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By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By M. Rudolph, D. H. Hoang, N. Kupka

"Froth flotation has been subjected to modelling since the 1930s and there is a large variety of approaches that intend to portray the entire process. Among these, three fundamental models could be considered exhaustive: the Pyke model [1], the Yoon model [2] and the Schwarz and Koh model [3]. The first model makes use of the generalized Sutherland equation collision model, the Dobby-Finch attachment model and its own stability model, the second model considers an extended DLVO approach for the attachment and stability whereas the third model makes use of computational fluid dynamics. Using a scheelite ore as a test case, a specific batch flotation test was repeated ten times and analyzed for chemical assays, mineralogical studies and froth properties. The detailed data are used to feed the three flotation models aforementioned in order to compare the outcomes of the three approaches, their capacity to reflect reality and to predict it. This article intends to pave the path towards reliable process models incorporating in depth mineralogy information, e.g. surface liberation, particle size and particle shape. KEYWORDS Froth flotation fundamental models, scheelite, automated mineralogy, critical assessment. INTRODUCTION In mineral processing, only three approaches aiming at describing froth flotation fundamentally could be considered exhaustive: Pyke’s collision and sliding approach [1], Yoon’s kinetic approach [2] and Schwarz and Koh’s approach [3]. The models will hereafter be referred to as Pyke model, Yoon model and Schwarz and Koh model. The first model makes use of the generalized Sutherland equation collision model, the Dobby-Finch attachment model and its own stability model, the second model considers an extended DLVO approach for the attachment and stability whereas the third model makes use of computational fluid dynamics. All three approaches rely on the widely accepted idea that flotation is a kinetic reaction dependent on a flotation rate constant kp, as expressed in Eq. [4]:"

Jan 1, 2018

By M. H. Moys, H. Dong

"Discrete Element Method (DEM) has become a standard tool to simulate grinding mills in order to gain information about load behaviour, power drawn, etc. However, parameters necessary to run a simulation are not always readily available. For example, the coefficient of restitution used in DEM simulation from the literature ranges from 0.1 to 0.9 due to lack of accurate values. The lack of correct input parameters results in the fact that some simulation parameters are adjusted to match the simulation prediction with the experimental results. It is inappropriate to tune one single parameter arbitrarily in order to fit the prediction with experimental results. The correct value of parameters for DEM simulation should be established, and rigorous validation on simulation results by DEM needs to be done.The objectives of the ongoing project are to measure the coefficient of restitution at conditions analogous to grinding practice. Equipment has been built to measure the coefficient of restitution. A typical case of impact test showing the vertical position of a ball as a function of time is presented in Figure 1. The coefficient of restitution between steel ball of different sizes and the targets including steel liner (e = 0.91), mild steel block (e = 0.57) and rubber liner (e = 0.7) have been measured. The coefficient of restitution reduces to 0.38-0.52 when there is a layer of coal particles (1-2 mm) on the steel liner. The effects of ball size, drop height on coefficient of restitution are investigated. Then a DEM code is developed of several contact models to simulate the impact process. This code can reveal details on velocities (translational and rotational) and forces (normal and tangential) during the brief impact interval. Figure 2 is a comparison of the rebound rotational velocity between experiment and prediction by different models. The results can be used as DEM input and to assess contact models."

Jan 1, 2003

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

By Sanchita Chakravarty, Sumantra Bhattacharya, Divya Jyoti, A. K. Mukherjee, Soni Jaiswal

