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By William R. Roy

Seven coal-related waste samples (mining, cleaning, and gasification) were characterized chemically and mineralogically. Laboratory extracts of each sample, using a variety of different extraction methods, were used in both acute and chronic bioassays. A coal slurry sample (coarse fraction) and two coal cleaning refuse samples were chemically and mineralogically similar, and generated acidic water-waste systems, both in the laboratory and in the field. Acidic laboratory extracts and field samples of acid mine drainage in the area where the solid samples were collected, tended to be in equilibrium with some type of CaSO4 phase and with maghemite. The chemical composition of the extracts was sensitive to the method used to generate the extracts, but generally had the same prevalent chemical character as the field samples. The acidic wastes contain appreciable quantities of soluble Al, Mn, Ni, SO4, and Zn as indicated by both laboratory extraction and field data. Long-term extractions suggest that some constituents (Al, Fe, SO4) continued to be released by the acidic wastes after 22 weeks with no apparent associated change in pH. Two mine spoil samples, essentially shale, tended to generate water-waste systems that were neutral in pH and consequently released lower quantities tit potential pollutants than the acid wastes. The gasification residue was compositionally similar to coal-fired power plant slag and fly ash and generated moderately alkaline extracts with low concentration of soluble potentially toxic constituents. All of the solid wastes contained a variety of organic compounds, many of which are on the EPA Priority Pollutant List. However, these compounds were essentially insoluble in aqueous media. Each extract was tested for acute toxicity with tour species of freshwater aquatic organisms; green sunfish (Lepomis cyanellus), fathead minnow (Pimephales promelas), a crustacean (Daphnia magna), and a snail (Physa anatina). The extracts of the two mine spoil samples and of the gasification residue were not toxic to any of the organisms while the extracts from the acidic refuse and slurry samples were acutely toxic to all of the organisms. For all cases, pH was significantly correlated to mortality while Al, Fe, Mn, Ni, and Zn were significantly correlated to mortality in specific instances. Data from 96-hour LC-50 determinations showed that dilutions up to 1:1000 were necessary to eliminate mortality. The most toxic extracts were those with the lowest pH which necessitated the largest amounts of dilution to eliminate mortality. Chronic bioassays with the same test organisms were investigated with leachate samples from a relatively unweathered refuse sample and an older, more weathered refuse sample. The unweathered refuse sample generated a leachate that was acutely toxic while the leachate from the weathered refuse sample was not acutely toxic. No detrimental chronic effects were noted in organisms exposed to dilutions of the non-toxic leachate while low concentrations of the acutely toxic leachate produced lower hatchability for the Lepomis cyanellus and Pimephales promelas eggs, increased mortality with chronic exposure for Lepomis cyanellus, Daphnia, Physa, and reduced weight gain for Physa. Dilutions of a toxic, high-Fe leachate resulted in the precipitation of ferric hydroxide that was implicated as the major causative factor accounting for the physical and physiological toxic effects exhibited by all of the test organisms in these acutely sublethal concentrations. The toxicity of this leachate demonstrates the potential effects that these types of wastes can have on the aquatic ecosystem if they enter a receiving water in a natural setting.

Jan 1, 1984

By W. D. Dietzman

In view of the developments and recent interest in recovering heavy oil, this report was prepared to present general information on more than 2,000 heavy oil reservoirs in more than 1,500 fields in 26 states. Information given on each heavy-oil deposit includes the following items: Field and formation, location, average or range of depth, average API gravity of oil, aver- age thickness of formation, areal extent of field, total productive wells drilled in field, discovery date of field, field status in 1963, cumulative production to Jan. 1, 1964, and all known types of secondary-recovery operations initiated (active and terminated) in the reservoirs. The geographical location of heavy oil accumulations in the United States is shown by a map, and a brief discussion of 14 different areas is given in the text. As of Jan. 1, 1964, 75 percent of the heavy oil reservoirs in the United States had produced more than 10 billion barrels of oil and are estimated to contain over 90 billion barrels of oil in place. It is also estimated that if the deposits which have had little or no production history, such as the one in Missouri, were included, the total remaining heavy oil in place would be in excess of 150 billion barrels. To find economical ways of recovering this vast reserve of heavy oil, industry is developing technology in several types of thermal-recovery methods. Some of the general considerations and more suitable limitations in selecting a prospect to study fur thermal-recovery techniques are: Lithology, depth, viscosity of reservoir fluids, gravity of oil, reservoir thickness, oil in place, and permeability and porosity.

