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By Gerald W. Elger

Research at the Albany Metallurgy Research Center has shown that high-purity rutile can be produced from relatively low-grade ilmenite obtained from a massive rock deposit. Ilmenite is first smelted in an electric-arc furnace to separate the iron and produce a slag enriched in titanium dioxide. Titania slag mixed with a phosphate flux is then oxidized to synthesize rutile and form a phosphate-glass matrix which contains the impurities. Attrition scrubbing the treated slag in dilute solutions of phosphoric or sulfuric acid liberates the rutile, which is concentrated by physical methods. Tests show that synthesized rutile containing 95 to 97 pct titania responds to chlorination at the same rate as natural rutile.

Jan 1, 1973

By Y. Luo

Although considerable progress has been made in the last decade in predicting surface subsidence over longwall panels, a number of important issues deserve further studies in order to improve the techniques and accuracy of subsidence predictions. Some of the problems are: (1) subsidence over the chain pillars between mined longwall panels; (2) subsidence development process after face stop due to either a vacation or the completion of a longwall panel; and (3) subsidence initiation and development process over the setup entry area in the initial stage of mining a longwall panel. In this paper, the measured data related to the targeted problems are presented, the data analysis techniques are briefly introduced, and some of the prediction methods developed based on the collected data are proposed. The proposed methods can be used as supplemental tools for the existing subsidence prediction models to improve their prediction accuracy.

Jan 1, 1991

By D. R. Taylor

Treatment of bentonite clay with mineral acids yields a modified clay product of high surface area and acidity which exhibits enhanced adsorptive and catalytic properties. A highly specialized segment of the clay industry based on this process has evolved into worldwide business with a capacity of about one-half million tons/yr. This paper will present data on the chemistry, mining, manufacturing and applications for acid- activated clays.

Jan 1, 1986

By I. Raposo, I. Moreno-Ventas, A. Palma, M. J. Díaz, M. Vázquez

The oxidative degradation kinetics of chalcopyrite have been studied by thermogravimetric analysis (TGA). The obtained data are necessary for the kinetic description of the flash fusion process, which can contribute to the optimization of the smelting process in copper extractive metallurgy. Activation energy (Ea) evolutions of the involved processes have been determined by several isoconversional methods; in this sense, the chalcopyrite oxidation processes could be adequately described, among studied models (E1641–16, Ozawa–Flynn–Wall, Kissinger–Akahira–Sunose and Friedman), by the Kissinger–Akahira– Sunose kinetic model. Using this method, Ea and A values are found to be very dependent on the conversion. Under lower conversion levels, higher Ea and A values have been calculated with respect to that found for medium and higher conversion levels.

By G. H. Roybal

Humic-acid-rich deposits exist in Arkansas, Florida, Louisiana, New York, North Dakota, Michigan, Minnesota, Texas, and Wyoming (Burdick, 1965) and in New Mexico (Shomaker and Hiss, 1974). New Mexico humic deposits are associated with coal in the northwestern part of the state where humate and weathered coal are presently mined. Discussion of the humic -acid industry in New Mexico requires an understanding of complex terminology and coal geology. TERMINOLOGY Humic material is not a pure substance so an ambiguous and complex terminology is in use by geologists, chemists, soil scientists, agronomists, and producers. Material mined for its humic-acid content is an extremely variable mixture of base-soluble humic, fulvic, and ulvic acids and their salts, formed during partial or complete decay of organic matter. This decay releases a high-molecular-weight organic material which is darkly colored, partly colloidal, and weakly acidic.

