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By Clarence Hall, S. P. Howell, W. O. SNELLING

The explosives used in coal mines not only occasion accidents such as occur in the use of explosives elsewhere, but they frequently cause widespread disasters by igniting explosive mixtures of mine gas and air and of coal dust and air, or both. In addition, the firing of ex- plosives so shakes the walls and roofs of the mines as to cause falls, with their attendant casualities. Considering the large number of explosives and their wide range in composition and properties, it is obvious that certain of them should prove more suitable for use in coal mines than others. The problem is to determine which explosives are the most suitable for this purpose and the precise conditions under which they may be used with the greatest safety. Of course this problem could be worked out in actual mining, but experimental investigations when accompanying commercial opera- tions are hazardous and slow. To obtain the information sought, in the speediest and most economical manner, laboratory methods must be resorted to. The adoption of such methods began about 30 years ago with experiments in an iron gallery mounted on wheels, at Zwickau, Germany. This laboratory method of attacking the prob- lem has so commended itself that it has not only been repeated else- where in Germany but has at intervals been officially adopted, with many modifications and additions, by the Governments of Belgium, Austria, France, and Great Britain. Such was the status of coal-mine investigations in Europe when in 1904, an organization in the Geological Survey, which in 1907 be- came the technologic branch, was created to investigate the mineral- fuel resources of this country. At that time no division of the Na- tional Government had official cognizance of conditions existing in our mines, but through its system of collecting fuels for tests the technologic branch was forced to recognize that coal-mine accidents are a factor that must be reckoned with in determining the extent and availability of our mineral-fuel resources. This became so apparent, and it was so obviously a function of this branch to make a systematic research as to the cause and prevention of such acci- dents, that in July, 1907, experts were appointed especially to deal with this problem. As a result, not only was Bulletin 333, on Coal- Mine Accidents: Their Causes and Prevention, prepared and pub- lished, but through personal inspection of foreign testing stations, and a study of their reports and the critiques of their methods and operations, definite plans for the establishment of such a testing station in this country were formulated. In the latter part of 1907, four grave disasters occurred in close succession consequent on explosions in the Monongah mines in West Virginia, where 368 men were killed, the Darr mine in Pennsyl- vania, where 160 were killed, the Naomi mine in Pennsylvania, where 34 were killed, and the Yolande mine in Alabama, where 61 were killed. These frightful disasters so quickened the public con- science, and so plainly demonstrated that both humanitarian and economic needs demanded that steps be taken to prevent the re- currence of such accidents, that in 1908 Congress made a special appropriation for an investigation as to the "causes of mine ex- plosions." A similar appropriation was made in the following year. By act of May 16, 1910, the Bureau of Mines was created "to make diligent investigation of the methods of mining, especially in relation to the safety of miners, the use of explosives, the prevention of accidents," and other matters relating to mining. Therefore, these investigations are at present conducted in obedience to an organic act instead of being dependent solely upon special appropriations. The first appropriation became available July 1, 1908. Through the courtesy of the War Department a portion of the grounds and buildings of the arsenal at Pittsburgh was granted for the use of the technologic branch of the United States Geological Survey. Work was immediately begun in procuring and erecting the necessary instru- ments and appliances for carrying out the desired tests and inves- tigations and in adapting the existing buildings or in erecting new structures to contain the apparatus. The Pittsburgh testing station was officially opened and regular work was commenced on December 3, 1908, the apparatus and appliances having been tested, the force drilled in their use, and the equipment and methods inspected and passed upon by foreign experts.

