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By D. Majuste

This paper describes an experimental approach to evaluate the effect of organic impurities or even additives on metal electrowinning and product quality. In addition to electrowinning tests and electrochemical measurements, the approach includes organic analysis by Fourier Transform Infrared spectroscopy and gas chromatography; video monitoring of the reaction interface; and product characterization by using scanning electron microscopy, crystallographic texture and bending tests. The mechanical behavior of metal cathodes was assessed with a customized bending device that is able to bend the cathodes up to angles similar to that of the stripping machine. In this work, the effect of a potential organic impurity, lubricating oil, on the production of electrolytic zinc is taken as a case study. The findings of the investigation allowed a better understanding on the role of this organic on energy consumption and product quality and a qualitative prediction for the behavior of Zn cathodes during the stripping operation. Simple control and optimization procedures resulted in significant energy savings.

By A. Warczok

The heat transfer coefficient between liquid slags and solid surfaces is important for the design and operation of metallurgical reactors. An experimental technique developed for the purpose of measuring the heat transfer coefficient between liquid slags and solid metals is described. During the initial heating up of a Ni cylinder upon immersion in a liquid slag, a layer of frozen slag initially forms, then melts. The heat transfer coefficient measured during the initial rapid heat-up of the Ni cylinder, is approximately twice as high as the heat transfer coefficient measured during the final heat-up of the Ni cylinder subsequent of the liquidus temperature of the slag. The technique was tested in various melts i) NaNO3, ii) NaCl, iii) Na3AlF6 and iv) 2FeO*SiO2, giving consistent results. It was found that the heat transfer coefficient increases with increasing bath superheat and stirring. The heat transfer coefficient during the heating up following complete remelting of the frozen slag, is related to the slag superheat(AT) and the specific stirring energy(W) per kg of slag(E) as follows.

Jan 1, 1993

By Yasumasa Hattori

An extensive study including fluid dynamic calculations, cold model tests, pilot plant tests as well as measurements in a commercial flash furnace was carried out in order to develop a new Sumitomo flash smelting concentrate burner. The pressure measurements in the commercial burner indicated that the premixing of the concentrate and reaction air in a burner was insufficient. Pilot plant tests showed that enhancement of the premixing of the concentrate and reaction air is very effective for improving the burner performance. Using the additional pressure drop of the reaction air as an indicator of the premixing, a new type Sumitomo premixed concentrate burner was developed.

Jan 1, 2003

By Ulrich E. Klotz, Gemot Pottlacher, Shahid Mehmood

"Platinum alloys are frequently used in technical applications and in jewellery. Their thermophysical properties such as density, heat capacity, thermal conductivity and surface tension play an important role in casting processes and are required as input data for casting simulation. Scope of this work was to investigate these properties by different methods. Platinum and four alloys namely, Pt96Cu4, Pt68Cu32, Pt50Cu50 and Pt25Cu75 were investigated. Melting range and thermal expansion was measured at fem by DSC and dilatometry, respectively.At TU Graz wire shaped samples were investigated by an ohmic pulse heating technique. This technique allows the calculation of specific heat capacity and the temperature dependencies of electrical resistivity, enthalpy, and density of these alloys in the solid and liquid phase. Experimental results were compared with available literature and data from thermodynamic calculation using the SNOBl database and ThermoCalc.IntroductionPlatinum is a precious element and its alloys are commonly used in jewellery. But Platinum is much more difficult to cast then other jewellery elements like silver or gold, because of its high melting temperature, large shrinkage during freezing, low thermal conductivity, high surface tension, and high viscosity. As a result there arise problems during casting. Hence to resolve these difficulties a detailed study of thermophysical properties of solid and liquid platinum and its alloys is necessary for simulation and casting. The Platinum alloy samples were prepared by vacuum induction melting and casting into copper molds. Rods of 3 mm in diameter and a length of 80 mm were prepared and drawn to wires of 0.5 mm in diameter."

