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By H. W. Kilau

The Bureau of Mines used a high-temperature rotational viscometer to test basic oxygen furnace slags to determine fluorspar requirements and to evaluate colemanite and fused boric acid as substitute fluidizers. A continuous technique of viscosity measurement was adapted to better determine the viscosity-temperature profiles of volatile fluorspar slags. Criteria used for estimating slag fluidizer effectiveness were (1) the apparent solidification temperature, and (2) the temperature range of slag crystallization. Colemanite and fused boric acid in high-basicity slag were superior fluidizers to fluorspar when compared on the basis of boron versus fluorine concentration. Fused boric acid was nearly equivalent to ceramic-grade fluorspar when compared on a simple weight basis, while colemanite was inferior to fluorspar. Fluorspar slags volatilized fluorine during viscosity testing. Colemanite and fused boric acid slags were stable, no boron losses being detected. A fluidizing limit was found for fluorspar at 2.9 percent fluorine concentration; higher concentrations impaired viscosity and caused foaming and crusting of slag. Concentrations of boron up to 4.4 percent resulted in very fluid slags with no fluidizing limit.

Jan 1, 1978

By R. M. Strong, Lauson Stone

Under the terms of the act establishing the Bureau of Mines, this bureau was authorized to carryon the work of testing and analyzing fuels which had been conducted by the technologic branch of the United States Geological Survey. That work included in its scope an investigation of the availability and uses ofliquid as well as solid fuels, for the original outline of the fuel-testing investigations contemplated, as soon as the funds would be available, a study of the liquid-fuel resources of the country and the making of related researches to determine how these resources could be utilized with greatest efficiency. Owing to the fact that many difficulties were being encountered in the adaptation of the heavier fuel oils for convenient use in internalcombustion engines, it was deemed best to begin the investigation of liquid fuels with tests of gasoline, a fuel in more or less general use. When this investigation began, the extensive introduction, especially by foreign powers, of liquid fuels for small naval craft had awakened much interest. However, the quality of gasoline was reported to vary materially in different countries and the quantity available was said to be rapidly decreasing, with the probability of a prohibitive increase in price. At the same time the claim was made that denatured alcohol, of fairly uniform quality, could be procured in all parts of the world, that unlimited quantities could be readily produced at a low cost, and that this fuel could be used much more efficiently than gasoline in internal-combustion engines. Such statements naturally led to a widespread belief that the time was near at hand when denatured alcohol would entirely displace gasoline as engine fuel. Therefore, the first investigations of the liquid mineral fuels logically embraced a careful series of comparative tests of gasoline and denatured alcohol in engines. A series of over 2,000 such tests was conducted at the Government fuel-testing plants at St. Louis, Mo., and Norfolk, Va., details of which are given in the following pages. The report is published by the Bureau of Mines because of the transfer of the fuel-testing investigations to this bureau.

Jan 1, 1912

By A. C. Fielder

It is with some diffidence that I venture to address the Montreal Section of the Society of Chemical industry on the subject of motor fuel from coal at a time when crude petroleum is produced in greater quantities than at any time in history, and at a time when the known reserves exceed all expectations, even the optimistic estimates of the Committee of Eleven of the American Petroleum Institute. Not only are new fields being discovered in America a -an embarrassing frequency but sources outside of the North American Continent show, unmistakable signs of adding materially to the world's sources of oil. Were it not for the tremendous scientific and technical importance of the work done in the past few years in transforming coal into liquid motor fuels, I should prefer to let this subject rest until a more propitious time, such as prevailed some years ago, when the gasoline consumption curve was rising rapidly and the production curve was slowing in its upward rise. That was the period which stimulated the researches which resulted in tetra ethyl lead and anti-knock gasolines on this side of the Atlantic and in methanol, synthetic gasoline and hydrogenation of coal on the other side. Some of you will recall a symposium on Motor Fuels and Oil Conservation held at the Chemists' Club n New York in September; 1925. Dr. R. L. Brown and I presented a paper at this meeting on "Complete Utilization of Coal and Motor, Fuel, in which we pointed out that coal was the most likely raw material source of gasoline substitutes if and when needed. We grouped the present and future, processes' for obtaining motor fuel from coal in three classes, namely:

Jan 1, 1928

By W. R. McDonald

The Bureau of Mines, U.S. Department of the Interior, conducted small-scale field tests on acidic copper tailings as part of its effort to develop, improve, and demonstrate technology for stabilizing mining and mineral-processing wastes. Two successful demonstration revegetation plots were established on an abandoned copper-tailings pond located on public land adjacent to Holden Village, Wash. The tailings were neutralized with treatments of either dolomitic lime or limerock and fertilized with processed sewage sludge and/or commercial fertilizer. Excellent plant growths covering 70 and 24 percent of the surface were achieved on 1/8-and 1-1/2-acre test plots planted in 1973 and 1974, respectively. Regar brame, Tegmar intermediate wheatgrass, and tall wheatgrass provided the best plant growth and surface coverage. The target pH of tailings neutralization was 6.8; however, good plant growth occurred in areas where the soil pH ranged from 2.9 to 5.8.