Jan 1, 1912

By Joseph Grumer

About a century ago Bunsen and his associates invented the famous burner that bears his name and was to become the ancestor of today's gas appliances. Over the years, Bunsen's invention became the starting point of a highly developed, practical technology that culminated in the gas industry as we now know it. However, it did not occur to the early workers to investigate the scientific potentialities of the new device, and as a result the science of gas-burner performance did not keep pace with the growing industry. It was with the objective of closing the rapidly widening gap between science and technology that the present research was undertaken Its immediate purpose was to provide basic information on the combustion characteristics of .fuel gases, in particular as they affect flashback, blowoff, and yellow tipping. Information obtained in the present research and contained within this report consists of the following: (1) Fundamental flashback and blowoff characteristics have been determined, it is believed, for all fuel-gas mixtures in which the gas industry may be interested. These are critical boundary velocity gradients for flames in free air, on burners with ports at room temperature and pressure. Burner aeration is characterized by the parameter, fraction of stoichiometric. These basic limits are explained, values are presented, and calculation procedure is given for deriving corresponding values of port loading and percent primary air (chs. I and II).

Jan 1, 1956

By D. R. Tesarik

The factor of safety, the traditional measure of stability for earth embankments, is graphically presented in factor of safety charts in this Bureau of Mines report. Factor of safety contours are drawn for homogeneous earth embankments for two contrasting situations: (1) no phreatic surface and (2) a phreatic surface that assumes 10-pct freeboard. The factor of safety can be read directly from the charts if the physical properties of the soil and the geometry of the embankment are known. The curves provide a quick first approximation of the "most stable" and "least stable" condition of the embankment. The Simplified Bishop Method was used for the safety factor calculations, and a sequence of least squares curve fitting steps was used to present the factor of safety in final chart form.

Jan 1, 1981

By Mackenzie Burnett

The Brattice Window Method was used to measure the leakage rates of a total of 42 ventilation stoppings in 8 hardrock mines. Various types of stopping construction were evaluated. The following types are listed in order of decreasing effectiveness: 1) Cinder block, 2) Timber and mortar, 3) Timber and polyurethane foam, and 4) Timber and brattice material. There are slight differences in the effectiveness of the first three types, while the timber and brattice type is substantially inferior to the others. The repeatability of the Brattice Window Method was found to vary with physical conditions in the mine such as stopping location with respect to intersections, regularity of drift cross section, and the presence of hardware such as air and water pipes, timber sets and wire mesh. The Brattice Window Method is viewed primarily as a tool for estimating and comparing stopping leakages for the purpose of determining where repair efforts should be concentrated. A laboratory test program resulted in the derivation of several "rules of thumb" for employing the Brattice Window Method, which will aid in securing accurate and repeatable data.

Jan 1, 1979

By NEFE NONE

Possible New U.S. Half-Dollar. - Tile George Washington Commemorative Coin Act, H.R. 3133, was introduced in the House and approved by the House Banking Committee. It would allow the minting of at least 10 million commemorative silver half-dollars the size of the same coin produced before 1965. A companion bill, S. 1228, was introduced in the Senate. Taxes and the U.S. Minerals Industry. - The General Accounting Office completed a report to Congress on "Assessing the Impact of Federal and State Taxes On the Domestic Minerals Industry." the study presents a quantitative method to assess the effect of taxes on profitability, and suggests ways to use taxes or tax credits to help marginal mine operations and possibly to increase mineral production, Limited copies of the 139-page report are available free of charge from U.S. General Accounting Office, Documents Handling & Information Sevices Facility, P.O. Box 6015 Gaithersburg, Md. 20760.

Jan 1, 1981

By James R. Dunn

Samples were taken of industrial mineral waste materials which are potentially capable of being used for filling underground coal mines for subsidence control in the Pittsburgh and the Scranton-Wilkes Barre areas of Pennsylvania. The samples were subjected to potentially relevant standard tests which are commonly used 1n the evaluation of soil materials and mineral "aggregate materials. Measurements of plasticity, liquid limit, and gradations, particularly in the -200 mesh size range, indicated a comparative lack of clay minerals. Cementitious reactions between sources of alkali, such as calcium hydroxide or portland cement stack dust, and of silica, such as clay or fly ash, were found to occur in various mixes of high-bulk materials. Strengths of up to about 400 psi at 84 days were observed. The possibility of emplacement of high-bulk material by both turbid flow (or density currents) below water and by mud flows above water were considered and both appear to be reasonable and possibly simpler than the current mechanisms of emplacement.

