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By Rüdiger Wunsch

The new high speed Vienna - St.Pölten line and the Lainzer tunnel are to be connected to the existing Western railway line in Vienna. This involves building an underground cut and cover branching tunnel which will be connected to the Western railway line by ramps. A key structure is the Herzmansky Street tunnel, which has a length of some 820m. It is to be constructed as a cut and cover tunnel using the top down method. The walls of the tunnel are designed as a water resistant structure consisting of double walls, an outer wall of bored piles and an inner reinforced concrete wall. The bored pile wall will be used as a temporary retaining wall during the construction phase and will also be a structural part of the per­manent tunnel wall. The retaining walls of the open pit, which will have a depth of up to 14m and a width of 12m, were investigated as a non-contiguous bored pile wall and overlapped bored pile wall. Preventing ground water from penetrating into the pit is of paramount importance. The high ground wa­ter level is the determining factor for the dimensioning of the bored pile wall and results in the require­ment for a water resistant concrete structure. It has been necessary to adopt adequate measures, therefore, in order to reduce the hydrostatic water pressure during the construction phase, assuming economical pile dimensions.

Jan 1, 2000

By Vic Sterner

As cities and towns continue to grow, the need to install sewer, water, gas and other utilities becomes a necessity and the blasting of trenches for these service lines probably constitutes one of the most important forms of blasting in built-up areas. There f o re, understanding how explosives can be safely used in the most efficient manner is of prime importance. The need for protection against flyrock must be emphasized. The first consideration is that all explosive c h a rges should be located well down in the blastholes. The golden rule is to ensure that the depth of top stemming is never less than the burden on the hole. In the case of shallow holes, the minimum depth of stemming should not be less than 18 times the charge diameter, if airblast and flyrock are to be controlled. If there is a doubt, then additional cover and/or blasting mats should be used. Putting too much burden on blastholes is another possible cause of flyrock and raising ground vibration levels. Overburdening of explosive charges will also result in the blastholes not breaking to grade. This in t u rn re q u i res additional drilling of shallow holes down in the trench to achieve grade, thus further increasing the h a z a rd of flyrock .

Jan 1, 2004

By L. A. Bakhvalov

According to the practice of mining management in the system of industrial complexes, the Kazakhstan gold mines are part of the mine processing industrial concerns providing ore-mining and ore-dressing. The cycle technology of winning operations used at the mining of vein deposits in the mines of the industrial concern is mainly provided by the systems of scrapping, scipping and electric locomotion. At present the information and computer system, elaborated on the basis of the Maikain underground mine is intended for creation of the system of automatic operation for the industrial complex mines. The information and computer system includes: - parametres characterising the accepted technology of works; - the main parametres characterising the technical devices of operation and control ; - information about the material, technical and personnel resources available at the mine; - mining and geological conditions of the deposit; - the facilities of the subsidiary units, of the mine; - the direct parametres and technico-economical indices in which the mine efficacy and activity is estimated. The suggested structure of the automatic operation system can be sensibly realized with the application of the microprocessor on the first level, the personal computer IBM PC/XT or PC/AT on the second level. For the complete realization of the project each mine will need 4-5 computers (as PC/XT), one IBM PC/AT and each mine complex - one super IBM for creation of the distributed information bank and its including in the integral world communication system.

Jan 1, 1992

By A B. Christie, R L. Brathwaite, A Swain

This study provides quantitative data on vein distributions within seven selected epithermal systems, four deposits hosted predominantly in rhyolitic rocks: Ohui, Wharekirauponga, Neavesville and Komata, and three major deposits mainly hosted in andesite: Martha Hill, Golden Cross and Karangahake. The technique of fractal analysis was used to help quantify vein distribution patterns. The fractal dimensions (D) obtained are related to the number of veins per metre, the degree of vein clustering, and vein thickness. An increase in any of these tends to increase the fractal dimension.   It is the relative relationship of these parameters that is important for the characterisation of vein distributions, and the comparison of different deposits. Within the same systems, the rhyolites are characterised by lower vein thickness and vein density, but have a higher degree of vein clustering compared to the andesites. Sections that are deeper and more centrally located within the epithermal system and/or close to major structures tend to have a greater degree of vein clustering, higher average vein thickness and density, and higher thickness to density ratios. This depth control is most pronounced in epithermal gold-silver systems because they have formed at shallow crustal levels where physico-chemical conditions change drastically both vertically and laterally. In addition to lithological and structural control at vein scale, deposit scale structure is of great importance in the deposition of economic mineralisation. Large open vein structures capable of sustaining high fluxes of hydrothermal fluid, favourable for the formation of large, high-grade gold deposits, are best developed in andesite sequences.

