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By H. C. Young

This paper deals with roof bolting in Alabama coal mines and iron-ore mines from the time it was introduced in early May 1948 to May 1, 1953, a 5-year period. The Tennessee Coal & Iron Division of the United States Steel Corp. began systematic roof bolting in early May 1948 in a coal mine and in an iron-ore mine, which had some of the poorest roof conditions in the Alabama mines. After the efficiency of roof bolting had been proved by the Tennessee Co. it was gradually adopted by other companies throughout the State, until in May 1953 approximately 53 percent of Alabama's total coal production and 100 percent of Alabama's total iron-ore production, mined underground, was being produced from roof-bolted areas. Statistics in this report will show the advancement made in roof bolting in the 5 years and also the amount of roof bolting that was being done as of May 1, 1953. Significant progress has been made in the coal and iron-ore mines of Alabama in reducing the roof-fall fatality rates during the past several years by adopting systematic roof bolting. The groundwork was laid through successful experiments early in 1948 by the Tennessee Coal & Iron Division of the United States Steel Corp. in cooperation with the Federal Bureau of Mines. This experimental work was based upon the previous experience of the St. Joseph Lead Co.2/ in its Southeastern Missouri mines.

Jan 1, 1954

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spectroscopy has been employed to· examine the role of tetraperoxochromate( V) ions (Cro:-) and other Cr(V) species in the generation of hydroxyl (OH) radicals in the reaction of Cr(VI) with H2O 2 in biological media. In contrast to earlier suggestions, the present ESR studies using crystalline K3CrO8 as a source of Cro:- show that decomposition of Cro:- in water or in H2O 2 does not generate significant amounts of OH radicals. Addition of NADH to a solution containing Cro:- yields a Cr(V)-NADH complex, which readily reacts with H2O 2 to generate OH radicals. Similar results obtained from several other biological reductants, including vitamin B2 , indicate that a vacant coordination site on a Cr(V) complex facilitates its reaction with H2O 2 to generate ""OH radicals. We thus suggest that in biological media, reaction [3] instead of [1] or [2] is the major pathway for the OH radical generation: While the carcinogenic potential of Cr(Vl)-based compounds has been well established via epidemiologic and animal studies (1), the underlying biochemical mechanism is still not well understood (2). In a recent development, however, Kawanishi et al. (3) have reported that hydroxyl (OH)2 radicals might be the key species in the mechanism of Cr(VI) toxicity. As to the mechanism of the ""OH radical formation they suggest that Cr(VI) reacts with cellular hydrogen peroxide (H2O 2) to form the tetraperoxochromate(V) (Crog-) ions, which decompose to produce hydroxyl radicals. It was also suggested (3) that the ""OH radicals thus produced cause genotoxicity via DNA base modification and deoxyribose phosphate backbone alterations. More recently Aiyar et al. (4) reported the detection of OH radicals in the reaction of Cr(VI) with H2O 2 in biological media, including the reaction of ""OH radicals with deoxyguanosine to generate 8-hydroxydeoxyguanosine adducts, confirming that ""OH radicals could indeed play a significant role in the mechanism of Cr(VI) toxicity. However, the mechanism for the ""OH generation was not clarified, although the role of Crog- ions as possible precursors was mentioned, somewhat along the lines suggested by Kawanishi et al. (3). The possibility of the participation of Crog- in the ""OH generation has also been indicated by Sugiyama et al. (5), since they mention that vitamin B2 enhances the formation of""OH radicals in the reaction of Cr(VI) with H2O 2 because of the generation of Crog- in the reaction."

Jan 1, 1990

The method of using large-diameter augers to recover coal was introduced to the mining industry about the end of World War II, and production of bituminous coal with augers has increased steadily to an estimated 7 million tons, or approximately 1.4 percent of the total mined in 1956. Although auger mining has proved to be a reliable and economical method of mining coal, a number of unfortunate fatal accidents have been experienced; consequently the need for these recommended safety standards is indicated for this comparatively new method of coal mining. As mining methods and equipment change from time to time and new hazards are introduced, these standards will be revised; therefore, questions or suggestions from the coal-mining industry will be welcomed and carefully considered.

