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By M. S. Alam, Jae-Chun Lee, M. Tanaka, K. Koyama

Extensive research work is being carried out at AIST for developing energy saving green technology for base and precious metals recovery. In the present work, a new flowsheet is developed for copper recycling from waste electronic circuit board where copper was recovered by leaching followed by solution purification and direct electrowinning of Cu(I) from ammoniacal alkaline solution. In this new technology, power consumption in EW circuit was greatly reduced. This paper describes the overall process with an emphasis on different aspects of solution purification where impurities were selectively removed by cementation and solvent extraction techniques under nitrogen atmosphere.

Jan 1, 2004

By Y. Dong, L. Li, L. Yu

Converter slag has become an important secondary raw material. Consequently, vanadium bearing converter slag is of great interest for the recovery of vanadium. Solidified converter slags are made up of three main mineral components: dicalcium silicate, calcium ferrite and wustite. Vanadium in modified slow cooling down converter slag of Magang is found mainly concentrated in a separate mineral phase. The mineral phase with high content of vanadium (24%, wt, V205), concentrating 83% of vanadium, can be separated from the slag for economical vanadium recovery. Some characters of the mineral phase were discussed comparing with dicalcium silicate, one of the typical mineral phases in converter slag studied well.

Jan 1, 2004

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By G. B. Harris

A new process for the recovery of copper and associated base metals from a polymetallic massive sulphide ore is described. The massive sulphide contains copper and especially nickel sulphide in a mineralogical form which negates both good recovery and high grades in concentrates using conventional flotation methods. Flotation concentrate processing and smelting from this ore is therefore probably not an economically viable option. Utilising the properties of high concentration chloride brines, a flow sheet has been developed and tested whereby the recovery of all of the metals and some of the power requirements for the plant itself can be derived from the ore. The new process overcomes the less-amenable-to-flotation ore characteristics, and provides the opportunity of economic processing in remote locations where the dependency on fossil fuels is both a logistical and an economic concern. The Ferguson Lake deposit of Starfield Resources in Nunavut, Canada, is the subject of this paper, which focuses on the leaching and copper recovery unit operations of the proposed flow sheet.

Jan 1, 2007

By K. Fukuda

The volatilization behavior of heavy metal in electric ash melting furnaces has a strong relation with its distribution between molten salt and slag. In this study, the distribution ratios of heavy metals between molten salt and slag phases were measured using a hermetic cell. The experimental results showed a relatively rapid loss of Pb and Zn from the salt in the first few hours followed by slow heavy metal vaporization with an almost fixed metal distribution between molten salt and slag. The distribution ratios of Pb and Zn decreased with increasing slag basicity. The mechanism of this effect can be explained by the chlorinated reaction of PbO and ZnO by CaC12.

Jan 1, 2004

By S. -H. Sohn, M. -K. Cho, G. -G. Hong

In order to evaluate the properties of coating materials for BOF, the effects of dolomites (dolomite and light burned dolomite) addition on durability of coating materials were investigated. In all coating materials, matrix was dicalcium ferrite(C2F) and both free MgO and dicalcium silicate(C2S) were precipitated. Fe203 content must be controlled to improve the adhesion and durability of coating materials for BOF during oxygen blowing process. The amount of dolomites added to BOF slag must be controlled in optimum condition with high refractoriness of C2S to improve the adhesion of coating materials for BOF. The weight ratio of converter slag to dolomite must be below 8 to improve the adhesion and durability of coating materials simultaneously.

Jan 1, 2004

By S. D. Logan

This presentation describes a lightweight automobile body structure concept developed at DaimlerChrysler to support a high fuel-efficiency vehicle project. This body structure consisted primarily of large thin-wall magnesium castings and resulted in a more than 40% weight reduction with a minimal cost increase over a conventional steel structure while achieving significantly improved structural performance as evaluated through CAE simulations. One concept vehicle was built for the purpose of demonstrating concept feasibility. Several slides showing the prototype build process are presented. The presentation also describes several large thin-wall die casting body applications that are in current production or have been used in recent production automotive applications and identifies areas where further development could improve the chances of a magnesium intensive body structure becoming a production reality at a later time.