"Release analysis is independent of collector and frother dosage and type, but it is primarily influenced by the degree of liberation or “state of release of the sample”. The shape of release curve is an indication of the degree of liberation. This paper briefs about the effect of reagent combination, particle size and surface characteristics on the release analysis of difficult-to-clean LVC coal.Release analysis of three LVC coal fines obtained from two different coalfields of India was carried out at three different size levels such as -0.5mm, (-0.5+0.1) mm, and -0.1mm. The collectors used were n-dodecane and commercial diesel oil. Incomplete liberation of coal fines even at a size of -100µm, corroborated by photomicrographs of ROM and clean coal macerals, in a great measure reduced the flotation-based cleaning potential of the fines. FESEM images of fines reveals that the adherence of ultrafine onto the surface of relatively coarser particles reduced the clean coal recovery. The results obtained also appear to be coal, reagent combination and, particle size and particle surface specific. Only one coal indicated the liberation as is usually expected for -0.1mm particles with a reasonable yield of 65% at 18% ash. INTRODUCTION Froth flotation has a long history of being used to treat coal fines. Coal flotation is considered to be difficult, if the percentage of Near Gravity Material (NGM), i.e. essentially locked particles, in flotation feed is >10% [Aplan, 1993], which is usually the case with all the coking coal fines in India. The fines are rich in vitrinite, so valuable for coking coal. Unfortunately, there appears to be no standard procedures to determine the separation efficiency of froth floatation. Release analysis proposed by C.C. Dell in 1953 [Dell, 1953], aimed to determine the ultimate floatability of coal. Several other techniques had been proposed but release analysis technique has been considered to be a vast improvement over the batch flotation process [Forrest et al. 1994]."

Jan 1, 2018

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001)."

Jan 1, 2018

By Carina Ulsen

The existing construction and demolition (C and D) waste recycling technologies and standards have been essentially focused on the production and use of coarse recycled aggregates. Very few papers focus on the production of recycled sand, although some previous results show that fine aggregates fraction represents around 40 to 60% (in mass) of the Brazilian waste and it is usually used as road sub-base or disposed in landfills. The quality of the recycled aggregate is strictly related to the content of porous and low strength phases, mainly the patches of cement remaining on recycled aggregate surface. Some technologies have already been described in the literature, even though, to the moment none of these technologies has clearly succeeded in reaching the large market available. This paper presents a summary of the main properties of the sand produced from C and D waste by tertiary crushing at vertical shaft impact crusher (VSI). Additionally mineral processing technologies were applied on the attained product, such as gravity concentration by shaking table and spirals and removal of cement paste by attrition. The main properties of recycled sand are discussed and compared to the previous C and D waste, respectively: particle size distribution, particle shape, chemical composition, cement paste content and porosity. The results demonstrates that the crushing allowed producing a VSI-sand with low porosity and water absorption due to the increasing on the content of silicates from natural rock phases and increasing liberation between these phases and porous cement paste; the particles from the attained product presented also a better shape (sphericity and aspect ratio). The attrition tests assayed on VSI recycled fine aggregates accomplished a further selective disaggregation of cement paste and other porous materials - the porosity was reduced from 10% to 7%. The concentration by shaking table at narrow sieve fractions led to a product with low porosity and reduced content of cement paste, however, concentration on spirals did not succeed since separation was performed essentially by the size of the particles. The heavy product from shaking table represented almost 75% in weight and has less than 60% recovery of CaO+LOI, and expressive reduction on porosity. The aim of producing sand from construction and demolition waste through mineral processing unit operations changes the recycling approach and contributes for up cycling the recycled sand. The exhaustion of sand deposits on Brazilian large centers, the increasing price and the construction boom encourages the development of alternative materials as construction raw material. Keywords: recycled sand, construction and demolition waste, technological characterization

Sep 1, 2012

By D. Hatfield, G. de Jager

"The rapid developments in computer vision and computational resources are creating new possibilities for the use of machine vision systems for industrial control. A number of commercial image analysis systems exist, and research into improved measurements of froth performance is ongoing. An integral part of the implementation of these systems is the validation of the relationship between image analysis measurements and flotation cell performance. This paper discusses the factors affecting concentrate flow and presents the results obtained from one such system with respect to its ability to estimate the flow of concentrate from a flotation cell.The relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell was investigated on two industrial operations, both processing PGM (Platinum Group Metal) bearing ores. Results are presented that show a relationship between froth flow speed and concentrate yield."

