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By J. Laskowski, J. Lekki

"The mechanism of joint action of a frother (alpha-terpineol) and a collector (ethyl xanthate) in the flotation of chalcocite has been examined. In order to study the dynamic effects of frother and collector in bubble-particle collisions, the following aspects were investigated : determination of zeta-potential. Measurements of the thickness of fluid film on the surface of chalcocite and adsorption of xanthate, as influenced by alpha-terpineol, induction time and flotation versus concentration of alpha-terpineol and ethyl xanthate.The mechanism of the adsorption-desorption phenomenon on chalcocite with regard to non-ionic molecules, e.g. a-terpineol, has been considered, and the influence of this on the stage and thickness of the intervening wet layer between a bubble and a particle, changing the probability of collision and attachment, is suggested."

Dec 1, 1971

By R. H. . T. Garnett

Contributed remarks on paper published in the Transactions, Mining industry section, vol. 100, September- December 1991, A121--45

Jan 12, 1992

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By J. A. Saunders, E. L. Rowan

It is now widely accepted that the metal-rich waters found in the oil wells are possible present-day analogues of the mineralising solutions that formed the Mississippi Valley-type (MVT) deposits throughout mid-continental USA and elsewhere. A study characterising the trace-metal content provides additional circumstantial evidence for a genetic link between sediment-hosted mineral deposits and basin brines: Ag, Co, Ni, As and Mo, detected in the scale, are locally present in accessory minerals in MVT deposits and the levels of Ag found in the wells support the conclusion that sedimentary sources for silver should be considered in evaluating the origin of Pb-Zn-Ag deposits in sedimentary terrains

Jun 12, 1905

By J. Cech

Discussion is presented of a decision-making support method for the spacing of ore passes along a long vein orebody and the division of the orebody into convenient stopes for future mining operations. The method was tested on a Slovak siderite deposit and also on some hypothetical cases with the objective of obtaining more general results

Jun 18, 1905

By Williams J. A.

"Changes proposed in 1969 to modernize legislation governing the exploitation of mineral deposits in the United Kingdom serve as the basis for a discussion of what is considered to be a desirable framework for future legislative proposals.Proposals with regard to prospecting and exploration, evaluation, and acquisition and exploitation are considered, as are suggestions relating, inter alia, to aerial surveys and land restoration.It is concluded that without legislation along the lines proposed there can be no significant revival of metal mining in Britain."

Dec 30, 1971

By M. L. Schmulian

"The Windarra nickel deposits display many of the characteristics that typify Archaean volcanic peridotite-associated nickel sulphide ores of Western Australia. The Fe-Ni-Cu sulphide mineralization, which comprises dominantly disseminated sulphides, occurs at the base of a differentiated ultramafic volcanic pile grading upwards from massive meta-peridotitic flows to thin, locally spinifex-textured meta-picritic units. The entire mafic-ultramafic belt has been subjected to mid-amphibolite- facies metamorphism. The ore-bearing ultramafic is immediately underlain by dominantly sulphide-facies banded iron formation (BIF), which commonly contains nickel sulphides adjacent to its contact with mineralized ultramafic. BIF-hosted ores are formed both by physical remobilization of ultramafic-hosted sulphides and by migration of Ni and Cu into pre-existing iron sulphides.At Mt. Windarra the mineralization comprises eight steeply dipping, steeply plunging elongate oreshoots, which display a marked parallelism with major and minor fold structures in the underlying BIF. Seven of the shoots occur at or close to the base of the ultramafic pile, and are hosted by at least three overlapping flows. The zone of overlap occurs at the northern end of each flow, where picritic ultramafic, representing a dominantly liquid portion of the flow, occupies the basal contact. A gross south- north ultramafic flow direction is inferred. The eighth shoot occurs in a stratigraphically higher position within the ultramafic sequence.At South Windarra at least two overlapping mineralized flows occupy the basal contact, the ore zone having a strike extent three to four times its downdip extent. There is no obvious structural control to the mineralization."

Jan 1, 1984

By D. Newman

Mineral production in the Highlands and Islands of Scotland during the last ten years has been confined to the sporadic production of industrial minerals—for example marble, anorthosite, limestone, talc and silica. From 1962 onwards there has been an upsurge in mineral exploration in the Highlands, increasing in tempo from 1966 onwards due to the efforts of the Institute of Geological Sciences, the Highlands and Islands Development Board, and private and public companies. Geological, chemical and economic aspects of some of the more interesting mineral prospects are discussed: these include anorthosite, feldspar, magnetite, quartzite and brucite marble. Reference is made to a geochemical survey undertaken in the Rosehall district of Sutherland, the results obtained being summarised. Problems that affect the future of mineral exploration in the Highlands are stated.