Jan 1, 1965

By Edward W. Ames

"The Jewell tunnel property, situated 3/miles north of Garfield, Chaffee County, Colo., was examined by an engineer3 of the Bureau of Mines in June 1943. Field work began September 16, 1944, but was recessed from December 26, 1944, to gay 15, 1945, because of heavy snows, and was suspended July 12, 1945, when rehabilitation of the New York tunnel workings was completed to the point desired.In its program of exploration of Mineral deposits, the Bureau of Lines has as its promary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as seen .as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples of ore and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.For their supervision of the project and their help in revising the report, particular acknowledgment is due Wm. P. Huleatt, district engineer, Denver, Colo., and Paul T. Allsman, chief, Salt Lake City Division, Mining Branch.The property is situated in secs. 15 and 22, T. 40 N., R. 6 E., N.R.F.M. Salida, the county seat, is on the main line of the Denver & Rio Grande Western Railroad. The property is reached from Salida by following U. S. Highway 50 westward for 18 miles to the village of Garfield, near Monarch Pass, then northward for 3 miles by a very steep mine-access road up Taylor Gulch (fig. 1).The highway to Garfield is accessible throughout the year, but the access road from Garfield is generally impassable from December until June because of snow."

Sep 1, 1946

By Clifford H. Summers

This report describes an experimental program which we conducted on behalf of the U. S. Bureau of Mines, to select from currently available materials two novel systems of construction for air-restraining bulkheads to be used in control of radon-polluted air in underground uranium mines. The program included both laboratory and field tests, the latter conducted in a portion of an operating mine owned and operated by Union Carbide Corporation at LaSal, Utah. The test site was a worked-out, double entry stope having a Volume of about 2000 cubic meters, and was located immediately adjacent to an exhaust airway. The bulkheads were constructed of 15 cm x 1.5 cm timber uprights, 5 cm x 15 cm horizontal members supporting a close-fitted 13 mm plywood curtain-wall., which was covered with a low-permeability membrane to seal in the radon-polluted air. The two membrane materials selected for testing were chosen from a list of twenty-two potentially acceptable candidates using criteria such as strength, flammability, ease of application, adhesion, radon permeability, and elasticity. Thirteen of the candidates were tested in our laboratories for adhesion to plywood and to both wet and dry concrete (simulating wet and dry mine rock surfaces), and for their general physical properties, including radon permeability. The final selections made by the Technical Project Officer, and based on our recommendation, were a pre-formed ethylene propylene diene monomeric rubber (EPDM) membrane 1.12 mm thick, normally used as a roof sealant in industrial construction, and available from Carlisle Tire and Rubber Co., Division of Carlisle Corp., Carlisle, PA, and Aquafas 48-00, a water-based mastic used in a wide variety of commercial applications and available from H. B. Fuller Co., Foster Products Division, Spring House, PA. The EPDM membrane was applied as a single sheet, laminated (dry) between two layers of plywood, and the Aquafas was applied both by troweling and spraying onto a plywood surface. In the field test, radon concentrations were continuously measured before, after, and in the trapped air behind each bulkhead. Temperature, pressure, and velocity of the air in the adjacent airway were also measured and recorded continuously. Radon fluxes at the rock/air interface and through the bulkheads themselves were measured manually on a frequent basis. All continuously acquired raw data were recorded automatically on two USBM Data Aquisition Systems (DAS), and the raw data were converted into engineering units and recorded on magnetic disks by a specially programmed microcomputer that was interfaced with the DAS's. Relatively clean (i.e. low radon concentration) air was pumped into a point near the face of one test bulkhead from a location 170 meters away through vent bag. Several air curtains and two air-restraining bulkheads were erected in passageways adjacent to the test area in an effort to control both velocity and radon concentration of the air flowing past the bulkhead faces. An average concentration of approximately 500 pCi/liter at a flow of 550 m3/minute was attained as the background concentration against which leakage through the bulkheads was measured. The entire field test period extended from October, 1981 to March, 1982, a total of six months, and was subdivided into seven successive time periods: 1) site preparation 2) background measurements prior to bulkhead construction 3) passive restraint, with bulkheads in place and totally sealed 4) open bleeder period of natural convection ventilation in and out of the bulkheaded area through a 10 cm (diameter) opening, with connecting tubing; leading into an Exhaust airway 5) open bleeder period, having forced exhaust through a 1.0 cm opening using a servo-controlled fan 6) charcoal trapping period, using the servo-controlled fan to exhaust air through the charcoal traps, to test the effectiveness of such traps in removal of radon from the exhausted air 7) site decommissioning Each of the two systems tested, one incorporating the pro-formed EPDM-rubber membrane and the other utilizing Aquafas 48-00, was assessed for effectiveness in controlling radon-polluted air by observing the change in the radon concentration in the ventilation air flowing continuously over the surface of each bulkhead. The sensitivity of the observed measurements was limited by the volume flow-rate of the ventilation air and the radon concentration in that air. The data would indicate that the observed increments in radon concentration in the ventilation air moving across bulkheads B-l and B-2 were essentially zero within the limits of sensitivity of the measurements. Data from radon flux measurement taken both on the sealed ribs adjacent to the bulkheads and on the bulkheads themselves did not differ significantly from blank data.