Jan 1, 1977

By R. L. Benner

The Bureau of Mines investigated the ZnO-Fe2O3-Fe3O4 system at 1,000°, 1,300°, and 1,400° C, with oxygen pressures between 1.0 and lx10-4 atmospheres. The results, divided into the thermodynamic properties as related to the spinel structure, and the thermodynamic properties as related to zinc concentrate roasting, were used to calculate the activities of ZnO, Fe2O4, and Fe3O4 within the spinel solid solution region of the ternary system, and the pseudo-binary activities of ZnFe2O4 and Fe304. The activities of both systems show large positive deviations from Raoult's Law, especially at high Fe3O4 concentrations. The free energies, the enthalpies, and the entropies of mixing for the binary system were calculated from the binary activities, and the entropies of mixing were compared with two statistical models, one representing an ideal solution, and one representing the mixing of a normal with an inverse spinel. The binary entropy of mixing seemed to be better represented by the latter statistical model, indicating that the tetrahedral and octahedral cations of the reactants tend to remain in the product, even at the high temperatures of the study. This comparison also indicated that the cations of the components are the major contributing factors to the thermodynamic properties.

Jan 1, 1966

By Terry S. Cory

This report is a comprehensive summary of the results of the propagation measurements program conducted for the US Bureau of Mines under Contract H0366028. Data was gathered in the MF frequency range from a cross sample of six mines representative of the industry having typical wireless requirements. From the raw data which was gathered, a logical method of data reduction is presented which culminates in a set of average attenuation characteristics for all mines visited. These characteristics define a typical MF wireless system when the communication range requirements are known. Direct through-the-earth propagation and the range enhancement mechanism due to coupling on and off conductors are evaluated and related to the planning of a typical wireless MF communications system.

Jan 1, 1977

By C. S. ROBINSON, T. M. Romslo

This investigation was conducted jointly by the Bureau of Mines and the Geological Survey to obtain further information on the source and economic possibilities of the copper mineralization exposed on the Copper Giant group of claims, Ajo mining district, Pima County, Ariz. The Copper Giant group of claims was first brought to the attention of the Bureau of Mines by Joseph Hunter (deceased), Phoenix, Ariz., part owner of the claims. In December 1942 these claims, and an adjoining group, were investigated by T. C. Denton, mining engineer, formerly with the Bureau of Mines, and Nels P. Peterson, geologist, Federal Geological Survey. It was concluded the area could not be considered as a source of copper for immed- iate emergency needs and that further investigation of the area, at the time, was not warranted. In the spring of 1948 the lessee, J. H. Greenway Albert, requested Bureau of Mines assistance in developing the property. J. H. Hedges, former chief, Tucson Branch, Mining Division, and Lincoln A. Stewart, mining engineer, Bureau of Mines, made a cursory examination of the property and noted that at numerous places, low-grade copper mineralization appeared on fractures and bedding of the Locomotive fanglomerate and Ajo volcanics, which are thought to be of Tertiary age. During the period of May 11 through 14, 1949, Bureau of Mines engineers3 mapped and sampled two areas of mineral- ization. On June 2 and 3, 1949, the areas selected by the Bureau and three other nearby mineralized areas were investigated by C. A. Anderson and R. S. Cannon, Jr., of the Federal Geological Survey. As a result of these examina- tions, further investigation of certain areas was believed to be merited. The Copper Giant area was selected as the most favorable in which to carry out exploratory and development work. The field work on the project was started in October 1949 and completed in December 1949. It consisted of road building, trenching, sampling, topo- graphic and geologic mapping, diamond drilling, and logging of core. Samples taken on the project and during preliminary examinations totaled 64, of which 63 were surface samples. Diamond drilling, started October 10 and completed December 7, consisted of two holes for a total depth of 1,542 feet.

