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By W. M. Zeng

A mixed culture of moderately thermophilic microorganisms was enriched from Acid Mine Drainage (AMD) samples collected from several chalcopyrite mines in China,which can leach copper from chalcopyrite effectively. Its tolerance to chalcopyrite was brought up to 80 g/L after being adapted to gradually increased concentrations of chalcopyrite. The effects of several leaching variables on copper recovery in Stirred Tank Reactor had been investigated. The ore contained chalcopyrite (62.2%) and galena (25.6%) as the main sulfide minerals. The results of the tests show that it is possible, operating at 8% of pulp density to attain copper extraction of 75% in 44 days. The leaching rate of chalcopyrite tends to increase with the dissolution of total iron. Microscopic counts of microorganisms in the solution tend to be higher at low pH range. Furthermore, the analyses of leached residues indicate that the passivation of this chalcopyrite is mainly due to the formation of a mass of jarosite and anglesite (about 48.3% and 21.7% in residue respectively), other than elemental sulphur layer. The bacterial community composition was analyzed by using amplified ribosomal DNA restriction analysis (ARDRA). Two moderately thermophilic bacteria species were identified as Leptospi-rillum ferriphilum and Acidithiobacillus caldus, with different proportion in the bio-pulp, 67% and 33%, respectively.

Jan 1, 2014

By Zay Jeffries

This paper will include a brief discussion of Prof. Howe's paper on The Supposed Reversal of Inheritance of Ferrite Grain Size from that of Austenite.l The general subject of grain refining in steel and iron will also be treated. The conclusions reached are stated in the following hypotheses which are discussed more in detail below. 1. The ferrite grain size in pure iron, the ferrite and pearlite grain size in hypoeutectoid steel, the pearlite grain size in eutectoid steel and the cementite and pearlite grain size of hypereutectoid steel are not inherited from the grain size of the mother austenite. 2. The only structural feature that is generally inherited from the austenite of hypo- and hypereutectoid steels on cooling through their transformation ranges is the position of the excess ferrite or cementite at the austenite grain boundaries, sometimes causing complete and sometimes incomplete networks which outline the old austenite grain boundaries. Rapid cooling through the transformation range will cause the non-inheritance of this structural (network) feature. 3. The austenite grain boundaries themselves are nearly always effaced in all steels and also in pure iron during the At transformations. 4. The grain-size refining of steel and iron is brought about by the combined effect of non-inheritance of the transformation products on either heating or cooling, i.e., the austenite transformation products do cst inherit their grain size from the austenite on cooling through the transformation range nor does austenite inherit its grain size from the products which form austenite on heating. 5. In general, in both iron and carbon steel the larger the austenite grain size, the larger will be the grain size of the transformation products on cooling. This, of course, assumes all other conditions constant except the austenite grain size. An exception is found to this general rule in very pure iron such as electrolytic iron. In this instance small austenite grains may form very large ferrite grains on cooling through Arg.