Jan 1, 1958

By Arnold J. Farstad

The Location Group conversed in the Petroleum Room of the Green Center with the purpose of addressing the following list of topics in light of the Bureau of Mines' requirements for detecting and locating trapped miners by electromagnetic methods. These topics include: Noise, Sources, Antennas (transmit and receive), the Propagation Medium, Signal Processing, Optimum Frequency, Receivers, Pulse vs. CW Techniques, Passive Location Techniques, and Obstacles. Practical constraints such as equipment size, weight and power requirements, cost and intrinsic safety were kept in mind during these discussions. It was emphasized that in-mine equipment must be inexpensive, rugged, simple and lightweight. Otherwise, the mine operators probably would not buy it nor would the miners be able to effectively use it. Present techniques for experimentally detecting and locating trapped miners were discussed, along with techniques to improve their location accuracy. Analytical, numerical, and scale modelling methods were considered as a means of giving further insight into measurement, anomalies caused by terrain variations, conductivity contrasts, and obstacles. After discussion of these topics, conclusions were drawn and existing problem areas were identified. These problem areas were addressed in developing guidelines for future efforts. Following the discussion period, the Chairman gave a summary of the Location Group report and comments were solicited from the entire group. 2.0 GROUP DISCUSSION HIGHLIGHTS 2.1 Noise W. Bensema asked the group whether the noise data provided by NBS was adequate. It was determined that for location systems analysis, the most important form of noise data was the frequency spectra of vertical and horizontal magnetic fields on the surface, and the answer to his question was affirmative. Drs. Wait and Frischknecht pointed out the difficulty in accurately measuring the true vertical magnetic field since these measurements are heavily influenced by the loop setting and the local geology. Nevertheless, these measurements are important since the same perturbations would also affect a receiving loop oriented to receive the vertical magnetic field. Dr. Rankin pointed

Jan 1, 1973

By Ivette E. Torres

Bulk carriers, freighters, and tankers are the three classes of seagoing vessels engaged in transporting mineral commodities. However, vessels in these classes are not exclusively devoted to mineral commodity transport. Bulk carriers move considerable tonnages of agricultural products as well as crude minerals, their concentrates, mineral fertilizers, and the like. Freighters, owing to their great variety, can be devoted wholly to hauling mineral products or wholly to nonmineral goods, as well as carrying mixed mineral commodities and nonmineral commodities. They include general cargo ships, full container ships, partial container ships, roll-on/roll-offships, and barge carriers. Tankers, although largely engaged in moving crude oil and refinery products, also transport liquid chemicals, molasses, wine, liquefied natural gas, and other fluids. Although physical characteristics of vessels such as size, draft, crew requirements, type of propulsion system, ratio of gross tonnage to cargo tonnage, and fuel costs have undeniable influences on shipping industry performance, problems of and changes in the quantity and types of materials moved also significantly affect the shipping sector of the world economy, and thus have a bearing on the minerals sector of that aggregate. Unfortunately, comprehensive global data reflecting changes in these critical variables are not published.

Jan 1, 1994

By J. T. McCartney

In an effort to correlate the size of pyrite particles in coal and coal-particle association with the removal of pyrite before burning, the Bureau of Mines conducted a study of 61 coals presently being used for electric power production. The results were obtained by visual microscopic studies of polished briquets of minus l4-mesh samples. Mean pyrite particle sizes ranged from 20 to 400 microns and proportions of pyrite contained in coal particles to an extent greater than 50 percent by volume (estimated) ranged from 20 to 95 percent. These parameters were correlated with reductions in pyrite accomplished by float-sink tests at 1.60 sp gr on 14-mesh, 3/8-inch, and 1-1/2-inch samples. The correlation coefficients between pyrite removal and mean pyrite particle size were 0.89, 0.84, and 0.79, respectively, for these samples. Correlation coefficients between pyrite removal and coal-pyrite association parameter were 0.92, 0090, and 0.85, respectively. It is apparent that extent of pyrite removal can be fairly well predicted from microscopic analysis.