Mar 1, 1952

By Motohisa Kanda

The time and amplitude statistics necessary to adequately describe electromagnetic (EM) noise in mines are illustrated through computer software techniques. They are 1) Allan Variance Analyses (AVA), 2) Interpulse Spacing Distributions (ISD), 3) Pulse Duration Distributions (PDD), 4) Average Crossing Rates (ACR) , and 5) Amplitude Probability Distributions (APD) . These statistics are illustrated using data taken from a rather large store of raw analog data recorded in operational mines. The curves generated for the illustrations characterize the noise environment in the mines from which the corresponding data were taken, and should aid in the design of reliable communication systems for such mines.

By W. S. Sanner

This report describes the commercial application of the launder screen in anthracite-industry fine-coal cleaning operations. No new device, the launder screen has been used since the early part of the present century to size, screen, classify, and deslime the fine-anthracite sizes (Buckwheat Nos. 1 through 5) recovered by "river-coal" men dredging along streams draining the anthracite fields. The launder screen is stationary, has no moving parts, requires ample water for operation, and can be constructed economically on the job. Essentially, it consists of a wooden trough with baffles placed through its width to form a well system. The wells are covered by fine-mesh woven-wire screening. Each well is tapped with a number of orifices, and the hydraulic suction head developed in this manner removes high-gravity fines and slimes through the screening as underflow to waste. Material retained on the screen surface discharges as overflow product.

Jan 1, 1954

By K. C. Dean

During investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from several properties in Montana. Extensive laboratory tests were made to determine the amenability of these ores to standard ore-dressing methods of concentration to produce marketable-grade products. The Tzarena claim, one of the properties sampled, is on the western end of the Rama or Black Chief vein in the city of Butte, Silver Bow County, Mont., on the southwestern periphery of the mining district. The Black Chief 'WAR system contains one of the largest and most extensive known rhodochrosite deposits in the world. Test work was conducted on two samples of Tzarena ore. Sample 1 is representative of a vain 5 feet wide on the 150-foot level of the Tzarena shaft. Sample 2 is representative of a vein 8 feet wide in the 100-foot level of the shaft. The Minnie Jane mine, 1/2 mile northwest of the Tzarena claim, contains ore similar in mineralogical composition to Tzarena ore but differing materially in manganese content and to some extent in physical characteristics. Ore-dressing investigations were made on three samples of Minnie Jane ore. Sample 1 represented stock-piled ore, sample 2 represented ore from Minnie Jane mine having a considerable sulfide content, and sample 3 represented low-grade ore.

Jan 1, 1951

By Philip C. Tully

These modifications to the Redlich-Kwong equations for pure hydrogen and neon were developed after an unsuccessful attempt to generalize a modification technique previously developed for helium. New coefficients of the B terms were developed by minimizing the residuals. No changes were made in the coefficients of the A terms. For normal hydrogen, B was changed to [0.08063Tc PcT] for temperatures from 980 to 423° K and pressures up to 1,050 atm. The average deviation in Z was 0.36 percent with maximum deviations less than 1 percent for all but a few low-temperature points. For neon, B was changed to [PCT 0.1025T], for temperatures from 120° to 973° K and pressures up to 1,500 atm. The average deviation in Z was 0.34 percent with maximum deviations less than 1 percent for all but a few high-pressure and low-temperature points. Efforts to attain a lower temperature range to comparable accuracy with this type of modification were unsuccessful. In the range of applicability, these equations should be used with caution when calculating derived thermodynamic functions, such as the isobaric specific heat.