Jan 1, 1978

By C. W. Dwiggins

This report describes the development, theory, and application of techniques and instruments for quantitatively determining nickel, vanadium, and iron in oils, using direct, X-ray emission spectrographic methods (5, 6).3 The methods developed apply to petroleum and other oils as well as some specific fractions of oils. The quantities of nickel, vanadium, and iron in various petroleums are of practical and theoretical interest. Even traces of nickel and vanadium may poison cracking catalysts, and X-ray methods have been used for determining nickel in such catalysts (7). At least parts of the nickel and vanadium occur as metal-porphyrin complexes, a fact which may have considerable bearing on knowledge of the origin of petroleum.

Jan 1, 1962

By V. Castranova, T-M. Ong, V. Vallyathan, M. J. Keane, W. E. Wallace Jr.

"Inhalation of certain forms of silica, asbestos and some other respirable dusts can result in pulmonary fibrosis, characterized by destruction of the surfaces of alveoli and respiratory bronchioles. Fibrous thickening of the alveolar septa decreases the lung's capacity for gas exchange.Pulmonary macrophage damage by respired dust may initiate the fibrotic response.In one proposed mechanism, dust particles interact with the plasma membrane of a macrophage. This damages the cell or induces some hyperactivity of the cell, resulting in excessive release of lysosomal enzymes and reactive forms of oxygen (1). These reactive enzymes or radicals then damage the alveolar surface epithelial cells. A second mechanism has also been pro¬posed (2,3) in which dust damage to the macrophage causes the release of mediator substances which induce pulmonary fibroblast cell proliferation and increased collagen synthesis. This produces fibrous tissue in the terminal air spaces (4,5).Mineral surface interactions with plasma membrane lipoproteins have been proposed as a mechanism of lytic damage of pulmonary cells by silica dust in numerous models (6,7). The significance of dust surface proper¬ties has been further revealed in studies showing significant changes in dust induced cytotoxicity as a function of dust surface crystallinity and organic or inorganic contamination or coating of mineral surfaces (8,9). Such modification of the mineral surface might interfere with surface sites responsible for the toxicity of dusts for pulmonary macrophages, thus interrupting the early stages of the process of fibrosis.In vitro cellular assay systems using erythrocyte hemolysis or the release of macrophage cytosolic or lysosomal enzymes following dust challenge, have been used to analyze the initial mechanism of dust damage to cells. However the ability of these assays to predict the pulmonary disease producing potential of various dusts is imperfect owing to some ""false positive"" results. These assays as performed are therefore questionable models for the initial lesion in pneumoconiosis or silicosis. In particular, kaolin frequently is found to have comparable biological activity to silica quartz in these assays (10,11).Silica and kaolin have distinctly different fibrogenic potentials. Silica is highly fibrogenic, resulting in both acute and chronic silicosis (12). Some epidemiological data and animal experimentation data have indicated that long term exposure to kaolin can result in pneumoconiosis; however, kaolin is relatively benign as compared to silica (13-18). Kaolin is also of interest because it is one of the major mineral inclusions in Eastern U.S. bituminous coals. We have observed that exposing respirable sized native silica or kaolin for two hours to pulmonary macrophages results in a greater enzyme release for kaolin exposures, on a dust mass basis. Exposure of erythrocytes to the dusts also results in greater levels of hemolysis by kaolin for equal mass respirable dust doses. Therefore, these results do not correlate positively with known disease inducing potentials of the two dusts.Characterization of physical and chemical surface properties of dusts involved in occupational exposures, and characterization of the alteration of those surface properties which are likely to occur upon deposition of the dust in the lung, should improve the identification of respiratory disease hazards.Inhaled dust particles deposited in the lower respiratory tract will come in contact with pulmonary surfactant. This surfactant forms a surface film on and emulsion in the liquid hypophase coating of the alveoli and respiratory bronchioles. The primary constituent of this pulmonary surfactant is the lipid diacyl glycerophosphorylcholine, lecithin (19). Because this lipid is also a major component of cell membranes, it is possible that surfactant can interact with mineral dust to alter its Interaction with macrophages and other pulmonary cells and, thus, it"

Jan 1, 1988

By R. V. Mrazek

The heat of formation of vanadium trichloride was determined at 298.15° K. Measurements were made in a solution calorimeter in which an aqueous hydrochloric acid-potassium dichromate solvent was employed. Data are presented for the heats of solution of vanadium trichloride and the vanadium trioxide "backup" compound, and for appropriate dilution reactions needed to preserve stoichiometry. The resulting heat of formation of vanadium trichioride (VCI3) at 298.15° K was found to be ?H°298.15° K = -138.89 ±0.37 kcal/g mole.

