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By Tasuku Fuwa, John Chipman, David H. Kirkwood

Fe-C-Si alloys in silica crucibles were held at 1600°C in a controlled atmosphere of CO and Co2 and the approach to equilibrium was obsertsed. Results were not of sufficient precision to establish the activity and interaction coefficients. Observations 012 the equilibrium provided an average value for the standard free-energy change which differed by + 1.1 kcal from the earlier accepted value. The C-SL relation at other temperatures is calculated and shown graphically. IN the refining of steel in an acid-lined furnace, it is well known that, unlike in basic refining, a very significant amount of silicon may remain dissolved in the metal even when the carbon content approaches a final endpoint. Further, it is known that the residual silicon increases with increasing temperature. The quantitative relation between silicon and carbon can be calculated for equilibrium conditions from data already available on the Fe-C-O and the Fe-Si-O systems. Such equilibrium calculations could show us approximately the limitations within which the reaction would be expected to operate in practice. In the oxidation of a bath containing both carbon and silicon it is well known that at low temperatures silicon is preferentially oxidized first. It can be shown by calculation that at high temperatures carbon will be oxidized preferentially. It is the purpose of this paper to record direct observations on the Si-C relation by means of experiments carried out in an atmosphere of carbon monoxide for Fe-C-Si alloys contained in silica crucibles. When such a system is brought into equilibrium, at a fixed temperature, the composition of the liquid metal is governed by the following equations: Both K1 and K2 are known with a fair degree of accuracy, and may be calculated from the tabulated In general the percentage of CO2 is extremely small compared to that of CO and in the experiments to be described the partial pressure of the latter was generally only slightly below 1 atm. EXPERIMENTAL METHOD The induction furnace employed was the same as that described by Rist and chipman' and by Fuwa and chipman.2 It was modified slightly in view of the change from alumina to silica crucibles. The small silica crucible was surrounded by a thin susceptor of molybdenum sheet which in turn rested inside a zirconia crucible. Since the zirconia was subject to breakage, it was supported inside an alumina crucible. The charge consisted of 30 to 35 g of electrolytic iron along with the required amounts of refined silicon and graphite to produce a melt of required composition. Purified carbon monoxide and carbon dioxide were passed into the furnace through carefully calibrated flow meters. Two separate and independent series of experiments were carried out. In Series I (D.H.K.) the melt was held in the furnace at 1600°C for periods of time up to 6 hr. Samples were taken at intervals in silica tubes and were analyzed for carbon and silicon. The results of the last one or two samples taken from each experiment and the direction in which equilibrium appeared to be approached are shown in Table I. In Series II (T.F.) the silica crucibles were of less satisfactory strength and the melts were held at 1600° C for periods of only 2 to 4 hr. In heats number 29 to 45 inclusive, the metal was cooled in the furnace and the ingot itself served as a sample for analysis. In heat 46 and all subsequent heats, samples were withdrawn in silica tubes at the termination of the heat, and these samples were analyzed. The results of all of these experiments in which equilibrium appeared to be approached are listed in Table II.

Jan 1, 1965

By Ivan L. Nichols

Tailings dumps at Mercur, Utah, contain about $7 million worth of gold in 3.5 million tons of mill tailings assaying about 0.07 ounce of gold per ton. Commercial mining and milling at Mercur ceased in 1942. To determine whether improved technology was now available that might permit economic reprocessing of the Mercur dumps, the Bureau of Mines probed for a low-cost method that would be applicable to these tailings. A composite sample prepared for laboratory studies assayed 0.062 ounce gold per ton. About 10 percent of the gold occurred as a water-soluble cyanide. Conventional cyanide leaching dissolved 32 percent of the gold, and hot, strong cyanide solution dissolved 42 percent. Results were not improved by pretreatment with acids, bases, or oxidants. After expensive preroasting, gold recovery by cyanidation was increased to 65 percent. The simple procedures were ineffective, and more effective procedures were too costly for economical processing of Mercur tailings.