Jan 1, 1985

By J. C. Watts

Monitoring and control of conventional industrial wet grinding circuits is conceptually straightforward. However, since production objectives and operating constraints can vary widely from plant to plant, there is probably no single overall grinding circuit control strategy which is "best" in all cases; in-variably some compromise is necessary between performance desired under ideal conditions and performance achievable in practice. The recent advent of relatively low cost, reliable, high speed small computer systems is revolutionizing daily operations in increasing numbers of metallurgical processing plants. Of special power and capability is a hierarchical computer network like that currently in use at the Pinto Valley Operations of the Cities Service Company. Several satellite processors for key plant areas communicate with a master computer operating under a powerful multitasking real-time operating system. Hardware and software structure is such that downtime on one of the processors -including the master -does not have a major impact on overall system operation. Admittedly, the powerful, core efficient table driven satellite software, which handles process/computer communication, calculation of nonmeasured process variables, and basic Direct Digital Control functions, is difficult to modify. However, important high level process monitoring, report preparation, graphic display, and supervisory control functions -including economic optimization -can be implemented by project engineers at the plant site. Thus, for example, new control strategies can be quickly examined and rapidly evaluated. Such computer monitoring capability also permits use of short duration process pulse tests for approximate dynamic modeling and rapid calculation of controller tuning constants for single loop dominant systems. Following a brief back-ground discussion of the Pinto Valley Project, we present some of the more interesting results and conclusions of our work over the past year.

Jan 1, 1978

By Roland B. Drugge

The adaptation of pelletizing processes involves the coordination of various factors such as temperatures, gas flows, productions, etc., in order to obtain optimum performance. The consequent problems are considerable due to the large number involved as well as the lack of knowledge of their correlation. It is therefore essential to establish a fundamental theory which takes into account the heat transfer phenomena and the secondary factors which are relevant to the properties of the product. Straight grate and grate kiln pelletizing processes involve heating of a stationary bed on a travelling grate. The heat transfer conditions are therefore of primary importance. This is why this article pays particular attention to conditions which obtain when a stationary bed is heated, in which certain special reactions occur. The conclusions drawn from this penetration of the heat transfer phenomena can be expressed in postulates acting as guide-lines for the establishment of proto-typal processes. Examples of elaborating such processes are also given in the article. Some operational experience at LKAB are also given.

Jan 1, 1975

By Yanli Huang, Qiang Sun, Jixiong Zhang, Yuzhuo Jiang, Dan Ma

Mining accidents due to inrushing water are caused by sudden changes in seepage owing to structural damage to key strata of the aquiclude. The backfill mining method can be used to control the movement of the strata, weaken the evolution of fractures owing to damage by key aquiclude strata (KAS), and control the channel for inrushing water. This study develops a mechanical model of a composite beam on a non-uniform elastic foundation of the KAS by analyzing the coupling relationship between the filling body and the key water-resisting layer of the aquiclude. Equations of the deflection-induced deformation, bending moment, and maximum tensile stress of the KAS are analyzed, formulae to calculate the allowable tensile stress and backfill materials’ compaction ratio (BMCR) to ensure structural stability are derived, and are used to provide the critical BMCR for their structural instability. The results of field measurements show that the subsidence of the roof was 600–700 mm with an average BMCR of 80.63%. Damage to the overlying strata was controlled to ensure safe mining and the disposal of solid waste from the aquifer. The research here is useful for ensuring safety during mining while protecting water resources.

Jul 12, 2022

By G. R. Brunskill

The molybdenite flotation plant at Magma Copper Company, San Manuel concentrator has been in operation since 1956. In January of 1980 the plant was converted from a hydrogen peroxide - ferrocyanide process to the current sodium cyanide - sodium hydrosulfide process. This paper is an operational review of Magma Copper Company's molybdenite recovery circuit, column cell flotation experience and use of on- stream x-ray flourescence analysis.

Jan 1, 1985

By N. P. Titkov

This paper presents the results of laboratory and pilot plant investigations for the development of efficient methods of beneficiating hematite ores from the Krivoi Rog, Kursk Magnetic Anomoly, Olenogorsk, and other localities. The tests included gravity, magnetic (in a high intensity field), flota¬tion, and magnetizing roasting methods. It was possible to develop efficient beneficiation methods depending on the mineral composition of the ore and degree of dissemination of ore and gangue minerals. The paper shows the relationship between the iron silicate and quartz content of the ore and the technologic indices of the various beneficiation methods. Some of the conclusions based on these investigations and the technical and economic computations related to the cost of one ton of pig iron produced from concentrates obtained by the various beneficiation methods are: 1. If the hematite ore is not disseminated uniformly, it is expedient to use a combined gravity and flotation process. Ore particles up to 50 am. in size are beneficiated by gravity (heavy suspension, jigging, and others) and yield a lump concentrate. The middlings from this process are recrushed and floated; 2. Finely disseminated hematite ores, containing small quantities (less than 5 percent) of iron silicates, are most effectively beneficiated by flotation. Anionic (sulphate soap, tall oil emulsion with various foam depressors) as well as cationic collectors may be used. Depending on the mineral and chemical composition of the ore, it is possible to obtain concentrates containing up to 65 percent iron with an extraction up to 94 percent; 3. Finely disseminated, mixed hematite-magnetite ores may be beneficiated by flotation or a magnetic separation-flotation process; 4. Finely disseminated hematite ores, containing large quantities of iron silicates and earthy hematite ores are most efficiently beneficiated by the magnetizing roasting method. This method will yield concentrates containing up to 68 percent iron with extractions up to 90 percent. Although beneficiation by the magnetizing roasting process is costly, it will nonetheless, when employed on this type of ore, yield the least expensive pig iron.