Jan 1, 1968

By Robert S. Sanford

Intensive investigations of domestic manganese deposits were conducted by the Bureau of Mines and the Geological Survey during the earlier part of the war minerals investigations when there was doubt that the quantity of manganese needed to produce the greatly increased tonnage of steel demanded for war supplies could' to obtained from its customary sources. Domestic deposits of ores that contain sufficient manganese for direct production of ferromanganese essential in steel Manufacture are generally small, and the bulk of the supply is imported. One of the few large deposits of low-grade manganese ore known in the United States is in the Artillery Peale district in southern Mohave County, Ariz. Manganiforous sediments underlie a very large area. Several large groups of claims, covering the most of the manganese-bearing ground, wore assembled in 1929 and 1930. The greater part of this area was leased by the M. A. Hanna Co. in 1937. Investigations by engineers and geologists for this company revealed that the average content of manganese is very low; but that the Maggio Canyon area, about 180 acres, contains higher-grade material. The company put down 28 vertical diamond-drill holds to explore this ground, under the direction of B. N. Wobbor, geologist.

Jan 1, 1948

By A. T. Sweet, G. Douglas Gardner

"INTRODUCTION In the ammonium sulfate process for the production of alumina from clay,,3/ the clay is baked with amonium sulfate at about 400ºC. to form anhydrous ammonium alum and free ammonia or ammonium carbonate. The alum is leached from the baked product with water and circulating liquors and is purified by recrystallization. Aluminum hydroxide is precipitated by treating thus alum the alum the ammonia or ammonium carbonate from the baking step. Ammonium sulfate is recovered from the filtrate for reuse, and the aluminum hydroxide precipitate is calcined to produce high-purity alumina. In this process, as in other acid processes for the production of alumina, 4/ a large part of the iron in the clay is extracted. The iron tends to build up in the leach liquors and contaminate the crystals, so that its elimination is one of the most important problems in the process. A number of large clay deposits occur in the Western States. Those that have boon explored most extensively 5/contain an average of 24 to 30 percent available A12O3 and 2 to 8 percent available Fe2O3. 6/ The available Fe2O3 content of various other clays ranges from less than I percent to more than 20 percent. The available Al2O3 or Fe2O3 is usually 90 to 98 percent of the total but may be much less. In generals the iron content bears no fixed relation to the alumina content and may vary widely within a given deposit."

Jan 1, 1948

By C. G. Maier

The fundamental chemistry of zinc smelting, especially that part dealing with the chemical reduction of the zinc-oxide content of a roasted zinc ore, has been discussed by metallurgists in some detail, but, in the light of present knowledge, unsatisfactorily. A considerable portion of the information available has been qualitative, or quantitative in a sense that could not be interpreted chemically. A number of attempts to elucidate the physical chemistry of zinc oxide reduction have been based upon unsubstantiated and, as is now known, incorrect equilibrium data. To write upon the chemistry of zinc smelting at this time, when electrolytic methods for the production of zinc metal from ore are becoming increasingly widespread, may seem a belated effort. So, for example, C. A. Hansen,3 in the communicated discussion of an article by the author,4 writes as follows:

Jan 1, 1930

By W. W. Adams

The accident-prevention record of the coal-mining industry in the United States was more favorable in 1936 than in 1935, both from the standpoint of the relative safety of the individual miner on the job and of the price in life and limb that the Nation paid for its year's supply of coal. The increase in relative safety of the individual miner was indicated by a lower death rate and a lower injury rate than in the preceding year per million man-hours of exposure to the hazards of mining; that is, per million hours of work performed by the employees. (See table 1.) A reduction in the price in life and limb that the Nation paid for a year's supply of coal was indicated by a smaller death rate and a smaller injury rate per million tons of coal produced. Thus the individual miner was a better insurance risk, as far as accidents were concerned, in 1936 than in 1935, and a ton of coal used in the homes and industries of the country represented less human suffering than in 1935. The two points of view are distinct, and both should be kept in mind when considering accidents and safety in coal mining or in other industries. More men were employed in 1936 than in 1935, and more workdays were available for the individual miner. Large gains were also made in the total number of man-shifts and man-hours worked in the industry as a whole. In number of tons of coal mined, 1936 showed large gains over 1935. Moreover, the average output of coal per man-hour worked was higher in 1936 than in 1935. All of these gains were made without lengthening the average number of hours of work per man per day.