Jan 1, 1969

By James S. Browning

The Bureau of Mines conducted laboratory and small-scale continuous tests of kyanite ore from Georgia to determine the technical feasibility of recovering commercial-grade kyanite concentrates by flotation. The research indicated that combinations of sulfuric acid and petroleum sulfonate may be used effectively for flotation of kyanite from quartzite-kyanite ore. Over 87 percent of the kyanite was recovered in a concentrate analyzing 55.8 percent A1203 and 5.3 percent acid-soluble Fe203. Subsequent treatment of the flotation concentrate by high-intensity wet magnetic separation reduced the acid-soluble Fe203 to 0.8 percent and increased the alumina content to 57.6 percent, with a recovery of 82.7 percent of the total alumina in the ore.

Jan 1, 1970

By M. J. Sapko

The pressure and flame development of the methane-air-nitrogen system was investigated in the Bureau's l2-foot-diameter sphere to define buoyancy effects and to develop relationships for predicting venting requirements. Pressure rise (?P) is defined as a function of time (t) and nitrogen dilution and is shown to deviate noticeably from the cubic law (?P = kt3), depending upon the period of combustion and the mixture composition. Corresponding flame speed (Sf) and burning velocity (Su) data are given which show that Sf is time dependent and that Na dilution has a greater effect than air dilution in inhibiting the flame propagation. The Su data agree with "accepted" values and are unique in that they are based on much larger flames than those used in other investigations. Downward propagation limits are shown to depend mainly upon buoyant forces, which can affect the burning of even stoichiometric CH4-air systems. Theoretical expressions, based on the mixture burning velocity and expansion ratio, are given for predicting the venting requirements for ignitions of hydrocarbon-air-nitrogen mixtures in spherical or cubical enclosures.

Jan 1, 1976

Determine what diameter piping is necessary to obtain sufficient water flow to spray nozzles used for dust suppression. Approach A simplified, diagrammatic method of calculating the flow of water through a proposed system consisting of a supply line and two banks of spray nuzzles is outlined. How It Works The pressure versus flowrate of the supply at the tapping point must be known or measured. The supply curve of typical city water at a 1 ¼ -inch pipe outlet is shown by the lowest curve in Figure 1. A supply curve for a typical pump fed from an open sump is shown by the middle curve. The combination of these, the supply curve of a pump fed by the city water supply is shown by adding the lower two curves to get the upper curve. A pump supply curve showing flowrate versus pressure is usually supplied by the manufacturer. The water supply line flow curve can be determined by measuring the time required to fill a 55 gallon barrel at various valve settings to determine flow, and by measuring corresponding pressures at the valve with a gauge.

Jan 1, 1979

By Ivette E. Torres

The series summarizing the prices of the major nonferrous metals on the stock exchanges of the United States and the United Kingdom (London Metal Exchange) has been continued this year in tables 22 and 23. Time constraints have prohibited preparation of other price information that has appeared in this study in previous years. Users are urged to consult the 1993 U. S. Bureau of Mines publication Metal Prices in the United States through 1992, which gives an analysis of historical price series and trends, or the 1993 edition of Mineral Commodity Summaries for current U.S. prices on non fuel commodities, and to utilize U.S. Department of Energy sources for information on fuel material costs.

