Search Documents

By N. N. Orekhova, I. V. Shadrunova, N. G. Novikova, N. ?. Volkova

The purpose of the research is scientific substantiation and formulation of strategy and technical solutions of handling liquid wastes of plants producing and refining copper-zink pyritic ores. In the course of research studied are chemical composition of technogenic waters of mining plants as well as water and alluvia of intake river within and outside a sanitary zone of Southern Ural mining plant using inductively coupled plasma mass-spectrometry and X-ray fluorescence analysis techniques. A particular focus is made on microcomponent composition. Novel data on Cd, Li, Be, Mn, Co, Cu, Zn migration with technogenic flows and accumulation of these elements in alluvia is obtained. It is showed that extraction of valuable components from technogenic waters is a novel problem for refiners that can be solved only in cooperation with mining industry ecologists. Laboratory research of selective copper and zink extraction into corresponding practical products by galvanocoagulation and sulphide precipitation is carried out. Common factors of phase formation are studied using physicochemical modeling, X-ray phase analysis and electronic microscopy. Methods of intensification of processes and increasing of extraction ratio of metals in products are elaborated. A technology of comprehensive processing of undersoil waters is proposed. Enlarged laboratory and pilot plant tests of technological solutions for protecting hydrosphere and extracting metals from mine waters carried out on several plants of UMMC-Holding Corporation showed a possibility of obtaining additional products having weight content of metal which is profitable for consequent metallurgical processing and purification of waters to comply with quality standards. A possibility of transformation of technological chain depending on season variability of water quality is put behind the designed technological schemes.

Jan 1, 2018

By Carin Laubscher, Francis W. Petersen, Jaap P. Smit

Waste streams, such as acid mine drainage, are often characterised by low pH values and high concentrations of heavy metals, dissolved solids, calcium and sulphates. Although lime remediation effectively removes most of the heavy metals as hydroxides, it is less effective at lowering levels of sulphates. Various methods of removing sulphates from effluents exist, such as precipitation with lime, precipitation with barium salts, co-precipitation with calcium carbonate, reverse osmosis, and ion exchange. Mintek developed a chemical precipitation (SAVMIN) process to treat acid mine drainage, which entails the addition of lime to precipitate the metal hydroxides, and the subsequent formation (precipitation) of calcium sulphoaluminate or ettringite. The key to the viability of the new technology lies in the correct use, regeneration and recycling of Al(OH)3 used to precipitate the ettringite. The water produced by this process is suitable for disposal to watercourses or for agricultural, domestic or industrial consumption. No brines are produced as the salts are converted to solid hydroxides, gypsum and calcium carbonate. The technology has been tested on several different waters in pilot plant campaigns. Results obtained indicate that potable water can be produced (containing less than 200 mg/L sulphate and no heavy metals) as long as the monavalent ions (Na+, Cl-, etc.) are within limits.

Jan 1, 2003

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

By C. B. Yu

The ore comprise of chalcopyrite, valleriite, pyrite, pyrrhotite and so on. Serpentine and talc are chief gangues. Copper phase of the tail shows that mostly valleriite be losed in tail, 70% mineral of copper is valleriite in tail, so severity reduce the recovery of copper. The traditional flow-sheet in acidity mine pulp to flotat the valleriite, but copper-sulphur separated in high alkaline pulp, so the valleriite be losed else. Explores the characters of the valleriite?s surface, studys on the flow-sheet of flotat valleriite and copper-sulphur separated. In neutral mine pulp, adopt of cationic collector to flotat valleriite, adopt of hyposulphite to depressant pyrite in low alkaline pulp can advance the recovery of copper to 5.06%.

Jan 1, 2014

By J. Y. P. Leite

In the Borborema Pegmatitic Province (Brazil) exploitations of several minerals are conducted by small producers. They use traditional techniques of gravity concentration in small-scale plants as jigs and vibratory tables. During decades the mining activity generated tailings with economic interest in particularly columbite-tantalite. Samples collected in tailing piles of a gravity plant were characterized in mineral composition, which shows in the heavy fraction the minerals spodumene, columbite-tantalite, ilmeno-hematite, garnet and cassiterite. The light fraction presents quartz, feldspar and muscovite. The degree of liberation of spodumene and columbite-tantalite were determined using optical microscopy that presents liberation in 100 µm (90% to columbite-tantalite and 100% to spodumene). Centrifugal concentrator Falcon SB-40 was used for concentration of these minerals and presents 65% recovery in mass to two stages with mass reduction about 85%.

