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By Rudy Rogers

When Gas hydrate formation rates have two steps: a nucleation induction step and an agglomeration step. Hydrate induction in distilled water is extremely slow because of lack of nucleating particles. Our laboratory found that synthetic anionic surfactants greatly improve both hydrate induction and agglomeration because the surfactant?s hydrophilic head absorbs water molecules and the hydrophobic tail absorbs hydrocarbon gas molecules, creating necessary nucleation sites. Vast hydrate deposits inhabit seafloors. What is the seafloor hydrate nucleating mechanism? We find that nano-particles of smectite clays (bentonite and nontronite) are hydrate-nucleating sites in sea-water-saturated, packed porous media, especially when trace quantities of anionic biosurfactants adsorb on the clay particles. Microbes and their bioproducts proliferate around seafloor gas hydrate accumulations. The seafloor microbe-mineral-hydrate synergy is explored in this paper. Keywords: gas hydrates, biosurfactants, crystal nucleation, smectites

Jan 1, 2008

By D. D. Banerjee, S. K. Kawatra, T. C. Eisele

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. The majority of the sludge is simply landfilled, but with increasing landfillimg costs this can cost the plant millions of dollars per year. As a result, this option is rapidly becoming less attractive. Producing marketable materials from the sludge is a far more promising avenue, provided that the products can meet the necessary specifications at a reasonable cost. In this paper, a method is described for using froth flotation and water-only cyclones to remove unreacted limestone from scrubber sludge. The water-only cyclone was found to be very effective for removing the coarser unreacted limestone, grinding ball chips, gravel, and similar coarse impurities. Froth flotation was found to remove fine unreacted limestone, with a minimum of reagent addition.

Jan 1, 1995

By J. Andres

"Freeport-McMoRan’s Sierrita operations refines molybdenum disulfide in a ferric chloride leach to remove impurities. To understand bottlenecks in the leach process and the true capacity of the leach system, a cross-functional team was established to look at theoretical models, kinetics of the leaching process, equipment limitations and operational strategies. A series of in-plant tests were run which resulted in a road map for improved throughput. INTRODUCTION Molybdenum, a vital component in the steel industry, is often found in nature as molybdenum disulfide (MoS2). Molybdenum disulfide deposits can exist as standalone components in an ore body, or can also be found within copper porphyry nodes. Processing for these copper/molybdenum porphyry ore bodies involves a first stage of flotation to produce a bulk concentrate before separation of the copper and molybdenum concentrates in a second stage of flotation. In this second stage of flotation, a reagent is added to suppress the copper particles, while allowing the molybdenum disulfide particles to remain hydrophobic and continue to float. This separation is very good at keeping the molybdenum out of the copper concentrate; however a portion of the copper continues to float through the circuit. As a result, there is typically some amount of copper in the final molybdenum concentrate. This copper must be removed in order for the molybdenum disulfide product to meet product quality specifications. Once the raw molybdenum disulfide product has been made, a separate process must be applied to remove any copper, lead, or other impurities remaining in the concentrate. This process usually involves the selective leaching of impurities out of the bulk solid. Gupta mentions three specific types of leaching agents, sodium cyanide, ferric chloride, and hydrochloric acid for the removal of sulfide impurities. Sodium cyanide is useful for the removal of copper compounds such as bornite, covellite, and chalcocite.1 Sodium cyanide solution dissolves these copper compounds, and the remaining molybdenum solids are filtered to produce a pure molybdenum concentrate. Ferric chloride works similar to that of sodium cyanide, but is particularly efficient in removing chalcopyrite and galena compounds. These compounds are easily chlorinated at elevated temperatures, producing copper chloride and lead chloride, through the reactions presented below:"

Jan 1, 2015

By K. Tempel

In December of 1999, Newmont Mining Corporation’s Eastern Nevada Operations commissioned its commercial biooxidation facility. The commercial biooxidation facility is a refractory gold whole ore heap process that uses bacteria to assist with the oxidation of sulfide minerals thus liberating occluded gold for further processing by cyanide for gold extraction. Before the commercial biooxidation facility was started, a decade of research went in to developing this state-of-the-art process. During final design and construction of the commercial facility a decline in gold price necessitated cost saving and project scope changes. As a result, the biooxidation process experienced many challenges. Some of the more significant challenges include poor heap permeability due to haul truck stacking, unhealthy bacteria population due to a lack of solution aeration, and insufficient biooxidation time because of limited pad space and high carbonate content in the ore. This paper discusses the many challenges encountered and addressed during the first 2-3 years of commercial biooxidation operation.