Jan 1, 1995

An incremental analysis based stope design optimization method was developed at Exodus, an underground project located 30 miles north of Carlin, Nevada. Traditional underground stope design methods, by manually drawing stope shapes, are typically very time-consuming and lacking of consistency and accuracy. For quick reserve calculation and economic analysis, a new method named '3D Incremental Analysis based Stope Optimization' was created for mine wide stope designs at Exodus. With this unique but practical method, multiple options of mine designs were completed within a short period time, which allowed us to select the optimal cutoff grade and best stope design option for the project.

Jan 1, 2012

By I. Yildirim

Water contact angles of talc powders were determined from the values of the heats of immersion measured using a flow microcalorimeter. The results were used to calculate the contact angles using a rigorous thermodynamic relation. In the present work, the calculation was carried out using the temperature coefficient of the contact angles determined experimentally using another method. The results obtained in the present work on several different talc samples are compared with those obtained using other methods.

Jan 1, 2001

By G. Reinberg, C. D. Clarke

Most underground mining operations are dependent on pumping installations to keep the mine unwatered. The reliability of such installations is obviously of paramount importance. The volume of water to be handled is often considerable, and the total head is relatively high. In these cases, both capital cost and operating expense of the pumping installations will become significant factors in overall mining costs. To insure reliability and to keep efficiencies, and hence operating costs, within acceptable limits it goes without saying that mechanical maintenance of a mine pumping installation must receive scrupulous attention at all times. Large mine pumping installations today almost invariably use multistage centrifugal pumps, since positive-displacement units would not be economically competitive except under very unusual conditions of small volume combined with extremely high heads. Centrifugal pump maintenance, under ideal circumstances, would be confined to parts subject to normal running water, i.e., bearing surfaces, stuffing box packing, and shaft sleeves. Under adverse conditions, however, metal may be lost from the wetted surfaces of a pump by erosive or corrosive action of the pumped fluid, and maintenance costs can easily attain enormous proportions.

Aug 1, 1956

By L. M. Demers, R. E. Edelson, M. P. Rose, D. T. Superdock

The pulmonary alveolar macrophage is a major defensive cell which counteracts the invasive properties of bacteria and particles when these substances invade the pulmonary environment. Pulmonary exposure to coal dust particles is believed to activate these macrophages to release a host of d1emical mediators which can neutralize or contribute to the harmful effects of these dust particles. Our efforts have been concerned with assessing a specific family of mediator substances produced by the alveolar macrophage from arachidonic acid when these cells are in contact with activating substances such as coal dust. Metabolites of arachidonic acid produce a vast array of effects which can impact significantly on pulmonary function both with normal pulmonary events and with pathologic processes of the lung. Our studies demonstrate that isolated alveolar macrophages obtained from rats or guinea pigs cultured in vitro release appreciable amounts of the cyclooxygenase products prostaglandin E2 and thromboxane A2 and release significant amounts of the lipoxygenase products .5-HETE and LTB4. In the presence of l x 104 -1x10·7 g/ml of a coal dust suspension, alveolar macrophages from the rats and guinea pigs alters their pattern of arachidonic acid metabolite release. In the rat, exposure of alveolar macrophages in vitro to the higher concentrations of coal dust causes a significant reduction in PGE2, TXB2 and LTB4 in a 4 hour time course study. In contrast, macrophages from the guinea pig in response to coal dust had little change in TXB2 release, only a slight inhibition in PGE2 production and an initial stimulation in LTB.t release over the 4 hour time course. Cells from guinea pigs released considerably more TXB2 than the rat under these conditions while rat cells formed considerably more LTB4 than guinea pig alveolar macrophages. These findings support the following conclusions.