Jan 1, 1970

By E. Heikkinen, J. Suikkanen, T. Siren, J. Valli, M. Hakala

Diametrically faced borehole breakout observations are a fairly good indication of magnitude of the secondary stresses acting perpendicular to the borehole. In cases of low in situ stresses, where borehole breakouts are not observed naturally, it is possible to increase the prevailing stress state around the borehole by increasing the rock temperature. When the temperature is increased sufficiently, thermally induced borehole breakouts will occur. By implementing the temperature increase in boreholes located at excavated tunnels, it is also possible to study the effect of the near-field stresses caused by the excavation. The near-field stress state changes as a function of borehole depth, thus increasing the information available from experiment. To study the feasibility of this proposed low cost method, a Borehole Thermal Spalling (BTS) experiment was executed in ONKALO Underground Rock Characterization Facility, in Western Finland in 2014. The first borehole pilot test with the method was conducted in ONKALO at the POSE niche in already at May 2010, with the second pilot test following in August 2010 at Äspö HRL. The major objective of the experiments was to define the trend of the maximum in situ stress component, while also providing knowledge of the in situ spalling strength of the ONKALO rock mass. The stress state in ONKALO is nearly isotropic in horizontal layer, causing problems for the use of more traditional stress measurement methods. With boreholes heated over long interval, the weakest rock parts are observed to fail, thus providing statistical confidence. For these reasons, continuous test sections have an advantage in ONKALO, compared to spatially limited stress measurement methods such as overcoring and hydraulic fracturing. The BTS experiment is conducted in 9 meter deep vertical boreholes located at the POSE niche, situated -345 m depth below the ground surface. The boreholes used within the BTS experiment are located in migmatitic granite, in an experiment area where the surrounding stress state and the rock strength are fairly well known. The prior knowledge of the stresses is favourable for the experiment, as it requires careful planning and iterations to determine the appropriate heating power domain. Too low heating power will not be sufficient to cause borehole breakout, while too high heating power causes breakout in all directions thus making determination of stress direction hard or impossible. The initial state of the borehole and induced borehole breakouts will be monitored using acoustic televiewer logging (ABI) and optical borehole logging (OBI) imaging techniques. Fracture mechanics modelling is used in planning of the experiment, also in back-analysis to link the observed breakout angle to stress state. Both the pilot test in 2010 and BTS test in 2014 resulted in similar borehole breakout direction. The results are in line with so called EDZ & VT1 stress interpretation, revealed the maximum horizontal component bearing the magnitude of 21.5 MPa, with the trend of 166°.

Jan 1, 2015

AGGLOMERATION U.S. 4,067,727 - In the sintering of a charge of iron oxide ore, a fuel and a flux on a travelling grate machine, the dust problem is minimized by providing a plurality of cooling zones and by directing heated dust-laden air from a first cooling zone to the sintering zone wherein the dust is filtered from the air by the material being sintered. Air from a further cooling zone can be exhausted directly to the atmosphere. Dust removal in the cooling zone is improved by using a purging zone in which higher pressure air agitates the dust in the sintered material. This patent is a division of U.S. Patent No. 3,973,762, dated Aug. 10, 1976. F. Cappel, assigned to Dravo Corp. Jan. 10, 1978. 6 pp. (75-5). Filed: 4-1-76 (672,748).

Jan 1, 1979

By Harold W. Lipper

Helium production and shipment reached new peaks in 1.361. The Bureau of Mines produced 727 million cubic feet, 13 percent more than the 1960 record, and shipped 552 million cubic feet, 16 percent more than the 1960 record. Production exceeded demand for the third successive year, enabling the Bureau of Mines to add 174 million cubic feet to the volume stored underground for future use. At the end of 1961, the total volume of helium in underground storage in the Clifside gasfield was 44-7 million cubic feet. Contracts to implement a long-range helium conservation program were completed with four companies, obligating all the contracting authority of $47.5 million a year made available by the Congress. The four companies will finance, build, and operate helium extraction plants to recover from natural gas an annual average of 3.1 billion cubic feet of helium that would ordinarily be wasted when the helium-bearing natural gas is used for fuel.

