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By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

By Jaime Lomelin

[First of all I want to thank the Society of Mining Engineers of AIME for the opportunity to present what Industrias Penoles, S.A. is doing in Mexico to reach the basic objetive of the enterprise without compromising, in short or long term, the living conditions of the community or attempting in an irreversible form against Nature. Industrias Penoles, S.A. is one of the largest mining and metallurgical companies in Mexico. It was founded in 1887 and at the turn of the century installed a lead smelting operation close to the village of Torreon, which became city five years after the start up of the Penoles smelter. Now Torreon has a population close to 300,000 inhabitants. In 1974 Penoles is still the largest industry in Torreon and the dynamic growth of the city is close related to this factor. Today Penoles in Torreon has a lead smelter with a capacity of 130,000 metric tons/year of bullion, an electrolitic zinc plant of 105,000 metric ton/year, and it is modernizing its lead smelter to control pollution and expand it to 190,000 metric ton/year of bullion including all the services and refinery. The Penoles complex in Torreon is the biggest in the non-ferrous metals field in Latinoamérica.]

Jan 1, 1974

Flotation of dolomite from apatite was investigated, using dodecylamine hydrochloride or sodium oleate as the collector, in the absence and presence of inorganic modifiers such as sodium chloride. Separation of dolomite from apatite was anticipated from the single mineral experiments under various pH and collector concentration conditions. Flotation selectivity in the mixtures, however, was found to be limited. Attempts to control the flotation response of these minerals by addition of salts such as NaCI and KCI indicated that selectivity is possible. The presence of sodium chloride was determined to depress apatite flotation using sodium oleate leaving dolomite flotation unaffected (Moudgil and Ince, 1989). In this paper, conditions for optimum separation and the effect of major parameters on the desired selectivity are discussed.

Jan 1, 1990

By Leon D. Keller

Fine screening, as discussed in this paper, pertains to the use of the Rapifine DSM Screen to make a 65 to 325-mesh separation at production tonnages. The greatest number of Rapifine Screen installations are in magnetic taconite plants where the unusual relationship between the grinding mill, cyclone classifier, magnetic separators, and fine screens makes the Rapifine Screen application unique. Since the initial fine screening installation on magnetite in 1961, (1) additional installations and further testwork have contributed to the fund of information which is the basis of this paper. The addition of fine screens to the grinding-classifying circuit of a magnetic taconite plant creates a change that effects all components of the circuit. Pine screens in a non-magnetic plant have also been investigated, but here the benefits have not' been as clearly defined. Screens classify according to the particle size. Hydrocyclones classify by a combination of particle size and particle weight. The change in the type of classification minimizes overgrinding of the mineral. The resultant savings in grinding power can be used to increase the throughput, upgrade the product, or increase recovery.

Jan 1, 1971

By C. Anastasiadis

The wettability of sandstone was investigated using the technique of dielectric spectroscopy in the frequency interval 1kHz-1MHz. The natural wetness of the material was modified to get two different sets of samples, one with sea-water wetness and the other with crude oil wetness. Measurements showed that the electric responses of water-wet and crude oil-wet samples were markedly different beside the fact that the dielectric response of both groups of samples obeys a general fractional power law. The dispersivity, of the complex permittivity component that expresses the material loss with respect to the electric field was found to be the most suitable parameter to check the wettability of the samples.

Jan 1, 2005

By K. F. Clark

Some 30 years ago Stevenson (1940) underscored the fact that most of the world's molybdenite production came from the Cordillera that comprise the western part of North America, and that the northern extension of the Cordillera into British Columbia is not essentially dissimilar to the United States section. Therefore, in view of the successful development of molybdenite resources in the United States, he concluded that prospecting in the Canadian section f the Cordillera should be encouraged. However, as recently as seven years ago Schneider (1963) remarks that no large economic deposits have been brought into production in British Columbia, although one important property was being evaluated. World production f molybdenum ore was sporadic until 1900. Among the very early producing areas in North America were Arizona and New Mexico in the United States. World War I provided the stimulus that brought the Climax deposit into production, and in 1920 Questa, New Mexico followed, although the ore came from fissure vein deposits at that time. In the early part f this century high grade deposits in various parts f the world containing 5-20 percent MoS2 were exploited. In Canada most production during World War I came from Quebec and Ontario. With the build-up of world tension and the inception f hostilities in 1939, British demand was satisfied by United States producers (Schneider, 1963).