Mar 1, 1989

By R. W. Hertzberg, F. D. Lemkey, J. A. Ford

The effect oj unidirectional solidification upon the microstructural, crystallographic and mechanical characteristics of high -purity A1-A13Ni eutectic a1loy specimens has been investigated. varying the growth rate caused the morphology of the Al3Ni phase to gradually change from platelets to rods. In addition, the effect of increasing the rate of planar liquid-solid interlace movement is to decrease the Al3Ni rod diameter and inter-rod spacing. The platelets and rods grow approxinlately parallel to each other and are aligned in a faulted substructure. A single unique crystallographic relationship hetween the A1 and ASNi phases was found and may he descrihed as : interface {001} Al3Ni {331} Al and growth direction <010>Al3Ni || <110> Al The platelet interlace and the aligned rows of rods are both uniquely defined by the above statements. Alignment of the Al3Ni phase by unidirectional solidification has given rise to a threefold increase in strength over that exhibited by specimens with an as-cast microstructure. These results illustrate the possible use of this eutectic alloy as a zohisker -reinforced structure. It has been demonstrated by Winegard et al.,1 Kraft and Albrighht,2 Chilton and winegard,3 Chad-wick,4 Yue,5 Tiller,6 and others that a planar liquid-solid interface may be established in binary eutectic alloys by proper control of heat flow during the solidification process. The unidirectional movement of such an interface results in a eutectic mi-crostructure consisting of an essentially parallel array of the two phases over an entire ingot. Two dominant phase micromorphologies have been produced using this technique: that of substantially parallel alternating lamellae of each phase or long thin parallel rods of one phase imbedded in a continuous matrix of the other phase. While not all eutectics can be controlled in this manner, it has been shown that a "normal" eutectic may, under properly controlled conditions of purity, liquid and solid thermal gradients, and solidification rate, be forced to solidify with essentially parallel phase particles. Kraft and Albright2 have demonstrated that, when the growth rate is too rapid or when the thermal gradient in the liquid at the growing interface is too low, a layer of constitutionally supercooled liquid, formed by impurity build-up, will stabilize a cellular rather than a planar interface. The unidirectional movement of the cellular interface forms the macrostructure of eutectic colonies.7 Chilton,3 Chadwick,4 and Tiller,&apos; studying eutectics of zone-refined Pb-Sn, A1-CuAl2, Zn-Sn, and Cd-Zn systems, noted that in the absence of impurities a planar interface is stabilized even when rapidly solidified. Although it is generally agreed that impurities break down a planar interface to form the eutectic-colony macrostructure, at present the origin of the varying micromorphologies (i.c., plates or rods) in a given normal eutectic alloy is not completely understood. Tiller8 has predicted that the micromor-phology produced may be dependent on solidification rate (i.e., at fast rates a rodlike structure is preferred whereas at slow rates a lamellar structure should form), and also suggested that rod formation may be favored at large phase-volume ratios. yue5 has experimentally verified Tiller&apos;s prediction in the eutectic Mg-Mg17Al12 by observing a lamellae-to-rod transition with increasing growth rate where the phase-volume ratio was approximately 2.3:1. However, Hunt and chilton9 more recently unidirec-tionally solidified over a wide range of growth velocities six different eutectic systems with phase-volume ratios between 12:l and 2.7:1 and observed no lamellae-to-rod transition. chadwickl0 has proposed that the change in micromorphology in some eutectic alloys is due entirely to the presence of impurities and further states that the lamellar structure is the characteristic structure of pure eutectic alloys even when the phase-volume ratio is as great as 12:l. Kraft11,12 has shown that the parallel lamellae in certain eutectic alloys assume a unique crystallographic relationship during unidirectional growth. This preferred crystallography may be developed

Jan 1, 1965

By K. Y. Haramy

This report describes the development of an equation for predicting the crushing strength of 2-inch (5.08-cm) cubes of coal from point load tests made on irregular lumps. The equation was developed from point load and cube crushing strength tests performed on coal samples from six Western U.S. coal seams. For the six coals tested, the means of the point loads [(P)] in kg at failure were approximately proportional to the deans it the distances [(V)], in cm between the platen points for lumps in the 2 to 10-cm size ramie. This finding is at variance with results of tests on other rock types reported in the literature, which tend to show that P is proportional to D2 , as is normally assumed (in theoretical grounds. [The average crushing strength of a 2-inch (5.08 cu) cane for each type of coal was plotted against the log 10 of the slope of the P vs D plots, AP/AID . A straight line was fitted to these plots. The equation of the fitted line is cr = 1.72 x 10 4 10gK -2.10 x 10 4, where Cr is re estimated 2-inch (5. 08-cu,) cube crushing strength of the coal in psi and K is the scope of the straight line fitted to a plat of P v D for the same coal.]