Jan 1, 1918

By B. A. Rogers, K. O. Stamm

BECAUSE it is the basis of the economically important operation of hardening steel by quenching, the A3 transformation in iron has been the subject of numerous investigations. Although the contributions to this subject are interesting, no general review will be given here. Readers who care to follow the matter further are referred to the comprehensive summary by Cleaves and Thompson,1 which covers the literature to about 1935. Their references to 53 papers on the subject suggest that further investigation is hardly justifiable. However, considerable interest has developed recently concerning the reversibility of the transformation. From thermodynamic considerations, the transition ought to occur at the same point on heating or cooling, if the change of temperature is sufficiently slow. Yet all of the earlier investigators found a difference of several degrees. Burgess and Crowe,2 who used thermal methods, obtained average temperatures of 912° for Ac3 and 900°C. for Ar3 on electrolytic iron. Their data indicate a considerable range of temperature over which the change occurs, both on heating and on cooling. Terry3 measured the susceptibility in the critical range and estimated from the steepest parts of his curves that Ac3 came at 9180 and Ar3 at 903°C. Ishiwara4 was one of the first investigators to report a shorter interval between the temperature of the change in the two directions. He measured the change of susceptibility of kaolin-coated samples of steel, in a hydrogen atmosphere, at rates of heating and cooling so low that about 3 or 4 hr. were required for the transformation to complete itself. His results show some variability between samples, but indicate that the difference between Ac3 and Ar3 is in the vicinity of 6°C. Roberts and Davey5 measured the space lattice in pure iron in the vicinity of 900°°C. and concluded that a change occurs reversibly between 907° ± 3° and 9100 ± 3°C., probably between 907° and 910°C. Wells, Ackley, and Mehl6 made dilatometric determinations of the Ac3 and Ar3 points in samples of hydrogen-treated carbonyl iron maintained under a vacuum. They used three rates of heating and cooling: 2°, '1/2°, and 1/8°C. per min. and found the spread between the two points decreased with low rates. At the slowest rate, the Ac3 transition occurred at 909° to 909.5°C. and the Ar3 change at 907°C. in three of the samples believed to contain the lowest percentages of alien elements. They concluded that if the rate of temperature change and the content of alien elements were low enough, the A3 transformation would be completely reversible at 909.5° ± I°C. The question of reversibility is an interesting one and when some iron with especially small percentages of alien elements became available the opportunity to conduct an investigation was welcomed. This iron was prepared by the Division of

Jan 1, 1941

By Eoghan T. M Doyle

Oxide mixtures of nickel (NiO), cobalt (COO) and chromium (Cr203) were prepared with graphite in stoichiometric amounts and the powder mixtures were compacted to produce cylindrical pellets. The composition of chromium oxide in these mixtures were varied. Pressed pellets were reduced in a flowing stream of argon-4% hydrogen gas (500 ml/min). Both slow and rapid heating methods were adopted to raise the temperature of a pellet during reduction of oxides to form superalloy powder. The reduction temperature was varied between. 1523 and 1623K. The effect of heating rate and niobium oxide addition on the microstructure of the superalloy produced was studied by using ordinary light and scanning electron microscopes. New phases formed as a result of reduction were identified by X-ray powder diffraction technique. The mechanism of reduction of oxides together with the microstructure of NiCrCo alloy are discussed. The thermodynamics of formation of ternary alloy phase is elucidated on the basis of binary phase equilibria and Gibbs free energy of mixing data for the constituent alloy compositions.

Jan 1, 1992

Between, 1980 and 1984, the demand for non- ferrous metals in the free world grew annually by 1.5 per cent for copper, 0.4 per cent for lead, 1.4 per cent for zinc, and 2.5 per cent for nickel. The growth rate decreased substantially compared to the rate experienced before 1980, and was far lower than the GNP growth during the corresponding period. The main reasons for this are considered to be 1. resource-saving efforts by industrialized countries resulting from the first and the second oil crises, 2. saturated demand for durable consumer goods, and 3. substitution of non-ferrous metals by new materials such as optical fibers.

Jan 1, 1986

By F. D. Wang

The Bureau of Mines has developed a computer program for evaluating pit slope stability by the finite element stress analysis and limiting equilibrium method. The program includes the finite element method of stress analysis using triangular elements, finite-element model mesh generation, plotting of the model mesh and stress contours, calculation of a factor of safety along a circular or a plane failure surface, and location of a critical circular failure surface. Instructions for preparation of input data, an example problem, and the program listing are presented.

Jan 1, 1972

By H. A. Kuhn

The Pittsburgh coal field in Western Pennsylvania is conceded to be the most important in the world.

