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By Xiang He, Xinzhong Wang, Ning Li, Bao Cao, Hongyang Bai, Zhigang Du

Revealing the periodic fracture pattern of the main roof and the key influencing factors of the support resistance is crucial for strata control and support selection of the shallow buried working face with large mining height. Based on the cantilever beam theory, an improved step rock beam model, and the measured strata pressure data of the 12,401 working face in Shangwan Mine, the mine pressure behavior law of the shallow buried with a large mining height working face was analyzed. The results show that both ratio of maximum principal stress to load (σ1/q) and ratio of maximum shear stress to load (τmax/q) inside the main roof increase with increasing periodic advancing distance, while the ratio of maximum shear stress to maximum principal stress (K) is the opposite, indicating that the increase rate of σ1/q is higher than that of τmax/q. K is less than 1 when the periodic advancing distance exceeds 8 m, indicating that the periodic fracture of the main roof will be dominated by tensile failure. Support resistance increases with increasing immediate roof thickness, main roof thickness, periodic fracture step distance of the main roof, and mining height, and decreases nonlinearly with increasing friction coefficient of periodic fracture rock block hinge surface. The main roof thickness, the periodic fracture distance of main roof, and the friction coefficient of the hinge surface of the periodic fracture rock block are the key factors influencing the support resistance. The advance breaking of the main roof and increasing the friction coefficient of the hinged surface of the main roof can reduce the support resistance of the working face. The support resistance of the 12,401 working face in Shangwan Mine presents an arch distribution characteristic. The average periodic weighting step interval, average support resistance, and dynamic load coefficient are 15.6 m, 17,552 kN, and 1.3, respectively. Finally, the rationality and validity of the model are verified by comparing the measured and theoretical values of the support resistance in the 12,401 working face of Shangwan Mine and other shallow coal seams with large mining height.

Apr 22, 2024

By C. S. Simons

The aphorism that provided the title of this paper is probably a couple of hundred years old, but it still expresses a fundamental truth in the metals industry. This truth will be illustrated through a brief review of the major developments in the extractive metallurgy of the oxidized ores of nickel - the "laterite" ores. While the details to be discussed are for the most part specific to nickel, a close parallel with other commodities - particularly in recent years - will be apparent even to those whose interest in nickel itself is slight. Thus it is hoped that this paper will be stimulating, at the least, to anyone who is concerned with the implementation of process improvement, "Invention" in the present context means any change from "conventional" process technology that shows a reasonable chance of reducing costs, increasing revenues, or both, in the production of a commodity. This can be anything from a simple rearrangement of flowsheet steps to a completely different basis for processing. And the result may reduce costs by more efficient use of energy or labor or reagents; may increase revenues by better recovery of the primary product or by introducing the recovery of previously ignored by-products; may insure sales volume (and thereby cash flow) through higher product purity or an improved product form. "Necessity" is the perceived need to attain at least one of these classes of results. This perception of necessity, however, varies widely from management to management and from project to project.

Jan 1, 1983

By Jinwang Zhang, Zhaohui Wang, Jiachen Wang

"Thick coal seams (seam height larger than 3.5 m) account for a large portion of the proven coal reserves of China, and underground thick coal seam mining provides about 50% of the Chinese annual coal production. Such seams are mainly mined using the longwall top-coal caving (LTCC) method. For safe and successful mining, a number of analyses on the stability of surrounding rocks in the LTCC face area have been extensively performed, and certain research achievements have been made. This paper introduces the main findings on rock pressure occurrence in the LTCC face during the last few decades and presents face and roof stability control techniques. INTRODUCTIONUnderground thick coal seams in China provide 1.8 billion tons of coal every year, which accounts for approximately 50% of the total Chinese annual coal production and 25% of the world, indicating that thick coal seams stand an important position in Chinese coal mining industry (Wang, 2005). Before the 1980s, thick coal seams were mined mainly by using the multiple-slice mining method. With the improvement of mining techniques and equipment in last two decades, longwall top-coal caving (LTCC) and high-seam, single-cut longwall are employed for thick coal seam extraction, offering advantages over multiple slicing from entry excavation and production perspectives (Wang, 2013).. The primary author of this paper introduced the most popular thick coal seam mining methods in China at the 30th ICGCM (Wang, 2015). This paper presents the stability of surrounding rocks in face area and ground control techniques for mining thick coal seams. For traditional longwall faces (seam height less than 3.5 m), the well-developed VoussoirVoussoir beam theory has been successfully used to analyze the movement of overlaying strata, which indicates that ground control techniques have become mature for this mining system. In such faces, the four-leg support with loading capacity of 4000–8000 kN is considered adequate for safe and successful mining. These faces normally have an annual yield of 1–2 million tons (Wang, 2007). For thick coal seams, however, the traditional support becomes inadequate and the ground control problem change to be more difficult and complex. Thus, development of large-scale mining equipment and ground control techniques for enlarged mined-out space and entries have been recognized as the most basic technical problems in mining thick coal seams."