Dec 1, 1971

By A. B. Holland-Batt

Two graphical techniques which are commonly used to assess batch separations are analysed in terms of reaction kinetics to provide a more powerful method of evaluation. An alternative and more general approach, based on the selection and application of suitable efficiency criteria, is also presented. The method proposed distinguishes between selection and collection efficiency in flotation and can be used to estimate the degree of liberation in the feed. Two examples are given: table concentration of monazite and ilmenite from a beach sand, and flotation of a pyrite-haematite ore

Dec 1, 1971

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

Two of the most important economies in coal-washing are in the actual washing of the coal and in a proper lay-out to reduce to a minimum the cost of labour for handling and washing. A guarantee is usually required for turning out a washed coal containing not more than 2% of free dirt and a resulting refuse with not more than 2% of free coal; any plant that gives results within such guarantees can he considered economical, provided that there are no other losses during the washing process. Various drainage arrangements and washery lay-outs are illustrated and discussed with respect to drainage, bunkers, sieves, settling tanks and conveyors and two further points considered: siding accommodation, which may become quite important with washeries of large capacity especially when the coal is brought in railway-wagons; and the irregularity with which the coal arrives. (Paper presented at the Manchester Geological and Mining Society's general meeting held in Manchester, April 11th 1916, with Mr. Leonard R. Fletcher, President, in the chair)

Dec 1, 1916

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By Z. Sawlowicz

Finely dispersed, primary sulphide mineralisation in the Cu-Fe sulphide zones of copper-bearing shale of the Polish part of the Permian Kupferschiefer is mainly present in the form of framboids and spherules. This type of mineralisation is especially well preserved in organic-rich shale, where it often dominates over a later diagenetic mineralisation that consists of large grains and veins. In microscopic observations special attention was paid to composite grains of copper and iron sulphides. The results suggest that the Cu-Fe and Cu sulphides precipitated in the Kupferschiefer sediment before pyritisation of the framboids had ceased and that they replaced metastable precursors of pyrite. The precipitation of copper sulphides could have been delayed owing to the formation of Cu-organic complexes.

Jan 4, 1992

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By O. E. Polter, W. J. N. Fernando

Smelter-grade alumina is usually produced by the calcination of gibbsite. The ideal energy requirements for the calcination of gibbsite have been analysed and compared with the actual energy consumption of some industrial calcination processes. The consumption of most of these is considerably in excess of the ideal. Methods suggested for calcining dry gibbsite feeds which claim energy savings of 10-14% consume 26-34% more than the ideal energy requirement for dry feeds. This study indicates that it should be possible to recover appreciably more energy, giving further improvements in fuel efficiency, both in existing gibbsite calcination processes and in methods that have been proposed for the stagewise calcination of dry gibbsite

Jun 13, 1905

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By K. M. Kinealy, A. R. Ramsden, D. H. French

A negative correlation exists between sphalerite composition and gold content when gold is transported as Au(HS)2(-); however, there are spatial and temporal differences within a single deposit. A previous model for the formation of volcanogenic massive-sulphide deposits within thermally intensifying and waning hydrothermal sytems in much the same way as is observed around modern sea-floor vents is supported. The results also emphasise that recognition of the mechanisms of gold transport in ancient deposits depends critically on an understanding of their mineralogy and stratigraphy

Jan 1, 1991

By T R. Marrero, J W. Wilson

This paper presents costs for a coal log pipeline that can transport coal over distances from 50 km to 1500 km. The coal log pipeline (CLP) concept is a new technology in w hich coal is compacted into water impermeable circular cylinders that can be suspended in water flowing through an underground pipe. CLP includes processes to prepare the run-of-mine coal for compaction, the injection of coal logs into a pressurised water-lilled pipeline, the conveyance of the coal through a pipe including special pumping stations, and the treatment of the coal logs and water at the pipeline outlet. An 8 inch (203 mm) pipeline can transport more than 2 Ml of coal per year. CLP components have been extensively tested in bench-scale facilities where these tests have included start up/shutdown steady state flow behaviour, end of pipeline treatment of water and coal log handling, water hammer effects, abrasion of logs and pipeline, coal log manufacture, and other engineering operations. Several sites are being considered in the United States (US) for the first commercial demonstration that will probably take place in 1998. The cost calculations are based on realistic values for all the components of a CLP. including a return on investment. For pipelines of different diameter, values for coal transportation are presented in terms of $(USVtonne as a function of distance.

Jan 10, 1996

By G. P. . RiddIer

The ninth symposium in the series 'Prospecting in areas of glaciated terrain' was organized by the Institution of Mining and Metallurgy in association with the British Geological Survey and was held in Edinburgh from 2 to 4 September, 1991. Dicussions of sessions are presented.

Jan 4, 1992

By R. Immele-Meziou, G. J. Long, D. G. C. Robertson, O. A. Pringle

The reduction of naturally weathered ilmenite concentrate occurs in two steps: reduction of Fe3+ to Fe2+, followed by reduction of Fe2+ to Fe. Small amounts of a magnetic phase were also observed and may correspond either to an Fe3O4-FeTiO3 ilmenite phase or to an Fe3O4-Fe2TiO4 spinel phase. The total amount of metallic iron produced after 12 hr was only 50% of the total iron present in the sample.

Jan 4, 1992