Jan 1, 1915

By Dale R. Ralston, Roy E. Williams, Gerry V. Winter, George L. Bloomsburg

INTRODUCTION This manuscript is based on site inspections of five existing mines and the detailed analysis of two of the five. The detailed analysis and mathematical models of the two mines are presented herein in order to demonstrate a method of predicting mine water inflow using existing mines as a data base. Water management procedures were studied at all mines. Our original criteria for mine selection were that the mines be less than five years old and have an inflow rate in excess of 2000 gpm (7.6 m3/min). Background hydrologic and hydrogeologic data were required so that two of the mines could be used for our computer modeling experiments. Our original criteria proved to be difficult to meet. We contacted numerous mines via various sources. Many mines were unable to meet the cri¬teria stated or were not interested in cooperating with us. Therefore, we allowed some flexibility in the application of these criteria to satisfy our orig¬inal requirements. Although the visitations at all the mines are not discussed herein the characteristics of the two mines simulated are presented. These simulated mines consist of a uranium mine in New Mexico and a lead mine in Missouri. The mines and owners will remain anonymous by request. URANIUM MINE-CASE HISTORY NUMBER 1 Mine Location The uranium mine that we simulated is located in northwestern New Mexico. The ground surface at the uranium mine is at an elevation of approx¬imately 7000 ft (2134 m) above mean sea level. The climate is arid to semi-arid with an average annual precipitation of approximately 10 in. (25.4 cm) (John and West, 1963). Geologic Setting It is essential that a conceptual model of the stratigraphy, hydrostratigraphy, and structural geology of a mine site be developed prior to simulation by a mathematical model. If such a conceptual model is not developed prior to simulation major errors are difficult to avoid. The uranium mine we have simulated is located in the San Juan Basin (Fig. 68), which is a structural basin located in northwestern New Mexico and adjacent parts of Colorado, Arizona, and Utah. The sedimentary rocks present in the deepest part of the basin are nearly 15,000 ft (4572 m) thick (John and West, 1963). The regional dip of the sedimen¬tary rocks in the Grants area is generally northward toward the San Juan Basin; the regional attitude is modified locally by normal faults and folds (Hilbert, 1963). The rocks of interest in this area are sedimentary in origin and range in age from Penn¬sylvanian to Cretaceous. They rest on the Precam¬brian core of the Zuni Uplift. Associated intrusive and extrusive rocks are of Tertiary and Quaternary ages (Hilbert, 1963). The deepest sedimentary unit of interest at this mine site is the Morrison Formation as described by Hilbert (1963). The Morrison Formation con¬sists of three members in the general area of the mine site; the deepest member is the Recapture. The Recapture Member consists of alternating beds of gray sandstone and grayish red siltstone or mud¬stone with strata up to several feet in thickness. Only a few small deposits of uranium are contained within the Recapture Member. The Westwater Canyon Member overlies the Recapture Member of the Morrison Formation. The Westwater Can¬yon Member is approximately 150 ft (46 m) thick and consists of light brown to gray, poorly sorted, arkosic sandstone, and some interbedded gray mud¬stone. The Poison Canyon Formation denoted in subsequent discussions, tables, and figures was de¬termined to be a part of the Westwater Canyon Member. The separate connotation is used for the description of mining operations and hydraulic properties but a separate physical description is not included. This member of the Morrison Formation contains many large deposits of uranium. This is (some pages in this article are damaged)

Jan 1, 1986

Jan 1, 1954

By H. L. Hazen

THIS is the story of the recent operations of the Standard Cyaniding Co., which owns the Standard mine, a low-grade gold property in sight of Highway 40 about thirty miles from Lovelock toward Winnemucca, Nev. The ore is mined by power shovel and cyanided after grinding to only 3/S in. A total direct cost of $1.24 was attained in 1941 on 600 tons a day. Mining operations ceased, under Government edict, in 1942, and only in recent months have been resumed. The operating difficulties of today are: (1) the high cost of supplies; (2) labor problems; and (3) Federal laws as interpreted and enforced by executive bureaus of the Government. Of these, the increased cost of supplies is the least important.

Jan 1, 1947

By J. Duran

Mining at Newmont Mining?s Phoenix?s Mine is currently done by surface operation in the Fortitude and Bonanza pits at a combined rate of approximately 100 kt/d (110,000 stpd). A portion of the orebodies targeted by these pits was mined previously by underground mining methods, dating back to the mid-to late-1800s. Most of the underground workings (voids) are located in the west central area of the Bonanza pit. The surface operation requires excavation through voids, and there is a risk of pit floor subsidence that has to be addressed. This article presents a review of the risk mitigation measures that were implemented to reduce risks to people and equipment working in the area.

