to simultaneously filter suspended solids and remove trace amounts of dissolved heavy metals from synthetic mine water. Greater than 95 pct removal of metals from influent at neutral pH containing 1 to 6 mg/L of dissolved Cd, Cu, Mn, Ni, and Zn can be routinely achieved by filtering through a granular bed of MgO at flow rates typical of rapid sand filtration (0.3 cm/s). Filtrate concentrations of most metals can be maintained below 0.1 mg/L for 160 bed volumes or more loading. The more mobile metals (those with larger solubility products) are more difficult to remove, and are strongly bonded to the MgO granules so that chemical stripping with chelating agent is required to clean the bed. Less mobile ions are easily removed by the filter and are effectively stripped by conventional filter backwashing. The fraction of metals recovered by chemically stripping the loaded MgO filters correlates to the zero points of charge of the metals. This process may be applicable to removal and recovery of trace amounts of heavy metals in mine drainage that is partly neutralized by liming. Also, since many of these metals are critical and strategic, the technique can be adapted not only to recycle process water from mineral and milling waste streams, but also to reclaim their metal values.

Jan 1, 1986

By J. B. Zink, M. J. Peterson

A semiquantitative spectrochemical method was developed and applied to the analysis of ash of U.S. coals . A low- temperature ashing procedure was used to minimize the loss of volatile elements . The analytical procedure provides for the estimation of 68 elements including major , minor , and trace constituents . Standards for the trace elements were prepared in a synthetic base mixture that approximates the average composition of U.S. coal ashes . Excitation was achieved with a d- c arc , spectra were recorded photographically , and interpretation was made by visual comparison of spectra of unknowns with spectra of graded standards series . Thirty- six trace elements were found in the analysis of 900 samples . Details of the procedure are presented , including sample and standards preparation , excitation and exposure conditions , spectral lines used , and approximate limits of detectability .

Jan 1, 1964

By Henry N. Toler

Development in the Jackson gas field, Hinds and Rankin counties, for 1935 continued at a slow pace, there being only nine wells drilled on the structure, of which five resulted in gas producers and four in dry holes. There were no wells drilled deep enough during 1935 to test any of the horizons below the producing Selma chalk. There are 113 producing gas wells in the Jackson gas field, with three wells on the southeast edge of the field making some oil with a large quantity of salt water; this oil comes from the same horizon as the gas. The combined open flow of the 113 gas wells is about 4,100,000,000 cu. ft. The proven area of the field is approximately 8000 acres. The production of 10,291,000,000 cu. ft. for 1935 represents the largest yearly pull from the field by almost a billion cubic feet. The total production from the field to date is 45,104,000,-000 cu. ft. It is interesting to note that the rock pressure has dropped from 1010 lb. per sq. in. initial to 943 Ib. at the end of 1935, a decline of only 67 lb. in 6 years. There is a difference of opinion as to the age of the deepest formation tested on the Jackson structure; some people holding that it is Tuscaloosa, others, Trinity, and still others that it is Paleozoic, probably Pottsville. The production of the Amory gas field, Monroe County, continued to decline and the capacity was far under the demand. Originally there were four producing wells in the field with a combined open-flow capacity of approximately 15,000,000 cu. ft. and a rock pressure of 680 lb. per sq. in. At the end of 1935 only two wells were producing with a combined open-flow of less than 1 million cu. ft. and the rock pressure down to 100 lb. or less. No attempt has been made to drill new wells in the immediate field but three wells are being drilled in the county in an effort to secure new supplies of gas. The wildcat operations for 1935, with only 11 wells drilled, were the lowest since 1932, just about one-half the number drilled during 1934. None of the wildcat wells drilled in 1935 resulted in producers and, so far as the writer is aware, did not uncover any large structures. The 11 wells drilled were abandoned or junked at comparatively shallow depths, except the well drilled in George County to 6928 ft. by the United Gas

Jan 1, 1936

By C. Blawert

In previous studies of various HPDC magnesium alloys we found that the corrosion properties of the skin are inferior in comparison to the bulk, However, this is surprising as one would expect better corrosion properties for the finer microstructure of the skin, In a more detailed study using 2 and 6 mm thick sections from HPDC AZ91 step plates, the corrosion results of the original skin, the slightly removed skin and the bulk were compared, Indeed, the corrosion measurements including potentiodynamic polarization, long term polarization resistance measurements and electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin. An explanation for this corrosion behavior was found, on the one hand, in the microstructure concerning especially the amount and distribution of the 13-phase and, on the other hand, in the composition, including the distribution of the most important alloying element Al and of some impurities such as Fe.

Jan 1, 2005

By Arden D. Fugate

The Federal Bureau of Mines conducted extensive studies on solid-state defluorination (laboratory scale) and tests on molten defluorination (intermediate scale) of siliceous fluorspars. The studies were made to develop a pyrohydrolytic process for liberating fluorine from offgrade fluorspars. Test results showed that more than 90 percent of the fluorine can be evolved by solid-state defluorination at 1,300° C., and more than 97 percent can be liberated by molten-state defluorination at 1,420° C. Solid-state defluorination conditions were established by conducting tests on mixtures of ceramic-grade fluorspars and high-purity silica flour. Pelletized mixtures were defluorinated under varying conditions of time, temperature, and relative concentrations of silica, calcium fluoride, and water. The effects of adding various amounts and combinations of aluminum oxide and iron oxide on defluorination were also studied. Investigations of solid-state defluorination indicates that the following two reactions are involved: 2CaF2 + 3SiO2 = 2CaSiO3 + SiF4, and CaF2 + Sio2 + H20 = CaSiO3 + 2HF, The second reaction is dominant, although significant defluorination can be achieved by the first reaction.

Jan 1, 1961