Jan 1, 1982

VOLUME I Volume I of this three-volume report is the result of development of a comprehensive, coordinated approach to site data-acquisition activities to produce key plans and reports during the evaluation and development of a surface coal mine. A logic diagram illustrates activities in the planning and decision-making process from exploration through post-mining monitoring. The report briefly discusses major elements, other than the site environment, which influence development of mining and reclamation plans and refers to other readily available literature for details outside the scope of this study. The essence of the rationale is shown to be the 1 employment of necessary skills at the proper time to evaluate specific data ' requirements and integrate them into a cost-effective program to produce initial and major feasibility reports, mining, and reclamation plans, and the environmental impact assessment.

Jan 1, 1976

By Richard D. Miller

This Bureau of Mines publication contains analyses and related source data for 271 natural gas samples from 22 States collected during calendar year 1982. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and chromatograph. The results of the investigation of the occurrences of helium are published annually to make the information available to the petroleum industry and the general public. Twenty-six publications have presented the results of 13,051 gas analyses vide prior to 1982. The first 3 bulletins (1-3)3 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24, 26) containing 7,833 analyses of samples collected since 1960.

Jan 1, 1983

By W. D. Dietzman

In view of the developments and recent interest in recovering heavy oil, this report was prepared to present general information on more than 2,000 heavy oil reservoirs in more than 1,500 fields in 26 states. Information given on each heavy-oil deposit includes the following items: Field and formation, location, average or range of depth, average API gravity of oil, aver- age thickness of formation, areal extent of field, total productive wells drilled in field, discovery date of field, field status in 1963, cumulative production to Jan. 1, 1964, and all known types of secondary-recovery operations initiated (active and terminated) Fn the reservoirs. The geographical location of heavy oil accumulations in the United States is shown by a map, and a brief discussion of 14 different areas is given in the text. As of Jan. 1, 1964, 75 percent of the heavy oil reservoirs in the United States had produced more than 10 billion barrels of oil and are estimated to contain over 90 billion barrels of oil in place. It is also estimated that if the deposits which have had little or no production history, such as the one in Missouri, were included, the total remaining heavy oil in place would be in excess of 150 billion barrels. To find economical ways of recovering this vast reserve of heavy oil, industry is developing technology in several types of thermal-recovery methods. Some of the general considerations and more suitable limitations in selecting a prospect to study fur thermal-recovery techniques are: Lithology, depth, viscosity of reservoir fluids, gravity of oil, reservoir thickness, oil in place, and permeability and porosity.