Jan 1, 2006

By R. Ham-Su, J. P. Healey, S. P. Farrell, R. S. Underhill, M. A. Gharghouri, C. V. Hyatt, L. M. Cheng

Magnetic shape memory alloys (MSMA's) are a class of materials where magnetic energy can be converted into mechanical energy and vice versa. NiMnGa-based MSMA's have attained magnetic field induced strains up to approximately 10% and have a relatively wide operating temperature range, from well below 0°C to above RT, making them very attractive for a variety of applications. However, these materials also suffer from low toughness. Using these materials in a composite could mitigate this shortcoming, and also overcome limits imposed by inertia and eddy current losses. In this work, we describe the manufacture and characterization of such composites. Composites with 30% by volume MSMA were fabricated under a magnetic field resulting in anisotropic magnetic properties. Damping properties were evaluated by dynamic mechanical analysis.

Jan 1, 2004

By S. Orzecki

The KGHM Copper Refinery Plant, Glogów 1, has operated for 35 years and -increased its capacity almost ten times.Cathode quality, expressed in terms of the total impurity content, has undergone a five-fold improvement. The present refining capacity is equivalent to 240,000 metric tonnes of copper cathode, with a total impurity content of 20 ppm, inclusive of 10 ppm Ag. These accomplishments result from combined implementation of current technological progress in electrolytic refining and KGHM's own solutions applied to the Glogów Refinery. The quality improvement measures feature both lowering actual current density, despite an increase in nominal current density, and diminishing the role of non-ion mechanisms which transfer impurities to cathodes. The paper contains a detailed discussion of these issues and outlines possible measures aimed at further production and quality improvements.

Jan 1, 2007

By G. B. Harris

A process for the recovery of copper from the waste oxide copper of a mined-out sulphide orebody is described. Hydrometallurgical recovery of copper from this and similar wastes has been tried several times previously without success. Leaching is carried out by sulphuric acid in columns under conditions that minimise the iron content of the pregnant leach liquor, and copper is then recovered by ion exchange rather than the more conventional solvent extraction. The resin is stripped by spent electrolyte and copper is electrowon. Results are presented for testwork originally carried out in 1993, and repeated in 2006, and the novel aspects of the process, leaching and ion exchange, are discussed. Finally, preliminary order of magnitude capital and operating costs are given, demonstrating that the process is cost effective.

Jan 1, 2007

By Marta Polgari, Eva Surova, Bohumil Molak

Abstract -The Ûrkút rhodochrosite deposit and Branisko Mn showings (rancieite, manganiferous calcite), located in Lower Jurassic marine sedimentary rocks with black shale, were studied by organic­ geochemical methods. Both depositionallocalities were affected by the Lower Jurassic Toarcian anoxic event. Ûrkút shales are rich in organic matter (av. 2.94 wt% total organic carbon), the composition of which indicates derivation mainly from marine sources, with some terrigenous component. The shales matured in a bacterially active environment under reducing conditions of diagenesis-catagenesis. Branisko shales (?0.2 wt% TOC) with lenses of Mn oxide ore were weakly metamorphosed and their organic matter thermally degraded. The model for Mn carbonate ore formation envisages reaction of Mn derived from sediments, with carbonate generated by a bacterially mediated process of decom­ position of organic matter that also involved Mn reduction.

Jan 1, 1992

By G. Plascencia, A. Warczok, M. Zamalloa, T. Utigard, N. Behnood

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.

Jan 1, 2004

By R. A. L. Drew, C. A. Rodríguez González, Caleym W. F.

This work addresses the need of new refractories for copper converters. Technological improvements and environmental regulations for chromium containing refractories have generated this need. Chemical interactions, mechanism of penetration and the effect of oxygen potential and temperature in the system Cu2S-FeS-SiO2-O2 are presented for two refractories: a burned magnesite chrome brick (typically used by the copper industry) and a chrome-free spinel direct bonded brick. The main difference determined in the refractory performance was the blister copper penetration resistance; burned magnesite chrome brick is penetrated while direct bonded brick is not. These results are very promising since blister copper penetration has been reported as the major cause of refractory wear. The results are explained in terms of refractory porosity and wetting characteristics.

