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By Marcia L. Harris

Toxic fumes produced by detonating explosives in surface mining and construction operations pose potential hazards to workers and the public. Blasting operations produce both toxic and nontoxic gaseous products; the toxic products are mainly carbon monoxide (CO) and the oxides of nitrogen (NOx). Since 1988, there have been 17 documented incidents in the United States and Canada in which carbon monoxide (CO) is suspected to have migrated through ground strata into occupied enclosed spaces as a result of proximate trench blasting or surface mine blasting. These incidents resulted in 39 suspected or medically verified carbon monoxide poisonings as well as one fatality. At worst people may be fatally poisoned and the least to be expected is increased public objections to blasting. Local and state agencies could demand a cessation of the blasting requiring more expensive mechanical means to break the rock. This paper discusses the most feasible means of preventing CO migration, mitigating CO that has migrated, and detecting CO in an underground enclosed space and may help reduce the exposure of unsuspecting area residents to carbon monoxide and help prevent the implementation of unnecessary regulations and limitations on blasting. Single-hole shots and small-scale multiple-hole blasts were performed that indicate promising means of prevention and mitigation.

Jan 1, 2008

By Bruce Pinkston

This report presents a description of the Prototype Demonstration Vehicle and Safety Guidelines developed under U.S. Bureau of Mines Contract No. JO 366003, ?Improving Man Transit Safety. This vehicle was constructed to assess the feasibility of a set of equipment related guidelines which were drafted in Phase I of the same contract. State-of-the-Art improvements are embodied in such areas as collision survivability, occupant comfort, and multiple mode (on and off rail) operation. The electric battery powered vehicle carries a twelve man section crew at speeds up to 12 mph. The description of the demonstration vehicle Is presented In Volume I. Safety Guidelines are presented in Volume II.

Jan 1, 1981

By A. Koning, P. Lauzon

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature, with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry's experience base. The impact of irreversible chemical swell, operating factors, design factors, and installation factors are presented based on modifications to the traditional one-dimensional mechanical stress model. A new stability criterion - that the brick lining remain in contact with the steel shell membrane - is presented. This new stability criterion imposes new restrictions on the lining design.The effect of geometry and adding additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional Finite Element Analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed.

Jan 1, 2004

By H. William Zeller

The Bureau of Mines is conducting research to determine whether the use of chemical surfactants improves respirable coal dust control and is evaluating laboratory test criteria for selecting effective surfactants. This publication presents the results from wetting effectiveness tests with emphasis on the capillary rise test. The test variables investigated included coal particle size, type of surfactant, surfactant concentration, test duration, and mineral con-tent of the water. In addition to the rise test, measurements of con-tact angle, zeta potential, and sink time for various coal and surfactant combinations were conducted. No significant correlations among the four wetting tests were observed, a surprising result which implies that each test type measures specific aspects of the wetting phenomenon and also that each test type should only be used to select surfactants for specific applications. For example, the rise test shows solution penetration into porous materials, and the sink test discriminates among surfactants for dispersing finely ground materials into suspension. Another important conclusion is that combinations of agents retain their individual wetting properties, allowing mixtures to be for-mulated to perform well in both rise and sink tests.

Jan 1, 1983

By Yun-tao Xin, Yu Yi, Kang Yan, Gang Li, Xiao-dong Lv

This study investigated the selective removal of arsenic from high-arsenic dust in alkaline systems and the effects of different leaching conditions. The results indicated that the liquid–solid ratio, NaOH concentration, and sulfur dosage had a significant influence on the process. The leaching efficiency of arsenic reached 99.57%, while that of lead was as low as 0.03% under appropriate conditions. In particular, the addition of sulfur can effectively promote the leaching of arsenic and reduce the dissolution of lead in the solutions. An artificial neural network was used to model the leaching process. It consisted of a back-propagation artificial neural network model with a “6–10–2” structure that could effectively simulate and predict the value with more than 99% accuracy. Based on the difference in weights of the different parameters in the neural network model, the relative importance of the parameters related to arsenic and lead leaching efficiency was obtained, which followed the order of NaOH concentration, liquid–solid ratio, sulfur dosage, temperature, time, and stirring speed.

