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By P. D. Rao

Chemical and physical properties of typical low-rank coal (LRC) ash are significantly different than bituminous coal ash. With the exception of extraneous ash, which is incorporated during mining or is due to ash partings within or between coal seams, LRC ash consists primarily of inherent ash that is bonded into the coal's organic matrix or finely disseminated mineral matter. This paper reviews the nature of LRC ash, both inherent and extraneous, and how this impacts the prospects of washing and utilizing LRCs. A literature review, as well as washability data, proximate and ultimate analyses and ash analysis of 25 Alaskan LRC seams are used as a basis for this discussion. The authors' recent research into the nature and distribution of phosphorous in an Alaskan LRC is also discussed

Jan 1, 1997

By Steven W. Hunt, Glen R. Frank

Assessment of abrasivity and cutter life are necessary to properly manage risks when tunneling in mixed face ground which includes ground with cobbles and boulders. Maximizing cutter life requires: (1) abrasivity and strength parameters for soil matrix and rock clasts, (2) methods of combining both, (3) proper selection of cutters and (4) modified TBM operation including use of boulder detection methods from the TBM to help make operation decisions. This paper presents approaches for addressing these factors sufficiently to improve tunneling success in mixed-face and cobbly-bouldery ground. Current laboratory abrasivity testing will be assessed along with equivalent quartz content correlations to soil matrix and rock clast abrasivity. New approaches to combining abrasivity testing of both the soil matrix and rock clasts for various cobble and boulder volume ratios will be suggested to estimate cutter life and intervention intervals. Methods for detecting boulders and using detection data to modify TBM operations to minimize boulder impacts are provided.

Jun 13, 2021

By Shiwei Wang, Ziwen Li, Chenhu Zhang, Peng Chen, Chengyong Wang

Accurate prediction of the partition coefficients in coal gravity separation is key to improving the preparation efficiency of coal and promoting its clean utilization. In China, the approximate formula method (AFM) has been applied to the calculation of coal gravity separation partition coefficients for decades, but its accuracy is limited. To improve the accuracy of the predicted partition coefficients, and thus the product yield of coal preparation plants, the present study proposes a modified hyperbolic tangent model to derive direct calculation formulas for the heavy medium and water medium separation partition coefficients. Four groups of coal samples were used to verify the accuracy of the direct formulas, and their predictions were compared with those of the AFM. The results showed that the partition coefficients and partition curves predicted by the direct formulas were closer to the actual values than those predicted by the AFM. Further, when the cleaned coal ash content was basically the same, the cleaned coal yield predicted by the direct formula was lower than that predicted by the AFM, and was also closer to the actual value. These results demonstrate that the direct formula produces more accurate results compared to the conventional AFM. As this formula has a reasonable theoretical basis, is simple to apply, and produces accurate results, it is expected to help improve the design and management level of coal preparation plants.

Oct 15, 2022

By Garry M. Hughes

Lynn lake, Manitoha, where Sherritt has operated a copper-nickel mine since 1954, is located north of the 56th parallel approximately SOO miles north of Winnipeg. Sherritt's new, 3,000 tpd, copper-zinc Fox Mine is situated 30 miles southwest of Lynn lake. This paper focuses on the Fox Mine concentrator, hut first some background information. Sherritt Gordon Mines Limited started mining operations as a copper-zinc producer in 1931 at Sherridon, Manitoba, 150 miles south of Lynn Lake. As Sherridon fizzled out development of a series of nickel-copper orebodies commenced at Lynn Lake. The Forward process was developed to treat the nickel concentrate from the Lynn concentrator. Sherritt's ammonia leaching process is now history and is expected to gain more prominence as pressure is applied to the mining industry for closer environmental control. But few are aware of the fact that the present Lynn Lake crushing plant and concentrator were dismantled in the autumn of 1951 and freighted from Sherridon by tractor train during the winters of 1952 and 1953. The copper-zinc orehody at Fox Mine was discovered early in 1961 by geophysical methods which included both airborne and ground surveys. It is part of a ,large body of massive and semi-massive sulphides consisting chiefly of pyrite; with chalcopyrite, sphalerite (containing 7-9% iron) and pyrrhotite in varying proportions which occur within a series of volcanic and sedimentary rocks. The total mineralized zone is a lenticular body with a minimum average length and width of 1,350 feet and 66 feet respectively, to the explored depth of 2,000 feet. The average sulphide content is 67%. Higher zinc zones are masses of pyrite grains cemented by sphalerite with lower than average copper content. Zones higher in copper and lower in zinc are slightly more quartzose. Gold and silver are present in small amounts roughly proportional to the copper content.