Jan 1, 1965

By Sara J. Davenport

Hydrogen sulfite has been listed (1)3/ as a possible hazard in 50 occupations, many of which are in the mineral industries. The effects of its occurrence in the petroleum industry made themselves felt more than two decades ago, resulting in a comprehensive study (2) of the toxic gases from Mexican and other high-sulfur petroleum products. The mining industry, likewise, has had cause to guard against this gas. Enough hydrogen sulfide has been found in coal and some noncoal mines during normal operations to cause severe eye irritation, some serious illness, end even fatalities. It is usually a product of the decomposition of sulfur compounds and may be produced by burning explosives containing sulfur; the gas in harmful qauntities is formed by the use of block blasting powder or by the use of dynamite in blasting sulfide ores. Hydrogen sulfide is readily soluble in water, and enough may be released from water streams in coal and noncoal mining to cause fatal poisoning it is found sometimes in stagnant water underground, particularly where ventilation currents are absent, and great care must be exercised when accumulations of such waters are disturbed, as exposure to comparatively low concentrations of the gas evolved therefrom has caused fatal accidents.

Jan 1, 1945

By R. W. Hiteshue, R. W. Fridy, W. Kawa

A study of the production of coronene , a high - melting ( 440 ° C ) , highboiling ( 525 ° C) , polynuclear hydrocarbon , was made by the Bureau of Mines to determine the maximum yield obtainable by the hydrogenation of coal and coalderived materials . Experiments were made with anthracite and bituminous coals and with asphaltenes and centrifuged residue obtained from heavy oil produced in a pilot plant by the hydrogenation of a bituminous coal at 2,000 psi and 480 ° C. With anthracite , yields of coronene of 0.5 to 0.7 wt pct of moistureand ash - free coal were obtained at 6,000 to 8,000 psi , 700 ° to 750 ° C , and a residence time of 30 minutes . With bituminous coal , yields averaging 0.4 wt pct of maf coal were obtained at 6,000 psi , 800 ° C , and 30 minutes ' residence time . With asphaltene and centrifuged residue , yields of less than 0.02 wt pct of maf coal were obtained at 6,000 psi , 700 ° C , and 60 minutes ' residence time .

Jan 1, 1964

By William W. Adams

Progress made by the quarrying and related industries of the United States during 1939 included increases in the number of men employed and the number of man-hours worked and reductions in the death and injury rates per million man-hours of exposure to risk. Forty-seven States reported quarries in operation; in each of 26 States the industry employed 1,000 or more men. Of these 26 States, 16 reported lower accident rates than in 1938. Among the operations of various types for which separate figures are published in this bulletin, the limestone, lime, and cement groups reported lower accident rates. During 1939, 79,449 men were employed in the quarrying industries. The period of operation of the plants averaged 236 clays per employee, with a total working time that equaled nearly 144 million man-hours. Accidents at the plants resulted in 48 deaths and 5,204 disabling injuries among the workers. Expressed as frequency rates, the accidents represented 0.33 fatality and 36.18 injuries for each million man-hours of work performed during the year. The major cause of fatal accidents inside the quarries was falls or slides of rock or overburden; nine deaths were reported from this cause. Four men were killed by explosives and four by falls of persons. Nonfatal injuries inside the quarries were clue chiefly to handling materials; about one-sixth of the total number at all operations in connection with quarries and related plants were in this class. Flying objects also caused numerous injuries, although only about one-half as many as did handling materials. Next in numerical importance were injuries from falls of persons. Then followed accidents caused by falls or slides of rock or overburden and accidents caused by machinery.