Jan 1, 1960

By Ranajit Kumar Sahoo, Shatrughan Soren, Surendra Kumar Biswal, Soumya Sahoo, Sachida Nanda Sahu

The presence of appreciable quantity of clay mineral in Indian hematite ore needs an attrition technique using screw scrubber in the beneficiation circuit to remove the ultrafine clays and avoid downstream operational problems. Spectroscopic analysis revealed that iron ore samples obtained from the Barbil region of Odisha contain a high amount of silica and alumina in the form of clay minerals (e.g., kaolinite) contributed as a loss on ignition (LOI) in the iron-making process. Iron ore fines of below 10 mm size were subjected to a laboratory-scale screw scrubber, and the effectiveness of scrubbing as well as the pelletization of the scrubbed product was investigated. The screw scrubber in the beneficiation circuit helps to remove the clay minerals, causes an increase in iron values from 63.65% Fe(T) to 66.18%Fe(T), with improved physical (CCS of 325 kg/pellet) and metallurgical (RDI of 2.24%) pellet properties.

Aug 31, 2020

By Vaughn E. Livingston

Washington State has a variety of industrial minerals and although not many are produced currently (1982) most have a history of production (table 1). The value of industrial minerals produced in the state exceeds by several times the production value of metallic minerals. In 1981, 15 minerals - cement, limestone, clay, gemstone, pumice, sand and gravel, stone, diatomite, gypsum, olivine, peat, talc, garnet, silica, and dolomite - were produced. Combined value of nonmetallic production for 1981 is estimated at $218,999,000. Cement had the largest estimated value at $102 million, followed by sand and gravel at $47 million, and crushed stone at $29 million. These figures are from the US. Bureau of Mines preliminary production figures for 1981.

Jan 1, 1982

By Kenneth W. Luke

In the development of the ultimate pit limits for a narrow ore body, pa¬rameters necessary in the design of a functional, or working, pit become highly sensitive factors in the determination of ore reserve levels and their associated waste to ore stripping ratios. Through the use of geologic cross sections, ore reserves can be roughly calculated by utilizing a straight line approximation for pit wall slopes. The optimum position of the pit floor can be substantially altered from such a preliminary design though with the introduction of functional mining parameters, such as a ramping network, and working bench heights, berm widths, and bench to bench wall angles. Originally a computer program was developed to quickly evaluate changes in cross-section pit design with minimal alteration of input data. After developing a satisfactory technique of cross-section evaluation which incorporates working mine parameters, an optimization algorithm, or procedure, was developed and included in the program to eliminate much of the tedious manual decision-making required in determining the optimum location of the pit floor on each cross section. Optimization in this case implies the maximum profit pit. When pit and processing costs are defined or hypothesized, this computer program can be used to design the maximum profit pit, constrained by the recognized functional mining parameters. A second way of stating the optimization is that the program can be used to develop a pit design which minimizes waste stripping at any desired ore reserve level. The basic method of cross-section evaluation parallels present manual methods. Program input is a combination of data obtained directly from cross sections developed for, geological interpretation and pit design parameters selected by the mine planner. As a result it is easy for the mine planner to comprehend what the program is accomplishing, and thus participate in the development of the computer assisted design.