Jan 1, 1982

By T. L. Iapalucci

To determine the behavior of chlorine in coal combustion, the Bureau of Mines burned 10 chlorine-containing coals, high-, medium-, and low-volatile, in a laboratory-scale pulverized-coal combustor. At carbon-combustion efficiencies of 94 to 98 percent, 1.6 to 7.1 percent of the chlorine or an average of 4 percent of the chlorine in the coal was retained in the ash; the balance, predominantly hydrogen chloride, was evolved in the combustion gas. Sulfur retention in the ash ranged from 2.3 to 10.7 percent or an average of 6.3 percent, Addition of alkali and alkaline earth carbonates to a medium-volatile coal containing 0.27 percent chlorine by preferentially reacting with the chlorine increased the Cl/S atom ratio in the ash, Lithium carbonate addition at 0.43 percent and K2C03 at 1.59 percent increased the C1/S ratio in the ash from 0.2 to 0.6.

Jan 1, 1969

By Christoph Müller

Information exchange for mine process optimization is essential. Today, modern mining equipment uses the IREDES standard to exchange production plans and reports for easy management and storage. To gain further benefits from process optimization, a mine wide access to real-time information is needed as e.g.: The current status of a machine, operational details etc. Presently, real-time data exchange systems are developed by machine producers. Each machine producer uses its own way of gathering, managing, and storing production data. These proprietary mining processes increase the complexity of cross platform data exchange and management for mines which involves machines produced by different vendors. Casting and unifying the data requires much effort. For this purpose, ?IREDES On-line? currently is being introduced. The standard defines an open, web based method for the exchange of volatile real time machine information. Two different principles are used: Web Services for cross platform information exchange within the IT world and the optional OPC UA for use with automation and process control systems. With such a standard information from machines of different vendors may be managed by using one common platform without spending the effort for dedicated interface development. Additionally, information management and storage will become straight forward since all the data are of the same format. The IREDES On-line standard utilizes the latest IT technologies as well as the knowledge and experiences gained from the previous IREDES standard. The paper explains the benefits, the use, as well as the technical design of the standard and gives application examples from the practice.

Oct 1, 2009

By A. F. Robertson

"INTRODUCTION This report is supplemental to R.I. 4178 and deals with the work accomplished between June 15, 1945, and September 7, 1945, on the Mitchell-Hodge mine, Grady mine, Albea and York property, and Cuzzort property.ACKNOWLEDGMENTSIn its program or exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurigcal Branch, O. C. Ralston, chief, analyzes samples and performs benefication tests.Acknowledgment is due Mitchell H. Kline, chief, Raleigh Division, Mining Branch; Abraham L. Fox, acting chief, Raleigh Division, Metallurgical Branch; and Rowe McCrae, district engineers, U.S. Bureau of Mines, Gainesville,"

Jan 1, 1946

With some notable exceptions, marine placers located just below, or just above, present sea level, are responsible for much of today&apos;s production of detrital ilmenite, rutile, zircon, and other minerals of value. The purpose of this paper is to discuss the paleogeographic and paleo-oceanographic factors which may have determined the location of presently submerged marine placers. These factors include changes in sea level, burial by recent marine sediments, stream capture and other changes in drainage patterns, and recent changes in climate. Selected geologic situations in the Yellow Sea off the coast of Korea, in the Atlantic Ocean off the coast of Portugal, in the Bering Sea off the coast of Alaska, and in the Arabian Sea off the coast of India, will be used to illustrate the author&apos;s point of view.

Jan 1, 1971

By Sandeep Kumar Jeripotula, Govinda Raj Mandela, Aruna Manglapady

Dozer operators are frequently exposed to whole-body vibration (WBV) during the execution of their work. Occupational exposure to WBV in Indian surface coal mines was evaluated by measuring vibration intensity and duration of exposure. A triaxial accelerometer was placed on the operator seat surface for taking the readings. Based on frequency-weighted root mean square acceleration equivalent to 8-hr shift duration, i.e., (A(8)) all dozer operators have exceeded an Exposure Action Value (EAV) of 0.5 m/s2 , and 90% of dozers did not exceed Exposure Limit Value (ELV) of 1.15 m/s2 . Based on Vibration Dose Value (VDV (8)), all dozer operators have exceeded Exposure Limit Value (EAV) of 9.1 m/s1.75, but no dozer operators have exceeded Exposure Limit Value (ELV) of 21 m/s1.75. Further, an epidemiological study was performed for identifying the extent of musculoskeletal disorders (MSDs) among dozer operators. For the detailed study, 42 dozer operators and 22 controls were selected from 2 surface coal mines. The control group was not exposed to WBV. It was seen from the cross-sectional study that pain in the lower back was predominantly higher (83.33%) in the exposed group when compared with the control group (31.81%). Likewise, pain in the neck (47.61%), shoulder (42.85%), knees (42.85%), and ankle (11.90%) was higher in the exposed group than that of the control group (22.71%, 0%, 45.45%, and 4.54%). A significant observation among the exposed group was that there was degradation in the quality of life. The outcome of the study would assist in monitoring and mitigation of machinery-induced vibration diseases (MIVD) in India and generally applicable to most of the mechanized mines as well. However, comprehensive studies are still needed to enunciate the magnitude extent.