Jan 1, 1941

By Heine Kenworthy

"INTRODUCTION In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral content of this ore was considerably higher than in, the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently, tailing losses, especially with respect to lead, were high. A few years later, in order to study the possibilities of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill, feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Sta¬tion for testing-. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values was present.A résumé of the ore-dressing treatment used in the Shenandoah-Dives mill follows. After crushing, the ore passes through a ball mill, the minus 5-mesh discharge of which is distributed to three tables. A finished lead concentrate is made on the tables, and the table tailing goes to the classifier which is in closed circuit with the ball mill. The classifier overflow is treated -by flotation to obtain a bulk sulfide concentrate at a relatively coarse size. The bulk concentrate is thickened and reground to about 95 percent minus 325-mesh before flotation treatment to separate a lead-copper and a zinc concentrate. A typical monthly average showed that the table concentrate contained about 45 percent lead, 1 percent copper, 4 percent zinc, 12 ounces of gold, and 40 ounces of silver; that the lead flotation concentrate contained '35 percent load, 6 percent copper, 7 percent zinc, 3.5 ounces of gold, and 50 ounces of silver; and that the zinc flotation concentrate contained 2 percent lead, 0.5 percent copper, 60 percent zinc, 0.15 ounces of gold, and 4 ounces of silver. Recoveries in salable products were roughly b5 percent of the lead, 70 percent of the copper, 45 percent of the zinc, 85 percent of the gold, and b5 percent of the silver."

May 1, 1948

By F. G. Miller

[Petroleum tscknologists nnd progressive operatorr. constantly are striving to increase the percentage of oil thnt may be recorered from reservoir rocks through wells. The exhaustive studies that hve boen made of the function of natural gas in the production of oil, for example, havo aided operators greatly in increasing tho quantity of oil recovered from reservoirs. Natural gas dissolv.3d in and otheraiso asnociatod under pressuro with oil in rsservoir rocks, howovor, is not tho only source of energy available for rnovi~~ oil through sands to wells. In becomine Veservoi~enorgy conscious^^ encineera havo lonrned that in nnny petroleum resorroirs the edgewater flanking the oil accurrulation constitutos a potantinl source of enorgy cnpnblo, through pro1,sr control, of increasing oil-recovory officioncies materially. ?To longer is tho oncronchmont of mter into the oil- and gas-fillod uart of tho reservoir conridsred as evil to be combatted by dovious mothods but rnthar a nrtturrtl consequence, incident to the withdraval of oil nna gas from tho rolls, thnt mP.y be used nd~~mtngeoualy in lengthening the flowing life of wells ,md incre~sing the oconornic recovery nf oil and gns. Little is knom a3out tho nac'n-~nisrn by mhich wnter qor-rtos in driving nil through reservoir rocks, nnd thjro is n scnrcity of published informa- tion on rates of rnovzrnant of ~ntcr +,hat will result in naxilnm oil recoveries. Bureau of Xine s er.gir.ess nr r'reciate the ~aucity of scientific knowledge on the best methods of lying the natural rater drive to in- crease oil-recovery efficiencies arid ar9 initiating stildies that rill, they hope, contributo to tho procont small fund of information now available on the subject. This rh~.ort is s syr,o_nsis or brief c03pilation of published dAta and thought nccumulntod 30 far, groliminary to la-uorgtory ox~eriment+ tion NI& further resaarch on the principlgs und~rlying the nnturnl wnter drive RS it nffocts oil rocovory. The vrritors hopo th2t the omosition of available information prosentod in tho rey~ort rill stindate constructive thought and efforts loading torard moro comrlote extraction of oil and gas from resorvoirs.]