Jan 1, 1971

By Koichi Nishimura

Japan's coal reserves are estimated at 8,583 million tons (according to the materials on X World Energy Conference,. 1976). Japan is a long island country in the shape of an elongated cashew nut whose top is pointing to the north and its lower tip is pointing to the west. And her major coal fields are located in the two extreme far parts of Hokkaido in the north and Kyushu in the south. On the other hand, Japan's major industrial center are located in the central part of the country far from either coal-producing areas. This fact places coal a great geographical disadvantage in comparison with petroleum whose refining bases are concentrated on the coastal regions virtually next to major industrial centers.

Jan 1, 1982

By G. S. Dobby

High-intensity wet magnetic separators have been successfully introduced into the mineral processing field over the past ten to fifteen years, due largely to rapid advancements in magnet design. Wet magnetic separation, until recent years, was applied solely to the concentration of minerals of high magnetic susceptibility, such as magnetite, at relatively coarse sizes. Now, however, high-intensity separators are capable of treating weakly paramagnetic minerals and have extended the range of treatable particle size down to about one micrometre(1,2). . One of the more recent-high-intensity separators developed is the Kolm¬Marston Marston type high-gradient magnetic separator (HGMS) (3,4) It consists basically of an iron-clad solenoid surrounding a matrix material - a fine, ferromagnetic steel wool or expanded metal lath. A schematic diagram of the device is shown in Figure 1. Large, highly localized, pertebations of the magnetic field are created by the ferromagnetic matrix. It is these field gradients that are instrumental in developing large magnetic forces which act on the mineral particles. Operation of the separator is simple. Slurried sample is fed through the matrix and, depending upon the mineral parameters of particle size and magnetic susceptibility and. the operating parameters of flow rate, field strength and feed weight, some particles will be attracted to and adhere to the magnetized matrix, while the others will flow through the matrix. The separation is completed by later removing the background magnetic field and flushing the captured mineral particles into a separate container. The process can also be applied on a continuous basis (S).

Jan 1, 1977

By K. C. Nathsarma

An attempt was made to extract niobium oxide from ~98.5% Nb2O5 using solvent extraction processes. Nb2O5 is used as the feed material in carbothermic reduction processes aimed at producing high-homogeneity, superconductor-grade niobium on a laboratory scale. The Nb metal used for superconductor applications requires a residual resistivity ratio (RRR) > 300, which in turn needs a stringent purity of Nb and allows impurities (substitutional and interstitial) in ppm levels only. In this paper, solvent extraction of niobium was studied under various experimental conditions, such as effect of different extractants, concentration of methyl isobutyl ketone (MIBK) in the organic phase and concentration of various acids. The concentrate was digested with hydrofluoric acid, with ammonium fluoride (NH4F) as a stripping agent. The extraction of niobium from low hydrofluoric- (HF-) bearing solution was found to be low. Thus, various concentrations of hydrofluoric acid and sulfuric acid, as well as hydrofluoric acid and hydrochloric acid, were investigated towards obtaining a maximum amount of niobium in the filtrate and a minimum amount of niobium in the residue. A McCabe - Thiele plot for extraction of niobium from the aqueous phase, HF-bearing solution using HCl with 85% MIBK in kerosene has been constructed to determine the O:A ratio and the number of stages of the process.