Jan 1, 2003

By B. Peszko

There are many measuring methods of grain sizes. Taking into consideration the fine grained materials, one of the existing techniques is measurement of grain size by the Coulter Counter method. This method is based on the measuring the changes of electrolyte resistance during grains flow through the calibrated diaphragm. This method is relatively simple to apply, significantly precise and the results are given quickly. However, the problem is that the measurements are limited by the size of diaphragm. Because of this situation, measurement of grain sizes by this instrument is possible in range from 10% to 60% of diaphragm diameter. This limitation causes the necessity of re-placing diaphragm in case when the measured grain size distribution concerns the material of large size range. In purpose of determining the total grain size distribution, the synthesis of some partial distributions, given for individual grain fractions (with different diaphragm applied), is required. This is possible to do by calculating the mixture of distribution functions, created from the partial distribution functions. Two materials were selected to research: quartzite and glass, which were comminuted in cylindrical crusher, additionally grinded, screened and then analyzed by Coulter Counter for five grain fractions: 0~125 µm, 0~80 µm, 0~56 µm, 0~40 µm and 0~25 µm. For each fraction, five different partial distributions were given (in case of glass ? four), which are the basis for the creating the joined grain composition. To assure the adequacy of the given distribution function, it is necessary to obtain the possibly best approximation of partial distributions. In the work, both the parametric and non-parametric methods of density approximations of investigated random variable. For each grain fraction the approximations were done by three traditional distribution functions: RRB, GSA and log-norm distribution functions and three methods of non-parametric approximation: Gauss kernel, Epanechnikov kernel and orthogonal Fourier series method. As the criterion of the certain distribution function acceptance, the value of the residual deviation was assumed, given by the formulae:

Jan 1, 2014

There is a strong demand for nickel metal due to quick development of stainless steel and new electrical materials, most of which is extracted from sulfide resources, resulting in a serious depletion of sulfide resources. Therefore, more attentions have been paying to extracting nickel from nickel laterite, which accounts for some 50% of total nickel metal production. In this paper prereducing?magnetic separation?reduction smelting process is developed to manufacture ferronickel rom two types of nickel laterite DN and GN, assaying 1.42% 1.83% Ni and 49.09% 26.08%Fetotal, respectively. Mineralogy of two types of nickel laterite was determined and optimization of process parameters was conducted to manufacture ferronickel. Prereduction?magnetic concentration process is used to upgrade low grade nickel laterite firstly, two kinds of Ni-Fe concentrates being prepared of DN assaying 2.26% Ni and 69.45% Fetotal and GN containing 2.76% Ni and 38.00% Fetotal. Finally, two types of ferronickel were produced by reduction smelting of prereduced concentrates DN and GN, DN and GN ferronickel contains 2.97% Ni and 6.58%Ni, 89.25%Fetotal and 89.95%Fetotal, respectively. The total recoveries of Ni and Fe of the two ferronickel are beyond 90% and 80%, respectively. There is significant difference in grade of magnetic concentrates and ferronickel between DN and GN laterite due to their different mineralogy, the former belongs to limonitic laterite and the latter saponite one. There are some advantages for this process to manufacture ferronickel from nickel laterite, including effectively upgrading low grade nickel laterite by prereducing?magnetic separation technique, higher throughput and lower energy available for reduction smelting section due to some 40% gangue being rejected in pre-upgrading section, and much less metallurgical coke consumption by using non-coking coal as reductant for prereducing?magnetic separation?smelting process.

Jan 1, 2014

By Evvie Chockalingam

Acid mine drainage (AMD) is a perennial problem particularly in abandoned mines, occurring due to the oxidation of sulphidic mine wastes. AMD is usually characterized by high concentration of dissolved metal ions, sulphate and low pH. The efficacies of substrates such as rice husk and the bark of Eucalyptus tereticornis (Sm.) are assessed for the removal of metal ions such as iron, zinc and copper from acid mine water obtained from an abandoned copper mine. Over 99 % of Fe, 98 % of Zn and 95 % of Cu removal could be achieved from acid mine water, with a concomitant increase in the pH value by three units using rice husk as an adsorbent. With respect to tree bark as an adsor-bent, about 96 % of Fe, 75 % of Zn and 92 % of Cu could be removed from the acid mine water with an attendant increase in the pH value by two units. The free energy of adsorption of the metal ions onto rice husk and tree bark is found to be negative in both the cases, while the adsorption process is endothermic in the case of rice husk and exothermic for tree bark. The adsorption process is found to adhere to the Lagergren pseudo-first order rate equation. The reduction of sulphate con-centration in the acid mine water is achieved using a typical sulphate reducing bacteria namely De-sulfotomaculum nigrificans. Desorption experiments indicate that about 88 % of Zn, 87% of Cu and over 77 % of Fe could be recovered from rice husk and over 70 % of Fe, 82 % of Zn and 77 % of Cu could be desorbed from the metal loaded tree bark using 5 M HCl. The possible mechanisms of metal ion and sulphate removal from acid mine water using rice husk and tree bark are discussed.