Jan 1, 1938

By Seth T. Reese

THE INJURY DATA and experience at coal mines in the United States for 1949 are presented in this bulletin under the following general sections: (A) General injury experience: 1. Tables 1 to 18: Contain current data on number of injuries, frequency and severity rates, average severity, major and detailed classification of injuries, and distribution of injuries by part of body and days of disability. (B) Selected injury data: 1. Tables 19 to 45: Contain current data on various selected factors of operating and physical conditions that have contributed to the occurrence of injuries at bituminous-coal mines and at Pennsylvania anthracite mines. These factors include extent of hand and machine loading, size of mine by employment and production groups, thickness of bed or vein, duration and number of work shifts, rating of mine as gassy, or nongassy, types of cap lamps, ventilation, explosives, and combinations of factors that influence mine safety. (C) Injury experience by States: 1. Tables 46 to 52: Contain current data on number of injuries, frequency and severity rates, average severity, major classification of injuries, injury records of all coal-producing States, and the relative standing by States according to injury-frequency rates. (D) Appendix: 1. Tables 53 to 84: Contain certain injury data for the years 1943-47 that have not heretofore been published.

Jan 1, 1953

By D. E. FOCG, A. E. Wells

When the United States entered the World War governmental agencies found little definite knowledge available as to the exact capacity of each sulphuric acid plant in the United States to manufacture acid under the stress of a great emergency. It is true that on account of the demand for acid for the manufacture of munitions for the Allies, prior to the entrance of this country into the war, most of the acid plants near industrial centers in the Eastern and Northern States were running at or nearly their maximum capacity, but, . for various reasons, many plants in these States and plants in other districts were not. For a number of years statistics as to the production of acid by the plants of the country were compiled by the United States Geological Survey, but obviously such figures did not give information as to the maximum capacities that might be available for meeting the he.a vy war ·requirements, or as to the steps that would have to be taken to bt-ing these capacities into use. During the summer and early fall of 1917 various attempts were made to obtain the desired information, but no satisfactory or complete data were obtained. Late in 1917, under the authority granted to the Bureau of Mines by the explosives act, the Director of the Bureau of Mines directed A. E. Wells, metallurgist of the bureau, to uiake a complete survey of the situation. Mr. Wells personally conferred with officials of the acid companies and visited most of the acid plants in the North that are east of the Mississippi River. The information obtained through this personal survey, together with that obtained through the ready cooperation of the subcommittee on ncids, and the subcommittee on fertilizers of the Committee on Chemicals of the Council of National Defense, enabled the preparation of a report containing the desired data concerning the sulphuric acid industry. This report was made immediately available to the War Industries Board and to those offices in the War and Navy Depart- ments that were most directly concerned in planning the explosives program and in obtaining the necessary supplies to produce the explosives. Beginning with this survey and report, the sulphuric acid section of the war minerals investigations of the Bureau of Mines took an active part in all matters pertaining to the sulphuric acid industry during the remainder of the war. Mr. Wells, the chief of the section, was appointed an associate chief of the sulphur, pyrite, and sulphuric acid sections of the War Industries Board. .Also, by this direct contact with the War Industries Board, the data obtained by Messrs. R. R. Hornor, H. A. Buehler, a.nd 0. Lindstrom, who were in charge, for the bureau, of the investigations concerning the supplies of pyrite and sulphur, were constantly made available to all interested Government agencies. D. E. Fogg, of New York City, was appointed chemical engineer to the sulphuric acid section to make special investigations relating to the acid industry, especially the possible utilization, in an emergency, of those sources of raw material.not then being used. Mr. E. E. Corbett, of Brooklyn, N. Y., was appointed chemical engineer to make investigations concerned primarily ,vith the conservation of acid. Direct and intimate contact with the industry was had through the close cooperation with the committee on acids of the Chemical Alliance, this committee during the greater part of 1918 occupying rooms with the acid section of the bureau. With the ending of the war and the close o:f the active work of the acid section of the bureau, the suggestion was made by many interested parties that a bulletin be prepared giving some qf the fun. damental and most important facts regarding the sulphuric acid industry, including a discussion of the technical :features of the manufacture of acid. During the war the bureau received -a vast number of inquiries in regard to various phases of the industry, a.nd this fact also made such a bulletin seem desirable. Therefore, the present bulletin was prepared to cover the main facts in regard to the industry in this country, including a discussion of the supplies of sulphur-bearing raw materials, the situation of the acid plants, the principal points in regard to manufacturing processes, and the uses of the acid. No attempt has been ma.de to discuss at length the manufacturing processes, as details differ more or less at the different plants and in general are carefully guarded by the acid ·companies. A great deal of the data given in this bulletin may be found in various pub]ications, but this is the first publication in which such data have been assembled and made readily available. Most of the data were obtained directly from observation and from cooperating acid companies or from individuals who had been or are now engaged in acid manufacturing and were liberal and generous in making their information available for publication. Care has been exercised to publish no data that were obtained as confidential by the bureau's representatives. The average acid manufacturer may be already more or less acquainted with most of the information presented in this bulletin, yet it is believed that the bulletin will be of value to those who wish to obtain a. general review of the present condition, both the economic and technical, of the sulphuric acid industry in the United States.

