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By M. Dubrovsky, J. W. Evans

A laboratory scale cell (approximately 50 amps current) equipped with a fluidized bed cathode was used in a study of the electrodeposition of cobalt from acidified aqueous sulfate solutions The effect of current density (in the range 0.1 to 1 amp/cm2 of diaphragm), cobalt concentration (4 8 to 100 glliter) and catholyte pH (1 35 to 6 2) on current efficiency and energy consumption were determined. Generally the current efficiency increased with increasing current density and cobalt concentration Current efficiencies were comparable to those reported in the literature for conventional electrowinning

Jan 1, 1981

By C. Abbruzzese, F. Vegliò, S. Ubaldini, R. Massidda

"Gold solubilised during cyanidation can be recovered by precipitation (Merrill-Crow process) or by adsorption onto activated carbon, these being the techniques applied in industrial plants.Precious metals (Au, Ag) adsorbed onto activated carbon are extracted during a subsequent stage in aqueous phase, by various technologies, such as hot elution (70-80°C) or under pression desorption (100-130°), with hydro-alcoholic solutions.This stage is of great interest from an economic point of view, due to the high energy costs. Temperature represents the critical kinetic factor.The aim of this paper was to study the influence of different water/organic solvent mixtures (isopropyl alcohol, ethanol and ethylene glycol) on the desorption process.The experimental work was carried out on laboratory scale, using activated coconut carbon with different temperatures and extraction times, without adding cyanide.Best results have been obtained in this order: isopropyl alcohol > ethylene glycol > ethanol. Starting from gold concentration of about 5 g Au per kg of carbon, best kinetics resulted in 97-100% of gold extraction, after 8 hours of desorption, at a temperature of 80ºC."

Jan 1, 2003

By Jack F. Harang, P. B. Leavenworth

Development during the year 1941 on the Texas Gulf Coast resulted in the dis covery of 27 new fields as compared to 26 fields for the year 1940. Drilling.—During the year, 1405 wells were drilled. Of this number, 1031 were completed as oil wells with 375,000 bbl. daily of new production; 50 were com pleted as gas wells and 324 were failures. The most active area was Jackson County, where 375 wells were drilled and 336 of them accounting for 190,000 bbl. daily of new production. Types of Fields.—Of the 2 7 new fields, 14 are considered to be oil fields, 8 are listed as gas-distillate fields and 5 as gas fields. This may be compared to 26 fields found in 1940, of which 14 were oil fields and 12 gas-distillate fields. Producing Sections.—Frio discoveries retained their predominant position by having 10 Frio fields discovered in comparison to 6 fields in the Wilcox, 4 in the Yegua, 5 in the Miocene and 2 in the Jackson. In the previous year 15 Frio fields were found, 4 in the Wilcox, 2 each in the Yegua, Cook Mountain and Miocene, and I in the Jackson. Production.—Production increased over 1940 approximately 10 per cent, being 113,726,893 bbl. for the year 1941 and 104,127,247 bbl. for 1940. The statistics in Tables I and 2 include distillate and condensate as oil production because no separate reports have been compiled. It is hoped that this separation may be possible some day, but as a great many fields produce both oil and distillate and these arc commingled in pipe lines, separation of statistics will be more difficult than for other areas. New Fields Big Hill, Jefferson County.—Stanolind Oil and Gas Company's No. I George D. Anderson was completed as a gas well from a Frio sand at 8705 to 8720 ft., on Dec. 24, 1941, after having been drilled to a depth of 9500 ft. Additional development is being carried on but it is not possible to evaluate this discovery at this time. Brushy Creek Field, Lavaca County.— Shell Oil Corporation's No. I D. G. McManus was completed as the discovery well in the Brushy Creek field on Oct. 29, 1941, from a Wilcox sand through perforations at 7225 to 7230 ft., making gas and 180 bbl. of 59° gravity distillate. This well was bottomed at 10,998 ft. in the Wilcox. No statement can be made at this time as to the importance of this discovery. Chenango Field, Brazoria County.—J. N. Rayzor et al. completed their No. I Sarah J. Christian through perforations at 8564 to 8572 ft. in a Frio sand, for 453 bbl. of 37.7° gravity oil, on Feb. 6, 1941, after having drilled to 9564 ft. Several wells were drilled in this area during the year but failed to establish important production. This is considered a minor discovery. Clodine Field, Fort Bend County.—Providence Oil Company's No. I Hatfield was the discovery well of the Clodine field, being completed through perforations at 7499 to 7502 ft. for 108 bbl. of 51.2° gravity distillate, on June 19, 1941. The well was bottomed at 8090 ft. Several wells