Nov 1, 2011

By F. Harold Weber

On July 13, 1967 the San Bernardino County Planning Commission approved publicly a request by American Smelting and Refining Company for a zone variance to conduct a silver mining and milling operation in the Calico district, southern California, Coincidentally, on July 14 the U.S. Treasury halted its sales of silver, and the U.S. free market price quoted rose immediately from $1.30 to $1.77 per ounce. In its request to the commission Asarco stated that about 13,500 to 15,000 tons of rock would be moved daily by surface mining, including 7,000 tons of ore. The ore would be crushed to minus three-quarters inches and the silver recovered "by a chemical process." The grade of the ore was not given, but the company said that it might also recover barite as a byproduct, The operation would employ 150-160 people. Additional activity in the district includes exploration programs by Superior Oil Company and Calico Silver Mines, Ltd. History and production: In retrospect, as the price of silver began to rise in 1961 from 91 cents an ounce, and as Asarco began its exploration program in late 1964, a new era for an old bonanza silver district would seem to have begun. The Calico district has been mined for silver only on a very, very small scale since 1882 to 1896, when an estimated $12 to $20 million (perhaps 15 to 20 million troy ounces) of that metal was produced from the 50-odd mines of the district and vicinity. These mines include the Silver King, Oriental, Waterloo, Garfield, Odessa and Waterman (which is about 8 miles west of the district). Much smaller-valued amounts of barite, gold, lead, and copper also have been produced from the ore deposits of the district; and from 1884 to 1907 the region yielded about $9 million worth of borate minerals.

Jan 1, 1967

By K. C. Nathsarma

An attempt was made to extract niobium oxide from ~98.5% Nb2O5 using solvent extraction processes. Nb2O5 is used as the feed material in carbothermic reduction processes aimed at producing high-homogeneity, super-conductor-grade niobium on a laboratory scale. The Nb metal used for superconductor applications requires a residual resistivity ratio (RRR) > 300, which in turn needs a stringent purity of Nb and allows impurities (substitutional and interstitial) in ppm levels only. In this paper, solvent extraction of niobium was studied under various experimental conditions, such as effect of different extractants, concentration of methyl isobutyl ketone (MIBK) in the organic phase and concentration of various acids. The concentrate was digested with hydrofluoric acid, with ammonium fluoride (NH4F) as a stripping agent. The extraction of niobium from low hydrofluoric- (HF-) bearing solution was found to be low. Thus, various concentrations of hydrofluoric acid and sulfuric acid, as well as hydrofluoric acid and hydrochloric acid, were investigated towards obtaining a maximum amount of niobium in the filtrate and a minimum amount of niobium in the residue. A McCabe - Thiele plot for extraction of niobium from the aqueous phase, HF-bearing solution using HCl with 85% MIBK in kerosene has been constructed to determine the O:A ratio and the number of stages of the process.

Jan 1, 2011

By Aleksandar D. Bugarski, Dylan A. Ritter

The results of laboratory characterization of tailpipe emissions for three “clean” engines that meet U.S. EPA Tier 4 final emissions standards were used to assess the viability and effectiveness of repowering existing engines and powering new mobile equipment with those engines as a control strategy for reducing exposure of underground miners to diesel aerosol and criteria gases. The evaluated engines were representative of those that achieve the emission standards through implementation of various in-cylinder emissions control strategies, use of crankcase filtration, and use of three types of exhaust aftertreatment systems: (1) diesel oxidation catalytic converter (DOC), (2) combination of DOC and the full-flow wall flow monolith diesel particulate filter (DPF), or (3) combination of DOC, diesel exhaust fluid (DEF) based selective catalytic reduction (SCR) system, and ammonia slip catalyst (ASC). The study showed that the highest reductions in concentrations of diesel aerosols in underground workings, in terms of both mass and number, could be achieved if the engines, preferably in all power classes, are fitted with viable DPF systems. The use of U.S. EPA Tier 4 final engines equipped with DOC and DOC/SCR/ASC systems could help operators to considerably reduce mass, but not number concentrations of aerosols. The emissions of two of the evaluated engines, one equipped with DOC and the other equipped with DOC/DPF systems, were characterized by substantial secondary NO2 emissions that would limit the viability of those engines for underground mining applications. It appears that the catalyst formulations used in the exhaust aftertreatment systems of the “clean” engines marketed to the underground mining industry need to be formulated to minimize the potential for generation of secondary NO2 emissions. The results indicate that the engines fitted with viable SCR/ASC systems present a low-NO2 alternative. All three “clean” engines were found to have low CO output. Therefore, due to nuances associated with the use of diesel-powered mobile equipment in underground mines, special attention needs to be paid to the selection and potentially optimization of “clean” engines for underground mining applications.