Jan 1, 1962

By Osvaldo A. Bascur

Intelligent systems (IS) technologies have received much attention in a wide range of process engineering applications including process operations. With the revolutionary progress in information and computer technologies applying the latest technologies in metallurgical complexes has become a serious challenge to both management and technical teams. Objects and components are changing the way everyone relates to their computer and networks. Goals of real time performance monitoring includes maximizing the profitability by maximizing production, improving efficiency, attending product quality, costs, maintenance, environmental and safety regulations. Designers must consider the greatly expanded desktop computing, Microsoft object technology, Internet and how to build these systems. This paper discusses some opportunities and challenges using objects, components in designing applications and integrating intelligent systems tools. Two examples using performance equations and IS technologies applied to mineral processing are presented.

Jan 1, 1997

By Woolsey McA. Johnson

In metallurgical circles it is known widely, but somewhat vaguely, that the ease of reduction of metallic oxides depends largely on the way they hare been prepared. It is likewise known that different forms of carbon have different and greatly varying reducing powers. It is the purpose of this paper to show somewhat more definitely and scientifically these facts. Some years ago the writer published an account of pyrometric determinations of the reduction temperature of zinc oxides variously prepared and of several kinds.' In said paper it was shown that the temperature at which zinc oxide evolves zinc according to the equa-tion ZnO + C = Zn + CO depends upon the nature of the two reacting bodies. The determina-tions had a range of accuracy of from 2° to 6°C., whereas differences were found to amount to an extreme of 90' C. So the differences are real ones and must have a definite cause. The equation of boiling water, (H2O)4 D 4 (H2O) has a fixed temperature for equilibrium of 100° C. at 760 mm. pressure. In general, all equations reacting in the liquid or the gaseous phase have well-defined constant physical conditions which govern the equilibrium point and reaction velocities. In a reaction where we have one or more solid phases, the tempera ture conditions requisite for the unbalancing of the stable system are found to vary. These variations are due to the fact that in a solid there is a very complex molecule and it is not a question solely of the tearing away of two interlocked atoms, but also of the destruction of a complex molecule containing hundreds, or possibly thousands, of smaller molecules. In other words, there are two forces to be overcome: a certain

Jan 1, 1914

By D Roldpo, M Vidigal, J F. C L Costa

The local cumulative distribution function (lcdf) of a selective mine unit (SMU) can be estimated by conditional simulations using the statistics derived from the sample points, generating multiple equally probable scenarios. Conditional simulations permit the evaluation of the lcdf at any support, taking into account the spatial variability, ie the variogram, and the two statistical moments, mean and variance, of the conditioning samples. The SMU ore losses and dilution depend on the mining method and mining equipment selectiveness that, in its turn, depends on the predicted block size. A new approach to predict ore loss and dilution was developed in this study. Monte Carlo simulation is used to randomly generate a grade value derived from the lcdf at the mining stage (Zs_mc(t)) in order to make a decision about the SMU destination, ie processing plant (ORE) or waste dump (WASTE). If Zs_mc(t) is lower or equal to the cut-off (Z_cut-off) the block is ORE and, conversely, if Zs_mc(t) is higher than the cut-off (Z_cut-off) the block is WASTE. Considering these binary destinations ORE/WASTE, at the mining time t, and combining each realisation of the simulated random function Zcs_i (X), there are four possibilities for each SMU simulated value: 1. the block was simulated as ore and is actually ore (OO), 2. the block was simulated as ore and is actually waste (OW),3. the block was simulated as waste and is actually ore (WO), and 4. the block was simulated as waste and is actually waste (WW).The dilution factor is given by possibility 3 (WO), while the ore loss factor is represented by possibility 2 (OW). These results comprise the classical classification and reconciliation plots used in the mining industry. The new procedure proposed in this paper is based on the use of all the equally probable simulations to define the ore loss and dilution factors. An application of this methodology was carried out at Vale's iron mine in Brazil. The grade of silica was simulated and 50 multiple equally probable 3D models were generated. The mean and the standard deviation of the ore tonnage (OO + WO) for the 50 realisations, was 233 Mt and 0.5 Mt, respectively. The mean grade increased for the diluted ore (OO + WO) as well as their respective coefficient of variation (CV). The CV increases from 62 per cent in the undiluted ore (OO), to 101 per cent in the ore, considering the dilution factor (OO + WO). The mean ore loss (OW) was 10 Mt and the waste tonnage dilution (WO) was 9 Mt.