Jan 1, 1942

By P. B. Leavenworth, Jack F. Harang

Development during the year 1941 on the Texas Gulf Coast resulted in the dis covery of 27 new fields as compared to 26 fields for the year 1940. Drilling.—During the year, 1405 wells were drilled. Of this number, 1031 were completed as oil wells with 375,000 bbl. daily of new production; 50 were com pleted as gas wells and 324 were failures. The most active area was Jackson County, where 375 wells were drilled and 336 of them accounting for 190,000 bbl. daily of new production. Types of Fields.—Of the 2 7 new fields, 14 are considered to be oil fields, 8 are listed as gas-distillate fields and 5 as gas fields. This may be compared to 26 fields found in 1940, of which 14 were oil fields and 12 gas-distillate fields. Producing Sections.—Frio discoveries retained their predominant position by having 10 Frio fields discovered in comparison to 6 fields in the Wilcox, 4 in the Yegua, 5 in the Miocene and 2 in the Jackson. In the previous year 15 Frio fields were found, 4 in the Wilcox, 2 each in the Yegua, Cook Mountain and Miocene, and I in the Jackson. Production.—Production increased over 1940 approximately 10 per cent, being 113,726,893 bbl. for the year 1941 and 104,127,247 bbl. for 1940. The statistics in Tables I and 2 include distillate and condensate as oil production because no separate reports have been compiled. It is hoped that this separation may be possible some day, but as a great many fields produce both oil and distillate and these arc commingled in pipe lines, separation of statistics will be more difficult than for other areas. New Fields Big Hill, Jefferson County.—Stanolind Oil and Gas Company's No. I George D. Anderson was completed as a gas well from a Frio sand at 8705 to 8720 ft., on Dec. 24, 1941, after having been drilled to a depth of 9500 ft. Additional development is being carried on but it is not possible to evaluate this discovery at this time. Brushy Creek Field, Lavaca County.— Shell Oil Corporation's No. I D. G. McManus was completed as the discovery well in the Brushy Creek field on Oct. 29, 1941, from a Wilcox sand through perforations at 7225 to 7230 ft., making gas and 180 bbl. of 59° gravity distillate. This well was bottomed at 10,998 ft. in the Wilcox. No statement can be made at this time as to the importance of this discovery. Chenango Field, Brazoria County.—J. N. Rayzor et al. completed their No. I Sarah J. Christian through perforations at 8564 to 8572 ft. in a Frio sand, for 453 bbl. of 37.7° gravity oil, on Feb. 6, 1941, after having drilled to 9564 ft. Several wells were drilled in this area during the year but failed to establish important production. This is considered a minor discovery. Clodine Field, Fort Bend County.—Providence Oil Company's No. I Hatfield was the discovery well of the Clodine field, being completed through perforations at 7499 to 7502 ft. for 108 bbl. of 51.2° gravity distillate, on June 19, 1941. The well was bottomed at 8090 ft. Several wells

Jan 1, 1942

By C. H. Burgess

ON June 5, 1947, Secretary of State George C. Marshall in a speech at Harvard University outlined a plan for the economic recovery of Europe. The plan contemplated that the United States should provide assistance which would enable the European nations better to help themselves and to help each other to reconstitute from their war-torn lands conditions which would make possible decent standards of living.