Feb 1, 2025

By I. Iwasaki

A low-grade copper-nickel deposit, with an estimated size of 4.6 billion tonnes and with average analyses of 0.6% copper, 0.2% nickel, occurs in northeastern Minnesota. In addition to copper, nickel, cobalt, and precious metals, the Duluth gabbro contains magnetite, ilmenite, olivine, plagioclase and biotite. It is estimated that the flotation tailings that would be produced by a concentrator of optimal size to sustain a smelter would amount to 20 million t per year. The flotation tailings, having already been ground, warrant a closer examination for the recovery and utilization of potential by-products. The residual sulfide minerals and fibrous minerals may also be isolated and treated separately for useful purposes or for disposal in an environmentally acceptable manner. Two flowsheets were developed; one involving preconcentration by low- and high-intensity magnetic separation and another involving preconcentration by gravity concentration. The concentration methods for recovering and purifying individual by-product minerals were investigated. From their chemical, physical and mineralogical characteristics, the potential areas of application and marketabilities of each product fraction were surveyed.

Jan 1, 1983

By M. S. Klima

This paper will detail the work that has been done in 1990 and 1991 at the Pittsburgh Energy Technology Center (PETC) on the development of the U.S. Department of Energy's (DOE) patented Micro-Mag Process. This process entails the use of a micronized-magnetite (minus-10 microns) and water mixture for cleaning fine coal (minus-600 microns) in a cyclone, along with the production and recovery of the magnetite. Emphasis will be on the results from micronized-magnetite recovery testing using both conventional wet-drum and high-gradient magnetic separators in which several key operating conditions were varied including feed percent solids, magnetite-to-coal ratio, magnetite grade, and feed rate. Also presented will be selected results from testing done on a 76-mm diameter cyclone at a relative density of 1.50 showing the effects of operating pressure, magnetite grade, and medium-to-coal ratio on separation efficiency. In addition, two methods for producing micronized magnetite, along with the corresponding size distributions, will also be discussed.

Jan 1, 1992

By Ronald C. Severson

Crystals of native gold occur in placer-type deposits. Gold, as a pure metal, is the most malleable metal known; therefore, delicate gold crystal forms should not survive mechanical transport and concentration processes involved in placer formation. To test the hypothesis that the crystalline gold is currently forming in place, two active gold-placer operations and an unmineralized background area in Alaska were examined. At these sites, rock outcrops, soil profiles, and native vegetation were sampled. At one sampling site, the soil was panned and yielded crystalline gold, as well as the more common rounded nuggets. The plants and soils were analyzed for their major, minor, and trace-element contents, especially gold. Two procedures, one a simple demineralized water leach and the other a partial digestion with acetic acid and hydrogen peroxide, were also used to extract gold and various anions from soils. The water-extractable gold ranged from <0.02 to 15.0 ppb Au in the extracting solution. This represents as much as a 104 enrichment in gold over average river water. This extractable gold is probably available to the native vegetation. Gold concentrations in the unashed dry plants from the two placer sites ranged between 0.4 and 106 ppb compared to a background range of <1 to <4 ppb Au. The presence of dissolved organic matter in the soils is thought to be responsible for the dissolution, transportation, and precipitation of gold in these placer soils, and this process is presently active in these soil profiles.

Jan 1, 2013

By J. Lorosch

Improvement of current leaching technology was found necessary when processing ores which are more difficult to leach because they generate highly viscous, air-rejective pulps. Cyanidation of these pulps has to run at low oxygen concentrations if the conventional aeration technique with compressed air is used. Since the dissolution rate of precious metals mainly depends on the concentration of dissolved oxygen in the pulp [1, 4, 5], the kinetics of the gold extraction become slow in such cases, which in turn often leads to a significant decrease in the overall gold output within the conventional leaching time of up to 48 hours.