By A Grace, C Sennersten, T Taylor, A Davie, R Lyu, D Pentecost, C A. Lindley, J Craig, L De Macedo Camargo

Many underground mine void spaces are not suitable for human entry due to unprotected roofs, instability or having an unknown safety state (eg if they are many decades old). Investigations of these voids may nevertheless be important for general mine safety, for example to detect propagating collapses or water accumulation, prevent accidental intrusion by new developments or drilling to reassess old spaces for re-mining. Robots are an ideal technology for investigating these spaces, especially flying, rotary-wing robots that can access and map vertical structures and spaces while avoiding rocks, water and mud that have accumulated on void floors. To operate in underground mines, we are developing customised unmanned aerial vehicles (UAVs) as well as interactive 3D virtual models of the vehicles and their underground environments for controlling vehicle operation and visualising incrementally gathered survey data. Using a game/simulation engine to provide an interactive interface for UAV operation makes it possible to orchestrate external spatial information and video feeds with in-game cameras for optimal visualisation that is not limited to the position, orientation or field of view of cameras mounted on the UAV. First and third-person points of view with respect to the UAV are provided, together with 2D and 3D gaze tracking to provide effective interfaces for geology and mine engineering experts without the need for specialist UAV piloting skills. Ongoing work is addressing the provision of greater levels of autonomy for these vehicles to support mapping well beyond the line of sight of operators and geological characterisation of rock surfaces using sensors mounted on them, including miniature X-ray fluorescence and Raman spectrometers. Gathered data is fed into more general 3D models of the mine, block models and orebody so that the UAVs function as elements of a mobile perceptual system for intelligent mining.CITATION:Sennersten, C, Lindley, C A, Davie, A, Lyu, R, Grace, A, Evans, B, Pentecost, D, Taylor, T, De Macedo Camargo, L, Craig, J, Salomao, G N, Hellicar, A, Biggins, D, Timms, G, Coombe, M, Shahriar, M S, Smith, G and Rahman, A, 2015. Unmanned aerial robots for remotely operated and autonomous surveying in inaccessible underground mine voids, in Proceedings Third International Future Mining Conference, pp 101–108 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By Peter Zhang

The immediate roof at the test site consisted of laminated clay shale that is likely to be susceptible to weathering. With seasonal dry-wet cycles in the mine ventilation air, the roof in the intake air would deteriorate and lose integrity over time. In many instances, the weathering-prone roof would gradually scale off piece by piece between bolts and over the entry corners. In some long-term entries, roof weathering could develop up to 2-3 ft deep with columns of bolted roof hanging under the upper intact roof. If wire mesh is used, the roof bags down and reduces the entry height, and the weight of the bagged roof tends to pull the bolts out and poses a safety hazard. An effective measure is always sought to support this type of weak roof that is sensitive to moisture degradation. One solution is to seal the roof shortly after entry development to prevent moisture penetration so that roof integrity can be maintained for the long term. In this application, a polymer-based sealing material was tested in the Rockspring mine for weathering protection and reinforcement. The material is a one-component polymer powder for spray application onto the roof and rib. The sealant material is mixed with water in the spraying nozzle to apply to the roof and rib as a paste. The product sets within 5-10 minutes and forms a membrane as thin as about 1/8-in. The membrane will quickly develop tensile and bonding strength within minutes and completely cure within a few days. Through sealing, bonding and lateral reinforcement, the integrity of the weak roof can be maintained. The material has been tried in a long-term evaluation over several months in a set of main entries in the Rockspring mine owned and operated by Rockspring Development, Inc., affiliate of Foundation Coal. Preliminary evaluation has shown that the material is an effective and economical solution to ensuring the long-term stability of weathering-prone roof.