Jan 1, 1968

By K. K. Kelley

This report contains heat-content values for hexagonal crystalline germanium dioxide between 298.15° and 1,350° K., and for germanium dioxide glass between 298.15° and 1,800° K. experimentally determined by the Federal Bureau of Mines. No similar data for these substances are to be found in the literature. The heat-content and corresponding entropy-increment data are presented both in tabular form and by equations. Free energy of formation values are estimated for germanium dioxide glass at 298.15° and 1,800° K.

Jan 1, 1961

By H. E. Powell

The magnetic susceptibility, the geographical source, and associated minerals are given for 44 copper-, 26 lead-, and 19 zinc-bearing minerals. Of the 44 copper minerals/ all had a susceptibility of less than 15 X 10-6 cgs, and about 20 percent of them were diamagnetic. Of the 26 lead minerals, all had a susceptibility of less than 11 X 10-5 cgs, and almost half of them were diamagnetic. And, of the 19 zinc minerals, all except four had a susceptibility of less than 9 X 10-6 cgs, and about one-fourth of them were diamagnetic.

Jan 1, 1968

Spectrochemical methods were developed to determine beryllium in the concentration range 0.0015 to 4.0 percent in siliceous mineral beneficiation products. Two methods are described. They are (1) a fusion-pellet-spark procedure (spark method) and (2) a sustaining alternating-current arc procedure (arc method). In the spark method the sample is fused with lithium tetra-borate and vanadium pentoxide. The resulting bead is crushed, mixed with powdered graphite, and briquetted. This is analyzed spectrographically using controlled high-voltage spark excitation. In the arc method the sample is diluted with germanium metal, graphite, and vanadium pentoxide. Weighed charges are packed into cupped graphite electrodes and subjected to excitation with a sustaining alternating-current arc. Vanadium serves as internal standard for both methods. Effects due to matrix variations in samples and standards are eliminated either by fusion with lithium tetraborate in the spark method or by dilution with germanium and graphite in the arc method. Beryllium determinations show deviations from accepted chemical values of approximately 5 and 8 percent for the spark and arc methods, respectively. Analyses can be made more rapidly by the arc procedure with a sacrifice in precision and accuracy. Either method can be applied to the determination of beryllium in silicate rocks.

Jan 1, 1962

By M. M. Jones

Natural brines are potential domestic resources of minerals. The brines of Searles Lake, CA, for example, contain an estimated one-fourth of our current reserve of tungsten. A key to Bureau of Mines research to recover this critical mineral is the ability to quantitatively measure concentrations of particular constituents in the large number of brine samples and process solutions produced under a multiplicity of test conditions. This paper describes procedures used to determine arsenic, boron, phosphorus, silicon, and tungsten in these solutions by simultaneous inductively coupled plasma spectrometry. A variable in-ternal standard method was used to compensate for tungsten interference on the other analytes in tungsten concentrates, and matching standards were used to determine tungsten in raw brine. Other solutions were analyzed using normal techniques. Analytes were determined down to 1 mg/L with an average precision of 2.5 pet relative standard deviation. Accuracy, estimated using synthetic solutions and by comparison with values obtained by other methods, averaged about 2.5 pet. The methods were rapid, required little sample preparation, and provided the needed sensitivity.