Jan 1, 2017

By Murray Greyson

A number of tests were made with various methanation catalysts in fixed-bed, conventional fluidized-bed, and multiple-feed, fluidized-bed equipment to develop catalysts and processes for methanation of synthesis gas. The results show: 1. Methanation reactions may be carried out in 1-inch, bench-scale equipment at high synthesis-gas throughputs with good temperature control of the reactions if a multiple-feed type of fluidized-bed design is used. 2. Nickel is superior to iron as a catalyst for the methanation of synthesis gas, unless the process is considered in terms of a combined operation that produces both gaseous and liquid products. 3. Techniques of catalyst preparation determine, to a large extent, the process life of nickel catalysts, and these techniques must be thoroughly investigated before any conclusions can be reached. 4. Enough data are available to indicate that the sulfur concentrations in synthesis gas that is used for methanation are extremely critical, and maximum process limits should be carefully evaluated.

Jan 1, 1955

By Ricardo Montero

At this time, over 300 tons of Au are used in electronic equipment each year with other precious and strategic metals such as Ag, Pt, Pd, Cu, Nb, Ta, etc. After the use-phase, the electronic devices become electronic waste (e-waste); consequently it is important to consider e-waste as a secondary supply for recovery of these metals. One of the most important components is the printed circuit boards (PCBs) because the amount of their precious metals is ten times higher than rich precious metals bearing ore. This paper presents the recovery of Au, Ag, Cu and Nb from PCBs of discarded computers using leaching column technique. The amount of these metals in used PCBs was: 613 g/ton of Au, 1515 g/ton of Ag, 36 g/ton of Nb and 23.4 % of Cu. The PCBs were crushed with a hammer mill until reaching a particle size between 3.33 mm to 0.43 mm. Then, it was leached with sodium cyanide solution in a glass column using the following conditions: sodium cyanide concentration 4 g/L, flux 20 L/kg PCBs day, pH between 10.5 to 11 and leaching time 15 days. Every day, after leaching, the pregnant solutions passed through a column with activated carbon to complete the closed loop system. The following recoveries were obtained: 46.6% of Au, 51.3% of Ag, 47.2% of Nb and 62.3 % of Cu. The products obtained are: a) loaded carbon that contains the desired metals and b) processed PCBs with precious metal contents. A preliminary technical-economic study shows the feasibility to create a small-scale PCBs recycling plant. The initial investment is on the order of US$ 155 639, considering the recovered metals from loaded carbon. The internal rate of return for 10 years period (IRR) and net present value (NPV) estimated are 27% and US$ 105 926 respectively. Keywords: printed circuit boards, recovery, precious metals, niobium, leaching column