Jan 1, 2014

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki

"Hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in various applications. It has also been reported to reduce the recovery of sulfide minerals. Moreover, the previous work applied H2O2 aqueous solution in selective flotation of chalcopyrite and molybdenite. However, the oxidation method suffered in pilot scale test due to too long conditioning time. Furthermore, the excessive reagent consumption increased the reagent cost, causing the method not economically feasible. Consequently, further improvement is required to reduce the conditioning time and the reagent consumption. The oxidation performance of H2O2 can be improved by using ferrous iron as catalyst, producing a Fenton’s reagent which is more powerful oxidizer than the H2O2 itself. Therefore, the effect of Fenton’s reagent on the floatability of chalcopyrite and molybdenite was investigated in this study. The flotation test results show that selective flotation of chalcopyrite and molybdenite might be possible at low concentration of H2O2 aqueous solution by adding ferrous iron. Moreover, the conditioning time could be shortened by this improvement. To understand the phenomenon, surface characterization using atomic force microscopy (AFM) along with x-ray photoelectron spectroscopy (XPS) analysis were carried out. The AFM images show that the surface of chalcopyrite was readily covered with mountainous features which alters its hydrophobicity after the oxidation treatment. Meanwhile, the molybdenite surface remained clean and relatively hydrophobic. The XPS results indicate that the mountainous features are various oxidation products (i.e., FeOOH, Fe2(SO4)3, CuO, Cu(OH)2). Possible mechanisms of this phenomenon were proposed in this work.INTRODUCTIONConventionally, copper and molybdenum ores are separated in selective flotation circuits by using copper depressants (i.e., sodium hydrosulfide (NaHS), sodium sulfide (Na2S), and Nokes reagent (P2S5+NaOH)). However, these depressants are usually toxic or hazardous. Therefore, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, ozone, and plasma pre-treatment (Arbiter and Young 1951; Barzyk et al. 1981; Curtis 1941; Hirajima et al. 2014, 2017). Recent study by Chimonyo et al. (2016) reported the effect of H2O2 on reducing the recoveries of sulfide minerals. Moreover, Hirajima et al. (2017) demonstrated that H2O2 depressed the floatability of chalcopyrite and could deliver a selective separation on copper and molybdenum (Cu-Mo) bulk concentrate in flotation process. However, they reported that this method required a higher concentration of H2O2 and a longer treatment time (4.5 h) to get a comparable result to that of using NaHS as copper depressant. Therefore, further improvements are necessary to reduce the conditioning time and reagent consumption."

Jan 1, 2018

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and the dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is the main parameter for precipitate flotation in pilot or industrial scales. The suggested limiting factor is the aggregate stability under the turbulence created by the rising bubbles. The stability of precipitate is related to the structural organisation of aggregates, which determines the size distribution of particles during precipitation and flotation stages.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions. The fractal studies allow the detection of a structural scaled organisation of the precipitate flocs. The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with restructuring or breakage phases.The destruction process, which occurs for the lowest values of the dissipation energy E (0.02 . 0.05 W/kg) was characterised by a fractal dimension Dg of size distribution. Besides, the destruction of floc produces very fine particles, and thus induces the difficulties of bubble-particle collision during the precipitate flotation in column."

Jan 1, 2003

By A. Boulton

Low molecular weight synthetic polymers substituted with hydroxyl, carboxyl or sulfonate functional groups were used to improve the flotation separation of zinc or copper sulfide minerals from iron sulfide gangue minerals in three massive sulfide ores of different mineral composition. These polymers produced significant improvements in zinc or copper grades as a result of a selective depression of iron sulfide minerals. It was shown that this selectivity was the result of preferential adsorption of the polymer on the surface of the iron sulfide minerals. The different types of interaction between the functional group on the polymers and the sulfide mineral surfaces could explain the trends observed in the flotation results.