Jan 1, 1985

By C. E. Augustine, P. Nicholls

"INTRODUCTION A layer of soot on the heating surface of a boiler decreases efficiency because it increases resistance to the flow of heat, with the result that the heat transfer to the water is lower and the temperature of the flue higher than they would be if the surface remained clean. The percentage of reduction in heat transfer depends on the position and area of the sooted. The percentage of reduction in heat transfer depends on the position and area of the sooted surfaces, the thickness of the most, until the percentage of the total heat absorbed by those surfaces when clean; thus it will vary with the type of boiler and in particular with the ratio of the area of the convection heating surface to the total area. Medium-size and large boilers usually are equipped with soot blowers, and tests have been published giving the increase in efficiency resulting from removal of the soot. Fuel savings up to,8 percent have been reported, but 4 to 5 percent is probably more conservatives. However, these savings may not be due wholly to a reduction the thermal resistance of the surfaces but may be due partly to improvement in the combustion because of better draft or more uniform flow of the gases. In addition, the deposits on the surface of boilers include as a clinker, and as the size of the boiler and the rate of burning increase very little or none will be soot.There are no corresponding test data on small boilers operated at low rates of burning. In stall boilers, deposits are much thicker, and it might be expected that the reduction in efficiency would be greater; in fact, statements have appeared suggesting that the decrease may be as high as 50 percent. This investigation was undertaken because the Bureau frequently receives requests for authoritative information on the effect of soot in small and other heating boilers."

Feb 1, 1935

By Robert D. Thomson

The Bureau of Mines has compiled coal reserve data for the United States as of January I, 1974, for bituminous and anthracite coalbeds 28 inches or more in thickness to a maximum depth of 1,000 feet and for Lignite beds 40 inches thick or greater. These data were organized by State, county, coalbed, and rank. To evaluate the reserve by sulfur content, the reserve and analytical data from the Bureau of Mines energy data bank were synthesized using computer techniques. The reserve base in the Eastern States was determined to be 202.3 billion tons. Bituminous coal accounts for the greatest reserve base: 161.5 billion tons of deep-minable coal, and 32.5 billion tons of strip-minable coal. Virtually all of the anthracite reserve base, 7.3 billion tons, is minable by underground methods. All of the lignite, 1 billion tons, is strip minable. Subbituminous coal is not significant in the Eastern United States, About 14 percent of the bituminous coal reserve base, 26.5 billion tons, contains 1.0 percent or less sulfur. About 87 percent of the anthracite reserve base, 6.3 billion tons, is low-sulfur coal.

Jan 1, 1975

By John H. Soulé

"INTRODUCTION The Peerless mine was examined by W. R. Storms, an engineer of the Bureau of Mines, on June 2, 1944, in conjunction with a mineral survey of the adjoining For Bayard Military Reservation. Storms again studied the mine on January 13; 15 and 16, 1945, to determine the possibilities of finding new ore reserves to replace these depleted by mining. A project to explore the Peer-less vein at depths below and to the south of the principal mine workings was proposed. Special attention was given to the possibility of exploring favorable beds in the Magdalena and Lake Valley limestones at points near the Peerless fault.The proposed project was approve and exploratory work started on January 2, 1946, and was completed on June 5, 1946. The mine was not in operation during the project, and all equipment had been removed."

Apr 1, 1947

By Jalna R. Zatko

Coal-clay waste slurries were dewatered in laboratory-and small-scale continuous tests by the Bureau of Mines using polyethylene oxide (PEO) as a flocculant. Dewatering from a nominal 7-wt-pct solids to over 50-wt-pct solids was accomplished using 0.5 lb of PEO per ton of feed in small-scale continuous tests. Parameters such as pH, initial solids content, and PEO concentrations were investigated. Water recovered from dewatering was reused as dilutant for PEO solutions.

Jan 1, 1982

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION In previous reports 5 results were given of a manhole investigation carried out over a period from June 1929 to July 193C in cooperation with the Edison Electric Illuminating Co. of Boston. Mass., and during 1931 in cooperation with the Edison Electric Illuminating Co. of Boston and the Boston Consolidated Gas Co., to determine the general hazards of combustible gases and vapors in manholes and other underground openings owned by the Edison Electric Illuminating Co. and to develop methods of eliminating these hazards. These investigations have demonstrated that the detection, control, and elimination of combustible hazards in manholes can best be obtained by a close cooperation of the interested parties through a systematic and continuous inspection of manholes, under proper supervision.The investigation carried out during 1932 has been along lines similar to those conducted during 1929, 1930, and 1931 test crew consisting of two men, one an employee of the Consolidated Gas Co. and the other an employee of the Edison Electric Illuminating Co., was continuously employed during the year in the testing of gases in manholes served by the Edison system. The test crew was under the direct supervision of John Campbell, superintendent of the special service department of the Edison Electric Illuminating Co., and F. M. Goodwin, vice president of the Consolidated Gas Co.As in the previous investigations, all tests were numbered. The test-data sheets, on which the information regarding the tests was recorded, were prepared in triplicate, ono copy going to the Edison Co., one to the gas company, and the third to the Bureau of Mines at Pittsburgh, Pa. These test-data sheets were then filed (1) according to the town, (2) the street location, and (3) the manhole number; in this way a complete record of each manhole tested was immediately available. A typical test-data sheet was given in the 1931 report. These data sheets were found to entirely satisfactory and no changes were made during the 1932 investigation. The procedure of sampling manhole atmospheres, shipment of the samples to Pittsburgh, and method of analysis has been the same as that described in the 1931 report and need not be repeated here. Likewise, there has been no change in the method of calculation of explosibility of the samples analyzed or the use of charcoal filter tests given in appendix A."