Jan 1, 2003

By B Scheiner, D. A. Stanley

Introduction Treatment of ores to recover metal and mineral values results in waste materials usually in the form of dilute slurries. The US Bureau of Mines (USBM) investigated a technique for dewatering phosphatic clay waste by flocculating with polyethylene oxide (PEO) and dewatering the resulting floes on a static screen and/or trommel screen (Schemer et al., 1985). In the investigation, it was determined that PEO was far superior to polyacrylamide polymers for this type of dewatering. This paper discusses reasons for this superior performance. Comparison of PEO with polyacrylamides Dewatering experiments were conducted by adding PEO solution from a burette to a stirred clay slurry. The dewatering endpoint was characterized by rotation of the floc mass as a unit, a clear supernate, a maximum floc size, and a minimum floc volume. Additional water was removed from the floes by hand squeezing (Schemer et al., 1985). The clays investigated were sodium, potassium, magnesium, calcium, and aluminum exchanged montmorillonite and attapulgite. Nine commercially available (Superfloc) polyacrylamides were compared with PEO at two polymer concentrations. Results are summarized in Table 1. The solids content of the dewatered clays ranged between 24% and 33% and was highest for PEO-treated material. These results and the data in Table 1 indicate that PEO is superior to polyacrylamide in terms of polymer dosage required. Superflocs 16 through 128, like PEO, are nonionic and should give similar results to those for PEO if the flocculation mechanism is the same for both type polymers. Superflocs 204 through 214 are anionic with increasing anionic character from 204 to 214. Generally, the anionic polymers gave the best results for the polyacrylamides tested, but in terms of dosage they were not as good as PEO. Correlation between flocculation and dewaterability of waste slurries The overall mechanism for mechanically induced clay dewatering is not completely known, but certain observations can be made. For instance, when a polymer is adsorbed on a clay such as montmorillonite, the polymer desorbs interlayer water. Polymer adsorption is driven by favorable entropy changes associated with this water desorption. It is also known that the -CH2-CH2- links of the PEO chain are sufficiently hydrophobic to lead to physical adsorption of the polymer (Theng, 1979). For montmorillonite slurries, the sheet-like fundamental particles, called tactoids, consist of a small, variable number of aluminosilicate layers together with interlayer water and exchange ions. The flocculation process consists of adsorption of polymer on the tactoid. Loops and tails of polymer that extend into solution then adsorb on another tactoid, forming a bridge. Mechanical action, induced by hand squeezing or in a trammel, joins the bridged tactoids face-to-face and edge-to-edge to form regions of high density. Similar orientation effects are observed for the needle-like attapulgite crystals (Schemer et al., 1985). Proposed flocculation model Generally, statements concerning flocculation and dewaterability apply to both PEO and the polyacrylamides. However, PEO has additional interaction with the clay material when compared with polyacrylamides. PEO is a polymer with repeating -CH2-CH2-O- groups and interacts with montmorillonite through a water bridge whose strength is greatly influenced by the exchange ion. To obtain insight into this interaction, a series of experiments were conducted in which different ion exchange forms of montmorillonite and attapulgite clays

Jan 1, 1987

By G. Orhan, C. Arslan

The possibility of producing metallic chromium from Cr2O3 via the aluminothermic route, with no external energy supply, was the subject of this laboratory-scale research. The experimental study focused on investigating the individual effects and quantitative optimization of the charge contents, i.e., the additions of CrO3, Al powder and CaO (or BaO). The highest chromium recovery of 98% was attained with the additions of 12% CrO3 and 1.2 times the stoichiometrically required amount of Al powder. The optimum CaO addition giving the highest chromium recovery was found when the CaO/Al weight ratio in the charge was equal to 0.3. When BaO was used, however, 95% Cr extraction efficiency was obtained at a BaO/Al weight ratio of 0.15.

Jan 1, 2000

By Richard S. Mateer

The percent ash in a coal blend is equal to the weighted average of the ash contents of the component coals. If the raw coals differ in washability characteristics, the total yield may be maximized by washing the component coals to different quality levels. A mathematical basis for blend maximization is developed and a computer program is described The program determines the component weights that maximize the yield, while meeting an individual coal-quality specification. The procedure is directly applicable to linear parameters of grade quality such as percent ash, percent sulfur and the calorific value. A transformation of variables permits program execution to meet a sulfur-compliance specification. Blends may consist of any number of component coals.