Sep 1, 2012

By Parry. V. F., W. S. Landers

"INTRODUCTION Approximately 1,250,000 tons of 2-1/2-inch and 1-1/2-inch slack, representing over half of the output from 40 to 50 mines, is produced in the Denver region each year. Part of this slack is made by crushing lump, and some of it is rescreened to make pea and modified pea sizes measuring 1-1/2 inches by 2-1/2 inches and 3/4-inch by 1-1/2 inches, round-hole. Modified pea is popular as domestic stoker fuel. Approximately 900,000 tons of slack 0 by 2-1/2 inches, 0 by 1-1/ 2 inches, and 0 by 3/4-inch in size are consumed by industrial plants, the principal consumers being a large power plant and the beet-sugar industry. The power plant uses annually 250,000 to 275,000 tons of pulverized fuel and can pulverize slack of any size, while the sugar factories consume about the same quantity of coal in stokers. The sugar factories store about 110,000 tons of 2-1/2-inch slack under water from January to October, and burn the remainder of their consumption directly during the campaign season from October to December. For this purpose, sugar-factory power plants can use any size of slack, which is recrushed to pass a 3/4- or 1/2-inch screen before burning on chain-grate stokers. About one-third of the 2-1/ 2- inch slack produced in the field is used in smaller industrial plants that employ stokers.Certain factors affect the utilization of 2-1/2-inch slack in the Denver region. The increasing production of hydroelectric power has reduced the consumption of coal at power plants slightly. If more hydropower is generated, the trend of consumption of slack might be downward, unless industrial activity offsets this greater output. Rapid increase in number of domestic stokers during recent years has necessitated preparation of greater quantities of stoker coal, with the result that more lump is crushed, and preparation facilities are changed. At present about 19 percent of the coal produced is crushed to meet the constant demand for industrial fuel as well as the increasing but variable demand for the small domestic stoker sizes. The quantity crushed has increased 12 percent during the last 6 years. These factors are shifting constantly. The trend toward the use of clean and smaller sizes for domestic stokers gives a slack having a larger proportion of fines. In future, even greater quantities of small stoker coal probably will be prepared, and the resulting greater quantities of small slack will have to be used for industrial purposes."

Aug 1, 1942

By A. I. A. Salama

The CANMET Western Research Centre (CWRC) has developed a hydrocyclone model simulation of dewatering and fine particle separation circuits. The simulation is based on an existing empirical model. Utilizing a cyclone manufacturer’s published data, some modifications have been developed and integrated into the model. Feed stream characteristics, cyclone mechanical dimensions, and operating conditions are used in the CWRC modelling simulation. The computer results are presented in 3D graphs and corresponding 2D maps showing the cyclone mass recovery, percent solids by mass in underflow and overflow, and cut size as functions of the cyclone apex diameter and cyclone throughput (i.e., inlet pressure or pressure drop). Results of the computer simulation have been used in the economic feasibility and design of several dewatering circuits in oil sand plants.

Jan 1, 2003

By Janine Acasi, Robert D. Rogers, Jonathan K. Trautman, Richard C. Cronn, James H. Wolfram

The demand for phosphate will continue into the future, because phosphate is currently irreplaceable as a plant nutrient and in many chemical applications. Phosphate is not recycled, so the supply must be replenished through a process of mining and purification. The most energy intensive part of the process, separation of phosphate from the ore, requires 54 to 78% (depending on the method used) of the estimated 0.5 quads of energy consumed by the U.S. phosphate industry. This paper provides data from a project designed to determine if a biotechnology can be developed to separate phosphate from its ore. Several hundred microorganisms (both bacteria and fungi) capable of solubilization of phosphate ore have been isolated from the environment. Work is ongoing to determine the mechanism for solubilization. In addition, how these organisms could be used in a bioprocess is being investigated.

Jan 1, 1989

By Mark Bauckman

Discussion Topics • Market Needs • Technology Developments & Best Practices • Industry & Government Developments • Future Possibilities & Your Role