Jan 1, 1920

By A. J. Kraemer

The properties of crude petroleum continue to interest the Bureau of Mines and constitute an important phase of its major studies on the mineral resources of the United States. The Bureau's interest in the subject has been intensified by frequent requests for information on the characteristics of crude petroleum from various producing fields. Since its inception the Bureau of Mines has collected and analyzed samples of typical oils and at present has surveyed and classified crude petroleums from nearly all the known oil fields of the Western Hemisphere. Results of these surveys have been presented in various Bureau of Mines publications. (See bibliography, appendix A, p. 145.) The nature and comparative value of crude oils from various countries and the extent to which these oils may be considered potential competitors for markets are of manifest importance to the petroleum industry in all lands, largely because all crude oils, wherever produced, are either actual or potential competitors for a market with all other crude oils. The numerous discussions of foreign production of oil that have appeared in the technical press in the past indicate the great interest of the United States in this subject.

Jan 1, 1937

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel.oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which typo of plant utilizes more thou the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which crude oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining. Although no outstanding technical developments of a fuel-saving nature were made in 1934, some progress undoubtedly was recorded. Heat exchangers, an effective fuel-saving device, wore enlarged, and some refiners now take off several cuts before the crude reaches the pipe stills. The total capacity of pipe stills increased 2.5 percent in 1934, and many of the less efficient shell stills were torn out.

Jan 1, 1935

By N. E. Hanna

An important goal in the development of coal mining explosives has been to improve their safety characteristics through suitable formulation. In the United States no systematic effort to establish factors influencing the incendivity to firedamp and to coal dust of explosives through research was made until the last decade. In consequence, American permissible explosives underwent only very slight modifications and many remained substantially the same as in the early years. As part of a long range program for increasing the safety of permissible explosives, the Bureau of Mines undertook to determine how the amounts and particle sizes of the principal constituents of these explosives affect their incendivity. It was found that an increase in the relative amount of sodium chloride and a decrease in its particle size significantly decreased the incendivity of our permissible explosives to firedamp (7-9).6 This is in agreement with findings reported by Dolan (4) for compositions of nitroglycerin and salt. One important result of the work at the Bruceton station has been the recent introduction of salt-formulated permissibles by several explosives manufacturers. This paper describes a statistically designed experiment for studying the effects of the particle size of ammonium nitrate and the type of carbonaceous materials used on the incendivity of permissible explosives. Interest in these particular effects goes back as far as the first formulations of coal mine explosives, around 1910 in the United States and even earlier in Great Britain and other countries. Although it is well established that fine

