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By J. Petersen, T. Moyo

Waste Printed Circuit Boards (PCBs) are a metals-rich fraction of electronic waste (e-waste) streams, and globally it has been demonstrated that they can be recycled gainfully to recover the metals. Reported successful cases of PCB recycling are carried out in large volumes, using high-level technology and high capital investment smelter house operations. This presents entry barriers for recyclers in developing economies where capital may not be accessible, and the waste volumes are not sufficient to warrant large scale operations. Hydrometallurgical processes have the potential to provide an option for the scalable processing of smaller volumes of PCBs and can be set up at relatively lower capital costs. However, to date, the hydrometallurgical treatment options available rely on precursor communition and classification processes that also require high capital and energy costs. This paper presents an overview of the work done under the Minerals to Metals signature theme towards understanding e-waste recycling processes and developing pre-processing and characterisation of PCBs in order to unlock potential for local end processing in developing economies, using South Africa as a case study. The structure of PCBs is reviewed, and the current size reduction techniques and the subsequent leaching processes are discussed. Keywords: Printed circuit boards (PCBs), PCB structure, pre-treatment, liberation, ammoniacal leaching

Jan 1, 2020

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

By H. M. Friede

A study was made of the smelting process in two experimental furnaces patterned on Iron Age furnaces excavated at Melville Koppies Nature Reserve, Johannesburg. In a number of smelting experiments, the influences of air supply, temperature, time of operation, fuel consumption, and other operational factors were investigated. Metallurgical and metallographic aspects of the furnace operation and smelting products are discussed, and the experiments are compared with similar research work conducted in Europe and Africa.

Jan 1, 1984

By D. J. Adams, R. G. Gürtunca

In situ measurements and numerical modeling based on elastic theory showed that backfill stresses are considerably higher than originally thought. This has led to a change in understanding of rockmass behaviour. After describing previous work on the behaviour of the rockmass, this paper discusses possible reasons for the high stresses measured in backfil, and identifies the rockmass mechanisms possibly generating these stresses. It is concluded that the joints and the geological stratigraphy can lead to increased elastic convergence, and that the inelastic behaviour of the rockmass is also partly responsible for the increased closure measured in backfill. The use of an in situ modulus is suggested as an interim solution until a new computer model that allows for joints, different layers, and inelastic closures becomes available.

Jan 1, 1991

By R. M. S. Falcon, L. M. Falcon

The prediction of the mechanical behaviour of South African coal on the basis of current proximate and other chemical parameters gives rise to problems, and the use of ultimate analyses and inferred maceral and rank analyses, although it has improved the situation to some extent, is still not satisfactory. In an attempt to reach a new level of understanding, this paper gives an in-depth review of the fundamental petrographic characteristics of coal and compares these parameters with the main types of mechanical performance. A two-tiered system of primary and secondary parameters is proposed for the prediction of coal behaviour. The primary or inherent parameters include rank and organic composition. The secondary or extraneous factors include such parameters as mineral mater, cracks or cleats, degree of oxidation, and size. In addition, an explanation is offered of several anomalous behavioural conditions in some South African coals.

Jan 1, 1987

By I. R. M. Chaston

A full and detailed description is given of the dense-medium cyclone plants used in Africa for the recovery of diamonds.

By C. L. M. Gough, L. A. Vermeulen, D. D. Howat

Formulae expressing the dependence of the mass of a grinding ball on the amount of material milled by a ball mill are derived. It is shown that, with the aid of these formulae, it is relativel rsimple for the results of a marked-ball test to be analysed and for the relative performance and cost-effectiveness 0 the various types of ball under test to be evaluated. Predictions based on theory and the results obtained in a marked-ball test in a ball mill are compared detail and shown to be in close agreement. The difficulties associated with marked-ball tests are considered, and an explanation for the decrease in the calculated consumption of the balls, which follows naturally from the theory, is presented. The marked-ball anomaly explained, and it is demonstrated that the ball consumption in a ball mill can be predicted with fair accuracy from the results of a marked-ball test.

Jan 1, 1983

By D. E. Scheck

A computer-aided blast design consultant system has been developed. The software consists of two modules: one uses theoretical and empirical formulae and procedures to design a blast based on user supplied geological and mechanical data, while the other is an expert system that analyzes blast vibration problems and recommends remedial action using knowledge based rules. The system is currently undergoing field evaluation.

Jan 1, 1987

Discussion of the above paper by G. J. van JAARSVELDt Mr Ortlepp's paper is important, and deals with a subject towards which much controversy and insufficient basic scientific logic, in my opinion, have been directed. He attempts to remedy some of our unscientific popular misconceptions, and for this we thank him. However, I regret to say that experience has shown that some of his statements cannot be allowed to pass unchallenged. Author's reply Mr Van Jaarsveld's contribution is welcome because it provides an opportunity for me to clarify certain points that were perhaps not adequately explained in the paper.