Jan 1, 1988

By Andrew J. Regis

Resource figures for bentonite clays are generally based on stratigraphic, sedimentary geologic data and drilling and sampling. Estimates of bentonite resources and/or reserves commonly found in the literature report on bentonite occurrences in specific localities or areas but none on any documented comprehensive estimates of bentonite resources. From 1974 thru 1977 the Bureau of Land Management conducted extensive studies of the resources of commercial grade bentonite in the three state region. These investigations consisted of: 1. Stratigraphic and geologic sampling with supplemental drilling data, followed by geostatistical analysis. 2. Data compiled from a systematic search of county and state records on mining locations, leases and acreage filed for bentonite. Estimates of resources of commercial grade bentonite using industry parameters were calculated from these data sources. It is concluded that there exists from 1.5 to 2.4 billion tons of in-place bentonite in Wyoming, Montana and South Dakota. Assuming a 5 percent annual growth rate for the industry, this would indicate a life of 62 to 73 years.

Jan 1, 1979

By Dan Nilsson

The Luossavaara "Research Mine" is the First large, offensive effort in mining research conducted by the Swedish state. Over a 5-year period, 1981-1985, the Swedish Mining Research Foundation works in the "Research Mine" on the development of mining systems and equipment. The purpose is to bolster the competitive strength of the Swedish mining and mining equipment industry. The previosly abandoned Luossavaara mine in Kiruna, in northern Sweden, has been reopened especially For the project. Ore is mined and sold during the course of the research project. The income from the sales covers a large portion of the costs for teh research.

Jan 1, 1985

By R. L. Amelunxen

P. T. Freeport Indonesia (PI) in conjunction with Crescent Technology Inc. has developed a method to predict the metallurgical performance of ores blends based on the behavior of their component ores. The question addressed in this paper is whether ores treated individually could be extrapolated to predict the behavior of a blend of ores. The work further investigates the use of modal analysis to establish individual mineral flotation kinetics in each of the ore zones. This information would lead to the prediction of grade-recovery curves of ores made up of those minerals. Nine samples of ore, representing various zones of FI&apos;s Grasberg ore deposit were tested metallurgically and examined microscopically. The same testwork was performed on blends depicting the 1994 mill quarterly feed. Flotation kinetics of the individual ores were then "mathematically" blended and compared to the results obtained from the quarterlies. The calculated kinetics of the actual blends of ore received by the mill were fed to the simulation program and compared to the actual mill performance.

Jan 1, 1995

Column flotation cells continue to gain acceptance in the coal industry for the treatment of high-ash streams containing clay slimes. Unfortunately, some industrial installations have failed to meet expectations due to improper scale-up, incorrect operation and poor ancillary circuit design. To overcome these problems, case studies have been conducted to fully define the capabilities of column cells for coal applications. These data have been used to develop generic engineering guidelines for column circuit design and operation. An economic analysis has also been conducted to illustrate the importance of key capital cost considerations. These analyses indicate that column cells are significantly more expensive than conventional machines, although this difference can be greatly reduced through the installation of very large-diameter columns.

Jan 1, 1999

By H. B. Oblad

Coal/pyrite fines were froth floated in a laboratory cell to examine the rate of pyrite recovery during conventional coal flotation. The effects of collector, particle size and carbon to total sulfur ratio on the kinetics of recovery were investigated. These data coupled with microscopic examination suggest that miniscule amounts of coal that remain attached to the pyrite surface affect the rate of flotation of pyrite.

Jan 1, 1985

By G. J. Hartman

The Fort Cady in situ borate mining project involves recovery of boron from a mineral deposit located over 1400 feet below the surface. The resource recovery method is being developed using in situ mining technology employing weak acid solution injected directly into the ore body. As the acid contacts the calcium based ore (primarily natural colemanite), the contained borate values are digested as boric acid. This boric acid solution is then pumped to the surface by use of submersible pumps. At the surface the borate values are recovered as a finely divided solid white powder after a series of chemical reactions and precipitations resulting in the production of calcium borate. The refined product is then sold under the trade name CADYCAL 100.TM All environmental permits for up to a production rate of 90,000 tons per year have been obtained. These permits required an Environmental Impact study (EIS) for federal lands and an Environmental Impact Report (EIR) for the private portion of the property. Regulatory permitting required over 5 years to obtain all the various authorizations for this project. The ore body has an average thickness of 118 feet extending over 273 acres. At a production rate of 90,000 tons per year with only a 70 percent resource recovery allowance, in place reserves are sufficient to sustain production for over one hundred years.

Jan 1, 1997