Jan 1, 1950

By Kazem Oraee, Mehran Gholincjad, Navid Hosseini

"Chain coal pillars are pans of the structure of longwall mining system that play a significant role in the stability of the entries. With mechanization and developments in the various aspects of the method, higher efficiency in optimization of the design of chain coal pillars seems appropriate. In this paper the three main methods of chain pillar design, namely the empirical analytical and numerical methods arc compared. Real data from the Tabaslran coal mines have been used in order to make the comparison process reliable. It is concluded that the most apparent advantage of the empirical method is the reliability of the results while the use of numerical methods enjoys the advantage of flexibility. On the other hand the analytical methods are complex unless simplifying assumptions arc made that can substantially decrease the accuracy of result which is thought to be the main advantage of the design method. A new method is therefore introduced here that combines all of the three presently used methods and by doing so the new method has the advantages of the three while minimizing complexities and inaccuracies associated with the use of the individual methods.INTRODUCTIONLongwall mining is a high production method that can use mechanization to its full extent. Its initial development can be traced to 17th century European collieries but it was not until the second half of the 20th century with the development of self advancing support systems that the method gained popularity in the USA (Oraec. 2001). During the last decade, the production of longwall faces has increased significantly (Peng. 2006). The ability for mechanization along with good safety condition is the main reasons for such development. In the longwall mining method a good design for panel and entries on both sides, are two essential parameters. In this method, the thickness of overburden (depth of mine) nom1ally ranges from 60 to 20 m (197 to 2.7 9 ft) (Hartman, 2000) and with increasing mine depth designing for stabilizing the entries on both sides of the panel become more difficult. Thus, for safety and stability the size of chain pillar must increase. This causes the overall coal recovery to decrease and increase mining costs per ton. As such wide pillars hinder the air flow and hence ventilation costs increases too. Therefore with accurate identification of loading conditions and stress analysis. pillar that are a minimum size and sufficient safety factor are carefully designed."

Jan 1, 2010

By Elaine T. Cullen

Underground mining, like many high-risk industries, is facing a crisis in the near future. This industry has traditionally relied on a master-apprentice relationship to train new workers, but experienced miners are retiring in large numbers, leaving few "masters" to properly train their replacements. With a recent resurgence in mining, many new miners are entering the workforce each day. The rise in the number of inexperienced workers has implications for worker safety in an industry in which one mistake can blow up the entire workplace. The explosion in the Darby Mine in May 2006 that killed five miners illustrates what can happen in hazardous environments such as underground mines. The Health Communications Team at the National Institute for Occupational Safety and Health Spokane Research Laboratory was asked to address this problem by developing new training and safety awareness materials to promote safe flame cutting and welding practices. This article describes how occupational ethnographic techniques provided insights needed for "new product development." The result of this work was a national initiative to raise awareness and to protect underground coal miners from the dangers of flame cutting and welding in an environment filled with solid fuel and methane (natural gas). Although this project was initially designed for the mining industry, the approach and lessons learned are applicable to any high-risk industry and should be of interest to other social marketing or occupational safety and health professionals.

Jan 1, 2009

By B. A. Kjarsgaard, C. J. Mwenifumbo

"Abstract - Natural gamma-ray measurements were made in the GSC Smeaton drillhole as part of the borehole geophysical classification of kimberlite pipe 169. In addition, forty samples of Cretaceous sediments (shales, siltstones, and sandstones) and thirty-five kimberlite samples, selected from the drill core, were analyzed for major and trace elements. These elements included potassium (K), uranium (U), and thorium (Th), which are the main naturally-occurring radioactive elements.Different phases of the kimberlite, and the Cretaceous sediments which show variations in the gamma-ray activity, can be easily delineated on the gamma-ray logs. The gamma-ray logs indicate that the radioactivity in the kimberlite derives mainly from Th, and, to a lesser extent, U. Most of the kimberlite units are enriched in Th and U relative to the Cretaceous sediments, and these radioelements are mainly hosted by accessory apatite and perovskite, and minor zircon. Potassium concentrations are low in the kimberlite. The higher K concentration in the sediments clearly distinguishes the Cretaceous sediments from the kimberlite.The U/K and Th/K ratios show important and distinct differences between the two major types of volcaniclastic kimberlite. Kimberlite lapillistones have higher U/K and Th/K ratios than the olivine crystal tuffs. Furthermore, standardized U/K and Th/K geophysical logs can be used to separate marine reworked olivine shoreface sands from other shallow marine sediments that contain kimberlitic detritus. The identification of different phases and/or stratigraphic facies of kimberlite on the basis of radioelement distributions means that gamma-ray spectrometry can assist exploration, particularly in regard to diamond grade distribution."