Jan 1, 1961

By M. C. Malamphy

The report of work accomplished on the United States Bureau of Mines' bauxite project in Pulaski and Saline Counties, Ark., is presented in this volume and in a series of Reports of Investigations immediately following this volume. This first volume covers the project as a whole, whereas the subsequent volumes contain maps of local areas and deposits developed, together with logs of the drill holes and descriptions of the separate deposits. The Arkansas bauxite project was initiated in December 1941 and continued for 4 years. The first 5 months were spent in studying the problems presented and in geophysical exploration, Core drilling began in May 1942 and ended in May 1945. The project was one of the larger and more important of those undertaken by the Bureau of Mines for the purpose of developing domestic sources of supply of critical and strategic minerals necessary for National defense and for the successful waging of modern mechanized warfare. Some of the results of the Bureau's bauxite exploratory work have been made available to the public through the medium of press releases, transactions of technical societies, and government publications. More information has been supplied to government agencies upon request and to land owners and mine operators of the deposits concerned in the form of maps showing locations of all holes drilled on the property and logs with chemical analyses of' all cores recovered. In October 1946, the factual data were made avail-able to .the public in manuscript form in an-"open file" at the office of the State geologist, R. B. Foxhall, Little Rock, Ark., and at the office of the. Bureau of Mines in Washington. For the purpose of providing a background for the presentation of the factual data obtained, the history of bauxite is reviewed briefly. Information relative to past production and reserves of bauxite in Arkansas also is given. A resume of the development of the industry in Arkansas, the exploration and mining methods employed, the various uses to which the bauxite is put, and a brief outline of the geology of bauxite in Arkansas complete the -background.

Jan 1, 1948

By John D. Sullivan

The present article is one of a series which is being prepared by the Southwest Experiment Station of the United States Bureau of Mines in cooperation with the Department of Mining and Metallurgy, University of Arizona, Tucson, Ariz., of papers dealing with factors involved in the leaching of copper ores. A knowledge of the time required to dissolve the various copper minerals present in ores, as well as of the consumption of leaching reagents is very desirable, because with the decrease of the Nation's total tonnage of sulphide ores increasing attention is being given to the recovery of copper by leaching methods from low-grade disseminated ore containing both oxidized and sulphide minerals. As leaching has already been applied with success and profit, this study was undertaken to determine certain fundamental characteristics that are applicable to all ores suitable for leaching.

Jan 1, 1929

By R. E. Heithecker, D. B. Taliaferro

"INTRODUCTION Recovery of core specimens from subsurface formations and their subsequent analysis are important aids in efficient development and operation of oil and gas fields. Gore specimens first were obtained mainly for the geologic information they revealed; now they are analyzed to determine many of the physical characteristics and conditions of the subsurface formations as well. Cores recovered from the producing formations may be analyzed for porosity, permeability, oil content, ""connate"" water content, and other physical and chemical properties of the formation, all to the end of furnishing enough data for making reliable estimates of the quantity and avail¬ability of oil and as within a reservoir and in devising efficient means for their withdrawal.Examination of bottom-hole samples of oil gives valuable information concerning the amount of gas in solution in the oil within the reservoir and the resultant shrinkage of the oil when the gas is released. Producing characteristics of reservoirs nay be determined by means of subsurface pressure and temperature gages and measurements male at the wellhead; however, unless reliable core analyses are available, these data have only limited use in any quantitative study of reserves. In such a study the quantity of oil, gas, and water contained in a unit volume of the reservoir formation is extremely important. Although reliable methods of analyzing cores have been developed and the data thus obtained are valuable, their applications become more limited or reservoirs at higher temperatures and pressures are discovered. This condition results almost entirely from the fact that in recovering a core from a formation of high pressure and temperature by present methods a large part of the fluid content of the core is lost or contaminated to an unknown extent. For a number of years most petroleum engineers have held that if this loss and contamination of the fluid content of a core were eliminated, the value of core analyses would be increased greatly."

Nov 1, 1939