Jan 1, 2003

By L. Q. Luo

SHP-F3200 wet high-intensity magnetic separator (HIMS) was successfully used to separate the complex and weakly magnetic iron ores being composed of specularite, limonite and siderite in Ji-uquan Iron and Steel (Group) Co Ltd (JISCO). It is more and more difficult to separate iron ores from gangues, such as quartz, jasperite and phyllite, as the properties of iron ores gradually become more complicated and refractory. Some technologies have been used to improve SHP-F3200 HIMS, including modifying angle of magnetic polar from 90°to 83°, cooling exciting coils by oil instead of air, adding reverse-washing device to wash off magnetic particles, adjusting the tooth-space of matrix from 5.0 mm to 3.5 mm or 2.5 mm, so as to enhance the recovery of fine iron ore particles. It is still difficult to meet the requirement for recovering more difficultly-separated iron and the demands for high-grade concentrate of iron. In this paper, after analyzing magnetic force exerting on iron ore particles within different separating sections of SHP HIMS, it is proposed to apply the flowing-film technique into the HIMS. Thus a new-type LY matrix is designed to form magnetic gradient vertically, combined with a special flowing-film feeder to improve the existing SHP HIMS. The moving pattern of magnetic particles in pulp in HIMS separation district also has been analyzed in this paper. And the test on the SHP-F700 HIMS shows, under the condition of iron ore containing 30.52% Fe, with particle size of ?0.074 mm accounting for around 75%, if applied with flow-film technique, the iron recovery will be up from 69.45% to 76.07%, by 6.62 percent, with the same grade of concentrates of iron. The calculation of iron yield of every size fraction and the tests showed that film magnetic separation (Film-MS) could promote the iron yield of each size fraction, denoting an excellent result of application of the film technique to SHP HIMS. The mechanism of the film magnetic separation technique is to convert the turbulent flow and disordered movement of dynamic mass particles in the pulp into a directional and ordered laminar flow along the surface of tooth plate so as to strengthen the separation effects.

Jan 1, 2014

By K. C. Corin, M. S. Manono, R. M. Manenzhe, J. G. Wiese

"Environmental concerns necessitate the recycling of process water within mining operations. Given that recycled water is chemically different from fresh water, and collectors are added such that they adsorb at the liquid-particle interface, changes in the aqueous phase are expected to affect collector adsorption. A Finnish nickel-copper ore was floated in synthetic plant waters of varying ionic strengths and plant waters obtained at Boliden Kevitsa Mine, with aerophine and sodium isopropyl xanthate as collectors. Of the tested waters, the copper thickener overflow was the least conducive to xanthate adsorption and valuable mineral recovery. The nickel thickener overflow, standard process water, and raw water were the most conducive to xanthate adsorption. For the raw water and nickel thickener overflow, increased adsorption correlated with increased valuable mineral recovery. Further, recycling xanthate retained in water affected the selectivity of the collector and hence the concentrate grades.INTRODUCTIONFlotation is a separation process that exploits the differences in the surface properties of the particles being separated. The efficiency of separation is dependent on the degree of hydrophobicity achieved by the particles meant to be floated, which are, in most cases, valuable minerals. The hydrophobicity is in turn dependent on the adsorption of the chosen collector onto the surfaces of the floated particles (Fuerstenau, 1984; Taggart and Hassialis, 1946). Empirical findings suggest that species dissolved in solution strongly influence collector adsorption and overall flotation response (Fuerstenau and Chander, 1986). Due to environmental concerns, it is becoming more pertinent for mining plants to recycle process water and hence limit the usage of potable water. There is an interest to ensure minimal discharge of plant water into the environment, as this water is typically polluted with process reagents that may render it toxic (Levay et al., 2001).Recycled water, however, has been shown to adversely affect flotation. Reagent efficiency can be reduced due to increased suspended solids. A loss of mineral recovery can occur due to competitive adsorption between reagents and other dissolved species, loss of reagents due to precipitation, and unwanted reactions. Further, a reduction in grade can occur due to non-selective coating of reagents on valuable and gangue minerals, and hydrophobic coating of microbiological material on gangue, causing unwanted flotation. Yet despite these drawbacks, water reuse has the advantages of minimal fresh water use and reduced reagent consumption by recovering the unconsumed reagents retained in wastewaters (Bruckard et al., 2011; Levay et al., 2001; Shengo et al., 2016; Slatter et al., 2009)."