Jan 1, 1999

ME?s Arizona Conference was held at the Hilton El Conquistador resort in Tucson on Dec. 2 and 3, 2007. The annual conference is organized by the Arizona Conference Board of Directors, which represents SME sections in Arizona and adjacent areas. The conference provides an opportunity for individuals and corporations associated with mining in the region to get together once each year to discuss the status of the industry. The 2007 meeting featured a keynote address, a distinguished lecturer and more than 25 technical papers that were presented in seven sessions. The sessions included environmental, geology, safety, metallurgy, mining, new projects and a special session on Mexico. Topics covered included mine closure, sustainable mining, exploration methods, health and safety issues, mining equipment and drilling. Much of the discussion at the conference concerned major new developments in the region?s copper mining industry. For example, Freeport-McMoRan?s new Safford Mine and BHP Billiton?s Pinto Valley restart were the topics of technical presentations. There was also much discussion among the attendees on the current and future price of copper, community relations, education issues and recruitment concerns. At the time of the conference, the price of copper hovered around $3.30/lb, up considerably from the 61 cents/lb in late 2001, when the industry was being challenged by world market conditions and a weakened domestic economy. Since then, strong demand from China helped push copper prices to record levels that at one time reached as high as $4/lb. The general consensus among the attendees is that the current price of around $3.30/lb will continue through 2008. Most attendees also expect increased corporate investments in the industry to continue. Copper mining in Arizona has been a major industry since the 1800s. In 2007, Arizona was the leading copper-producing state in the United States and produced more than $5 billion worth of copper. The copper mining industry in Arizona also produces byproduct gold, silver and molybdenum. Arizona is the second largest molybdenum producer in the United States.

Jan 1, 2008

By Harold F. Yde

Hydraulic tailings fill in the Butte deep level mines was based upon studies made in 1958 by the Anaconda Company Mining Research Department, which published Bulletin No. 35, entitled "Hydraulic Stope Filling". Since then, many things have changed. At the time of the Research Departments study, dry mine tailings were hauled by rail cars from the Anaconda tailings ponds, twenty-five miles distant, to the underground mines' tailings fill plants at the Leonard Anselmo, and Mt. Con Mines. Now, with the installation of the new Weed Concentrator in Butte, tailings is delivered by pipeline to a cyclone at the Kelley Shaft, and stope filling has become more highly automated and streamlined. Presently, mill tailings at approximately thirty percent solids by weight, is pumped from the concentrator, eight thousand feet horizontally and upward, to the Kelley Fill Plant, where they are dewatered and deslimed by three Krebs Model D20B Cyclones, which discharge the material into the cased and grouted mine delivery bore holes at desired densities up to seventy percent solids. The vertical boreholes and four-inch rubber lined Victaulic pipe carry the material downward to horizontal distribution lines, which in turn tap into the stops-filling, three inch, unlined steel Victaulic pipelines. The slurry may travel several thousand feet before it finally discharges into the stope, where it lends support to the mined-out area.