Jan 1, 2004

What Discounted Cash Flow Analysis can do for you: ?Provide an accurate financial analysis of a project for the first 25 to 30 years of operations ?Identify cash flow requirements ?Identify relative sensitivity of the project to the various input parameters ?Place a value on the resource in place after 30 years of operations ?Correct for errors in input parameters

May 1, 2010

By Maurizio Violo, Arjan Beqiraj, Umberto Masi

"Abstract - Four main podiform occurrences of chromite have been distinguished in the ultramafic Bulqiza massif, Albania; they are associated from the bottom to the top with: i) basal harzburgites (lower tectonite sequence), ii) dunitic lens-bearing harzbugites (middle-upper tectonite sequence), iii) layered chromitite-bearing dunites of transitional zone, and, iiii) the stratigraphically lowermost part of the magmatic section. However, only the occurrences hosted by rocks ii) and iii) are economically important.Chromite compositions similar to those of other podiform chromites are bimodal. Thus, chromites from occurrences ii) and iii) are richer in Cr than chromites from the other two occurrences. Accessory chromite disseminated throughout the massif is richer in Fe than orebody chromite, displaying similar range of the Cr/Cr+Al ratios, with accessory residue chromite matching the characteristic (Cr/Cr+Al >0.6) range of type-III Alpine peridotites. Both orebody and accessory chromites show compositional ranges correlating with host-rock compositions, i.e., the Cr-rich chromites are hosted by the most refractory ultramafic rocks. Therefore, the Cr/Cr+Al and Mg/Fetot (Cr/Fetot) ratios of chromite are useful for exploration of high-grade, metallurgical chromite ore at Bulqiza and in other massifs of similar geodynamic setting."

Jan 1, 2000

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By S. K. Sadrnezhaad, B. Hashemi, Z. A. Nemati, Z. Moghimi

Based on the kinetics relationships of a solid - gas model, a software was developed for the prediction of oxidation. Preliminary prediction of oxidation by the software and experimental results of MgO-C refractories were studied and compared. By using the obtained data from this approach, the effective diffusion coefficient, intermolecular diffusion coefficient and diffusion activation energy in the MgO-C refractories, containing various amount of graphite were obtained at different temperatures. First of all, the prediction by the software was very compatible with experimental results, for different oxidation mechanisms in the MgO-C refractories. The results showed that pore diffusion is the predominant oxidation mechanism in this system. The results indicated that when graphite content was above 10wt%, the intermolecular diffusion coefficient was independent from graphite content, and it was closed to a constant value at each temperature.

Jan 1, 2004

By Fengxiang He, T. Meadowcroft, Yanjun Zhang

Slag from the zinc fuming furnaces contains about 3 percent zinc and 0.1 percent lead. The paper outlines several experimental techniques for recovering these components from liquid fumer slag. The simplest method, remelting followed by a hold period, indicated that a substantial fraction of the metal values was recoverable as a result of fuming into the gas phase, presumable by reduction of the metal ions by divalent iron ions. Following on from this, slag samples were equilibrated with copper, chosen because the activity coefficients of zinc and lead in copper are very low. This improved metal recovery, with substantial amounts of lead and zinc reporting to the liquid copper as well as to the fume. Application of an electrical emf across the slag-metal interface, using a graphite anode and a liquid copper cathode, resulted in further gains in metal recovery.

Jan 1, 2004

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By T. Hartmann

The presence of crud represents a permanent challenge for solvent extraction in the hydro-metal industry. The crud is a stable emulsion which slowly spreads along the phase boundary between the aqueous and organic phase. The crud can significantly impair the efficiency of hydro-metal extraction because the phase boundary between the aqueous and organic phases assumes substantial proportions, and the settlers cannot react flexibly. In a chain reaction, all settlers connected in series become infected with crud. The transfer of organic phase to the electrowining (EW) cell can cause 'cathode burn'. Continuous treatment of the crud is extremely effective and reliable with a 3-phase separating solid bowl centrifuge. All three phases are separated distinctly from one another. All associated process steps exhibit a steady uniform efficiency. First and foremost, they ensure a reliable, continuous extraction process and, second, they recover valuable re-usable organics from the crud.

Jan 1, 2007