Sep 1, 2012

By Miguel Becerra, Daniel Jordán, Jorge Soto, Luis Torres

"Most SAG grinding operations currently use ball sizes between 5.5 and 6 inch maximum size. However, in most cases the use of this ball sizes hasn’t been justified by a phenomenological analysis of the real effect on the grinding process, but rather by trial and error. The analysis of the influence of ball sizes in SAG grinding hasn’t been developed in detail by considering the effect on process parameters inside the mill, grinding efficiency or internal classification. Historically a conventional grinding reference has been made on the empirical procedure developed by Azzaroni (1980). Further to Azzaroni’s methodology, Sepulveda (Sepúlveda, 2007) developed the SPEC methodology, incorporating the ball size effect on the grinding efficiency parameters using a population balance model included on Molycop tools spreadsheets.This paper demonstrates a detailed analysis at pilot scale of the ball size employed in SAG grinding and scaling that exists between the different levels. This analysis includes assessing the effect of balls sizes on parameters associated with grinding efficiency and its effect on the total fill level, product size distribution and specific energy consumption, among others. In a complementary way it develops a technical - economical evaluation from industrial data comparing two different ball sizes and its effect on the grinding process analysed integrally."

Jan 1, 2014

By Rong Fan, Andrea Gerson

"The small recovery of Ag, often in the order of 50%, by traditional flotation and leaching process strategies is closely related to the complicated and heterogeneous nature of Ag-bearing minerals with Ag typically being associated with numerous minerals within any given ore-body. Moreover, grain sizes may be extremely fine with micron-scale common. In order to design cost-effective Ag-bearing mineral flotation and leach recovery strategies it is firstly necessary to characterise the speciation of Ag and its correlation with other elements, e.g., Cu, As and Sb, within the ore matrix and process streams. The traditional QEM-SCAN analytical approach can prove problematic for some mineralogies due to difficulties in recognising degrees of crystallinity, polymorphs, complex solid solution series, high value trace element mineralogy, very fine grained materials; and the requirement for a comprehensive data base. Moreover, there is difficulty ‘seeing’ either surface films or surface contaminants which can both lead to poor flotation performance. There is therefore clearly a need to develop confirmatory and complementary approaches when these uncertainties arise. Synchrotron X-ray microprobe analysis provides a powerful tool for the mineralogical characterisation of finely segregated heterogeneous Ag-containing materials. These measurements enable comprehensive characterisation of the Ag-bearing components using synchrotron microprobe X-ray fluorescence mapping (µ-XFM), X-ray diffraction (µ-XRD) and X-ray absorption spectroscopy (µ-XAS). Further analytical strength is provided by principal component analysis of laboratory ToF-SIMS data which enables the statistical identification of correlated surface species enabling examination of surface chemical characteristics responsible for mis-reporting of Ag containing components within flotation streams. We describe the application of these techniques to a selected Ag-containing feed and tail and demonstrate how these compliment and extend traditional analytical methodologies."

Jan 1, 2014

By Polezhaev S. Yu, I. V. Ukraintsev, Boduen A. Ya, Saburbayeva L. Yu

"Comparison studies of different technologies are performed when selecting optimum option for gold ore and concentrate processing. Methods of ultrafine grinding, oxidizing roasting, bacterial leaching and pressure oxidation are used to extract gold from refractory ores and concentrates. Refractory gold flotation concentrate produced from pyrite-arsenopyrite ores of Bestobe deposit is a case study in this paper. The results of the experimental tests of the direct leaching of flotation concentrate and pre-oxidation products using different methods (oxidizing roasting cinder, pressure oxidation and bacterial leaching cakes) are the following: - cyanidation of original flotation concentrate provides recovery of Au at 46.6 %; - oxidizing roasting increases gold recovery from 46.6 % to 85 %; - BIOX increases gold recovery up to 86 %; - preliminary pressure oxidation of flotation concentrate ensures steadily high Au extraction in the follow-up cyanidation at 94.9-96.5 %. Pressure oxidation and bio-oxidation has changed dramatically the strategy of refractory gold ore processing. These solutions provided for development of ore deposits that considered earlier non-commercial. However, refractory ore processing has a complex character in terms of developing process flowsheet and requires large amount of studies to be performed for each new project. Gold extraction is the basic but not the only criteria to technology selection for gold ore and concentrate processing. Opex and capex, ore reserves, regional geography, developed infrastructure and skill personnel should be considered. Process studies and feasibility study of the developed technology shall be provided for each specific gold ore deposit. INTRODUCTION Due to changes in available feedstock and depletion of easy-to-process ores, refractory ores containing finely disseminated gold and silver in sulphides (primarily, in pyrites and arsenopyrites) are more and more involved into processing. Experts say that such ores amount above 40 % of the world’s gold reserves. Conventional technologies of gold extraction from refractory ores include flotation, roasting and cinder cyanidation (Fraser etal., 1991). However, today’s best available practice for refractory gold ore processing are bacterial (BIOX) and pressure (POX) oxidation."