Jan 1, 2011

By M. K. Yelloji Roa

Effect of conditioning with Thiobacillus ferrooxidans on the floatability of sphaierite and galena has been determined in this work. The flotation behavior of the conditioned minerals clearly shows that such bacterial conditioning does produce marked modification of their surfaces. The variables affecting the surface modification and thereby the flotation response of the minerals were found to be cell concentration used for bacterial conditioning, the period of biotreatment and the pulp density. Importantly, while the enhancement in flotation obtained due to sulphuric acid treatment was retarded by biotreatment in the case of galena at all cell concentrations due to electrochemical effects, such decrease occurred in the case of sphalerite only at cell concentration sufficiently high for their attachment to the mineral surface. The effect of bacterial conditioning has significant implications to the differential flotation of sphalerite and galena. Mechanisms responsible for the modification of the surface properties of these sulphides due, to bacterial conditioning are discussed.

Jan 1, 1991

By Boyd Davis, Vladimiros Papangelakis, Joshua LaMarre, Jan de Bakker

"HCl leaching using molten salt hydrates has the potential to improve the extraction of nickel from laterite ores. However, as in other HCl leaching applications, recovery of HCl is key to process economics. Spray pyrohydrolysis, which is used in current chloride-based flowsheets, is associated with a high energy cost. The authors have developed a proposed laterite leach circuit using an alternative HCl recovery route. The leach circuit envisions a leach by concentrated (33%) HCl in an MgCl2 molten salt hydrate (MSH) or brine medium, followed by Ni/Co recovery and iron precipitation. Magnesium and chloride are precipitated from solution as magnesium hydroxychloride; this hydroxychloride is thermally decomposed to produce HCl gas. The proposed flowsheet employs a chloride leach circuit with simpler equipment and lower energy cost than in the conventional practice of pyrohydrolysis. Laboratory work investigated key aspects of the flowsheet, including precipitation of magnesium hydroxychlorides and their composition; magnesium hydroxychloride thermal decomposition; and iron control.Introduction As sulphide nickel ores become harder to mine and more complex to process, laterite ores will increase in importance. Laterite ore deposits can be divided into two main mineralogies. Limonite ores consist mostly of hydrated iron oxide, FeOOH, with 1-3% nickel substituting for the iron. Saprolite ores consist of iron-magnesium silicates, (Fe, Mg)2Si04, again with some nickel substituting for the metal ions. Limonite ores can be treated using the HP AL (High Pressure Acid Leach) process, in which the ore is reacted with sulphuric acid at high temperature in an autoclave. HP AL, however, cannot in general be used to treat saprolite ores because the magnesium enters solution and consumes sulphuric acid, which results in excessive spending on lixiviant. It is therefore desirable to find a hydrometallurgical process specifically for saprolite ores that can provide better results than the treatment options currently available."

Jan 1, 2011

By G. A. Brooks

Increasing interfacial area through gas injection is one of the main methods for accelerating reaction between slag, metals, and gases in modern pyrometallurgical reactors. In slag-metal reactors, the generation of a large number of metal droplets into the slag phase through high gas velocity has a much larger effect on the overall kinetics compared to the enhanced mass transfer through mixing. Top blowing technology generates large interfacial areas (>300 m2/tonne) through high impingement gas velocity at short distances between the exit of the injection lance and the metal-slag interface. Phase separation may become a limit at the case of very high interfacial areas, though there is still only limited understanding of the trajectories of metal droplets in slag-metal-gas emulsions.

Jan 1, 2003

By E. Oshima

In May 1991, a New Mitsubishi Continuous Copper Smelter Line started operation at Naoshima. Recently, it has been continuing steady operation and one and a half year campaign life has been achieved. In 1996, new records of on line time, the amount of copper concentrate treated and copper anode production were achieved. 1t proves the superiority of the process with respect to pollution control, energy efficiency, flexibility and easiness of the operation and over all economy including off gas handling cost. Furthermore, .plans are underway to prolong the campaign life for two years and to improve the process efficiency. This paper describes recent operation, improvements, and a future capability study.