By Freddie Hunter

An underground mining method for extracting an eight metre (26') coal horizon, containing a sandstone layer. A decrease in the thickness of the rock strata between the number two and number three seams of the Sasolburg Coal Field, has resulted in a total mining horizon approximately eight metres (26') thick. This parting varies in thickness and competency and in some areas is impractical to cut with a continuous miner. In addition, the general mining area is highly jointed. The top seam is first mined to a normal bord and pillar plan with a continuous miner. The bottom seam is then mined by selectively undercutting the stone parting constituting the floor of the top seam. In areas where this parting is between 0.75 - 2.50 metres (29.5" - 98") thick, it is suspended from the primary roof support installed when mining the top seam. Secondary, high extraction retreat mining is then undertaken in the coal pillars adjacent to the suspension supported headings in the bottom seam. Left in-situ, the parting provides lateral support to the pillar sidewalls in both the top and bottom seams, enabling high percentage extraction rates in what was previously thought an uneconomically mineable area. The paper proposed, presents the challenges and practical implications of executing the mining method, including the primary roof control of the top seam and the stone parting between scams.

Jan 1, 2003

New Caledonia is a major metallogenic unit of the south-western Pacific Rim. Its mineral production is of world significance and it has an unusually well diversified mining history. New Caledonia's main metallogenetic potential is, however, associated with its unique ophiolitic complex and its important mineral- izations of nickel, chrome, cobalt and iron. Gold has been found in all the four basic tectonic elements of New Caledonia: the Central Massif, the West Coast basalts, the ophiolitic complex and the Caledonian North. Some analogies are attempted. Only the Caledonian North has supported mining operations (213 kg Au). More recently tenuous gold indications have been found within the ophiolitic complex, possibly associated with Oligocene plutonism.

Jan 1, 1987

By J. Morgan Clements

The manufacture of coke in Peru, as practiced at the coalmines of the Quishuarcancha and Goyllarisquisca districts, is intermediate between the primitive coke-heap and the bee-hive oven. The method of coking is quite simple. In constructing the coal-heap, preparatory to burning, the ground is first leveled, and a simple stack of stone and clay is built, giving the bottom, to a height of 6 ft., approximately 6 ft. of external diameter. The size of the stack varies in different districts, but is generally 9 ft. high, and slightly smaller at the top than at the bottom. The walls of the heap are from 12 to 14 in. thick, which allows an inside diameter of from 3.75 to 4 ft. These walls are pierced at intervals by three or more tiers of openings or flues, connected with the central flue. The radial flues have a diameter of about 5 in. and are built with a gentle upward slope. The stack (shown in Fig. 1) is permanent; and in this respect the practice in Peru differs from other primitive practices in which nothing is permanent except the yard. Above the permanent 6-ft. portion of the stack there is added a cap of clay, about 3 ft. high, which contracts toward the top, where it has an inside diameter of about 2 ft. This clay cap is temporary, and frequently has to be renewed after each burning. Before charging the coal, there are first built, from the lowest tier of flues upon the ground, a number of temporary flues, leading from the central stack out to the edge of the coal-heap, and constructed of blocks of coal for the greater part of the distauce, the outer edge alone being of rough stoue. The coal is then piled up over these flues and around the stack to a height of about 6 ft. The bottom flues are the only ones that

Jan 1, 1905

By Y. Takasaki

For zinc hydrometallurgical extraction, reducing the electric power consumption of the electrowinning process is an important issue for energy savings. At the Zinc & Lead 2000 symposium, the authors suggested that by using the Pb-0.5%Ag-0.6%Ca alloy, the electrolysis energy can be decreased compared to the conventional Pb-0.9%Ag alloy. In this study, the corrosion behaviors of the Pb-Ag-Ca electrode in a sulfuric-acid electrolyte were investigated. Based on the results Or me Pb-0.5%Ag-0.6%Ca anode after 20 days of electrolysis, the bath voltage and the quantity of anode slime decreased compared to the Pb-I%Ag anode. Subsequently, beta-PbO2 on the electrode surface was detected by XRD and its peaks were sharper than the Pb-1 %Ag anode. Moreover, a dense beta-PbO2 layer on the 0.6%Ca a anode surface was observed. Therefore, it was suggested that the dense beta-PbO2 layer on the anode surface is one of the factors that leads to a lower bath voltage and decreasing quantity of anode slime.