Jan 1, 1971

By Yuexin Han, Mu. Yufan, Yanjun Li, Peng Gao, Yongsheng Sun

"The objective of this study was to evaluate the effect of reduction temperature, reduction time and binary basicity on the size of metallic iron particles in coal-based reduction products of an oolitic iron ore. The particle size distribution behavior (i.e., cumulative passing percentage and mean size of metallic iron particles) during reduction was investigated in detail. Results showed that the particle size distribution of metallic iron particles was strongly influenced by reduction temperature, reduction time and binary basicity. The cumulative passing percentage and mean size significantly increased with reduction temperature and time in the entire range of the experiments. All curves of cumulative passing percentage versus particle size under different conditions demonstrated a similar trend (continuous increase). The size distribution parameters and mean size slightly increased with increasing binary basicity and significantly decreased when the binary basicity exceeded 1.0. The size of metallic iron particles could be controlled by adjusting the reduction conditions during coal-based reduction.IntroductionThe increasing demand for iron ore coupled with diminishing high-grade iron ore reserves has resulted in the urgent need for innovative technologies in order to use refractory iron ores. Oolitic iron ore is a typical refractory iron ore with tremendous abundance globally. Based on published literature, oolitic iron ore reserves are approximately 140 million tons in Europe, 10 billion tons in China and 66 million tons in Pakistan (Kazmi and Abbas, 2001; Wu et al., 2011; Yu and Qi, 2011; Sun et al., 2013a). Therefore, the efficient exploration and use of oolitic iron ore resources can play a significant role in easing the mineral resource crisis in the iron and steel industry. However, oolitic iron ore cannot be effectively upgraded by traditional beneficiation methods due to its mineralogical characteristics (e.g., low grade of iron, poor liberation of iron minerals and high phosphorus content) (Li et al., 2011b; Sun et al., 2013b).Researchers recently proposed coal-based reduction followed by magnetic separation to recover iron from refractory iron ores (especially oolitic iron ore) and a certain degree of breakthrough was achieved in both theory and practice. In this technology, iron minerals in the ore are directly reduced by coal to metallic iron, which grows into particles of different sizes. After comminution and liberation, metallic iron is concentrated by magnetic separation (Srivastava and Kawatra, 2009; Sun et al., 2013a; Li et al., 2011b; Sun et al., 2013b; Li et al., 2011c; Gao et al., 2013). Sun et al. and Gao et al. used this technology to examine the recovery of iron from oolitic and Bayan Obo iron ores, respectively (Sun et al., 2013a; Li et al., 2011b; Li et al., 2011c). Metallic iron powder with more than 90% iron content was obtained as the final product, which could be used directly in steel production."

Jan 1, 2015

By W. J. Wuest

The U.S. Bureau of Mines (USBM) has recently developed a rock mass classification system for evaluating the structural competency of bedded roof strata; the Coal Mine Roof Rating, or CMRR. When compiled with the companion Lotus 1-2-3 spreadsheet, which is simple to learn and use, CMRR data are a useful tool with applications to longwall gate road pillar design, safety hazard mapping, and artificial roof support analysis. This paper demonstrates these applications under actual conditions found in current U.S. mining operations.

Jan 1, 1995

By Daniel R. Walton

This paper covers several points of interest to mine engineers and planners involved in evaluating or conducting geostatistical coal reserve estimates. In particular, the ability to optimize borehole drilling locations and minimize drilling costs is addressed. Also discussed is the concept of confidence intervals for estimated coal characteristics obtained through geostatistical estimates and their importance in decision-making for mine planners. Finally, a discussion is presented on how geostatistics enables identification of invalid data points and actually forces strict attention to data editing and proper geologic interpretation.

Jan 1, 1982

By L. D. Savage

Several experiments were conducted using a large crib fire adjacent to a Kennedy Metal Products steel stopping in a simulated cross cut to evaluate the proposed mechanisms by which a mine fire would breach the stopping. Temperatures in the convective air paths on both sides of the stopping, at the surface of the roof and 16mm within the roof were measured to evaluate the effects of heat transfer. The results indicate that roof failure is the prime method of breaching this design of stopping.