Jan 1, 1970

By Edoardo Misano, Magali Schivre, Martino Semeraro, Alain Bochon

"INTRODUCTIONThe Laboratoire Souterrain de Modane (LSM) is an underground research laboratory located in the Western Alps on the French – Italian border. It is located in the middle of the 13km long Fréjus highway tunnel that links Modane (France) to Bardonecchia (Italy) in correspondence of the highest overburden of 1800m. The LSM current activity is mainly based on the investigations about the dark matter and requires very sensitive instrumentation which shall be protected from cosmic rays. To comply with the new legislation about safety in tunnels, the highway tunnels owners agreed in 2007 the construction of a parallel safety tunnel, at an average distance of 50m from the existing tunnel and the laboratory owner CNRS (Centre National de recherche scientifique) also decided to extend the existing laboratory with the construction of a new 17000 m3 cavern allowing the installation of wider and more powerful instruments that could increase chances of success of research. Preliminary studies stated that, considering both geological and functional issues, the most appropriate location for the new laboratory shall be in between the two tunnels and parallel to the existing laboratory (see Figure 1).Hence, the CNRS asked Systra, already in charge of the works supervision of the safety tunnel, to realize the design of the new cavern. The laboratory extension includes the construction of a 40 m long cavern with 300 m² cross section and two smaller tunnels connecting the safety tunnel and the existing laboratory to the new cavern. The minimum distance between the front face of the new LSM and the highway tunnel is about 25 m.The French and the Italian authorities, responsible of the exploitation of the Fréjus highway tunnel, asked the CNRS to develop an accurate study indicating that the construction of the laboratory extension would not have any negative impact on the existing structures of the highway tunnel. The main results of the developed study by Systra are summarized hereafter. The construction works should begin prior to the end of the construction works of the Fréjus safety tunnel in 2018."

Jan 1, 2016

By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

Historically, as for most reagents used in flotation, the wide-spread use of dialkyl dithiophosphinates as collectors in practical applications has preceded a detailed scientific understanding of how they work. Dialkyl dithiophosphinates are a technologically and commercially important class of collectors used in the flotation processing of Cu-Au, complex polymetallic, and precious metal ores. Plant usage has demonstrated that dithiophosphinates exhibit higher selectivity and flotation rates for Cu sulfides, galena, and precious metal values in the presence of other gangue sulfides, than the traditionally used collectors such as dialkyl dithiophosphates and xanthates. They also have an attractive health, safety, and environmental (HSE) profile. Although dithiophosphinates received little attention in the past in the flotation research community, recently, there has been significant interest in this chemistry, and numerous studies have been conducted to understand the fundamental interactions of dithiophosphinates with several base metal sulfides and precious metals. A critical overview of fundamental studies, laboratory ore flotation, and plant practice of dithiophosphinates is given in this paper. The findings from these studies are rationalized and explained by drawing on concepts and insights from coordination chemistry. A comparison between the interactions with various minerals and metals of dithiophosphinate and dithiophosphate analogues brings out some of the subtleties that seemingly minor changes in collector chemistry can make. The critical overview and analysis given here is useful in identifying gaps in knowledge regarding this important class of compounds. This in turn can provide a basis for the design of studies to advance our understanding of dithiophosphinate flotation performance.

By J. V. Bymark

It is the intent of this paper to discuss the autogenous grinding circuit at Hibbing Taconite. The scope of the presentation includes; a brief history, the process flowsheet and the steps taken to improve mill productivity, availability and metallurgical performance. Hibbing Taconite is located near the center of the Mesabi Range in Northern Minnesota 100 miles from the Canadian border and 80 miles north of the Lake Superior Port Cities of Duluth and Superior. A 105 mile railroad connects us with the port of Superior, Wisconsin, where our pellets are loaded into lake carriers for lower lake destinations. It is worthy to mention the Mesabi Range's most famous landmark which is immediately to the south of our mine area. This is the Hull Rust Mahoning Mine which operated until the mid-1970's producing more than 700 million tons of red ore between 1893 and 1973.