Jan 1, 2009

By D. C. Willett

INTRODUCTION The Symposium on the Development of Underground Space, held in Seattle, Washington, from October 1 through 3, 1980, was organized by the "Deep Space" subcommittee of the ASCE's Underground Research Technology Council. The primary objective of the symposium was the exploration of the interfaces between the investigation, design and construction of large underground facilities in "deep space" which, for the purposes of the committee, has been defined as starting at 100m below ground surface. The meeting focussed primarily on tunnels, caverns and shafts in hard rock; the meeting format comprised a number of brief presentations concerned with the technical aspects of investigation, design and construction, followed by an open discussion, and concluded with the assembly of recommendations regarding the interface problem by the symposium participants. The principal considerations brought out during the symposium, and a general review of the conclusions, are briefly presented in the following paragraphs. INVESTIGATION The sessions dealing with "Investigation" were chaired by Dr. H. Pratt. Presentations were made by Dr. D.C. Banks, Dr. W.A. Hustrulid and Dr. Pratt. The extent of the interface of the investigation phase with the other (design and construction) phases of an underground facility will depend in large measure upon the nature of the facility; at one end of the spectrum, the investigation must be in continuous and closely coupled relationship with the design of a radwaste facility. At the other end of the spectrum, for (say) a small mining operation, the interface is largely associated with the initial development, with only minor on-going involvement.

Jan 1, 1981

By George S. Rice

INTERESTING developments going on in European coal mines look to: (1) increasing mechanization; 12) concentration of mining; (3) improvement in safety appliances; and (4) studies in bettering roof supports and. incident to this, studies of the way a roof behaves under different conditions of support and methods of mining and back-filling. Mechanization and concentration off mining is being adapted to a considerable extent in Great Britain coincident with the development of conveyors. Belt conveyors, shaker-pan conveyors, and a combination of the two are used. For pitching seams not steep enough for the coal to run in station-chutes, the. shaker-pan conveyor is more popular. For large outputs from a contiguous face, the double-unit system of face layout-that is, the conveyors meeting at a common point-is favored.

Jan 1, 1934

By S. S. Indi, D. Santhiya, S. Subramanian, K. A. Natarajan

The interaction of sphalerite- and galena-adapted Bacillus polymyxa (B. polymyxa) cells with sphalerite and galena has been investigated through adsorption, electrokinetic and flotation studies. The amount of sphalerite-adapted cells adsorbed onto sphalerite and galena is found to decrease with increase in pH. On the other hand, the adsorption density of galena-adapted cells onto galena shows a feeble maximum around pH 8, and the amount adsorbed is marginally higher in the pH range of 8 . 11.5. In the case of sphalerite the amount adsorbed is higher in the pH range of 5 to 7. The adsorption density of both the adapted cells is higher for galena vis-à-vis sphalerite. Electrokinetic studies indicate significant surface chemical changes on the chosen sulphide minerals and the bacterial cells, consequent to microbe-mineral interactions. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite could be preferentially floated from galena, using galena-adapted cells, but not with the sphalerite-adapted cells. The cells adapted to galena assay a higher polysaccharide content and are more hydrophilic, while the sphalerite-adapted cells have a higher protein content and possess greater hydrophobicity. Transmission electron microscopic studies have provided evidence in support of the differences between the cell surface characteristics of sphaleriteand galena-adapted cells. Possible mechanisms of interaction between the minerals and the bacterial cells are discussed.