Jan 1, 1997

By D. Akers, R. Dospoy

Introduction The geological processes that form coal can also concentrate trace elements in the coal. For example, the average concentration of arsenic in bituminous coal (20 ppm) is ten times the average concentration found in all the other rocks that make up the earth's crust (2 ppm). Similarly, other elements, such as antimony, cadmium, mercury and selenium, are more concentrated in coal than in the earth's crust. When coal is burned, trace elements can be further concentrated. Although no new constraints on trace clement emissions were placed on the power generation industry under the 1990 Clean Air Act Amendments, the act does mandate a three-year study of air toxics. Any new regulations aimed at electric utilities as a result of this Federally-mandated study will almost assuredly be very costly-an estimated $1 billion per year. Many trace elements in coal are associated with mineral matter. For example, arsenic is commonly associated with pyrite, cadmium with sphalerite, chromium with clay minerals, mercury with pyrite and cinnabar, nickel with millerite, pyrite and other sulfides, and selenium with lead selenide, pyrite and other sulfides (Finkelman, 1980). There are also cases in which some of these elements are organically bound. Just as both organic and pyritic sulfur can be found in the same coal, the same trace element may be both organically bound and present as part of a mineral in the sane coal. Physical coal cleaning techniques are effective in removing mineral matter from coal and can potentially remove at least some of the trace elements associated with specific minerals, thereby reducing the release of these elements into the atmosphere. Conventional coal cleaning to remove trace elements As part of a project funded by the Electric Power Research Institute, CQ Inc., a wholly-owned EPRI subsidiary located in western Pennsylvania, has demonstrated that large reductions in the concentration of many trace elements are possible if conventional coal cleaning techniques are properly applied. Four examples are given in Tables 1 to 4. In each example, the results shown were generated by cleaning the coal at CQ Inc.'s commercial-scale cleaning test facility. Cleaning results for Upper Freeport Seam coal from Northern Appalachia are provided in Table 1. Data are presented in the table in two ways: as a weight-based concentration (parts per million) and as a concentration per heat unit (grams per billion Btu). Grams per billion Btu is analogous to pounds per million Btu, but avoids the use of numbers with many decimal places. The heat-based concentration provides a better measure of boiler impacts, because the increased heating value obtained through coal cleaning reduces the number of tons that must be burned to produce a given thermal output. Reducing the quantity of coal burned reduces the quantity of trace elements entering the boiler. This raw coal is relatively high in several trace elements of environmental concern, including arsenic, cadmium and chromium. Cleaning provided large reductions in the quantity of arsenic, barium, cadmium, chromium, fluorine, lead, mercury, nickel, silver and zinc. The results for tests with a Powder River Basin coal, Rosebud/McKay, are presented in Table 2. Large reductions in arsenic, barium, cadmium, fluorine, mercury, nickel, selenium and zinc were observed with cleaning. The concentration of chromium increased with cleaning, while lead concentration increased in one test and decreased in another. Table 3 presents test results for Croweburg Seam coal from Oklahoma. Large reductions in arsenic, barium, cadmium, chromium and zinc were obtained with cleaning. Smaller reductions were obtained with lead and nickel, while chromium, fluorine and mercury increased in at least one of the tests. Table 4 presents cleaning test data for Kentucky No.11 Seam coal. In this case, large reductions were obtained with all elements measured. In general, these data indicate that physical coal cleaning is effective in reducing the concentration of many trace elements, especially if they are present in the coal at relatively high concentrations. The degree of reduction achieved is coal-specific, relating in part to the degree of mineral association of the specific trace element and the degree of liberation of the trace element-bearing mineral. The extent of trace element removal also depends on the method of cleaning the coal. Figure 1 is a washability plot, by size fraction, of arsenic vs. ash content for Upper Freeport

Jan 1, 1994

By Haydn H. Murray

A hydrothermal bentonite located in the high Sierras in Nevada is being mined and processed for use as a natural dietary supplement. Because hydrothermal clay deposits are normally zoned and not uniform in composition, a special stockpile was constructed to assure uniformity of processed products. The stockpile of clay was layered and rectangular in shape. Channel samples were taken from 10 locations around the stockpile and were mixed and quartered to provide representative samples. The samples were then chemically and mineralogically analyzed. The results showed excellent uniformity. The mineralogy and chemical analyses will be discussed in the paper.