Jan 1, 1998

By George Oprea, Tom Troczynski, Joe A. Rigby, Waiman Lo

The refractory lining of the tuyere line in Peirce Smith converters have usually much shorter life in service than the rest of the lining, above or below it. There are already recognized chemical, thermal and mechanical factors which contribute to the wear of the lining. Our study presents the experimental results on microstructural changes occurring on these tuyere line bricks in a nickelcopper converter. The experimental bricks, after use at the tuyere line, were investigated using SEM/EDS and XRD techniques, to identify the mineralogical changes due to interactions with the nickel-copper matte or fayalite type slag at the process temperatures. The microstructural changes were correlated with physical and mechanical properties of the brick before and after use and a wear mechanism was suggested. Although the matte does not theoretically react with the mineralogical components of the brick, a partial oxidation of the Ni-Cu sulphides was identified using a line analysis by SEM/EDS in the densified layer at the hot face, which allows for mineralogical changes at the matte-refractory interfaces, with a high probability of microcrack formation due to the thermal cycling during use. These microcracks were also identified to open through inter-granular fractures parallel to the hot face, which appeared to be the main cause of lost lining during use. The reactions between the fayalite slag and refractory brick could eventually play a role in chemical dissolution of the brick only in the superficial layer at the hot face, as no slag components were identified deep into the brick.

Jan 1, 2009

By Abhishek Lahiri

Titanium dioxide is extracted from titaniferous ores by chloride and sulfate processes. These two processes produce wastes in the forms of iron chloride, iron sulfate and rare earth oxides gangue, each of which has to go through a further treatment before it can be disposed safely, which may be expensive. The shortage of high-grade ores is also making the two conventional processes less efficient. In view of the above mentioned problems, an alternate beneficiation process of roasting titaniferous ores with soda ash is discussed. The advantage of this process is that, there is no production of wastes. The impurities present in the ore can be selectively separated after the roasting process. The roasting of titaniferous ores with soda ash was carried out between temperatures of 873K and1173K for several hours. The roasting process resulted in the formation of complex alkali compounds and various sodium titanate compounds, depending on the Na2CO3to ore ratio. The phases formed after roasting were characterized using the X-ray powder diffraction (XRD), X-ray florescence (XRF) and scanning electron microscopy (SEM) techniques. The phase equilibria in the Na-Ti-O system are evaluated and compared with the phases obtained after the roasting process. The effects of temperature and the proportion of sodium carbonate on titaniferous ores are also discussed. From the experimental data, the overall reaction kinetics and phases formed were analyzed to ascertain the mechanism of overall reaction and the rate-limiting steps.

Jan 1, 2006

By J. P. Schde

The authors deal with nickel production and usage patterns, nickel's first-use and end-use, examples of nickel applications in modern technology, e.g., energy generation and conservation, environmental protection, the oil and gas industry, construction and machinery, food production, conservation and distribution, consumer durables and the like. A special section of the paper is devoted to new applications of nickel in the electronic industry, modern corrosion control and the building and construction industries. The need to defend traditional markets for nickel while striving to find new applications, is also stressed.

Jan 1, 1988

By Thomas P. Battle

Ilmenite (iron titanate) is the source of over 90% of all the titanium produced in the world today. At some point during production of titanium dioxide or titanium metal the iron impurity must be removed. Too often it becomes a waste instead of a product. DuPont and MINPRO have developed a solid-state process which separates the iron and titanium components of ilmenite into different high-purity powders, which can be separated using conventional mineral processing techniques. The main reactor in this process is a unique high-temperature ball mill, where the iron segregates from the ilmenite lattice with the assistance of catalytic quantities of He\. The results of lab, pilot plant, theoretical, and scale-up studies are presented and discussed.