Jan 1, 2003

By Arthur F. Wendt

IN 1697 King William the Third granted unto his well-beloved subject Adolph Philipse, a certain tract of land, now known as Putnam County, N. Y. At the death of Adolph Philipse the land descended by inheritance to his nephew, Frederick Philipse. In 1751 his surviving three children partitioned the surface into nine parcels and divided them equally amongst themselves, but reserved the mineral rights which they held in common. Thus, at this early period in the history of the colonies, the existence of valuable deposits of iron-ores in Putnam County seems to have been a matter of common knowledge. Yet it is only within the last five years that the county has become a prominent, producer of iron-ore. Desultory mining had been carried on before that period at the Sump, Croft, arid Tilly Foster mines, but only a limited output was achieved, and few of our iron-masters suspected the existence of an abundance of good ores only forty miles from New York harbor. The accompanying map shows the location of those deposits of ore which are now generally known, and have been worked to considerable extent. Without doubt there are many more still awaiting the miner's pick, for no systematic exploration has ever been attempted within the borders of the county. Geologically, the occurrence of the ore is a counterpart of that of the New Jersey and Lake Champlain magnetites. The countryrock, and even the physical geography, are identical. Many small lakes dot the surface of the county. It is from these and their tributary springs and streams that the metropolis derives its farfamed Croton water. Abrupt hills divide the lakes and ponds. Some of the lakes, notably Lake Mahopac, are on the crest of hills, and are fed by subterraneous springs. The prominent mines of the county, in the order of their productiveness, are the Tilly Foster, Mahopac, Croton Magnetic, Sump, Croft, and Island mines. Of these, the first two are at present the only producers, and are quite exceptional in their nature. In fact they are the only ones of their kind in the Appalachian range, if not in the world.

Jan 1, 1885

By Kazuteru Tozcwa

The oxidation of several sulfide minerals in aqueous ammoniacal solution is discussed thermodynamically. The region in which Cu(NH3)2 4+ is stable has been estimated as a function of pH and concentration of total ammonia, {[NH3) + [NH4)}. In ammonia leaching when copper in sulfides is assumed to be extracted in the form of Cu(NH3)2 which will be rapidly converted to cupric ammine, thermodynamic data predict that such minerals are oxidized readily in the following order, CuS, Cu2S, CuFeS2, ZnS, NiS, Ag2S. This agrees with investigations on ammonia leaching of sulfide minerals, reported previously. The leaching of copper sulfide concentrate has been examined experimentally. Copper in a copper sulfide concentrate, in which the main constituents were chalcopyrite and pyrite, was effective¬ly extracted. The copper extraction was affected by factors such as (1) agitation intensity, (2) oxygen partial pressure, (3) NH3/Cu molar ratio, (4) leaching temperature and (5) addition of ammonium sulfate. From the results obtained in this work, it is concluded that mass transfer of oxygen plays the most important role in ammonia leaching of copper sulfide minerals.

Jan 1, 1976

By T. S. Bannos

Section 1417 of the Safe Drinking Water Act Amendments enacted by the O.S. Congress prohibits the use of lead containing solders for potable water systems in new construction or when making repairs. The legislature defines "lead-free" solder as containing less than 0.2% lead. In the development of a new solder it was recognized in addition to the lead free requirement, the alloy should perform as well as the popular 50/50 tin lead solder, both in application and properties. Another objective was to have only nontoxic elements. This led to the development of a 4.0% copper, 0.5% silver and 95.5% tin solder. Review of the merits of other alloy systems and the development of the physical properties along with test data are presented for the lead free tin. rich alloy.