Jan 1, 2003

By J. S. Hardison

In the fall of 1912, the appearance of water in the oil of the Nevada Petroleum Co., Coalinga, Cal., made necessary the installation of a dehydrating plant to reduce the water below the 3 per cent. limit prescribed by the agency. Unlike the mining industry, technical literature of the oil industry is limited and extremely unsatisfactory. Until the recent efforts of the Petroleum and Gas Committee of the American Institute of Mining Engineers, no concerted movement has been instituted to secure publication of papers dealing with the problems of the oil business, and because of the additional fact that dehydrating of oil has not been practiced in California to any extent up to comparatively recent time, it was found necessary to experiment in order to determine the most satisfactory plan for this purpose. It is easy to write regarding successful enterprises, but, while not SO pleasant, it is equally desirable to write of failures so that others may be saved the loss incident to such investments. The water in this oil occurs both free and as an emulsion. Free water easily settles out, but the emulsion requires treatment. So far as can be determined, the emulsion consists of globules of water surrounded and enveloped by a film of oil. Starting with this hypothesis the theory has been evolved that in order to break up this emulsion the water must be heated at least to boiling point, when an explosion takes place destroying the globule. Unfortunately, this condition was not recognized in the installation of the first plant, which was planned on the following lines: A heater was arranged so that all the oil from the wells could be heated before reaching the shipping tanks, these being already fitted with coils for steam heating. Tanks were filled with about 4 ft. of water, live steam was turned into the coils and the water brought nearly to the boiling point, when the heated oil was run in. This for a time was partly successful, but the length of time necessary to apply this heat was too great for practical operating.

Jan 1, 1915

By W. Zhang

"The adsorption of collector on chalcocite has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). The AFM images show that xanthate, such as potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbs strongly on chalcocite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. The result clearly shows that the adsorption of xanthate on chalcocite is totally different from its adsorption on chalcopyrite, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. AFM images also showed that increasing solution pH to 10 doesn’t prevent the adsorption of xanthate on chalcocite much and the result confirms with the fact that chalcocite floats well in a wide pH range up to 12 with xanthate being used as a collector. INTRODUCTION In flotation, the adsorption of collector on mineral surface is vital for a successful flotation process to achieve a satisfying metal recovery. Historically, many works have been carried out to clarify the adsorption mechanism of collectors on sulfides. (Gaudin and Schuhmann, 1936, Poling and Leja, 1963; Allison et al., 1972, Fuerstenau, 1982; Leja, 1982; Woods, 1984) The adsorption of xanthate on chalcocite surface in aqueous solution also attracted the interest of many researches. Gaudin and his colleagues (Gaudin et al., 1934; Gaudin and Schuhmann, 1936) studied the solubility of potassium ethyl xanthate and its reaction products in organic solvents and firstly proposed there was initially chemisorbed xanthate (X-) on chalcocite surface followed by insoluble cuprous xanthate (CuX). Allison et al. (1972) studied the reaction products of various sulfide minerals with xanthate solutions and reported that the measured rest potential of chalcocite in 6.25×10-4 M KEX solution at pH 7 was +60 mV and the reaction product of PAX on chalcocite was cuprous xanthate. Mielczarski and Suoninen (1984a, 1984b) applied the XPS and studied the adsorption of potassium ethyl xanthate on cuprous sulfide. It was reported that there was a relatively rapid formation of a well-oriented monolayer of xanthate ions followed by a slow growth of disordered cuprous xanthate molecules on top of this layer. Richardson et al. (1984) carried out an electrochemical study of chalcocite flotation with the addition of ethyl xanthate. It was proposed that cuprous xanthate and possibly cupric xanthate were adsorbed hydrophobic species on chalcocite surface due to the exchange and charge transfer oxidation reactions. Leppinen et al. (1989) applied an in-situ FTIR study of ethyl xanthate adsorption on sulfide minerals under conditions of controlled potential and they concluded that, for chalcocite, there were three different potential regions of xanthate adsorption, including chemisorption, copper ethyl xanthate formation on the surface and multilayer formation."