Jan 1, 2006

By Frederick T. Wallenberger

"Laser assisted chemical vapor deposition (LCVD) is a new containerless fiber process whereby growth of small diameter fibers or microstructures (microsprings, microsolenoids) occurs directly from the vapor phase. The laser beam has a focal point adjusted to coincide with the tip of the growing fiber inside the reaction chamber. Since the growing fiber is not in contact with reactor walls or foreign materials, it is chemically pure, and suitable for optical uses and uses requiring high structural uniformity. Continuous fibers and multifilament yams are possible. The use -of high reaction chamber pressures (1-10 bar) and a small wavelength Nd-YAG laser made it possible to fabricate small diameter fibers at growth rates >1 mm/s. This paper describes the synthesis of single crystal, polycrystalline and amorphous fibers by LCVD, and provides a comprehensive analysis of phase transformations occurring during their fabrication.IntroductionLaser assisted chemical vapor deposition (LCVD) is a new containerless fiber process [1-10] whereby growth of small diameter fibers or microstructures occurs directly from the vapor phase. The laser beam has a focal point adjusted to coincide with the tip of the growing fiber in the reaction chamber (Figure 1). The diameter of the growing fiber corresponds to that of the laser focus. Depending primarily on the laser energy (Le., the temperature at the growing fiber tip), it is possible to obtain single crystal, poly crystalline or amorphous fibers by this method.Since the growing fiber is not in contact with reactor walls or foreign materials, it is chemically pure, and suitable for optical uses and uses requiring high structural uniformity. Laser assisted CVD is a potentially continuous process; continuous fibers and multifilament yams are possible."

Jan 1, 1994

By A. Kiziltas, D. J. Gardner, C. W. Mcllwraith, J. W. Bridge, M. L. Peterson

"Dynamic mechanical thermal analysis (DMTA) tests were conducted on high-oil content, paraffin-based wax used in wax-coated granular composites. These composites make up the surface of synthetic Thoroughbred horse racetracks used in North America. The modulus and damping response from the DMTA tests were correlated with the dynamic triaxial shear strength response of the bulk track material taken at two different operational temperatures and at four strain rates. The purpose of these tests is to understand the mechanisms of shear strengthening of the bulk track material as the wax is heated through the first crystalline solid to liquid nominal transition temperature. Previous work using differential scanning calorimetry confirmed that under common operational surface temperatures, the wax coatings undergo distinct thermal transitions. The resulting increase in triaxial shear strength values affects the consistency of the racetrack which, in turn, can potentially affect Thoroughbred racing performance and safety of the track surface.IntroductionSynthetic granular composite materials are being used in nine Thoroughbred horse racetracks in the United States as well as in other tracks around the world. In one case, their use was mandated by the state of California in 2007 due to testimony that these tracks were significantly safer than traditional dirt tracks [1]. Several synthetic tracks have shown substantial reductions in injuries since switching to synthetics; one California track showed a 75% reduction in catastrophic horse injuries during the first year as compared to the previous year racing on a dirt track [2]. The composition of the tracks in the U.S. generally consist of silica sand (>70%), polymer fibers (<5%), and rubber particles (0-15%) all coated with a paraffin-based, high oil content wax [3, 4]. In a recent study of several synthetic racetracks, to include the track location in this study, the oil content ranged from 34 to over 44% by mass [5]."