Jan 1, 1996

By Tam Tran

Most new gold mines in Australia are required to treat tailings to reduce cyanide levels before they are discharged to storage ponds to meet the stringent environmental management guidelines set by government statutory authorities. In New South Wales, the average level of weak acid dissociable cyanide allowed in open tailings dams is now limited to 20 ppm, As stringent environmental guidelines continue to be enforced in Australia as well as in other parts of the world, the management of cyanide wastes has emerged as a key issue for the gold mining industry. This paper provides a critical evaluation on technical aspects related to the use of ion exchange resins and affiliated processes in cyanide management and tailing treatment. Particular attention is given to the use of ion exchange resin technologies in the processing of mixed gold-copper ores, where cyanide usage is the highest. Information presented in this paper is heavily drawn from the experience on the application of ion exchange resin processes at May Day mine, in New South Wales, Australia and associated pilot plant test programs. Issues related to the management of thiocyanate, especially with respect to the recovery of cyanide from thiocyanate are also discussed.

Jan 1, 1998

By Shize Jin

Effect of four polyols, namely ethylene glycol (EGL), glycerol (GCL), propanediol (PDL), butanediol (BDL) and three organic acids, namely oxalic acid (OA), malonic acid (MA) and succinic acid (SA) on the current efficiency (CE) and the cell voltage during zinc electrowinning was studied. Galvanostatic polarization was conducted in a supporting electrolyte (SE) containing 180 g dm-³ H2SO4, 60 g dm-³ Zn2+ and 8 g dm-³ Mn2+ at 38°C with magnetic stirring. The imposed current density was 50 mA cm-². The anodes were made of a Pb-Ag alloy and the cathodes were made of an aluminum alloy. The results showed that all the polyols tested in this study decreased the current efficiency and the cell voltage, but the decrease of the cell voltage was not important. Oxalic and succinic acids decreased the current efficiency to a less extent than the polyols, but did not decrease the cell voltage much. The only compound that increased the current efficiency was malonic acid, and its capacity of decreasing the cell voltage was the highest within the seven tested organic compounds.

Jan 1, 2003

By M. I. Novgorodova

Most of the gold in the earth's crust occurs as finely-dispersed gold and accounts for much of the gold lost in extraction processes and during exploration for gold. The Compositions, sizes, and morphology of fine gold particles (0.01 to 10 ~m in diameter) were studied with high resolution electron microscopy coupled with electron microprobe and microdiffraction devices, using colloidal carbon replicas. Correlations were made between fine gold, mineral associations and ore genesis. The results provide qualitative information on the proportions of finely dispersed, invisible and visible gold distribution in ores. Such knowledge is fundamental when planning an optimum technological recovery process.

Jan 1, 1991

By Ivan Imris

The common problem of new and conventional technology of copper production is the copper losses in the slags, which may be divided into mechanical and physico-chemical losses. In the first group can be included particles of mechanically entrained or floated unsedimented matte particles which coexist with slag. On the other hand, the physico-chemical losses are caused by solubility of copper in the slag in the form of sulphide and oxide. The copper losses in the slags from different processes has been predicted by calculation from thermodynamic data and compared with those determined by microscopic examination and quantitative electron microprobe analysis. Depending on the forms of copper losses in the slag the reduction of copper losses in the slag or the slag cleaning process could be suggested.

Jan 1, 2003

By Stephen M. Testa

Several methodologies are available for the remediation of contaminated soils including bioremediation, vapor extraction, chemical fixation, incineration and direct disposal. A proven innovative and cost effective alternative for the fixation of contaminated soils is via cold-mix Environmentally Processed Asphaltm (EPA"'). EPAm methodology utilizes contaminated soil as an ingredient in an industrial process to produce a commercially viable product. Petroleum hydrocarbon and metal affected soil is incorporated with a water-based asphalt emulsion and varying amounts of aggregate to produce a range of cold-mix asphaltic products that fulfills the requirements of a variety of end uses. This viable and creative use which is within the intent and spirit of current regulations in producing, in lieu of a landfill waste, an end product for use as a berm, road base, liner, or other site specific application. Consideration of certain engineering and environmental factors including durability, stability, chemical resistance and ageing, biological resistance, permeability, leachability and geochemical aspects suggests that cold-mix asphalt incorporation of affected soil will perform more than adequately under normal conditions for a long period of time.