Jan 1, 1994

Improve the safety and comfort of operators of large mining equipment. Approach Develop an improved driver restraint system that is easy to use, reliable, and cost-effective, while providing increased protection in the event of a collision or rollover. The Novel Restraint System There are several problems associated with conventional lap-belt type restraint systems. Among these are: restriction of movement, lack of comfort, and fear of entrapment. Standard seatbelts become dirty and oily from lying on the vehicle cab floor and can ruin a driver's clothes. Some haulage equipment may not even have seatbelts available to drivers since they are sometimes removed during maintenance activities or as a result of vandalism. Recognizing a need to address such problems by providing a more acceptable means of driver restraint, the Bureau of Mines designed and fabricated a novel vest-type restraint system. The vest is designed to be worn during a driver's 8-hour shift and would be issued much like safety glasses, hard hats and safety shoes, thus becoming part of the operator's individual protective equipment and assuring that each vehicle has a restraint system when in operation. The vest-

Jan 1, 1985

By John B. Umhau

[' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta l' is ann.tal surve:' gives sta.tistical data regC:ll~dirg rims.ry and feCOA-dUTY or ~cra:p tin used in thL United States by industries anc. includcc dc..ta ]

Jan 1, 1938

"The U.S. Bureau of Mines established on August 15, 1983, The Generic Mineral Technology Center for Respirable Dust (Dust Center) within the Mining and Mineral Resource Research Institutes (MRIs) at The Pennsylvania State University and West Virginia University, and in association with participating MRIs at Massachusetts Institute of Technology and the University of Minnesota. In 1986, Michigan Technological University (MTU) was awarded a grant through the Dust Center. The center's research program has been developed with recognition of the stated objective of the Federal Mine Safety and Health law, which is ""... (to) permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis of any other occupation-related diseases..."" The Dust Center's program is designed to foster an accelerated attack through fundamental research on problems confronting the control of respirable dust in mines. The interactions of the universities and the research program components in the characterization of coal seams, respirable dust particles and the workers lungs are depicted in the logo of the Dust Center.The primary goal of the Dust Center is to reduce the incidence and severity of respirable dust disease through advancing fundamental understanding of all aspects of respirable dust associated with mining and milling, and the interaction of dust and lungs. The Dust Center's research program explores these concerns with the objective of refining existing strategies and developing new respirable dust control techniques that are consistent with the fundamental dust-lung interaction processes that lead to mine worker disability. The work concentrates on: (1) control of dust generation; (2) dilution, dispersion and collection of dust in mine airways; (3) characterization of dust particles; (4) interaction of dust and lungs; and (5) the relationship of the mine environment, geology, and seam characteristics to dust generation and mobility. The fundamental aspects of this work are applicable to the control of respirable dust problems in both hard rock mines and coal mines, and to other dusts such as those generated by diesel equipment. Achieving the Dust Center's goals also involves the training of engineers and scientists, graduate students, and undergraduate students through their respective institutions, and technology transfer to industry. The distribution of personnel in the various universities are presented in Table 1. A directory of Dust Center principal investigators is presented in Appendix 1. A summary of degrees granted and mineral sector employment is presented in Table 2. The subjects of theses developed under the various research projects are presented separately in Volume 7. The center research is fully compatible and complementary with the existing and ongoing U.S. Bureau of Mines activities (see Volume 2). Additionally, the expertise and facilities of the NIOSH--Division of Respirable Disease studies are available as a result of the existing relationship between NIOSH and West Virginia University. Figure 1, Respirable Dust Center Projects and Activities, presents the various projects in the five major areas of investigation and the scope of characterized dust samples, the suite of tests, the sampling and dust generation methods, and the size, chemical and mineralogical analysis performed in the center. Table 3 presents a summary distribution of the 95 publications and presentations that have emanated from the center. In addition there are more than thirty presentations made at each annual Dust Center review meeting. The titles, authors and location of presentation for publications supported by the Dust Center are presented in separate publication volumes for 1984 (Volume 3), 1985 (Volume 4), 1986 (Volume 5) and 1987 (Volume 6)."