Jan 1, 2018

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By Stoyan Groudev

Two experimental plots consisting of a slightly acidic soil heavily contaminated with radionuclides (mainly uranium and radium) and non-ferrous metals (mainly copper, zinc, and cadmium) were treated in situ under real field conditions using the activity of some representatives of the indigenous soil microflora. This activity was enhanced by suitable changes in the levels of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. The treatment was connected with solubilization and removal of the contaminants from the top soil layer (horizon A) due to the joint action of the soil microorganisms (mainly acidophilic chemolithotrophic bacteria) and leach solutions (diluted sulphuric acid) used to irrigate the soil. In one of the plots, the dissolved contaminants were removed from the soil profile through the drainage soil effluents and were subjected to cleaning by a constructed wetland located near this plot. In the other plot, the dissolved contaminants were transferred to the deeply located soil subhorizon B2 where they were precipitated as the relevant insoluble forms (uranium as uraninite, and the non-ferrous metals as the relevant sulphides) as a result of the activity of the sulphate-reducing bacteria inhabiting this soil subhorizon. This activity was enhanced by injecting water solutions of acetate, lactate, ammonium, and phosphate ions to this soil subhorizon.

Sep 1, 2012

By A. P. Chaves, D. Jose Neto, M. G. Bergerman, E. S. Mano

"More complex ore comminution and concentration operations have found increasing application in the mining industry due to lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. They allow removing a significant mass of material with little or no content of the relevant mineral before the ore is fed into the processing plant, with the consequent reduction in the mass to be processed in downstream operations. Significant benefits arise out of the use of pre-concentration, such as higher contained metal output without the need to increase the grinding or flotation capacity, and longer mine life. The grade of marginal ores could be enhanced to a level that would make their exploration economically feasible, which would result in increasing exploitable reserves. Nevertheless, few studies to date have assessed the resulting impacts on ore grinding energy consumption and wear after the gangue is removed through pre-concentration operations. This study evaluated the energy consumption and wear of grinding circuits in Brazilian mining operations in which the feed has gone through a pre-concentration stage. Such assessment was based on different samples of sulfide and oxide ores. Laboratory tests were carried out to investigate the power consumption and wear of grinding circuits with and without a pre-concentration stage. Laboratory test results were used to simulate industrial grinding circuits based on both alternatives and illustrate the environmental and economic benefits of each one.INTRODUCTION Increasingly complex ore concentration operations in several stages have found broadening application in recent years in view of lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. Different ore processing technologies can be used for that purpose, such as magnetic separation, density segregation, and separation methods based on high-tech sensors (ore sorting). Currently, the most common methods are gravimetric processes, in view of their low cost, particularly jigging and dense medium separation methods, such as the drum and cone separators manufactured by Western Machinery Company, Teska, Drewboy, Norwalt, Dynawhirlpool and Tri-flo, and dense medium cyclones (CAMPOS; LUZ; BRAGA, 2010). The use of dry ore sorters has also grown significantly in recent years (Jose Neto et al. 2017). The selection of the separator type depends essentially on the ore particle size, required flows, and operating density ranges. All these methods may even be used after preferential blasting in mining (Grigg & Delemontex, 2015)."