Jan 1, 1969

By A. G. Guy

IN the course of a research on steady-state diffusion it became necessary to make diffusion calculations for a finite solid. This problem was found to be sufficiently different from the corresponding problem for the semi-infinite solid for an entirely new approach to be necessary in obtaining a useful solution. The assumption of an exponential variation of the diffusion coefficient with concentration' was no longer a practical necessity, so that the new solution offered the possibility of handling diffusion in semi-infinite solids for arbitrary variations of the diffusion coefficient with concentration. In discussing the principle on which this method of calculation is based, it is convenient to consider the relatively simple problem of one dimensional diffusion into a matrix that initially contains none of the diffusing substance. The solution of the set- ond Fick Law,?C/?t=D0?2C/?x2, for diffusion into a semi-infinite solid is3 C/C=1-F(x/2vD0t [1] where C is the concentration of the diffusing substance at a depth x cm below the surface after dif- A. G. GUY, Member AIME, and M. GOLOMB are Professor of Metollurgicol Engineering and Professor of Mathematics, respectively, Purdue University, Lafayette, Ind., A. S. YUE, formerly with Purdue University, is now with the Research Laboratory, Dow Chemical Co., Midland, Mich. TP 4505E. Manuscript, July 18,1956. fusion has occurred for t seconds; C, is the concentration of the diffusing substance at the surface of the matrix; Do is the diffusion constant, expressed in sq cm per sec; and + represents the Gauss error function. The corresponding solution for diffusion into a finite solid of thickness, 1, is conveniently written for the change in concentration, C+, at a point midway through the matrix and for times, t, great enough for the following equation to be used4 c1/2/C1=(1/2-2/?e-?2D0t/l2) [2] In Eqs. 1 and 2 the diffusion coefficient is represented by the symbol Do (rather than by D) to emphasize that these equations are valid only for constant values of D. To understand how these equations can be modified to take account of actual variations of D, such as that shown in Fig. 1, first consider the fact that for a given time of diffusion theconcentration at a given point is determined, not by the D value alone, but by the ratio x/vD0 in Eq. 1 and by a similar ratio, l2/D0 in Eq. 2. Even though in fact D varies, it is possible to keep this ratio constant by using a special coordinate system, x,, that varies with D in the appropriate manner. The necessary character of this special coordinate system can be easily visualized by imagining that

Jan 1, 1958

Gravity concentration of tin at Renison Limited uses tables and spirals to treat the various coarser fractions produced from sulphide flotation tailing. An acceptable final tailing cannot be made from one pass over the tables and spirals and therefore the tailing from these separators is reground and combined with the sulphide flotation tailing as the feed to the classification section. The gravity section became increasingly overloaded in the years preceding 1976 due to efforts to maximize tin recovery to the gravity concentrate. In April, 1976, two 2DSV Reichert cone concentrators in series were installed to treat the table and spiral tail- ing stream, prior to regrind, to scavenge a small tonnage of hard, coarse low tin grade material for rejection to final tailing. Gravity section loadings were decreased markedly, allowing operator attention to be directed more to table performance than to spillage collection. An increase in mill throughput of approximately 15% was possible following the commissioning of the Reichert cones. The cones are currently operated to make the minimum tonnage of tailing consistent with reasonable- gravity section loadings.

Jan 1, 1978

By Marcin Ziemski

This paper reports on an energy efficiency analysis completed as part of a research project looking at energy reduction opportunities in minerals processing operations. The plant discussed is a gold production facility owned by Newmont Gold in the Tanami region of central Australia. Due to its remote location, lack of nearby gas pipeline or power grid, the operation has been completely dependent on diesel fuel for its electricity generation and transport needs. The mine and processing plant use electrical power at a rate of 12MW to 18MW, resulting in a monthly electricity cost of over US$1.5M. The high cost of diesel combined with an impending power generation capacity shortage drove Newmont to undertake the energy efficiency study. An energy audit of the plant showed opportunities for significant energy savings through the strategic use of waste heat, fuel replacement alternatives and renewable energy sources.

May 1, 2007

By F. R. Hensel

THE absorption of oxygen by molten metals is a quick and convincing method to determine the metallurgical characteristics of various types of furnaces.1 The investigation was restricted to the use of coreless induction furnaces. A major variable in induction furnace practice is the frequency and its influence was studied by comparing melts made in a 5000-cycle and a 60-cycle induction furnace respectively.2 The authors are not aware that such a comparative study has been made before and therefore present this paper in the belief that the results will be of general interest. ANALYTICAL METHODS FOR DETERMINATION OF OXYGEN IN NICKEL An analytical procedure for determining NiO by a quick and simple, laboratory method has been worked out in collaboration with Dr. Herty, of the Pittsburgh Station of the Bureau of Mines. It was found that Dr. Herty's aluminum method as used for the. determination of FeO in iron and steel was very suitable for use with nickel if instead of hydrochloric acid a 10 per cent solution of nitric acid is used for bringing the metal into solution. Essentially this method involves deoxidizing the nickel-oxygen alloy with aluminum (2Al + 3NiO = Al203 + 3Ni) and determining the resulting Al203 by a residue analysis. The original oxygen content can then be calculated from the amount of Al-20,. The method as suggested by Dr. Herty3 is referred to in the present paper as method B. A slight modification of method Bled to the application of method A, a description of which is given below according to F. W. Beiter?:3