Jan 1, 1979

By J. S. Preston

The properties of some recently developed solvent-extraction reagents for the separation of cobalt and nickel sulphate solutions are reported. New commercial extractants based on alkyl phosphonic and alkyl phosphinic acids are described. These reagents show much improved selectivity for cobalt compared with established extractants. Some novel extractants developed at Mintek for the selective recovery of nickel in the presence of cobalt are also described. These reagents, which are based on mixtures of carboxylic acids and non-chelating oximes, are of interest in that no commercial nickel-selective reagents are currently available. Graphs showing metal loading and stripping, and pH-functionality, are presented. together with details of the metal separations achieved in batch countercurrent- extraction experiments with the various reagents.

Jan 1, 1983

By M. B. Cortie

An account is given of the development of ferritic stainless steels since their discovery in the early years of this century. The alloys became very widely used in the 1950s, the market during that decade being driven strongly by a demand for automobile trim made of ferritic stainless steel. The production of ferritic stainless steel declined as a proportion of the total at the end of the 1950s as consumer preferences changed. However, the market is now growing strongly again, this time driven by a demand for oxidation-resistant alloys for motor-vehicle exhaust systems. The tonnages produced, applications, and market shares of the various alloys are discussed and compared. Trends in world stainless-steel production, product forms, technological development, and usage are examined.

Jan 1, 1993

If you have problems or questions relating to the installation of this disc, please either telephone Document Transformation Technologies at (+27 12) 667 2074, or e-mail: nigel@doctech.co.za Si vous avez des problèmes relatifs àl?installation de ce disque, veuillez appeler Document Transformation Technologies au (+27 12) 667 2074, ou nous écrire par courrier électronique: nigel@doctech.co.za Produced by: / Produitpar:Document Transformation TechnologiesP O Box 560 ?Irene ?0062 ?South Africa.Tel: (012) 667 2074; Fax: (012) 667 2766; International Code (+27 12) e-mail: doctech@doctech.com website: http://www.doctech.co.za

Jan 1, 2004

By D. G. Krige

Using a very large number of chip-sample values from a mined-out area of the Hartebeestfontein mine and accepting these as equivalent to borehole values (also areas of 1 km by 1 km as equivalent to 'mines'), the authors apply a series of borehole-valuation procedures to these 'mines', Large undeveloped sections of existing mines are also regarded as the equivalent of such 'mines'. These procedures start with the orthodox arithmetic mean and then introduce additional information in the form of the Iog normal frequency distribution model for Sichel's 't' estimator. Knowledge of the average log-variance within mines leads to the tH estimator. The mean grade of the 'family' of mines to which a new mine belongs is then introduced via regression or elementary kriging. Next, further information on the macro spatial structure of the grade is used, together with the grades of adjacent existing mines in ordinary and simple macro-kriging procedures; finally, via the distribution model, the grade is seen as a function of the logs of the grades and their variances. These are introduced as spatial variables, and both are estimated by macro-Iog normal ordinary and simple kriging procedures with grades and variances from adjacent mines'. Comparisons are also made between macro-kriging on lognormal transformed values versus untransformed values. Conclusions are drawn on the relative importance of the various items of additional information used, on the procedures followed, and on the significance of the advantages gained

Jan 1, 1992

By O. L. Papendorf

The method presented in this paper can be used, instead of lengthy cash-flow determinations, for the calculation of present values in the face of physical growth and inflation.

Jan 1, 1981

By S. Budavari

The effects of shaft pillars left in deep-level hard-rock mines during the extraction of tabular deposits were studied some time ago, resulting in the formulation of design principles and procedures, which have been used with success in the design of shaft pillars in the deep-level gold mines of South Africa. The method has not yet been utilized in the design of shaft pillars in shallow and moderately deep hard-rock mines. The purpose of the present study was to remedy the situation since a great number of deposits are worked at those depths. The object of this paper is to present governing equations for the components of stress and differential movement as derived by use of an elastic model. The pillar is taken to be circular in the plane of a horizontal deposit. On the basis of the numerical results obtained, a study was made of the distribution of the vertical strain and tilt along the axis of the shaft, and of the vertical stress along the shaft and across the pillar. In every case investigated, the most adverse geometry was taken into consideration. By use of an empirical criterion and the results of some in situ observations, the determination of pillar dimensions and differential displacement components for South African gold-mining conditions is demonstrated. Pillar dimensions for shallow and moderate depths are compared with those accepted for deep-level conditions.

Jan 1, 1986

By S. M. Rupprecht

The transportation of men, material and rock in mechanization programmes is often neglected, or at least plays only a secondary function, as the primary focus is on proving the technology. This is despite recognition of the fact that mechanization is essential if gold mines are to remain competitive. However, the use of totally mechanized systems will require further research in the short to medium term before they become generally available. Thus, there is a real need to improve mechanized men, material and rock transportation systems as they are currently used. This applies to both reef horizons as well as to horizontal transport systems. Keywords: Transportation, rock handling, material handling, men transportation, face cleaning, gully cleaning, continuous scraper, monorail, mechanized raise climber, mechanization.