Jan 1, 2005

By Greg Blerie

The requirements placed on belt conveyors grow increasingly complicated No longer is it sufficient for the conveyors to merely move material from "Point A" to "Point B. " Now these systems must be able to produce a specified flow, guaranteeing a plant can operate as scheduled without peaks and valleys in material flow and production rate. In addition, the conveying system must provide effective control, to minimize the problems and costs associated with the escape of fugitive material these problems include unscheduled shutdowns, premature equipment failures, regulatory headaches, poor neighbor relations, and health and safety issues. The key to accomplishing these goals is the loading and discharge of the conveyor belts. Fortunately, new designs for the chutes that accomplish conveyor loading and discharge can move material efficiently, without blockages and while minimizing the amount of dust generated This innovation is the development of engineered flow chutes

Jan 1, 2004

By M. Misra

Jan 1, 1992

By William D. Mayercheck

The introduction of continuous mining machines in the late 1940's prompted the mining industry to reassess shuttle car batch-type haulage. Between place changes, the continuous miner could cut and load coal on a nearly continuous basis, but after loading a shuttle car, the high-capacity machine had to wait until the second shuttle car came inby and spotted itself under the miner tail boom. Thus, the wait-for-shuttle-car delay periods became the new bottleneck for increased coal production from the mine section. Recent studies have shown that nearly 25 pct of the continuous miner cycle time is consumed by delays in the haulage system, usually waiting for shuttle cars. Computer simulations of a face operation indicate that up to a 45 pct increase in coal production may be realized through the use of a continuous haulage system, assuming of course that the outby haulage system can handle this increased capacity. Coincidently, there are recent claims by some mines using continuous face haulage of a production increase of 45 pct compared with shuttle car haulage. These documented production records, computer simulations, and common sense indicate the potential of continuous face haulage in underground coal. The late 1960's and early 1970's saw several mining machinery manufacturers market mobile bridge carrier and piggyback bridge conveyor continuous haulage systems for use in underground coal mines. These systems have shown limited potential in some mines and outstanding success in others. It appears that no one system can be universally applicable to all underground mining conditions; thus, the Bureau of Mines has conducted extensive research over the last few years to investigate different types of continuous haulage systems for use in high and low coal seams that will advance the state of the art.

Jan 1, 1977

By Deepak Malhotra, Robert Dorfler

Modern engineering mill design has been refined over the years to the point where detailed ore and process specification criteria can be developed In the engineering design phase of the project. The plant Is then built to the detailed criteria and performance acceptance tested by the owner to see if the as-built mill meets the criteria, This performance testing is critical to the owner; the test must be systematic with sample collection coordinated throughout the plant. Despite the availability of systematic approaches to plant development, the new plants often fall short of design criteria. This paper discusses the key Issues a Project Manager/Process Engineer should Implement to ensure that plants meet design criteria.

Jan 1, 1991

By D. R. Zeni

Today's mine development requires the safe, expedient and economical construction of vertical shafts for both ventilation and access. This construction must be accomplished within diverse ground conditions. Advancements in large-diameter shaft drilling have led to many exceptional mechanical refinements in shaft-drilling technology. The author traces the history of the equipment and methods employed by the large-diameter shaft-drilling industry and explores the likely paths of future development. Case histories that illustrate the adaptability of shaft drilling as a versatile tool for advanced, worldwide mining operations are cited. Safety, scheduling, costs, environmental impacts and capabilities are discussed.

Jan 1, 1996

By T. McWaters

In 1911, Miami Copper Co. began a block caving operation at its Miami, AZ property. A gravity mill was used to separate copper minerals from the Pinal Schist host rock. Until 1932, the mill tailings were deposited by the upstream method using perimeter launders and spigot valves in six canyons adjacent to the mill. In 1928, the larger and more distant Solitude tailing pile was developed. By 1932, it was receiving all tailings. In 1925, Miami Copper converted the gravity mill to flotation with sulfide copper recoveries. From 1934 to 1943, Miami, Copper ran a leach-precipitate float (LPF) circuit on mined ore and, in 1943, began sulfuric acid in-place leaching of a portion of the caved area formed by block caving. The pregnant solutions were collected underground and pumped to the LPF precipitating drums to harvest copper. In 1954, the company started mining low-grade ore. This led to the running an old LPF plant on select mill tailings from April 1957 to March 1959. In 1959, block-cave mining ceased. Solution mining became the only source of production using a launder precipitation plant. In the mid-1960s, Miami Copper merged with the Tennessee Corp. In the latter part of the decade, Cities Service Co. bought the combined properties. In 1976, Cities Service commissioned a 15-t/d (16.5-stpd) solvent extraction electrowinning(SX-EW) facility at its Miami copper property to replace the precipitation plant. In 1982, Occidental Petroleum Co. bought Cities Service. In 1983, the Miami operations were sold to Newmont Mining Corp. and set up as a subsidiary company, Pinto Valley Copper Corp. Finally, in 1987, Newmont Mining spun off a combined Pinto Valley and San Manuel unit as Magma Copper Co.