Jan 1, 2011

By Harvey Cline, Donald P. Ferriss

THE violent outgassing of commercial tungsten and other refractory metals when melted in an electron beam zone refining apparatus1"3 is dealt with experimentally by one or both of two approaches. One is to provide a suitable emission current control1,2 the other is to purify the metal in the solid state before melting.4 The first of these is usually sufficient, but the authors chose also to investigate the source of the troublesome gases and to devise means of solid-state purification. Some further insights into the use of tungsten as a structural material at temperatures near its melting point were also revealed in the course of the work. One may speculate on the causes of gas formation in tungsten at high temperature by inferences from the literature and an examination of the impurities in commercial wire. Davenport5 observed microporosity in both tungsten and molybdenum filaments heated to several hundred degrees below their melting points. Studying the function of oxygen in molybdenum welds, Perry, Spacil, and wulff8 attributed similar porosity to the disproportionation of Moo2 to molybdenum metal and Moo3. Tungsten dioxide also disproportionates7 above 2000oC to yield WO3 vapor at considerable pressure. Commercial tungsten contains some 5 to 20 wt ppm O and a similar concentration of carbon depending on the details and precautions of processing. Therefore, evolution of CO is also a strong possibility as a source of gas at high temperatures. Furthermore, even for activities in the order of 0.01, it may be calculated that the pressure of CO at 3000°C would be over 4000 psi, which is in excess of the tensile strength of tungsten at this temperature.9,10 Powder metallurgy tungsten contains some 0.02 pet Fe and 0.002 to 0.005 pet of the elements Ni, Si, Al, Ca, Mn, Mg, and Mo; at temperatures over 2800°c, therefore, these elements will exhibit appreciable vapor pressure, though small compared to that of WO3 and CO. Some of these impurities may react to form high-pressure monoxides such as SiO and A10. Finally, dissolved and occluded nitrogen is an ever-present source of high-pressure gas. Commercial Type 218, General Electric filament wires, 0.025 in. diam, were heated by resistance in 10 -4 mm of Hg and in argon or hydrogen at pressures from 50 µ to atmospheric. For temperature determinations in vacuo, the Jones - Langmuir8 current-temperature relationship was employed. For gaseous atmospheres, the burn-out temperature was assumed to be the same as in vacuo so that a small, constant correction could be made for temperatures below burn-out conditions (i.e., local heating to failure). Several dozen experiments may be summarized by pointing out some structural observations. At 3050oC in 1 atm of A, porosity is very evident after 30 min, as shown in Fig. 1. For the section in Fig. 2, failure occurred 200°C below the melting point and many voids have grown in the grain bound-

Jan 1, 1962

By Khamis Y. Haramy

Curing temperature, density, and moisture significantly affect the velocity measured in the crosshole sonic logging, the rate of strength gain, and the final strength of concrete in drilled shafts and, thereby, affect their structure capacities. Non-destructive field measurements can enhance the QA/QC program by measuring temperature, density, moisture, and sonic velocity of curing concrete during the construction and curing of drilled shafts. The curing environment can greatly affect the concrete strength, and requires close attention during construction. This article shares the experience with the NDE technology used in the QA/QC program in the drilled shaft construction. To understand the mechanism by which a drilled shaft cures under field conditions, two newly constructed drilled shafts were monitored for up to seven days, immediately following concrete placement using the following geophysical logging methods: a) temperature logging; b) crosshole sonic logging; c) gamma-gamma density logging; and d) neutron-moisture logging. One additional drilled shaft was also monitored to a shorter duration. Temperatures were monitored using the sensor in access tubes and/or thermocouples embedded at the center of a drilled shaft and near its reinforcing cage. For a small shaft under 1m diameter, curing temperatures appeared to peak at 41° ? 68° C at different depths at around 24-hour curing time and decreased to and stabilized at around 23° ? 35° C in 6 days. The shaft curing rate varied with depth, shaft diameter, surrounding geo-material types, and the depth of ground water. CSL logging was performed in one shaft from top to bottom from six access tubes and limited monitoring in another shaft. The velocity increased with curing time till 4 to 7 days, and, at a specific time, the velocity appeared to be inversely correlated to curing temperatures. The gamma-gamma density log (GDL) results from 5 different depths were obtained at a source-detector separation of 355 mm. The average density was found to increase with curing time, but decrease slightly in 3 to 5 days. At a given time the GDL density curves seemed to correlate with the neutron monitoring logging (NML) moisture curve. The NML moisture was monitored from 1st to 6th day after concrete placement. The moisture was highest when surrounded by bedrock, then clay, and sand due to different hydration rates.