Jan 1, 1985

By Henry S. Brown

At least two dozen massive sulfide deposits in the southern Appalachians have supported significant mining operations. Literally hundreds more deposits are known to exist, but are too small to be of commercial interest. Essentially all that are being, or have been, mined are those deposits that were exposed at the surface when first discovered. It is reasonable to assume that many more massive sulfide deposits, large and small, exist hidden not far beneath the surface. The ideas I am sharing with you here today are based both on my personal studies of some of the deposits and on descriptions of deposits in the literature. An attempt will be made to account for the genetic interpretation problems raised by many of these deposits posessing both "syngenetic" and "epigenetic" features. In addition, an examination will be made of the possible relationships between the massive and the not-so-massive sulfide deposits in this region. Hopefully, these observations added to those of others will eventually lead to the synthesis of a better model on which we can base exploration programs in the southern Appalachians.

Jan 1, 1976

By Kal V. S. Sastry

Mathematical and expert system models are being used extensively for mineral process engineering. There exist no standardized methodologies for their computer implementation. In meeting this need, this paper introduces the concept of a process software model, or simply a software model and presents a two-step methodology for its development involving software model specification and development. The software model specification is to be performed after extensive discussions with the ultimate users of process software based on which the software model is developed. These software models provide a formal basis for the design and construction of software objects corresponding to the real world process objects.

Jan 1, 1994

By D. F. Cater

The Macassa Mine is a mature mine with a 61 year history of continuous production. The majority of past production has been derived from a zone called the '04 Break (Main Break). Recent underground mine exploration has been successful in locating several neighbouring ninera1ized zones. This paper will characterize the spatial location, geometry and mineralogical properties of these secondary zones. Future plans for underground mine exploration to follow-up on these target zones will be outlined.

Jan 1, 1995

By J. S. Peterson

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Center (PRC), has conducted research to improve electrical fault detection on coal mine direct current (dc) trolley systems. Present circuit breaker protection systems are current-magnitude-based and cannot discern between normal traffic and high resistance electrical faults. Tests were conducted at cooperating mines to assist in developing a neural-network-based detection algorithm for distinguishing between electrical faults and normal operation. The Fast Fourier Transform of the trolley rectifier current signature served as baseline data for the neural network. During field tests, the algorithm performed with greater than 90% accuracy.

Jan 1, 1997

By D. G. Ball

Other than being used to convey fill material for the gob stowage or building of ribside packs on advancing longwell faces, pneumatic conveying has not been used for the transport of materials on a large scale in mining operations. The technique is extensively used in the wood products industry for conveying wood chips, limestone and other ingredients for the manufacture of paper, for the transfer from railcars, barges or ships to silos or stockpiles and further transfer into the pulp mills. This method of material transfer has the distinct advantage of transporting suitable material over horizontal and vertical distances within the same system. In considering material associated with mining, this includes, ore, coal and rock up to 4 inch cubed size, throughputs of 200 tons per hour over horizontal distances of 3000 feet or vertical lifts of 2000 feet. In recent years tests have been carried out to determine the physical and economic limitations of pneumatic hoisting, the results of which have led to the installation of two fully productive coal hoisting systems at mines of the National Coal Board in Great Britain. The equipment used for the pneumatic hoisting of coal or waste rock is described in this paper, together with a brief history of the tests which led up to the installation of the two hoisting systems in Great Britain.

Jan 1, 1977

By C. Ptacek, D. Hiller, J. L. Janbor, H. Mccreadie

Between 1991 and 1994, metallurgical residues from a pressure-oxidation autoclave at the Campbell Au-quartz mine at Red Lake, northern Ontario, were neutralized with dolomite-rich flotation tailings and were deposited in a polyethylene-lined disposal area. Mineralogical analysis indicates that most of the As occurs as a crystalline ferric sulfarsenate, and some is associated with Fe oxides and with K-H3O jarosite. Field pore-water geochemical data from 1994 and 1995 showed increases in Fe(II) and As(III) concentrations, suggesting that the sulfarsenate and jarosite are dissolving; none of the discrete As phases included in a thermodynamic database limit dissolved-As concentrations, and these concentrations may continue to increase. These results demonstrate the potential for Fe and As loading through groundwater systems.

Jan 1, 1998

By B. M. Davis

Frequently ore reserve studies utilize samples from a series of drilling or other types of sampling campaigns. Sometimes there is a mix of sample types, say for instance, channel samples from underground workings and drill core from surface drilling. Since drilling, sampling, logging, and sample preparation protocols tend to change over time, there is always a question whether the samples give similar results that vary only by chance alone. The problem of comparing the various campaigns is complicated by the presence of spatial relationships among the samples. Geostatistical tests take the spatial correlation into account, but these tests may be complicated and cumbersome to implement. A comparison method based on familiar statistical graphics is presented which accounts for the spatial relationships. It allows comparisons to be made quickly by using simple statistical graphs such as scatterplots and boxplots.