Jul 29, 2021

By Shawn A. Cefalu, Matthew J. M. Krane, Kent J. VanEvery

"Segregation during electroslag remelting (ESR) of a nickel-chromium-molybdenum alloy (Ni-8 wt% Cr-25 wt% Mo) has been modeled. Features of the model include species transport and AC electromagnetic effects coupled with fluid flow, heat transfer, and solidification. The effect of varying ingot diameter and melt rate, on macrosegregation patterns, local solidification time, and liquid pool profiles obtained from this model are demonstrated. The results show that the macrosegregation in the ingots correlates to the filling velocity.IntroductionElectroslag remelting (ESR) is a secondary melting process used to refine the chemical composition and the microstructure of metals. Macrosegregation of solute elements causes defects in ESR ingots, including freckles and the maldistribution of phases. These defects are not correctable through heat treatment due to the large length scales over which they occur. However, the frequency and distribution of these defects may be minimized, or even prevented, through process control based on an understanding of the conditions that lead to their formation.In the past, studies have been conducted on the effect of the process parameters on the shape of the melt pool and the thickness of the mushy zone [1-7]. In these studies, the shape of the liquid pool is determined by consideration of the heat and fluid flow induced by electromagnetic (Lorentz) force and thermal buoyancy. The transport of solute and the resultant solutal buoyancy effects were not considered in these macroscopic models. Defect formation is tied to formation of secondary phases (e.g., freckling and white spots in nickel superalloys) [5,8]. In cases where secondary phase formation is calculated (e.g., [6]), phase fractions are determined using a micro-scale model given the local solidification time (LST) and local thermal history from the macroscale model.Using the local thermal history from the macroscopic transport model to predict microstructure increases the importance of the accuracy of those results. This investigation models the macrosegregation of molybdenum during the ESR of a Ni-Cr-Mo alloy. The effect of macrosegregation on pool shape and depth is demonstrated, along with its effect on the local solidification time. By comparing the relative effects of the melt rate and ingot radius, a better understanding of the factors that affect macrosegregation, and ultimately secondary phase formation may be obtained."

Jan 1, 2004

By W. Norman Sims

A number of forces are at work that are now having an influence on coal handling systems. Changes are occurring and will be occurring at an increasing rate during the next few years. 1. Environmental concerns will dictate that dust pollution and spontaneous combustion and its resulting problems be rigidly controlled. 2. Slurry pipelines will be a reality despite the opposition of the railroads because they are economical and make good business sense. Artifical roadblocks can only survive for a limited time. 3. Coal is now and will remain the most economic fuel, particularly for power generation. This is true in most of the developed nations not just the United States. Increase in demand requires a close inspection of transportation systems. 4. A projected major increase in the export of U.S. coals may never occur without major port developments not the least of which will be the ability to accommodate large ships without demurrage time now affecting such shipments at U.S. Ports.

Jan 1, 1982

By Rafael Padilla

In the production of copper from chalcopyrite (CuFeS2) concentrates by the smelting and converting technology, the ambient pollution with gaseous S02 and toxic metals such as arsenic compounds is still a serious problem, especial1y in the converting step due to the batch nature of the conventional Peirce Smith process. Non-SO2 emitting alternatives are leaching processes. However, few of them have had a limited industrial application and they are not very effective in discarding safely the toxic impurities. A combination of pyro-hydrometal1urgical methods: the sulfidation of chalcopyrite and subsequent leaching of the sulfidized material is a non-polluting alternative to treat not only clean chalcopyrite concentrates but also complex chalcopyrite-enargite concentrates. In this article, this alternative is discussed concerning the thermodynamics and kinetics of the sulfidation of chalcopyrite with gaseous sulfur. The kinetics of the leaching of the sulfidized concentrate in an H2SO4-NaCI-O2 system is also discussed.

Jan 1, 2003

STANDING COMMITTEES Executive-A. R. LEDOUX, chairman. Membership-GEORGE C. STONE, chairman. Finance-J. V. N. DORR, chairman. Library-E. GYBBON SPILSBURY, chairman. Papers and Publications-BRADLEY STOUGHTON, chairman. Nominations-POPE YEATMAN, chairman.