Jan 1, 1996

By George McArthur

GEOLOGY One of the largest copper resources in North America occurs in the Bingham mining district, located 40 km (25 miles) southwest of Salt Lake City, UT. Anaconda's present contribution to the development of this resource is the Carr Fork mine. (Fig. 1, Bingham district plan map.) The Carr Fork story began about 300 million years ago when a thick sequence of sedimentary quartzite and limestone was deposited in the Oquirrh Basin. Subsequent earth stresses formed a series of west-northwest-trending overturned anticlines and synclines that were later offset by northwest-striking thrust faults and northeast-trending normal faults. (Fig. 2, Bingham district cross section.) About 38 million years ago the Bingham stock was intruded into some of the folds, resulting in the formation of porphyry ore in the intrusive, and fissure, replacement, and skarn ore deposits in the sediments. The Carr Fork skarns were formed preferentially in two limestone units, called the Yampa and Highland Boy, which average about 46 m (150 ft) in thickness, separated by about 76 m (250 ft) of quartzite. Copper mineralization consists almost entirely of chalcopyrite associated with pyrite and molybdenite in a gangue of garnet, diopside, magnetite, quartz, and carbonate. Molybdenum, gold, and silver are economic byproducts. (Figs. 3 and 4, indicated ore in plan and section.) EXPLORATION HISTORY The West Mountain mining district, of which Carr Fork is a part, was organized in 1863, after leaf-silver ore was discovered in the Carr Fork of Bingham Canyon. However, it was not until 1873, when the Bingham and Camp Floyd railroad to the town of Bingham was completed, that the mining camp flourished. Many small mining companies in the district were reduced, often through consolidation. By 1937 only the National Tunnel and Mines Co. was active in the Carr Fork area. In 1948 it declared bankruptcy, and was later purchased by The Anaconda Co. Anaconda conducted geologic investigations in the Bingham district until 1968, when a concerted diamond drilling program was initiated to fully evaluate the geologic potential of the Carr Fork area. The exploration program commenced with one diamond drill, but was enlarged to three drills following discovery of the first major ore intercept. Near completion of the exploration effort, large oil well rotary drills were used to drill to depths of 762 to 914 m (2500 to 3000 ft), after which the holes were completed by standard diamond drilling techniques. All holes were collared vertically, but considerable deviation occurred because of structure and rock conditions. Wedging and directional drilling were used to keep the holes on target and to provide multiple ore intercepts in the deeper holes. Geophysical surveys, in-

Jan 1, 1982

By B. Markovic

Performance of mineral filler particles in ceramic applications can be enhanced markedly by adsorbing polymers of optimum molecular structure and dosage. In a recent work by Chen and Somasundaran (1997), a novel scheme of controlled polymer adsorption was used to produce nanocomposites of unique core-shell designs. Towards this purpose, adsorption and desorption behavior of selected polyacrylic acids (PAA) on three minerals; alumina, titania, and silicon carbide, was examined as a function of relevant parameters. Adsorption of P AA was found to depend on polymer molecular weight, pH, as well as solids loading. Specifically, the adsorption density was found to increase with increase in polymer molecular weight for non-porous alumina while it was found to decrease in the case of porous alumina. This is attributed to the inaccessibility of the pores to the larger polymers. An unexpected finding was the change in the adsorption density of PAA with solids loadings. PAA adsorbs on silicon carbide only at low pH values when the particles have very low surface charge suggesting that the adsorption in this case is controlled by electrostatic forces. Using polyacrylic acid as bridging agent between the alumina fillers (core) and nanosize alumina or titania particles (shells), controlled layer by layer deposition of nanoparticle on the core particle surface could be obtained.

Jan 1, 1997

By A. S. Ibrado

Research investigations on the chemistry of the adsorption of gold cyanide on activated carbon have mostly reduced the role of activated carbon as the provider of the large surface area needed for adsorption. Most do not go beyond suggesting that oxygen functional groups on carbon play a key role in the adsorption process. Our research shows that the nature of the material, specifically its structure, is a crucial factor in the adsorption equation. To delineate the effect of adsorbent properties, gold cyanide was adsorbed on a series of carbonaceous adsorbents, including lignite, coals, anthracites, carbon blacks, graphite and activated carbon, which covers wide variations of composition, surface acid group content, and degree of graphitization. The results show that the adsorption of gold cyanide per unit area of adsorbent is not related to the amount of oxygen groups on the surface or even the total oxygen content of the material. However, they show very strong correlation with the degree of graphitization of the adsorbent, which indicates that the graphitic plates of activated carbon play the most important role. The findings suggest that majority of the adsorption occurs on the plate faces of the graphite crystallites of activated carbon.

Jan 1, 1992