Jan 1, 2015

By Frederic P. Dewey

Having shown1 the difficulty of assaying so-called cyanide bullion and the extreme variations often found in the results, an investigation was undertaken to discover, if possible, the causes of these variations by a series of tests upon the specific action of various metals during cupellation. Zinc.—In order to test the effect of zinc, 48 assays were made in sets of 6, 2 rows of 3. The charge for the middle cupels consisted of 500+ mg. Au, 1,125 mg. Ag, 10 mg. Cu. To the end cupels 50, 75, 100 and 125 mg. Zn were added, and a set of each proportion was cupelled with 4 and 8 grams Pb. The cupels were assayed and showed the following gold contents in milligrams, the figures being arranged as the cupels stood in the muffle: In many instances the zinc does not appear to affect the cupel gold, but various exceptions are apparent, generally in the cupels in the back row. With 100 and 125 mg. Zn, in some cases the Zn burned with its characteristic flame' before it could alloy with the other metals. Also, less fusible oxidized lumps were observed during the cupellation and some cupels showed a scum. In order to lessen the premature burning out of the Zn, an alloy of 2 parts Ag to 1 part Zn was used. A uniform charge of 500+ mg. Au,

Jan 1, 1918

By Jiang Feng, Zhang Libo, Peng Jinhui, Guo Zhanyong, Ju Shaohua, Lei Ting

The clean utilization of the residue containing chloride, CuCl residue, produced from zinc hydrometallurgy is very important for the recycle of valuable metals. And drying is the main process in recycling. In this study, response surface methodology was used to optimize operating conditions of the drying of CuCl residue in a convection oven and desirability function used as the methodology for the optimization. Optimization factors were air temperature (80–100°C), material thickness (10–25mm) and process time (80–120min) while investigated responses was final moisture content. The optimum conditions were found to be the temperature of 95.48°C with the material thickness of 13.47mm for the process time of 89.48 min. Under optimum conditions, the predicted moisture content of CuCl residue was 4.11% while the experimental date was 4.13%. The experimental value after process optimization was found to agree satisfactory with the predicted value. After drying, XRD was used to analyze the main phases of CuCl residue. The CuCl residue is made up of CuCl,Cu2O, ZnS and other compounds.

Jan 1, 2015

By J. T. Brown

AS far as could be ascertained, no one had previously investigated the creep strength of silicon poly-crystals. Literature has appeared showing evidence for plastic deformation in silicon single crystals and whiskers.*1"6 Also the fact that germanium, a material of similar crystal structure to silicon undergoes plastic deformation under stress at temperatures above about 60 pct of its melting temperature, has been known for some time.2"4'7 This investigation was performed for the purpose of determining the strength and ductility of silicon polycrystals under creep conditions that would give fairly long times to rupture. PROCEDURE The silicon specimen blanks were obtained by first placing granulated transitor grade silicon (99.999 + pct pure) in a silica crucible. The crucible was surrounded by a graphite susceptor, and induction heating was used for melting the silicon in a vacuum furnace. Blank specimens were formed by freezing molten silicon onto a polycrystalline seed of silicon in a vacuum furnace. The seed was attached to a motor driven revolving rod. As silicon solidified, this rod was gradually withdrawn from the melt. A shape with a contracted center section was obtained by varying the rate of withdrawal from the melt. Specimens for the creep-rupture tests were ground from these "pulled" blanks. Creep-rupture tests were performed in spring loaded machines under constant load at 1800" and 2000° F. RESULTS AND DISCUSSION A test specimen which was sectioned longitudinally is shown in the photomacrograph in Fig. 1. Very little deformation has taken place in the portion of the specimen shown, however, slip lines from several slip systems within the same grain, and deformation band formation was seen. The elongated appearance of the grains is due to the method of growing the specimens. One of the most interesting aspects of the results obtained from the creep-rupture tests was the high strength and the accompanying large amount of ductility. The data obtained is listed in Table I which shows the stress to rupture in 100 hr at 2000°F is between 8000 and 9000 psi. This indicates that silicon's strength at 2000°F is about equal to that of the best commercial super-alloys. It is important to mention that silicon has less than 1/3 the density of iron-, nickel-, and cobalt-base alloys. The usual type alloys for high-temperature applications

Jan 1, 1960