Jan 1, 2018

By Erico Tabosa, Kym Runge, Peter Holtham

"The distribution of turbulence in an industrial scale mechanical flotation cell and its effect on flotation kinetics was studied using a fully instrumented 3m³ cell. The cell was operated at a copper concentrator in Australia with different combinations of airflow rates, impeller speeds and sizes and cell aspect ratio providing a wide range of hydrodynamic conditions. An analysis of the overall flotation cell performance showed that the overall copper recoveries were very similar for the conditions tested. However, by decoupling pulp effects from froth effects it was possible to evaluate whether the changes made affected the pulp zone and/or froth zone responses. The analysis showed that the overall recovery has the potential to be up to 7% higher, if not limited by froth recovery. The cell hydrodynamics were characterised by the overall energy dissipation rate and, to understand the distribution of turbulence within the cell, localised measurements were made using a piezoelectric vibration sensor. By comparing the metallurgical performance of the cell with the different hydrodynamic conditions it was found that the collection zone flotation rate constant was not directly related to overall energy dissipation, as is commonly observed at laboratory scale, where energy is usually only changed by varying impeller speed. In this study, energy dissipation rate was varied using not only impeller speed, but also the size of the impeller and the cell aspect ratio. In these circumstances, the best correlation was found to be between the collection zone flotation rate constant and the distribution of turbulence, i.e. the size of the turbulent zone."

Jan 1, 2014

By J. Drzymala

Ores and raw materials are subjected to mineral processing operations to increase the content of their useful components. Upgrading of these materials can proceed with different selectivity and therefore, there is a need to know and monitor the separation results of the process. The separation results can be evaluated using tables and graphs called upgrading curves. The course of lines in the upgrading curves is usually complex and depends on the graph type and process parameters. The Halbich grade vs. recovery plot is frequently used because is practical and it indicates several characteristic features of separation results. Separations by means of flotation of several different shale, dolomite and sandstone copper ores were performed along with determination of their mineral composition, copper content, liberation degree, and the maximum theoretical copper content in the first concentrate. These data, plotted as the Halbich upgrading curves, allowed to find other characteristic points such as practical maximum copper content in the first concentrate, maximum curvature coexisting with the liberation degree, maximum recovery of ore valuable components, and the slope the recovery-grade line at high recoveries as a measure of liberation. Correlations between theoretical and practical maximum copper contents in the first concentrate as well liberation degree and maximum curvature were also presented. They show that the ore type significantly influences the shape of the Halbich curve and its characteristic points.

Sep 1, 2012

By Yang Xiao, Zhang Yimin, Bao Shenxu, Liu Chun

Stone coal is a unique vanadium-bearing resource in China. Many techniques, such as salt roasting-water leaching, blank roasting-acid leaching, direct acid leaching etc. have been developed for vanadium extraction from stone coal. The vanadium leaching rate can reach 74.9% for stone coal from Jiangxi, but only about 27% of vanadium is leached for Hubei ore by applying salt roasting-water leaching technique. This paper investigats the vanadium occurrence in stone coal by microscope observation and electron probe, and compares the minerals components of stone coal from Jiangxi and Hubei. Although most vanadium exist as an isomorphism by replacing Al(III) from dioctahedral structure in mica group minerals in stone coal from two regions, the free vanadium is remarkably abundant in Jiangxi stone coal than in Hubei stone coal, which results the fact that vandium is relatively readily extracted from former. Moreover, the content of calcite in Hubei stone coal is much higher than that in Jiangxi stone coal. Calcium can react with V2O5 to form water insoluble calcium vanadates during roasting and this may be the reasone why the water leaching rate of vanadium is low for Hubei ore. Acid leaching is more beneficial to the vanadium leaching but other extra methods, such as adding aid-leaching agent and/or increasing acid concentration is need for the ore where vanadium is embeded firmly. This study can effectively guide the selection of vanadium extraction techniques for stone coal from different regions.

Jan 1, 2014