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By Chen Bang, Xia Xiao’ou, Zhang Feng

"Ores with compressive strength lower than 150 MPa are usually easy to be crushed by conventional jaw crushers and cone crushers. However, for hard ores with compressive strength exceeding 150 MPa and 200 MPa and even up to 250 MPa, such as andesite, hard basalt and olivine, it is difficult to reach satisfactory crushing size and yield or difficult to meet service life and stability use requirements of quick-wear parts by using conventional crushers. As continued increase in ore mining depth and constant generation of new type materials, equipment demand for crushing hard ores becomes increasing high. A new type inertia vibrating crusher is designed. It is powered by a high-speed rotating vibration exciter and can obtain required crushing force by adjusting eccentric mass, eccentricity and rotating speed so as to crush various ores with high hardness. This paper introduces the design process of its structure and working principle, discusses the design calculation methods of vibration excitation system, vibration damping and energy storage system and other key mechanism and provides technical references for this type of vibrating crusher.DESIGN PHILOSOPHYThe conventional jaw crusher mainly acquires extrusion force from crank motion to realize crushing. The motor drives the eccentric shaft via the transmission device to bring the moving jaw to swing relative to the stationary jaw. When the moving jaw moves close to the stationary jaw, ores between them are crushed by extrusion; when the moving jaw moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving jaw and the stationary jaw.The conventional spring cone crusher and the hydraulic cone crusher mainly acquire extrusion force from cranking motion to realize crushing. The motor drives the eccentric sleeve via the transmission device, the moving cone shaft generates an eccentric distance to make cranking motion under the action of the eccentric sleeve. When the moving cone moves close to the stationary cone, ores between them are crushed by extrusion. When the moving cone moves away from the stationary jaw, crushed ores are discharged from the discharge gate at the lower end between the moving cone and the stationary cone under the action of dead weight."

Jan 1, 2016

By Jose A. Caceres

Mine planning and mineral processing optimization are usually treated as two unconnected problems, especially at open pit and panel caving mines where the cut-off grade is practically the only variable optimized and analyzed for in the planning proposes. Using existing planning tool, the output is a reserve consumption strategy privileging higher grades. With the earlier consumption of the highest grades, every year produces revenues which are closer to the cost and potentially even below cost. However, there are other ore characteristics that can also affect the profitability of the operation. A new methodology has been developed, incorporating the grinding and flotation relationship into the mining economic models for the simultaneous analysis and optimization of the throughput-work index-recovery relationship through changes in the mining limits, sequence and redefinition of the reserve consumption strategy. A mine-site that implements this new planning strategy, can expect to increase the NPV from 5 to 15% depending on the actual operational settings. Two case studies have been developed, showing how the inclusion of the work index in the economic model changes the phase and mining sequence in an open pit mine and the caving sequence and the optimum column height in a panel caving mine.

May 1, 2004

By C. -G. Berg, J. T. Tuominen

Since the beginning of the 20th century, energy efficiency in copper smelting has been improved by a factor of 30 as a result of adopting autogenous smelting processes with more and more efficient waste heat recovery systems, increasing use of oxygen enrichment and countless smaller improvements. Nevertheless, energy in the form of electricity and fuels continues to be the biggest contributor to smelter operating cost. Metallurgists around the world are under constant pressure to find ways to save those precious megajoules wherever they can. One area that is often neglected is the removal of water contained in concentrates. Copper flotation concentrates, as delivered to a smelter, typically contain some 8–12% moisture. This moisture must be removed and the only way to do this is by evaporation, which consumes a lot of energy. Several studies have shown that the most efficient way of removing this moisture is to use a steam- heated indirect dryer—the least efficient way being the feeding of wet concentrate directly into a smelting furnace. Even in the most efficient smelters that employ modern steam drying, the energy needed to remove the moisture from the concentrates constitutes over 15% of the total energy consumption of a smelter – acid plant complex. The major steps that have been taken in the past to lower the energy consumption of moisture removal are the use of drying in general and the adoption of steam drying. The energy efficiency of concentrate drying has been improved by 25% over the last 20 years. The latest giant leap in this area, the Kumera Heat Recovery Dryer, is the result of Kumera’s long-term development in improving the efficiency of concentrate drying. The Heat Recovery Dryer is a novel application of steam drying that uses the waste heat from dryer exhaust gas for drying concentrates, thus, cutting the energy consumption by a further 30%. This paper discusses energy consumption in copper smelting in general and analyzes the energy consumption of concentrate drying in detail. Different dryer types are compared especially from the perspectives of energy consumption and environmental emissions. Applicability of different energy sources for drying is evaluated and discussed. The principle of the Kumera Heat Recovery Dryer is presented along with results from extensive continuous pilot plant tests. Potential applications and the feasibility of Kumera Heat Recovery Drying technology are discussed.