Jan 7, 1919

By J. A. Herdlick

At the request of the War Production Board a preliminary examination of the Big Ben molybdenum prospect near Neihart, Cascade County, Mont., was made by the Bureau of Mines under G. N. Bennett, mining engineer, Bureau of Mines Montana district office, in September 1942. Formal investigation, consisting of sampling, core drilling, and metallurgical testing, was later undertaken and completed in 1943. Field work was directed by Robert D. O'Brien, mining engineer, Montana district office, under the supervision of E. W. Newman, supervising engineer, Montana district office. This report describes the deposit, presents the factual data obtained from the sampling and core-drilling operations, and summarizes the results of the metallurgical studies. The deposit was first located and prospected in 1922 by the present owner, Frank Mansikka of Neihart, Mont. Periodic examinations made by responsible mining interests were culminated in 1938 when the Federal Mining & Smelting Co. optioned and investigated the property. No ores have been produced from the deposit to date.

Jan 1, 1949

By T. H. Miller

This piper is a continuation of a series of yearly review articles started in 1925 by Thomas Varley. The development of flotation has been rapid, and better understanding of the functions o' flotation reagents has resulted in many changes in the kinds and quantities o reagents used. It is the purpose of this report to present the information in such a manner as to be of value to the milling industry as well as to the manufacturer of flotation reagents. These data have been compiled from a. survey of approximately 250 flotation plants of all classes within the United States. Many of these plants made complete reports of their operations, out others were apparently unable to supply this information in sufficient detail to meet the requirements of this investigation. Although it is realized that the data obtained in this survey are not as full as they should be to render the greatest service possible to the milling industry, it is hoped that succeeding articles will include complete information regarding milling; conditions and recoveries. As in the past, every effort has been made to conceal individual plant operations. RESULTS OF INVESTIGATION Table 1 gives the tons of ore treated by gravity and flotation methods and the concentrates produced as reported by 208 plants. The totals of 77,043,535 tons of ore and 4, 596,640 tons of concentrates from this table compare with totals of 78,973,012 tons and 4,683,972 tons respectively (furnished by the Bureau of Mines, Division of Mineral Statistics), indicating that the milling survey is about 98 per cant complete.

Jan 1, 1930

West Virginia University, Engineering Experiment Station, Morgantown, W Va C E Lawall, Director. For copies of Bulletins or other information address the Director Two classes of the Bulletins published by the Engineering Experiment Station are of particular interest in this directory- Research Bulletins, and Extension Bulletins, or bulletins published for use in extension work They are. Research Bulletin 1, The conservation of natural gas in West Virginia (1918), 2, Acceleration stresses in hoisting ropes (1927), 3, Classification of gas wells for operation (1927), 4, Mining methods in West Virginia (1929), 5, The whiteware industry of West Virginia, Extension Bulletin 1, Electricity in mines, series

Jan 1, 1933

By J. E. Tiffany, Gaigler. Z. C.

"PREFACEIn presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 16 and 21 outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible.In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 16 and condition 2 on page 21. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.PERMISSIBLE EXPLOSIVES TESTED UNDER SCHEDULE 17CAn active list of permissible explosives was published in December 1937 as part of Bureau of Mines Report of Investigations 3361, under the title ""Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1937.n This list included 196 brand names.Changes in the list that have been authorized to June 30, 1938, placed 7 additional brands of permissible explosives on the active permissible list as a result of tests, changes in brand names, or transfer from the inactive list. Twelve permissible explosives were transferred from the active to the inactive list. The present list contains 191 brand names. The brand names of the permissible explosives placed on the active list are as follows:"

Oct 1, 1938

By John D. Foulkes, David A. Curtis, Robert L. Lagace, John L. Rothery

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal mines. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to deter- mine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m5 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to be attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977

By H. Kandemir

An experimental study of the bacterial oxidation of naturally occurring high-purity sulphide minerals (FeS2, Fe1-xS, Cu5FeS4, ZnS) is presented using a mesophilic strain of T. ferrooxidans. As well as metal analyses and solution pH, partitioning of sulphide sulphur into elemental sulphur and sulphate has been monitored as a function of leach time. Partially oxidized sulphide substrates have been characterized, at regular time intervals, by X-ray diffraction methods and extracellular organic compounds reporting into leach solution .have been identified by thin layer -chromatography.