Jan 1, 2009

By Sitotaw Y. Fantaye

"The first segment of the Second Avenue Subway extension is approaching construction completion. The new extension will operate along Second Avenue from 96th Street to 63rd Street, where it will divert west along the existing 63rd Street line, stopping at the Lexington Avenue/63rd Street Station. The new line will have stateof-the-art stations at 96th, 86th, 72nd and 63rd streets.Most of the two-track, twin-tunnel subway was constructed using bored tunnel methods (Figure 1), with a tunnel boring machine (TBM). The launch and retrieving box of the TBM was strategically located at the south end of the 96th Street Station where bedrock exists approximately 70 ft (21.3 m) below street level. The TBM launch box and the 96th Street Station (Figure 2), including the ancillary facilities adjacent to the station, were constructed by the cut-and-cover method. The cut-and-cover work required the contractor to design and implement a stiff, tightlybraced retaining wall, approximately 100 ft (30.5 m) long, to tie the existing tunnel constructed in the 1970s to the new station, temporary street decking over the entire excavation, and a wide range of excavation support systems at various locations.The cut-and-cover construction posed significant challenges including: installation of street decking on busy Second Avenue, relocation and suspension of the myriad utilities beneath the streets, and configuration of a lateral support system that would minimize movement of adjacent structures but not slow down excavation activities. This article describes the innovative solutions developed to manage and facilitate safe and efficient construction without disrupting Second Avenue, a major southbound one-way thoroughfare.The work was performed in several phases involving: (1) preconstruction condition survey of existing buildings, (2) installation of instrumentation and monitoring, (3) major utility relocation efforts to move vital utilities from within the alignment of the slurry wall on both the east and west sides of the avenue, (4) implementation of maintenance and protection of traffic plans, (5) installation of temporary street decking across the entire avenue and over the excavation to allow an orderly movement of traffic and pedestrians, (6) staged excavation and installation of an intricate temporary bracing system beneath the decking (7) step-by-step construction of the new subway station’s structure and (8) staged removal of the bracing as the structure gained sufficient strength to resist the lateral loads. The main focus in this article is the design and construction of the temporary street decking and lateral bracing systems; the utility suspension system and the north tie-in that allowed the daunting task of excavation and construction of a new subway station in bustling New York City, with minimal disruption to the community, businesses and everyday traffic."

Jan 1, 2016

By Neil F. Archer

Due to the increased chance of violations and shutdowns by the U.S Occupational Safety and Health Administration(OSHA) and the U.S. Environmental Protection Agency (EPA), a company can save itself problems by taking control of the dust caused by conveying material. A complete dust-control policy can keep these emissions confined, sealed and suppressed, protecting the environment from fugitive, airborne dust. Material handling and processing, storage and traffic are the major dust producing sources. All industries that convey dry, light material need a dust control system.

Jan 1, 2003

By F. L. D. Cloete, A. K. Haines, T. D. Sampson, T. H. Tunley, W. A. M. te Riele

The recovery of zinc from pickle liquors by ion exchange A. K. HAINES. Ph.D. (Visitor) T. H. TUNLEY. B.Sc;.(Chem.Eng.)(Visitor), W. A. M. TE RIELE. pr, Eng.. Ph. D. (Visitor), F. L. D. CLOETE. M.Sc. (Chem..Eng.)(Visitor), and T. P. SAMPSON. Pr. Eng.. BSc, (Chem.Eng,). B. Econ. (Visitor) Picklers and galvanizers in and around Johannesburg are encountering an ever-increasing problem in disposing of spent liquors from their hydrochloric acid pickling baths. Particularly troublesome is the zinc-contaminated liquor that is produced as a result of the clean-up of rejects from the galvanizing operation. Because of the volatility of zinc chloride. this liquor presents difficulties when processed in a conventional pyrohydrolysis acid-recovery unit. The paper describes the Metsep Process. developed by the National Institute for Metallurgy and Woodall-Duckham S.A. (Pty) Ltd. which involves the use of continuous ion exchange for the separation of the zinc from the pickle liquor. and the use of liquid-liquid extraction for the conversion of zinc chloride eluate to salable zinc sulphate. A description of laboratory and pilot-plant tests is given. and the approach used in the design of a full-scale continuous- ionexchange plant is outlined.

Jan 11, 1973