Jan 1, 2007

By C. I. Garcia, G. Zhou, W. Gao, A. J. DeArdo

The development of X-100 and X-120 linepipe steels was investigated using a series of low-carbon Mo-Nb-B steels. The laboratory steels were vacuum melted and processed using advanced thermomechanical processing (TMP) philosophies. Prior to the laboratory hot-rolling experiments, the grain coarsening temperature, the conventional T95 and T5 start-stop recrystallization temperatures and the transformation behavior of y were studied using a computer-controlled high temperature deformation MTS-458 and a Theta-IV High Speed dilatometer systems. The results from these experiments provided the guidelines for the design of the laboratory hot-rolling TMP processing experiments. The mechanical properties of the experimental steels showed yield strengths in the range 700-850 MPa and CVN impact properties of over 80 J at -20°C. The best balance of mechanical properties was obtained by using CCR+DQ+Tempering treatments. The major microstructural features responsible for the observed mechanical properties in order of importance were: a) substructural refinement associated with lower bainite, b) dislocation strengthening, c) fine recrystallized ferrite, and d) small amounts of retained austenite. Fine Nb(C,N) precipitates formed in ferrite were observed, however their contribution to the strength was minimum. Most of the Nb(C,N) precipitation took place in austenite. This precipitation was used to exert microstructural control of austenite during hot rolling. The physical metallurgy and optimum TMP to achieve the mechanical properties are detailed in this paper.

Jan 1, 2005

Jan 1, 2001

By W. C. Holliman

This report on the characteristics of commercial aviation gasolines is one of a series of such reports. It presents compilations of&apos; inspection data furnished on their products by 15 manufacturers of commercial grades of aviation gasoline and special data obtained in Bureau of Mines laboratories on 68 samples of these gasolines. Data are presented for 18 samples of grade 80, 20 of grade 91/98, 21 of grade100/130, and 9 of grade 115/145 aviation fuels. The gasolines are designated January 1948 production, although some of the samples actually were produced at a later date.

Jan 1, 1948

By E. S. Peterson

The selective separations of trace metals- and organics from water are processes of importance to industry. The application of a new metals capture technology coupled with polymer membrane technology has proven to be one avenue to accomplish such selective separations. The polymers used in these studies are polyphosphazenes. Polyphosphazene polymers consist of an alternating backbone of nitrogen and phosphorus atoms. The polymers have high thermal and chemical stabilities. Experiments at the Idaho National Engineering Laboratory demonstrate that polyphosphazene membranes coupled with Chromato Chem,"Chelation Chromatography" process are capable of removing both chlorinated hydrocarbons and metal ions from process streams. These results point to a wide range of potential industrial and environmental applications for such systems. Data will be presented which show the efficiency and selectivity of separations, postulated separation mechanisms, and the initial designs of industrial demonstration units which are currently under construction. Parts of this work have been performed under a Cooperative Research and Development Agreement (CRADA) between ChromatoChem, Inc. and Idaho National Engineering Laboratory (INEL). The work at INEL was been sponsored by the United States Department of Energy&apos;s Office of Industrial Technologies

Jan 1, 1995

By K. V. Raj, M. McNinch, A. L. Miller, J. Wilson, D. A. Parks

Diesel particulate matter (DPM) has been shown to contribute to various adverse health effects on underground miners. In order to reduce worker exposures, it is critical to measure the levels of DPM in the active work settings and in real time. However, the 5040 method, developed by the National Institute for Occupational Safety and Health (NIOSH), which quantifies the mass of elemental carbon (EC) and organic carbon (OC) in the samples, is based on full-shift samples, and can take days or even weeks for results. Use of real-time monitors could significantly reduce the risk of DPM exposure to miners, and available monitors have been shown to quantify DPM, mainly using the EC and other surrogates. The NIOSH Spokane Mining Research Division is conducting research aimed at developing a field-portable DPM monitor that is able to quantify both EC and OC. One part of this work is to understand the effect of OC on currently available real-time DPM monitors. This paper will present the results from experiments that were designed to observe the effect of OC on real time monitors and compare the results with the NIOSH 5040 method. BACKGROUND Diesel engines remain ubiquitous in mining environments and, as such, are one of the primary sources of ultrafine- and nano-aerosols in the mining environment in the form of diesel particulate matter (DPM). As a result of their small size, DPM has longer residence times in a mine atmosphere than the typically larger mechanically generated dust [1]. In addition, the small size enables DPM to penetrate deeply into the respiratory system [1], and exposure to DPM has been shown to contribute to various adverse health outcomes of the pulmonary system [2] and cardiovascular system [3]. Diesel exhaust has been classified as a carcinogen to humans (Group 1) by the International Agency for Research on Cancer [4]. Due to mounting concern about adverse health outcomes, extensive efforts are being made to reduce workers’ exposure to DPM, with the high exposures that often occur in underground mines being of particular concern [5]. New technologies are being developed to reduce engine emissions and thereby airborne DPM levels, including advanced engine technologies, a host of aftertreatment systems [6], and a variety of alternative fuels. The latter have been shown to markedly decrease respirable DPM and other hazardous components of diesel emissions from mining vehicles [7], yet high exposures persist, especially in underground mines [8]. In order to reduce worker exposures, it is critical to measure the levels of DPM in active work settings. In mine settings, exposures to DPM are measured by collecting air samples on filters (usually full-shift samples) and sending them to a lab for analysis using the Mine Safety and Health Administration (MSHA) P13 method, a variant of the National Institute for Occupational Safety and Health (NIOSH) 5040 method. The 5040 method is designed to quantify the mass of elemental carbon (EC) and organic carbon (OC) on the samples [9], which is then used to determine the concentration in the sampled air. MSHA has set a limit for exposure, which is based on the concentration of total carbon (TC), or the sum of both EC and OC. The allowable TC in the air (time-weighted average over the shift) is 160 μg/m3 of TC [10].