Jan 1, 1996

By Tania Schmid, Marco Portal Valdivia, Sandra Nowosad

Today’s mining industry faces rapid transformation driven by automation, climate responsibility, and ESG demands, requiring more than technical expertise. Future mining engineers must blend engineering excellence with key human skills such as communication, leadership, resilience, empathy, adaptation to change, curiosity and lifelong learning. Based on two recent surveys, one to senior leaders with over ten years of experience in the mining industry and a second, focused on understanding the perceptions of young professionals, this paper explores which skills become core competencies by 2030 for navigating complexity, leading responsibly, and enabling sustainable transformation. Furthermore, it also examines how educational institutions can adopt strategies to foster the development of these critical skills, preparing future mining talent for evolving challenges.

Feb 22, 2026

By M. L. Free

Acid consumption in copper heap leaching is determined by the minerals present in the ore. Gangue minerals such as biotite and chlorite consume acid together with copper-bearing minerals such as chrysocolla and malachite. Acid consumption is affected by the rate of acid application and the particle size. Some gangue minerals undergo alterations and cause precipitate formation during acid leaching. Other minerals form due to precipitation as dissolved ion concentrations from a variety of mineral sources combine to exceed saturation levels. Copper recovery is related to all of these events. This study presents information on acid consumption of various gangue minerals as well as data for copper recovery from an associated copper ore.

Jan 1, 2010

By John K. Liu

The trend to larger grinding mills, requiring total drive power in the range of 10,000 KW(13,400 HP) or so provides the incentive for developing new power transmitting techniques, since conventional girth gears are limited to about 3700 to 4500 KW per mesh (5000-6000 HP). For the immediate future, the synchronous motor, with its beneficial power factor, and the squirrel cage induction motor, with its high reliability record and low maintenance, still promise to be the best choice for prime mover(s). Due to the abovementioned single mesh power limitation of the gear train, however, two or more motors must be combined to attain the required drive power. This paper describes a scheme for coupling these motors to the mill using a straightforward, essentially mechanical means that is based on proven components and controls.

Jan 1, 1977

By S. Hearn, S. Boskovic, A. Smethurst

"The digestion of minerals in strong acids or at elevated temperatures can result in the release of large amounts of silicic acid which can polymerize in solution to form colloidal silica and gels. Colloidal silica can cause a number of problems including interfering with flocculation, initiating crud formation in solvent extraction (SX), decreasing SX extraction kinetics and increasing SX phase disengagement times. Huntsman’s POLYSIL® polyether coagulants have a “lock and key” relationship with the surface of colloidal silica to help lower the concentration of these particles in solution, improve process efficiency and reduce reagent losses by minimizing crud formation. This paper investigates some of the issues caused by colloidal silica in hydrometallurgy processes and illustrates how the use of POLYSIL® coagulants has helped to improve process outcomes. INTRODUCTION Coagulation differs from flocculation in a number of ways. Coagulants are relatively small molecules that modify the surfaces of fine particles, weakening repulsive forces between them and allowing particles to stick together, while flocculants are generally molecules that are large enough to bridge the boundary layers between the particles. With flocculation, addition rate and mixing all make a difference to the flocs formed. Coagulation, on the other hand, is an equilibrium process. With coagulation it is only necessary to achieve good mixing, and coagulates will form as Brownian motion pushes the particles into each other. In real systems, this process is complete within seconds. Huntsman’s POLYSIL® polyether based coagulants have a strong affinity with the surface of colloidal silica formed by the polymerization of silicic acid. While silica found in minerals has a low aqueous solubility, large amounts of silica as silicic acid can be released as these minerals are digested in strong acids at elevated temperatures. The solubility of free silicic acid is about 150 ppm under pH conditions typical in acid leach environments (1), so the bulk of the silica will polymerize in solution to form colloidal silica. Colloidal silica can pass through a hydrometallurgy process without affecting any of the operations. However, it can cause a number of problems. These include gelling in a leach, interfering with flocculation or crystallization, initiating crud formation (2,3,4), decreasing extraction kinetics and increasing phase disengagement times (5,6) in solvent extraction. In these cases, coagulating the silica with POLYSIL® coagulants can reduce or eliminate the problem by enabling these particles to be flocculated and removed from the solution."

Jan 1, 2015