Jan 1, 2019

By Z. X. Cui, X. D. Ma, L. Contreras, X. Jiang

The bath smelting process is one of the key techniques applied in the current copper smelting production, which includes bottom-blown and side-blown furnaces differently from the direction of gas injection. Liquid matte and slag form the bath in the smelting furnace. To better understand the fluid dynamic of the bath and further optimise the operational efficiencies in the smelting furnace, physical simulation of the bath in the horizontal cylindrical reactor was investigated. The mixing behaviour and wave motion of the bath in the bottom-blown and side-blown furnaces have been studied systematically. The mixing time is reduced with increasing gas flowrate and height of the lower layer, while it increases significantly with increasing the height of the upper layer. The wave motion in the furnaces can be suppressed with the presence of the upper layer, but the bath with a lower density generates higher wave amplitude. Overall, in comparison to bottom-blown mixing, side-blown mixing shows better mixing efficiency and lower wave amplitude. In addition, the plume eye and splash phenomena occurred in the bottom-blown furnace have also been studied. INTRODUCTION The bath smelting process is one of the principal techniques used in the current copper making industry. The bath smelting techniques have some advantages of high smelting efficiencies, low capital costs, low energy consumptions and reduced dust generations. From the direction of gas injection, the bath smelting techniques can be classified into five general types: (1) top-submerged blown, e.g. Ausmelt and Isasmelt; (2) top-suspended blown, such as Mitsubishi smelting; (3) top direct-to-copper smelting, such as Outokumpu smelting; (4) submerged side-blown, such as Noranda and Teniente smelting; (5) bottom-blown, such as Dongying Fangyuan bottom-blown copper smelting furnace (Schlesinger et al., 2002; Zhao, Cui, & Wang, 2013; Perez-Tello et al., 2018). In many metallurgical processes involving bath smelting situations, the objectives of agitation are to accelerate the bath homogenization inside the bath which makes a significant contribution to process efficiency and product quality. Extensive mixing studies have been performed for ladle refining and tundish associated to steelmaking processes through water physical models. Mixing time is the parameter used to quantify the efficiency of mixing in the liquid bath and the first empirical equation predicting mixing time was proposed by Nakanishi, Fujii and Szekely (1975). Later on, more systematic studies have been carried out on ladle mixing and researchers realized that the geometry of the vessel could also have a significant impact on mixing (Khajaviand & Barati, 2010). However, the investigations using ladles which are vertical cylindrical vessels, cannot be directly used in the study of mixing behaviour in horizontal cylindrical reactors. Understanding the fluid dynamics inside horizontal cylindrical bath smelter is useful from the industrial perspective. Recently fluid dynamics of horizontal cylindrical smelter related to copper smelting have been studied by the authors’ group (Shui et al., 2015a, 2015b, 2018a; 2018b; Xu et al., 2018, 2019).

Jan 1, 2019

By A. Suzue, T. H. Okabe, Y. Taninouchi

Methods for the physical separation and enrichment of platinum group metals (PGMs) from autocatalyst scrap were studied in order to develop an environmentally friendly and efficient recycling process. In general, an autocatalyst has a honeycomb-structured ceramic substrate that is coated with a catalyst layer containing platinum (Pt), palladium (Pd), and rhodium (Rh). Therefore, physical separation of the PGM-containing catalyst layer directly from the ceramic substrate is favorable for upgrading the autocatalyst scrap. In this paper, the authors present a scrap-upgrade process consisting of electroless iron plating and magnetic separation techniques. Iron was plated on the surface of a catalyst sample used to represent an autocatalyst, which was then crushed and magnetically separated. The Pd in the catalyst sample was successfully extracted and concentrated in the magnetic powder. Under certain conditions, the process increased the Pd concentration by a factor of 4 and recovered 89% of the Pd in the autocatalyst sample.

Jan 1, 2014

By David Dreisinger

Arsenic occurs in nature in association with many valuable metals including copper, nickel, cobalt, gold and platinum group metals. The recovery of these valuable metals is of course complicated by the need to extract and stabilize arsenic in a form suitable for disposal. In this paper, a review of some recent developments related to hydrometallurgical treatment of arsenic bearing materials is provided. The key aspects of metal dissolution, arsenic stabilization and disposal are discussed.