Jan 1, 2019

By J. Keith Haddock

"Introduction The Coal Valley Mine is operated by Luscar Stereo (1977) Ltd. with the Alberta Energy Company having a minority interest. The mine produces 2.0 million tonnes of bituminous thermal coal per year. Deliveries include 1.5 million tonnes to Ontario Hydro and 0.5 million tonnes to the export market via bulk handling facilities on the west coast near Vancouver, B.C. There are a number of mining methods utilized at the mine including open-pit by truck and shovel, strip mining with large draglines and stripping with scrapers. The mine is located 100 km south of Edson, Alberta. Geology The coal measures are concentrated within a 210-metre int~rval of the Paleocene section. The coal seams were originally named by the mining companies in the earliest days of development of the area and these names continue to be used today. Of the five main seams, only three are presently economic to mine based on quality, thickness and depth of cover. These are the Val d'Or, Upper Silkstone and Mynheer. The Coal Valley Mine is located in the structurally deformed foothills area of Alberta and the structure of each mining area is therefore very complex. The general bedding strike is 305 degrees azimuth but major thrust faulting and folding has extensively deformed the natural seams as a closer examination will show. The Mynheer Seam, located at the base of the coal measures, ranges in thickness from 5 m to 10 m and has numerous bentonite and shale partings. Because of inherent geological features, the Mynheer Seam has been subdivided into two zones, the Mynheer 'A' and the Mynheer 'B', and the mining of coal in these zones has necessitated the utilization of distinctly different mining methods. The structural regime of the Mynheer 'A' zone consists of an overturned asymmetrical anticline crest containing a steeply dipping major thrust fault which has raised the seam above the present topographic level. Further extensive shearing and rotation of the coal has resulted in the coal taking a 'pod' shape. The Mynheer 'B' Zone is a continuation to the southeast along strike from the Mynheer 'A' Zone. The bedding dips to the southwest at an average of 12 degrees and is interrupted at the south end by a transverse fault and to the north by its outcrop at the surface."

Jan 1, 1985

By Vitalij K. Pecharsky

Recent interest in complex aluminohydrides as potential near ambient, ultra-high capacity, solid-state sources of hydrogen (e.g., for fuel cells) calls for an improved understanding of the processes occumng in these hydrogen-containing materials during both the release and the uptake of hydrogen. Lithium aluminohydride (LiAlH4) rapidly releases 5.2 wt. % of hydrogen (i.e., nearly four times more than LaNis-based alloys) during mechanochemical processing at ambient conditions in the presence of transition metal catalysts. Using a variety of solid-state characterization techniques, the mechanochemical transformations in a series of LiAlH4 - metal catalyst systems have been examined and preliminary insights on the mechanism have been obtained. Surprisingly, the well-known hydrogenating-dehydrogenating catalysts, such as Ni and Pt, are practically inactive in the mechanochemical dehydrogenation of LiAlH4.

Jan 1, 2002