Jan 1, 2018

By C. A. C. Sequeira, G. N. Anastassakis

"The separation of fine or even smaller size mineral particles with conventional methods is inefficient due to the specific properties of fines (small mass, high specific surface area, and high surface energy per unit area). Hence, the production of high-grade concentrate with high recovery is very difficult to impossible and a significant share of mineral values is lost to the tailings. The aim of the current research is to investigate the possibility to efficiently separate value minerals from gangue of fine particle size. The objective of the current work is to develop separation schemes of fine mineral particles by combining an initial stage of particles agglomeration with the use of collectors (hydrophobic agglomeration) with a subsequent conventional separation method. In the current research, magnesite was used as mineral value to be separated: a) from quartz, and b) from mineral mixture (serpentine, ilmenite, and olivine). In each case, tests on single minerals and artificial mixtures were carried out. After hydrophobic agglomeration, the separation of magnesite from quartz was achieved by settling; in the second case (gangue: serpentine, ilmenite, and olivine), magnetic separation of the co-agglomerated gangue was applied. In both cases, the results of the preliminary tests on single minerals suggest that the separation of mineral value is feasible and efficient. These findings were also confirmed from the results of the tests on artificial mixtures of magnesite and gangue, either quartz only or mineral mixture. Both separation schemes provided with magnesite concentrates of commercial grade (95% magnesite) with high recovery. INTRODUCTION The generation of fine particles is inevitable in many operations of mineral commodities processing. Especially in the case of low-grade ores, the mineral value is finely disseminated in the ore, and considerable liberation occurs at a fine size range. Although there is not a uniform classification system with respect to mineral particles size, fines are usually characterized the particles with a size range of -100µm+20µm, very fines those of -20µm+5µm, ultra fines of -5µm+1µm, and colloids smaller than 1µm (Sivamohan, 1990)."

Jan 1, 2018

By S. L. Zheng

The compound material of Nano-TiO2 Supported on the diatomite was prepared by the hydrolytic method with purified diatomite and TiCl4. The compound material was characterized by SEM, XRD, TEM, EDX, XPS, and the application test of the compound material was studied. The characterization test results showed that the Nano-TiO2 was coated on the surface of diatomite, the crystal of TiO2 is anatase, and the average crystal size is 12 nm. The pore diameter was reduced, but pore volume and surface area of the compound material are increased after Nano-TiO2 Supported on the diatomite. The application test results for treating coking waste water and formaldehyde gas show that the compound material of Nano-TiO2 / diatomite has adsorption and photo-catalytic function and strong degradation performance for phenol and formaldehyde.

Jan 1, 2014

By C. Gomez, J. Finch, R. Dalhke, J. Torrealba-Vargas

The velocity of gas passing through a flotation cell can be estimated by collecting bubbles by natural buoyancy in a closed tube and measuring the rate of pressure increase. The governing equation is derived and verified. Single- and two-tube gas velocity sensors are described. The latter design permits a correction for bulk density and level change during signal collection.

Jan 1, 2003

By de Vaux. D.

Synthetic water with a calcium concentration of 80 ppm and 500 ppm was prepared and the flotation results obtained compared to a simple electrolyte in order to determine the effect water quality has on pentlandite and pyroxene surface alteration and, ultimately, floatability. During the study, the possible effect of interactions between the minerals investigated and Ca2+ ions in the presence of sodium isobutyl xanthate was studied at pH 6 and pH 9 by means of zeta potential determinations, microflotation tests and ToF-SIMS analysis. The results obtained have demonstrated that water quality does play a significant role in flotation recovery at the experimental conditions used.

Jan 1, 2003

By B. Friedrich, A. Weyhe, H. Heegn

"Nickel-metal hydride batteries (Ni-MH) are storers of electrochemical energy, which have a higher specific storage capacity than lead or nickel-cadmium batteries. The demand for Nickel-metal hydride batteries is increasing rapidly since their market launch in the early 1990’s. Today there is no suitable and sustainable recycling process to recover nickel, cobalt and rare-earth metals. The discarded batteries are used today in the steel industry as alloy material because they contain nickel. Cobalt and rare-earth metals (RE) are lost; they are non-recycleable.In a German governmental funded research project, IME Aachen, ACCUREC Mühlheim and UVR-FIA Freiberg are cooperating in processing as well as in creating a feasibility study. The target of this project is the development of a new recycling process for metal recovery from Ni-MH-batteries. The proposed process described in this paper consists of a combination of mechanical, pyrometallurgical and hydrometallurgical processing steps. This process is capable of treating all types of Ni-MH-batteries. After comminution steel and organics are separated. The separated Ni-MH is smelted in an electric arc furnace. The products are a nickel-cobalt alloy and a slag phase enriched with rare-earth oxides for further treatment to ‘mischmetal’. Both the Nickel-Cobalt alloy and the ‘mischmetal’ will be directly used in battery production."