Jan 1, 1988

By B. J. Scheiner

As part of the goal to maximize minerals and metals recovery from primary domestic resources, design factors associated with minimizing current leakage in bipolar cell configurations were studied by the Bureau of Mines as a means of improving the efficiency of bipolar e1ectrooxidation cells. Initial studies that were conducted in a small bipolar cell operating at 140 to 145 volts and 15.4 amp indicated how design factors could be employed to minimize cur-rent leakage around adjacent electrodes during cell operation. Based on these results, a 40-electrode, 108-kva prototype of an industrial-sized cell was constructed and tested for extracting metal values from offgrade molybdenite concentrates. The feasibility of recovering molybdenum and rhenium from the oxidized pulp also was determined. Feed to the process sequence consisted of flotation concentrates containing 16 to 35 pet Mo as molybdenite and 6 to 15 pct Cu. E1ectrooxidation in the prototype cell resulted in 84 to 97 pct Mo and Re extraction with a corresponding energy consumption of 9 to 13 kwhr/1b Mo extracted.

Jan 1, 1979

By N. S. Dalal, B. Jafari, F. H. Y. Green, V. Vallyathan

"INTRODUCTIONThe mechanistic details of the biological events leading to coal workers pneumoconiosis (CWP) are not yet fully understood, despite several decades of extensive epidemiologic1.2 and laboratory studies.2-6 Epidemiologic studies1.2 have shown, for example, that the incidence and severity of CWP differ markedly in the different regions and mines at comparable exposures, but laboratory investigations2-6 have demonstrated only partial correlation of the epidemiologic data with the differences in the mineral composition and the rank of coal mined. In particular, while epidemiologic data indicate1.2 direct correlation of the· prevalence and severity of CWP with the rank (i.e., % carbon content) of coal, this correlation has not been established by laboratory4'6 and animal exposure3 studies. In order to explain these results, in 1980 Artemov and Reznik' suggested that perhaps they arise from the fundamental differences in the surface properties of the coal. dusts inhaled by the coal miners and those used in the laboratory studies: while the miners inhale freshly fractured coal particles, henceforth called the 'fresh' coal dust, the laboratory studies generally utilize 'aged' coal dusts (i.e., dusts that have been stored for many days or even longer). Reznik and Artemov' used electron spin resonance (ESR) spectroscopy to show that the mechanical crushing of some Soviet Union coals generated organic free radicals and that the concentration and the decay times (hence the reactivity) of these radicals were higher for the coals of higher ranks. Since some of the radicals decayed within a few minutes in air, the authors surmised that while these radical species could lead to certain specific pathogenic reactions at the sites of mining operations, this might not be the case in the laboratory studies, due to the conventional use of 'stored' dusts which would be expected to contain significantly smaller free radical concentrations. This is consistent with the recent findings that, standardized, aged coal dusts exhibit minimal cytotoxicity. 8While the above mentioned work of Artemov and Reznik7 did suggest a possible new clue to the pathogenesis of CWP (i.e., the role of the coal based free radical species), no direct biological/cytotoxicity data were provided to show that 'fresh' coal dusts were, indeed, more pathogenic than the 'stale' ones. Because of the rather significant implications of the Artcmov-Reznik hypothesis to the understanding of 1hc biochemical mechanism and, hence, the strategies for the eventual containment of CWP, we have initiated a comparative study of the free radical formation and cytotoxicity properties of freshly crushed coal ·particles. As done by Artemov and Reznik, 7 we have used the ESR technique as the direct method of measuring the concentration and decay kinetics of the coal based free radicals. Our preliminary ESR studies on two Pennsylvania coals, a bituminous (carbon content 72 % ) and an anthracite (95 % carbon) coal, have confirmed the Artemov-Reznik finding that the crushing-induced free radical sites are higher on the coals with higher carbon content (i.e., higher rank).9-11 In the present work we describe our more recent results of a parallel study of the time dependence of the decrease in the free radical content of a freshly made anthracite dust (as measured via ESR) and that of the dust's cytotoxicity potential as measured by the extent of hemolysis of (sheep) erythrocytes. We have also investigated the effects of free radical scavengers on the cytotoxicity potential of the dust and deduce that indeed the free radicals could play a significant role in the initial events in the mechanism of the cytotoxic effects due to the inhalation of coal dust inhalation."