Jan 1, 1990

By Bern Klein, Rafael Fernandes de Mesquita, Fatima Regina Ney Matos, Andre Xavier

"193 United Nations members are signatories of the 17 Sustainable Development Goals (SDGs). Even though it does not make it legally binding to the country members, the SDGs establishment incites national and managerial frameworks to achieve the SDGs. The mining industry inserts itself in this context by its global presence and frequent location within ecologically sensitive and less developed areas. This paper aims to consolidate the state of academic research on mining, sustainability and sustainable development, by organizing the results of previous studies within a systematic review on the SDGs set. To do so, the ISI Web of ScienceTM Core Collection database was chosen as a database of record, as it is one of the most widespread databases of academic journals. We have used all years available in the ISI database, from 1945 to 2016 (for complete years). The systematic review process comprised of five steps: (i) to search terms [(“sustainability” or “sustainable development”) and mining] on the database and to apply filters of criteria; (ii) organizing papers; (iii) metrics and relations between papers and authors; (iv) classification of the results through content analysis techniques; and (v) synthesis. The results were divided in two groups: the highly cited and the most recent papers, to include papers that have academic impact and those which show the newest contributions to the field. The results showed that, in spite of a growing amount of publications in the past years that relates to mining and sustainability, the main focus of these publications are still on the environmental dimensions of the UN goals. This suggests that more practical and academic work in the mining sector are required to fill in the blank spaces regarding the other set of goals that compose the SDGs framework.Introduction A total of 193 United Nations members are signatories of the 17 Sustainable Development Goals (SDGs). Even though it does not make it legally binding to the country members, the SDGs establishment incites national and managerial frameworks to achieve the SDGs. The mining industry inserts itself in this context by its global presence and frequent location within ecologically sensitive and less developed areas (Atlas 2016). The goals are important because they add common targets for different countries and easily establish discernible criteria for it (Costanza et al 2016). A forward-looking approach like the SDGs would be able to attach the sustainable development framework with profitable activities taken by the mining companies (Starke 2016). This paper aims to consolidate the state of academic research on mining, sustainability and sustainable development, by organizing the results of high impact previous studies and recent publications, within a systematic review, on the SDGs set. By doing so, the results can portray the actual concern and the lacks that the academic field had on this subject in comparison to the UN contemporary agenda."

Jan 1, 2017

By W. Z. “Ben” Wu

The investigation provides a method of efficiency evaluation among several kinds of tools employed to cut different types of rocks. A ballistic test stand incorporated with a modified Hopkinson bar was used to simulate a percussive drilling tool. An Apple IIe microcomputer was employed for high speed data acquisition and numerical analysis. A newly developed method for remote monitoring the rock-tool interaction, including contact force, bit penetration and energy transmission,is presented in the paper. Theoretical predictions and experimental results appear in faily good agreement

Jan 1, 1986

By Denise Herzog, Sukumar Bandopadhyay

This paper presents an application of analytical hierarchy pro- cess (AHP) to predict the ranking of three beneficiation methods for a low grade, bulk gold deposit located in the interior Alaska. Seven criteria (attributes) were used for evaluating each beneficiation method. For each criterion a matrix of pairwise comparison between methods was developed. The normalized eigenvector of each matrix scales the beneficiation methods with regards to that criterion. An overall scale is constructed by weighting the scales of all the criteria. Methodology used also indicates a measure of inconsistency. This measure is useful in identifying possible errors in expressing judgments as well as actual inconsistencies in the judgment themselves. The outcome of the pro- cess is the best or optimum beneficiation method, considering all the necessary objectives, criteria, and alternatives in a single integrated framework.

Jan 1, 1996

By V. E. Cole

For the successful execution of a major project, the project team must be thoughtfully organized, manned, instructed and motivated. This is true of both the engineer/constructor team and the mining company team. Then these teams must be carefully related so that they function effectively as one organization on the job. This paper describes the organizing techniques and the human ingredients and know-how of a successful project.

Jan 1, 1980

By Yoginder P. Chugh, M. Silverman

Premining investigations involve the determination of roof, floor, and coal seam characteristics to delineate areas of troublesome ground control prior to development of a mine. Data obtained can be useful in mine design, equipment selection, estimation of face productivity, development of ground control plans and assessing ground control costs, and in conducting feasibility studies and financial analyses. This paper discusses 1) the causative factors associated with ground instability, 2) how useful data can be obtained for these factors during premining investigations, and 3) analysis techniques to delineate probable areas of ground instability.

Jan 1, 1982