Jan 1, 1990

By S. Lohmeier, D. Gallhofer, B. G. Lottermoser

In Southern Africa, historic mining and mineral processing of base metal deposits have almost exclusively focussed on the extraction of major metals, leading to the loss of remaining valuable raw materials into tailings dumps and waste rock piles. At the Namib Pb–Zn mine (Erongo Region, Namibia), historic base metal tailings deposits are present as unreclaimed exposed waste piles. The tailings comprise silt- (fraction A: d50 = 25 to 48 μm) to sand-sized (fraction B: d50 = 86 to 185 μm; fraction C: d50 = 210 to 230 μm) material and contain major concentrations of base metals (Pb av. 1.15 mass%, Zn av. 3.20 mass%), S (av. 9.95 mass%), as well as lower values of other metals (Cu av. 490 μg/g, Cd av. 133 μg/g, Ag av. 22 μg/g), and critical elements like Sb (av. 14.7 μg/g) and In (14.3 μg/g). Former mineral processing only targeted the extraction of galena and sphalerite. As a consequence, qualitative mineralogical composition of the tailings is similar to that of the primary ore. Ca–Fe–Mg(–Mn) carbonates, quartz, micas, chlorite, minor graphite, magnetite, and rare parisite relate to the former host rock and gangue matrix, whereas Fe-rich sphalerite, galena, magnetite, pyrite with minor pyrrhotite, rare arsenopyrite, marcasite, cassiterite, and accessory scheelite are original constituents of the primary ore. Reprocessing of such a material would be challenging, but a mixed Pb–Zn concentrate enriched in Cd and Ag might be obtained. In future, possible reprocessing of Namib tailings and associated disposal of wastes into an appropriately designed repository would not only generate valuable metal commodities, but such activities would also eliminate a major metal pollution source from the local environment.

Sep 9, 2024

In a letter to Prof. L. P. Breckenridge, chairman, urging the continua-tion of the Fuel Conservation Committee of the Engineering Council, Edwin Ludlow calls attention to the millions of tons of culm in the an-thracite region that can be utilized in properly equipped plants and the electricity generated transmitted to. New York, Philadelphia, and other nearby cities. He says: "Experiments have shown the economic value of No. 4 Buckwheat, which passes through a 1/16-in. mesh and over a 1/32-in. mesh. Culm passing through a 1/32-in- mesh is pulverized until it passes through a 300 mesh and is then burned under boilers. Two plants of this kind are now in successful operation in the anthracite region. Another rather interesting experiment was using 30 per cent. of this pulverized coal with 70 per cent. of oil in the generation of steam in the place of pure oil. This utilization of the fine anthracite, which has always been a waste product and thrown away, is not only fuel conservation in its truest sense but in the case of a bituminous strike, when no strike is contemplated in the anthracite field, will furnish fuel to manufacturing plants that otherwise would be obliged to shut down."

Jan 12, 1919

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014

By L. O. Howard

L. D. RICKETTS, New York, N. Y.-The advance which has been made in Smelting has been in the line of cheaper cost of handling, due to larger units and decrease in losses. At the International smelter, Mr. McGregor designed everything to handle the ore under cover. But we do find an unaccounted for loss of 0.7 per cent. of our copper, which is serious. Mr. Wallace has made a suggestion that I think metallurgists ought to know of and think about. He made it years ago-and that is that one of the chief losses is undoubtedly in the charging and discharging of the calcine cars. His idea is that possibly the dryers and heaters might be put immediately over the reverberatories So that they could discharge in conveyors. They could feed on both sides, and thereby the dust raised by discharging in the cars from the hoppers could be overcome. E. P. MATHEWSON, Anaconda, Mont.-I might Say a few words on the plants we have visited So far. I was particularly struck with the cleanliness of the plants, which is next to Godliness. I noticed also that the skull-cracker arrangement they have for handling their converter slag is very good. And they have paid considerable attention to ventilation, and are taking steps to take care of the health of the men. "Safety first" has been well looked after in all the plants we have visited so far. The steel structures are right up to date, and the buildings are of the most modern type, and everything is conveniently arranged. I think the designers of the plants in the Southwest are to be congratulated on what they have done.