Jan 1, 1994

By Martin Reyes, Juan Hernández, Julio Cesar Juárez, Isauro Rivera, Ma. de los Ángeles Hernández, Francisco Patiño

The dissolution of Ag contained in metallurgical tailings was studied by adding ions Cu2+ and Zn2+ in S2O3 2- medium. Chemical analysis of mine tailings by cupellation revealed a Ag concentration of 71 g/ton. The XRF and XRD analysis confirmed the preponderance of SiO2 in the mineral matrix. The experimental dissolution process was conducted in alkaline solution using six concentrations of NaOH and five of S2O3 2-, at different temperatures, also using five concentrations of Cu2+ and Zn2+ as a catalyst. The results showed similar values for both systems (96.8% and 97.13%). The ion Cu2+ and Zn2+ increases the dissolution of Ag, and decrease the reaction time of dissolution. Under the conditions used, pH and stirring rate did not affect the dissolution of Ag.

Jan 1, 2015

By Linfeng Zhou, Yuanbo Zhang, Rong Sun, Guanghui Li, Zhiwei Peng

The volatilization behavior of rhenium in the process of oxidative roasting of a molybdenite concentrate with 43.55 wt.% Mo and 321 g/t Re is explored based on identifying the relationship between volatilization of sulfur and rhenium. The results show that rhenium volatizes after sulfur and precise control of operating variables plays an important role in separating rhenium from molybdenite concentrate. When the roasting parameters are optimized as follows: roasting temperature 600 oC, roasting time 2 h, roasting atmosphere air, the volatilization rate of rhenium reaches 89.26%. In the process of solidification roasting, the volatilization rate of rhenium decreased almost to zero when the ratio of slaked lime/molybdenum concentrate was 10% excess to the stoichiometric requirement at 600 oC for 2 h.

Jan 1, 2016

By T. T. Chen

This mineralogical study is based on samples from typical "wet" nickel laterites of humid tropical to sub-tropical regions. An in-situ nickel laterite sample from Goro and a transported laterite sample from Plaine des Lacs, New Caledonia, are predominantly limonitic. Two-thirds of the particles in the Goro sample are <10 um in size; they consist of skeletal goethite and serpentine, as well as minor amounts of talc, gibbsite, chlorite, quartz and clay minerals. The coarser grains are mainly Cr-spinel, serpentine, gibbsite and Mn oxide. Nickel occurs mainly in goethite, serpentine and Mn oxide; cobalt occurs in goethite and Mn oxide. The Plaine des Lacs sample is finer-grained and contains more Al and CO3, but less Mg and Si than the Goro material. The sample contains more kaolinite, chlorite, siderite and feldspar, but less serpentine and gibbsite than the Goro material. Nickel is detected mainly in goethite, serpentine, Fe-Mg silicate and Fe-Mn oxide. The Indonesian ore from Sorowako, as sampled from the reduction kiln feed containing some reverts, is predominantly saprolitic, with apparent particle sizes ranging from <100 um to > 1 cm. The sample of reduction kiln feed is rich in Mg silicates, Mg-Fe silicates and goethite, and exhibits complex alteration textures. The nickel contents vary from particle to particle. Nickel is present mainly in serpentine, olivine, chlorite and amphibole, and in subordinate amounts in goethite and Mn oxide. Cobalt is detected in the Mn oxide. Keywords: Nickel Laterite; Mineralogy; Nickel Carriers; Goro, New Caledonia; Plaine des Lacs, New Caledonia; PT Inco., Sorowaki, Indonesia

Jan 1, 2004