Jan 1, 1932

By Yingda Zhai

The range of interburden thickness between coal seams in Datong Mining District of China is large. From mining operation point of view, the closer is between the two seams, the greater is the impact from the upper seam when the lower seam is mined. This impact is most notable when the two seams are ultra-close. In this paper the definition of ultra-close seams and its practical method of determination are presented. Based on the difference in strata thickness in the interburden and the concept of "yield depth ratio" which is defined as the yield zone depth in the interburden to the total thickness of interburden, the roofs of the ultra-close multiple seams in the Datong District of China were divided into 3 types: (1) false roof or rock partings in coal seam. This type of roof does not require special handling except mining them simultaneously as one single seam. The roof thickness is slightly less than 0.5 m; (2) completely broken roof. In this type of roof, the yield depth ratio is larger than (or equal to) 1. When the roof thickness is larger than 0.5 m but less than 2.0 m, the yield depth ratio must be smaller than 1; and (3) fractured roof. In this type of roof, the yield depth ratio is less than 1 while the roof thickness is larger than 2.0 m. In retreat longwall mining, if the gateroads of the lower seam are located under the gob of upper seam, roof bolting can be used in the 3rd type of roof. But if the 2nd type roof exists, powered supports must be used.

Jan 1, 2005

By R Thompson, D Tulloch

"Wet-weather or 24×7 wet-trafficability is a commendable design objective for unpaved mine haul roads, but practically often difficult to achieve, due both to the road sheeting material selected, and also its breakdown under the action of traffic and environment. Accidents allied to wet-trafficability issues, either due to rain or often more commonly, over-watering of mine roads, is increasing and especially the loss of control or uncontrolled vehicle movements categorisation. The dominant system failure is that once vehicle control is lost, control cannot be regained.The friction supply, or ‘skid resistance’ of a mine haul road sheeting is critical to the safe operation of the road and data has to be collated concerning the variation of friction supply with sheeting material engineering or indicator properties. In the light of the paucity of data existing in this field, this paper presents the contributory research that informs the development of improved and validated unpaved mine road friction supply estimates, based on a number of mine site evaluations across a range of sheeting material types and characteristic parameters, leading to improved predictive models of friction supply.Results from this preliminary review will enable operators to assess their road sheeting materials, improve and validate unpaved mine road friction supply estimates. This will contribute to improved road design, management and 24×7 operability decisions and contribute to a reduction in heavy vehicle loss of control incidents on gravel-surfaced mine haulage roads.Citation:Thompson, R and Tulloch, D, 2016. What's Stopping You? The Role of Sheeting Material Selection in Safe Haulage Operations, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 253–264 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

The mIning operations of Bougainville Copper Pty. Limited are located at Panguna on the Island of Bougainville which is part of the Territory of Papua and New Guinea.C.R.A. Exploration Pty. Limited first established mineralization in the Panguna area in 1964. Exploration work since then has established ore reserves estimated to be 900,000,000 long tons of ore assaying 0·48 per cent copper and 0·36 dwt/ton gold. An economic feasibility study completed in July, 1969 enabled a decision to be made to proceed with a major mining operation. The ore will be mined by open cut methods and will be treated in a conventional concentrator with a nominal capacity of 90,000 short tons/day. The concentrate will be pnmped as a slurry through a 16 mile long pipeline to a port established on the east coast where it will be filtered and dried ready for export. Other supporting facilities for the mine include two towns, a 135 MW steam power station, and access roads.

Jan 1, 1971

By Derek V. Ellis

Coastal and marine mines affect the seabed?s biological resources, eg fisheries, when large volume wastes such as tailings are placed on the seabed, and by the extraction processes from marine mining. Worldwide monitoring of such effects for the past 30+ years now provides information to describe Best Practice design, construction and monitoring procedures. The critical environmental factors for submarine tailings placement (STP) are the selection of an appropriate deposition site and discharge depth, the deposition rate of the tailings, and the speed of biodiversity recovery to a sustainable ecological succession. These should be predictable at new sites using current modeling and experimental procedures. Prediction procedures are still needed to minimize potential destabilization of deposited tailings, and consequent biodiversity recovery setbacks. Comparable environmental information is needed from marine mining sites.