Jan 12, 1916

By E. W. Dewing

The nature of solid solutions of sodium in non-paphitic carbon at temperatures near 1000°C has been investigated by an electrolytic technique. The activity coefficient is found to vary strongly with the heat-treatment temperature of the carbon, and an analysis of the energy terms involved suggests that this is due to variations in the Fermi level. The diffusion coefficient for sodium is in the range implying that the sodium atoms (or ions) are not bound to specific sites on the carbon, in agreement with lack of evidence for specific compounds in the activity -composition curves. In the light of These results phenomena occurring in aluminum reduction cell linings are dis-cussed. It is concluded that sodium migrates by diffusion through the carbon lallice and not the pores, and that A14C9 is formed within the lining hy The excess of NaF invariably found in used linings is formed by this reaction and by air oxidation: There has recently been much interest in the swelling of carbon which occurs when it is made cathodic in an aluminum electrolysis cell, and there is general agreement that the phenomenon is due to the penetration of sodium atoms, derived from the reaction on the carbon lattice. (NaF and AlF3 are constituents of the fused-salt electrolyte.) The low-temperature lamellar compounds of potassium with graphite are well-known, and one compound between sodium and graphite has been reported.4 There is, however, virtually no information on the basic chemistry of the interaction of sodium with nongraphitic carbon at high temperatures, although Dell3 has made some fundamental studies of rates of penetration. At the time the present work was carried out these were not available. Rapoport and samoilenkol had measured rates of physical expansion in a dilatometer, using the fractional increase in length of a carbon specimen after electrolysis in a cryolite bath for 2 hr as an index of susceptibility to cathodic swelling. Work here with a similar apparatus showed that expansion (of a 1.5-in.-diam cylindrical specimen) ceased in less than 20 hr, and that the final expansion was much more reproducible than the value at some intermediate time. This suggested that an equilibrium was being set up, and that a thermodynamic approach was required. The results obtained are not as accurate as had been hoped, but they are the only ones of their type available and have enabled useful conclusions to be drawn. The experimental work was divided into two parts: an investigation of the activity-concentration diagram for sodium in carbon, and a rough determination of the diffusion rate. For the former, most of the experiments were made with petroleum coke even though this is not a form of carbon used in cell linings. It has the advantages, however, that it is a homogeneous material, that it is low in ash, and that its structure is reasonably well understood. Anthracites and coal cokes gave results of the same type as obtained with petroleum coke, but the reprodu-cibility from specimen to specimen was extremely poor. EXPERIMENTAL 1) The Activity-Composition Diagram for Sodium in Carbon. The petroleum coke was ground, pressed at 40,000 psi into plates 19 by 9 by 2 mm without added binder, and heat-treated. The sodium activities were established by an electrolytic technique. The carbon was made anodic in a cryolite bath with an aluminum cathode, and a controlled potential, E, applied so that the sodium activity at the anode was given by ln Na = 1n asa - EF/RT [21 where as, is the sodium activity generated by Reaction [I]. The relative activity is sufficient for many purposes and is simply given by The value of Na not at present known, but when the thermodynamics of the Na-A1 system have been worked out it can be derived from the equilibrium

Jan 1, 1963

By S. M. Saghaeian

The studies on the product finer than 12 mm due to crushing and sizing plant of Gol-e-Gohar Iron Ore mine showed which this material contains significant amount of valuable iron minerals. Based on the carried out experimental studies on representative samples of fine hematite iron ore, a processing flow sheet was designed to upgrade iron content. This plant is known as first hematite iron ore enrichment plant in Iran which the dry medium intensity magnetic separators (with magnetic field intensity 4500 gauss and high gradient) has been used. The main objective of the plant is production of high iron product with iron content more than 61% and weight recovery more than 55% from the feed with iron content of 54%. In this plant, at first material are screened by a single deck screen (6mm), then oversize particles is separated at one stage by magnetic separator, while undersize ones at two stages. Based on the results of experimental tests, a final high iron product with iron content of 62.4% and weight recovery 63.9% can be achieved. It should mention which the iron content can be enhanced through increasing the speed of magnetic separators especially at the part of separation of finer iron ore.

Jan 1, 2014