Jan 1, 1985

By James P. Bennett

The Bureau of Mines investigated the role of imported natural flake graphite in dolomite-carbon refractories used in steelmaking processes. Fundamental engineering data were obtained to enable the evaluation of substitute materials. Changes in oxidation resistance (2,000° F), hot strength (2,750° F), and deformation under load (2,7500 F) caused by 10-wt-pct additions of five different kinds of natural flake graphite and increasing quantities (0 to 30 pct) of a 90-pct-carbon natural flake graphite were studied. Results indicated that carbon purity of 10-wt-pct-graphite additions did not influence hot strength or deformation under load. When the quantity of 90-pct-carbon graphite addition varied between 0 and 30 wt pct in a dolomite-carbon brick, hot strength was highest and de-formation under load lowest with 10-wt-pct additions. As hot strength test temperature was increased from 5000 to 2,750° F, the strength difference observed between 0-and 30-wt-pct additions of a 90-pct-carbon graphite became smaller. Additions of a boron-treated graphite caused significantly higher strength and lower deformation under load at high temperatures, while an addition of ball clay significantly reduced strength and increased deformation.

Jan 1, 1987

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By S. J. Macnaughton

The Olympic Dam deposit in South Australia contains 2% copper and 0.06% uranium, which are present as bomite, chalcocite, chalcopyrite, uraninite, coffinite and brannerite. The copper is principally recovered using flotation. The flotation tailings, which contain the bulk of the uranium, and typically 0.3% copper, are leached using sulfuric acid and an oxidant at atmospheric pressure. This paper describes the results from a detailed investigation of the leaching behaviour of this ore. The influence of acid strength, Fe3+ concentration, redox potential and temperature on the dissolution of uranium and copper minerals was studied. Experimental data were obtained from extensive batch leach tests. Mineralogical studies, including SEM analysis of individual mineral grains, were also carried out. The maximum extraction of uranium determined experimentally was in good agreement with that predicted from SEM determination of the proportion of refractory brannerite in the ore. The leaching rate of copper was found to be independent of acidity over the range 20 g L-' to pH 2.0, but was strongly dependent on temperature and Fe3+ concentration. Uranium extraction showed a weak de endence on acidity, Arrhenius temperature dependence and a complex co-dependence on F>+ concentration and redox potential. A kinetic model has been developed, which predicts copper and uranium dissolution. This model will be incorporated into a more comprehensive model that can be used to predict leach performance and reagent consumption for specific ore samples.

Jan 1, 1999

By Savidis G

The characteristics of 'Z' (Back-over run) and 'R' (Reverse) ventilation systems are dis- cussed in relation to their suitability for longwall mining. Experience in European mines has been described as a basis for comparison with Australian conditions. In assessing the merits of each ventilat- ion system, such factors as longwall layout (pillar design, number of headings and gateroad stability), the need for gas drainage and bleed- er systems, as well as the influence of seam dip have been considered relevant. The R system is generally applicable for single and two heading development in seams where gas emission is a less serious problem. In contrast, the lower extraction to development ratio of the Z system (which arises from using three or more heading layouts) is considered more favourable where high gas emission occurs. The Z system provides greater flexibility with respect to the provision of refreshing air at the tailgate end, access of men and materials, installation and retrieval of gas drainage systems and the ability to interchange main- gate and tailgate roadways in cases where roof strata loads are difficult to control, or where cpam in hac an influrnra

Jan 1, 1983

By X. X. Jiang

An efficient recovery of finely divided magnetite particles of 400/500 mesh from a mixture of magnetite/silica particles has been investigated by imposing a delicate balance between centrifugal and surface tensional forces on these particles. The effect of centrifugal force, surface tensional force, density and size of particles on the overall metallurgical efficiency has been examined. A mathematical model based on a momentum balance on the particles at the liquid/liquid interface has been developed. The validity and limitations of the model are discussed in view of the experimental results obtained.

Jan 1, 1992