Jun 1, 1933

By A. L. Service

The four periods of test operation described in Report of Investigations 5219 indicated that planer mining of phosphate rock was feasible. Corrective measures proposed for design deficiencies indicated in test 4 had to be evaluated, however; and, before the attempt to design a prototype production model, it was considered advisable to test the original machine under more severe operating conditions. Planer A was modified, therefore, during the latter half of 1955, and one additional period of experimental operation was conducted in the Anderson mine of the Montana Phosphate Products Company near Garrison, Mont., during the first 4 months of 1956. Test 5 was made in a stope, where the phosphate bed had been offset in a number of places by minor faults. Considerable difficulty was found in negotiating the irregularities caused by these faults, and productionwise the test was not as successful as some of the previous ones. Information obtained, however, was valuable in designing model B.

Jan 1, 1959

By R. Blickensderfer

An impact wear testing machine was devised by the Bureau of Mines that simulates the repeated impact conditions encountered in large milling and grinding operations where breakage and spalling are problems. The apparatus provides data on materials that may help in the design of alloys with improved resistance to deformation, spalling, and breakage. The test blocks are 2 in thick by 6 in by 8 in. Impacts are produced by dropping 3-in-diam balls weighing 4 lb from a height of 10 ft. Tests were run until breakage occurred or to a total of 100,000 impacts. Four types of failures of the test block were observed: (1) cold flow of the bulk material by plastic deformation, (2) flaking of the surface in the impact region, (3) spalling of the block to form a crater in the region of impact, and (4) breakage of the test block into two or more major pieces. The effects of composition, heat treatment, microstructure, and hardness on types of failure are discussed.

Jan 1, 1983

By J. Mutmansky, C. Lee

"The size distribution of coal mine dust is one of its most important characteristics because the particle size is known to govern the region of deposition of dust within the human respiratory tract. In addition, dust characteristics, particle settling rate, transportability of the dust and the efficiency of dust control measures are all affected by the particle size. As a result, particle size distribution of the airborne dust in a coal mine is a fundamental property that impacts on the health of underground workers.This paper deals with some basic findings on the size distribution of cool mine dust based upon the results of data collection in six underground coal mines using continuous miners. All airborne dust sampling was performed on development sections using eight stage cascade impactors and permissible 2. O l / min pumps. Samplers locations were fixed in the sections with respect to the continuous miner and roofbolter or with respect to the intake and return airways • Sampling times varied from 45 minutes to 6 hours , depending upon the dust concentration. The first topic of analysis was the test to determine whether the commonly used lognonnal distribution is valid when applied to airborne coal mine dust. Secondly, the conventional method of representing the· distribution using two parameters, the geometric mean and the geometric standard deviation, is questioned. Since almost all size data were found to show some degree of bimodality, the two parameter lognonnal distribution may not represent the total airborne coal mine dust size , quite adequately. Bimodal lognonnal distribution was tested to be a good approximation in the case with two modes in the size distribution.The final topic discussed in this paper is the 'locational variation of the airborne dust size distributions within the continuous mining section. The size distributions varied considerably at the different sampling locations with the continuous miner and roofbolter producing the coarser distributions. Fine size modes in the range of 2 to 4µ m including mostly respirable dust particles were present in almost all samples • Second dust generating sources such as the shuttle car movement were found to be major causes of high respirable dust concentrations in some cases ."

Jan 1, 1988

By Webster S. Anderson

Two series of tests were run with planer model 'BB": one at the Arickaree mine of the San Francisco Chemical Co., Rich County, Utah, and one at the Roslyn No. 9 mine of the Northern Pacific Railway Co., Roslyn, Wash. The tests at the Arickaree mine were started on June 25, 1958, and continued until September 30, 1958. Prior to these tests, an electrically activated remote-control system was installed, and other modifications were made on the planer. The tests showed that the planer in general and the remote-control system worked very well; however, the various cutting tools used would not consistently penetrate and cut the phosphate rock. This indicated that the cutterhead design had to be changed before the planer would operate efficiently in phosphate beds similar to the "A" bed in the Arickaree mine.

Jan 1, 1962