Jan 1, 1990

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By Joseph A. DeCarlo

According to the annual survey of beehive-coke plants by the Bureau of Mines, United States Department of the Interior, there were 61 plants with 9,549 ovens in the United States on December 31, 1956, This publication in¬cludes only those for which an annual report was filed with the Bureau of Mines. Not all plants listed were active, however, as nearly one-third of those canvassed were idle all year. A compilation of the returns showed that 44 plants with 6,920 ovens were active part or all year and 17 plants with 2,629 ovens were idle throughout the year. The capacity of beehive ovens has fluctuated between 6 and 14 million tons during the past decade. At the end of 1956, the annual coke capacity of beehive ovens on which reports were received amounted to 5.8 million tons. As noted in table 2, however, not all of this capacity was in operating condition, as 2,093 ovens with a capacity of 1.2 million tons were not operable on [ember] 31, 1956.

Jan 1, 1958

By W. L. Staker

The Bureau of Mines investigated the use of shredded automobile scrap for copper cementation. Air agitation was used to improve the cementation rate and prevent excessive buildup of copper on the iron. The pieces of scrap were too large to be properly evaluated in the laboratory; therefore, a pilot scale test unit was constructed and the process tested at field locations. Pregnant solution was obtained from industrial leaching operations, processed in the test unit and the barren solution and cement copper were returned to the plant process stream. The test results showed that the air-agitated launder containing auto-mobile scrap was an effective means for recovering copper from leach solutions. A continuous l4-day test run was made without a noticeable decrease in cementation efficiency. The most suitable scrap product was obtained from incinerated automobile hulks shredded in a hammer type of shredder. However, it was necessary to remove small pieces such as nuts and bolts because they interfered with the discharge of the copper product.

Jan 1, 1976

Reduce shaft sinking costs and workers exposure to mechanical hazards, drill dust, blast dangers, and fumes. Approach Replace drilling and blasting by using a large, cab-mounted impact breaker suspended from the bottom work deck of the galloway. How It Works The pneumatically actuated impact breaker is positioned by an articulated boom con-trolled from an operators cab. The breaker delivers 2,000 ft-lb blows that fragment the rock at the shaft bottom. Mucking is accomplished by a backhoe bucket on an articulated boom mounted on the cab. See photograph. The mucked material can be removed either by dumping into a previously drilled borehole or by being lifted out in a muck bucket as shown in the drawing. Positioning of the breaker, rotating the cab around its vertical axis, and moving the cab support frame around the perimeter of the shaft are all controlled by one joystick. Separate controls position the mucker boom, which can be swung horizontally through a 180° degree arc towards either side of the cab. Because the cab can be rotated to any position around its vertical axis, and can also be moved in a horizontal circle around the shaft, virtually any position on the bottom of the shaft can be reached by the breaker and mucker.

Jan 1, 1981

By G. E. McClelland

The Bureau of Mines investigated chemical methods for producing high- purity gold from precious-metal-bearing zinc precipitates and steel wool cathodes. Precious-metal-bearing zinc precipitates and steel wool cathodes are unrefined products from conventional cyanidation and heap leaching-cyanidation operations. The zinc precipitates contained 14,40 pct Au and 0.35 pct Ag. The precious-metal-bearing steel wool cathodes contained 20.65 pct Au and 4.84 pct Ag. The precipitates and cathodes were treated with dilute acid to solubilize the silver and/or base metals. The gold-bearing residue was leached in dilute aqua reqia to solubilize the gold. High-purity gold was precipitated from the aqua regia solution with oxalic acid, sulfurous acid, sodium bisulfite, and gaseous sulfur dioxide. The leaching-precipitation experiments recovered 99.9 pct of the gold. The gold precipitates ranged in fineness from 997 to 999 fine. The chemical refining method provides a viable technique for the smaller operator to produce high-purity gold without using pyrometallurgical refining methods.

Jan 1, 1985