Jan 1, 2003

By S. M. Bradshaw, R. Smith, J. H. van Vreden, C. A. Snyders

"The re-treatment of gold tailing heaps has shown to be a potentially significant revenue stream for both large and small scale gold companies. Limited access to capital and lack of skilled labour remain restrictive especially when dealing with a refractory ore and/or where limited amount of material are available. Alternative techniques such as low temperature pre-leaching options to unlock value are therefore in demand. Several low temperature pre-leaching experiments in acidic and alkaline solutions, followed by cyanidation were performed which ultimately led to the further investigation of a caustic pre-leaching step. It was found that the Au recovery from a refractory ore tailings heap could be significantly improved from ˜ 15 to 20% to greater than 60% with a simple atmospheric NaOH pre-leaching step. It was further considered, that since the NaOH pre-leach liberate the Au associated with refractory sulphide minerals, the overall process may benefit by the inclusion of a froth flotation step to separate refractory sulphides from the free milling ore. Froth flotation on weathered tailing heaps are, however, known to be difficult, ultimately resulting in poor recoveries. A process flow sheet, incorporating a caustic pre-leaching step and a process which includes flotation and caustic pre-leaching of the concentrate, are technically evaluated and ultimately compared to simple cyanide re-processing. INTRODUCTION South Africa consists of a large number of gold tailings dumps. Janse van Rensburg (2016) estimated that there was about 517 dumps in the Gauteng area, covering approximately 320 000 ha of surface area. Recovering value from the dumps has received a great deal of interest but can be problematic due to the dumps often being refractory, preg-robbing and weathered. High recovery of valuable metals (Au and Ag) are possible (Fleming and Brown, 2010) but would most likely require pressure oxidation and subsequent neutralisation which can be very capital intensive demanding a high skill set to operate and maintain. In addition, these flowsheets target high processing tonnages due to the economy of scales at the lower grade feed materials, further increasing the capital requirement."

Jan 1, 2018

By Paulo Castillo, Cesar Gomez, Jaime Alvarez

Operations using flotation to produce mineral concentrates require testing of frothers to characterize their ability to preserve bubble formation size and to build a stable froth. Many techniques have been proposed to measure parameters associated with these two roles. These techniques focus, in general, on only one of these roles and are based on special equipment operated at conditions quite different from those existing in industrial cells and columns. Both roles have been simultaneously characterized in a laboratory flotation column, but the requirements associated with the installation and operation of one of these units, are a serious limitation for its use on-site. A technique based on the use of a laboratory mechanical cell, a common piece of equipment in operations, will have wider application. Establishing the ability of a frother to control coalescence by preserving bubble formation size is done through bubble size measurements as a function of frother concentration. Froth build-up and stabilization is associated with the amount of water carried by bubbles into the froth layer, which has been demonstrated to correlate with the gas holdup in the collection zone. Procedures devised for determining the critical coalescence concentration (CCC) from measurements of bubble size as a function of frother concentration, and the gas holdup by collection of water displaced from the cell by the presence of bubbles at different frother concentrations, were tested. Three analytical-grade frothers were utilized: a straight-chain (1-heptanol) and a branched (MIBC) alcohol and a polyglycol (PPG425). The results obtained at a standard set of conditions, demonstrated consistent differences between these frothers, and the ranking from least to most effective for reducing bubble size or decreasing water drainage followed the same sequences found when more complex frother characterization techniques are used.

Jan 1, 2014

The flotation of nickel sulphide minerals is normally difficult in the presence of serpentine minerals due to the coating of serpentine particles on the nickel mineral surface. To improve the flotation, dispersants such as polyphosphate and carboxy methyl cellulose are normally used to remove the slime coating. However, in the flotation using high ionic strength process water, these dispersants are invalid due to their ionic nature. In this study, a new type of non-ionic dispersants, Pluronic triblock copolymers were examined with an objective of improving the flotation of ultrafine pentlandite (a nickel sulphide mineral) in the presence of lizardite (a serpentine mineral) in saline water. Three Pluronic triblock copolymers varying in solubility and hydrophile-lipophile balance (HLB) values were studied by flotation tests, settling tests and froth measurement. It was found that two of the copolymers improved pentlandite flotation against lizardite, and one copolymer deteriorated the flotation. The effect of Pluronic triblock copolymers on the flotation was actually linked to their dispersibility and foamability, which were governed by their physical properties. The two copolymers with a higher solubility or HLB value produced more stable mineral suspensions and more stable froth in the flotation resulting in better nickel grade and recovery in both rougher and cleaner flotation. Keywords: ultrafine particle, flotation, slime coating, dispersion, saline water, triblock copolymers

Sep 1, 2012