Jan 1, 1939

By Albert W. Deurbrouck

This report describes the preparation characteristics of the significant, presently producing coalbeds in Mercer County, W. Va. Approximately 650,000 tons of coal was produced in Mercer County, W. Va., in 1960, of which over 630,000 tons was cleaned in four preparation plants. In 1960 the Pocahontas Nos. 3, 6, and 11 coalbeds supplied 99.5 percent of the total coal mined in the county. Because the number of working mines In this county was small, only six samples were collected; four of which were of metallurgical quality as mined. The remaining two samples could be upgraded by washing at suitable specific gravities. Many of the samples taken were of metallurgical quality as mined; however, the float-and-sink analysis on these coals has been included to point out their amenability to the production of premium quality, special purpose coals. In general the coals were low-volatile bituminous in rank with low ash and sulfur contents.

Jan 1, 1963

By Lloyd Williams

1. The investigation shows that the Coal Creek has been the most productive, bed in Campbell County and contains the largest recoverable reserves of coal. The Pewee, Red Ash, and Jullico have been relatively productive beds and contain appreciable recoverable reserves of coal. The Blue Gem also has been productive in the past, but available information indicates that most of the remaining coal is Less than 28 inches thick. The Big Mary has relatively large reserves over 28 inches thick, but the coal is high in ash and sulfur. Thick partings in the Windrock bed have discouraged mining in that bed. The Poplar Creek and Rex beds generally are below drainage, and large areas have been excluded from the reserve estimate, Reserves in the Walnut Mountain bed will be difficult to mine due to the irregu¬lar thickness and lack of continuity of the bed. Estimated coal reserves are- small in the remaining five beds. 2. Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 short tons per acre-Foot of coal in place, are estimated to be 398 million tons as of January 1, 1953, o? this total, 267 million tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, these should be added to the total estimated reserves.

Jan 1, 1956

By L. H. ADAMS, C. N. HASKINS, J. K. CLEMENT

In the course of its investigations of the fuel resources in the United States and of the methods by which these resources could be utilized with greatest efficiency, the United States Geological Survey tested a great variety of coals and lignites as gas-producer fuel. Early in these testa it was found that many factors controlling the formation of gas in the generating chamber of the producer and, consequently, having a direct bearing on the management of producer-gas plants, were not as well understood as they should be. The Geological Survey therefore took up a detailed investigation of the chemical and physical processes that take place in the producer, keeping in view not only the possibility of increasing the efficiency of the producer as a source of energy, and the ensuing benefits to the public of cheaper power and greater utilization of low-grade fuels, but also the application of the results to the problems of boiler-furnace operations. - The Bureau of Mines, to which the testing and analyzing of fuels as carried on by the United States Geological Survey has been transferred, is continuing producer-gas investigations at the testing station at Pittsburg, Pa. Results of the gas-producer tests a made at the coal-testing plant erected at St. Louis, Mo., and of a study of some of the problems° that came up in the tests have been published by the Geological Survey. Results of the tests made at Norfolk, Va., and Pittsburg, Pa., and of further studies of particular problems, will be published by the Bureau of Mines. In the gas producer solid fuel is transformed into more readily combustible gaseous fuel. The transformation is relatively slow and consists of several processes: 1. The distillation of the volatile hydrocarbons from the freshly fired fuel at relatively low temperatures. 2. The combustion of the fuel by its combining with the oxygen of the air forming carbon dioxide (COO. 3. The formation of carbon monoxide (CO) and hydrogen (11 3), the essential constituents of producer gas, in accordance with the equations:

Jan 1, 1911