May 1, 2002

By R. W. Heckel, R. A. Tanzilli

Treatment of the finite, diffusion-controlled, two-phase, moving-interface homogenization problem has been carried out by numerical methods for a wide range of input parameters. Solutions have been obtained for planar, cylindrical, and spherical diffusion geometries. The effects of parameters such as the interdiffusion coefficients (concentration-independent) of- both phases, the concentrations (time-independent) of each phase at the interlace, mean composition, initial size of the dissolving- phase, and initial composition of- the two phases are considered. The results are displayed to show both the position of the interjace and the degree of homogenization (expressed in terms of concentration at the matrix phase symmetry boundary) as a function of diffusion time. Typical exaw~ples to which the results may be applied are discussed. A limited number of exact, closed-form solutions to the multiphase, diffusion-controlled, moving-interface problem exists in the literature, e.g., Refs. 1 to 7. The exact, closed-form solutions generally consider the outermost phases to be infinite in extent and also assume an interfacial velocity function. It is through use of such boundary conditions that closed-form solutions are readily obtained. An extensive literature also exists on numerical solutions to the mathematically analogous solidification problem, e.g., Refs. 8 to 12. In addition, a numerical solution involving mass transfer with spherical interfaces and infinite boundaries has recently been carried out.13 A practically important class of diffusion problems exists, however, in which the boundaries of each phase away from the interface are finite. For example the finite boundary condition arises when one sets up a model for analyzing the homogenization behavior of two-component powder compacts in two-phase systems or for studying the solution behavior of precipitates. Although exact, closed-form solutions have as yet not been found to this class of problems, solutions are possible using numerical methods. The purpose of this paper is twofold: 1) to describe a numerical method for treating the two-phase, diffusion-controlled, moving-interface problem involving finite boundaries with planar, cylindrical, and spherical interfaces; 2) to present the results of a parametric study which identifies the role played by each variable appearing in the analytical model. R. A. TANZlLLI,Student MemberAIME,onleaveofabsence from the General Electric Co., Re-entry Systems Department and A. W. HECKEL, Member AIME, are Graduate Student in Materials Engineering, and Professor, Department of Metallurgical Engineering, respectively, Drexel Institute of Technology, Philadelphia, Pa. Manuscript submitted May 6. 1968. IMD MATHEMATICAL MODEL The three geometries analyzed are shown in Fig. 1. For each configuration a symmetry element is shown, across whose boundaries the mass transfer is zero. Mean composition, C, and the characteristic solute-rich phase half-thickness (or radius), 1/2, are the independent variables while the characteristic symmetry element half-thickness, L/2 (measured from solute-rich phase center to the matrix phase plane of zero mass transfer), is a dependent variable. The symmetry element for a planar interface accurately represents a real diffusion situation involving the stacking of symmetry elements of constant size. Because cylindrical and spherical symmetry elements of constant size cannot be stacked to fill space, the meaning of the dimension, L/2, for these situations may be considered in terms of the following approximations: and where NA is the number of parallel cylindrical elements per unit area on a surface normal to the cylinder axes and Nv is the number of spherical elements per unit volume. The model consists of a solute-rich phase matrix phase composite of limited mutual solubility. The concentrations at the interface are assumed constant with time; no assumption of local equilibrium at the interface is necessary except for the case where the

Jan 1, 1969

By R. Strydom, J. H. Selby

Published information is available on the radiological impacts of disposing of zircon sand in a landfill. Zircon flour by virtue of its finer particle size presents a different set of issues during disposal. This paper describes two options for disposal of such fine grained materials – namely incorporation into concrete aggregates and agglomeration by addition of cement. The study considers the radiological exposure of the public from such disposal methods and concludes that these options are viable alternatives for the safe disposal of waste zircon flour. The disposal of zircon into concrete aggregates at a rate of 10 per cent produces a sufficiently low effect to allow such aggregates to be used in building foundations or other such mass concrete applications. The use of cement agglomeration methods will also provide a safe method of landfill disposal provided at least 20 cm of soil cover is included.

Jan 1, 2003