Sep 1, 2001

By P. A. Botha

The production of iron and steel generates various types of waste materials containing oxides, carbon, and flux material. Usually, these materials are land-filled at the plant site or are hauled away for disposal. Some of these waste materials are hazardous, and they must therefore be recycled or disposed of properly. The influence of different waste materials in iron-ore sinter blends on the quality and operational parameters in sinter production is described. The recycling of waste materials such as dolochar, scrap fines, mill scale, electric-arc furnace slag, basic-oxygen-furnace mud via the sintering process can achieve a saving in the cost of the raw materials (for example, fuels and flux) and a reduction in pollution. A comparison of a typical sinter with a sinter produced through the utilization of waste materials shows a distinct correlation between certain types of waste material and some metallurgical properties and operational parameters. Dolochar (and arc-furnace slag) in a sinter blend acts as part of the fuel and flux that are normally added to a sinter mix. In general, dolochar improves the quality of the sinter and decreases the consumption of coke. Other waste materials adversely influence the quality of the sinter, but not necessarily the operational parameters such as the production rate. At Vanderbijlpark, approximately 15 kt of various waste materials per month are successfully recycled in the sinter plant. Investigations into the handling and recycling of other waste materials may indicate that even more waste materials can be utilized.

Jan 1, 1993

By N. Coulson, P. Ledwaba

"The University of the Witwatersrand presents an accredited four-course training programme for community relations practitioners (CRPs). Between May 2013 and October 2014 six courses were facilitated for 145 participants, of whom 82% were from sub-Saharan Africa, 62% worked in mining, and 58% worked directly with communities. Thematic analysis of the comments of course participants collected during course exercises found that there were a set of coherent drivers for resilient companycommunity relationships, but that the restrainers to resilient relationships were often context-specific and dominated by politics. CRPs reported facing as many difficulties in the internal company environment as in the external environment. These findings for CRPs in Africa resonate with those worldwide.InroductionMuch has changed in how the extractive industry responds to social and community issues. There has been a growing prioritization of community-related issues within the extractive industry globally (Kemp, 2010; Tatar, n.d.). According to Kemp (2010) this can be attributed partly to escalating pressure from local-level stakeholders to push mining companies to take greater responsibility for the social, economic, and environmental impacts of mining. Securing and maintaining the social licence to operate is ranked fourth in terms of the top risks facing the mining and metals industry in 2016, up one place from 2015 (Ernst & Young, 2016).Conflicts between local communities and large-scale mining companies arise because of the social, environmental, and economic impacts of mining. Worldwide, large-scale mining companies have a poor reputation amongst communities, including those in Africa (Gilberthorpe and Banks, 2012; Kemp and Owen, 2013a; van Wyk, n.d.). For mining companies, conflicts for whatever reason, result in loss of productivity, lost opportunities, lost time, and adverse impacts on reputation (International Council on Mining and Metals, 2015). Conflicts also have a significant financial impact on mining operations (Franks et al., 2014). Davis and Franks (2014), estimated that US$10 000–50 000 is lost each day when a project is delayed during the exploration phase, and about US$20 million per week when in operation. Today these costs could be expected to be higher due to increasing input costs."

Jan 1, 2017

The kinetics of adsorption of gold di-cyanide onto activated carbon has been investigated extensively over the past two decades. These studies have demonstrated that both film and intra-particle mass transfer affect the kinetics. The dominant mechanism of intra-particle mass transfer has not yet been identified. In the work described, surface diffusion and pore diffusion are considered as possible rate-determining mechanisms of intra-particle mass transfer. Mathematical models are described that incorporate film mass transfer and the respective intra-particle mass transfer mechanism with equilibrium described by a Freundlich isotherm. Rate constants of film mass transfer and pore or surface diffusivities were estimated by the fitting of the respective models to experimental carbon adsorption data. The estimated pore diffusivities, after they had been corrected for the porosity and tortuosity of the carbon, were found in most instances to be higher than the molecular diffusivity of dilute gold di-cyanide in aqueous solution. This situation is not physically viable. The surface diffusion mechanism acting in parallel with the pore-diffusion mechanism is thus responsible for the intra-particle transportation of most of the gold.

Jan 1, 1996

By R. Rubin, P. A. Laxen, G. S. M. Becker

An account is given of developments in the use of activated carbon for the recovery of gold from cyanide solutions. The carbon-In-pulp process employed at the Homestake Mine is described, and its various applications in South Africa and their effectiveness are discussed. Probable future work on the carbon-in-pulp process and other possible applications of carbon for the recovery of gold are outlined.

Jan 1, 1979