Jan 1, 2014

By R. A. Parra, Fuentes, C. Godoy, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

In this paper, we report on the detection of spectral molecular emission of iron oxide (FeO) and copper oxide (CuxO) emitted by reactions occurring in a laboratory scale flash smelting process of pyrite (FeS2) as well as copper concentrate. The novelty of the technique is that, the molecular spectral emission sensing is achieved by using a low spectral resolution and low sensitive radiometer, enhanced with signal processing and matrix factorization techniques. The method was validated using a highly sensitive spectrometer, with a high spectral resolution; achieving a similar FeO spectral pattern as the one obtained after signal processing techniques over low resolution spectral signals. INTRODUCTION Visible-near infrared (VIS-NIR) spectroscopy is an optical contactless sensing technique commonly used to capture information about the emitted, absorbed, transmitted or scattered radiation in a physical or chemical process, with the presence or absence of an excitation light source such as a laser or a broad spectral band source. These techniques coupled with signal processing and machine learning algorithms, sometimes referred as chemometrics (Pisapia et al., 2018), can be found in processes such as: pharmaceutical (Kandpal et al., 2016); food (Coelho et al., 2016); combustion (Ballester & García-Armingol, 2010); siderurgy (Strakowski et al., 2014) industry, among others. In the extractive copper industry there are several technological developments using optical sensing techniques aimed to retrieve information about copper ore and concentrate mineralogical composition such as X-Ray Fluorescence, Qemscan® (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) and X Ray Diffraction (XRD) analysis, however, because of the manual procedures to analyze the samples with these laboratory instrumentation, only discrete information during a daily based operation can be retrieved, making impossible for the operators to take decisions over the involved processes in real time. The aim of our research work presented here is to contribute with sensing and data analysis procedures based on VIS-NIR spectroscopy for the flash smelting process characterization, particularly in this paper, with the detection of FeO and CuxO molecular emissions in a laboratory scale setup.

Jan 1, 2019

By E. Rosseland

Glencore Nikkelverk is operating its Chlorine Leach Process in Kristiansand, Norway, producing nickel, copper and cobalt metals by electrowinning. The copper tankhouse, with an annual capacity of 40 000 tons, is based on traditional technology with copper starting sheets and cast lead anodes. Due to the integration of this copper sulphate process in a nickel chloride refinery, operating conditions are unique. In recent years, operating costs have escalated, and health, safety and environment are top priorities. Test work on a new copper process involving permanent cathodes was therefore initiated in 2007, and a pilot plant was started up in 2012. The objective was to introduce innovative technologies and tailor these to be robust in the Nikkelverk process, to form a basis for a new sustainable copper tankhouse with a high degree of automation. Key learnings from more than 10 years of R&D work is presented, focusing on cathode materials and copper metal deposition including product quality, robotic stripping, coated titanium anodes, electrode contacts and alignment, electrode current monitoring with Hatch HELM tracker technology and acid mist capture using cell hoods with off-gas scrubbing. The new copper tankhouse project was approved in December 2018, and commissioning is planned in 2022. INTRODUCTION The Kristiansand nickel refinery was started up in 1910, processing nickel-copper matte originating from Norwegian mines. It was the first industrial plant in the world to produce nickel by electrolysis using the Hybinette electrorefining process. After roasting to burn off sulphur in the matte, copper was leached and recovered as cathodes by electrowinning with lead anodes. In the first years, the copper cathodes were fire- refined and cast into ingots for sale (Thonstad Sandvik, 2004). The Nikkelverk refinery was acquired by Falconbridge Ltd. in 1929, and since then matte from Sudbury, Canada has been the main feed source. The Hybinette process was in operation until 1975 when conversion to the newly developed Chlorine Leach Process was started (Stensholt, Zachariasen, & Lund, 1986). In this process still used today, nickel and part of the copper in the matte is leached using chlorine gas generated on dimensionally stable anodes in the nickel and cobalt electrowinning tankhouses, as illustrated in Figure 1. The presence of dissolved copper ions in the strong chloride leach solution is essential for effective chlorine absorption and nickel dissolution. To improve copper-nickel separation, slurry from the atmospheric leach is pumped to autoclaves and then to cementation tanks for precipitation of copper as copper sulphide, which is collected in filter presses. The leach residue, also containing the precious metals, goes through a 3-stage wash to remove chlorides before being introduced as a slurry to fluid-bed roasters for sulphur removal. The resulting calcine is then leached in spent electrolyte from the copper electrowinning tankhouse, to dissolve most of the copper and also some nickel, cobalt and other elements. After separation of the leach residue, elements like Bi, Te, As and Ag are removed from the strong copper sulphate solution by reaction with metallic copper in three columns in series filled with cut copper cathodes. The purified solution then passes polishing filters before being mixed with spent electrolyte and returned to the electrowinning cells.

Jan 1, 2019

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

By Wallace R. Horn

"MR. CHAIRMAN AND GENTLEMEN :I begin this talk by making a couple of comments which are of the nature of disclaimers.Firstly, and as the Chairman has otherwise indicated, I was neither ""born into"" nor have I spent more than a few years of my professional life in the mining industry. I mention this because many might, and perhaps rightly, consider that an added qualification in presenting a report of what the industry has accomplished. Indeed, I am not here to blindly defend all of its actions and inactions in respect to environmental control over the years. Nor am I here to seek absolution of the industry's past transgressions - if indeed that is the word. Mistakes might be a better one. I concluded some time ago that the effects of those mistakes are too difficult to assess against the sea of errors of our total society. I should mention too that I am not an environmental engineer or specialist - only a portion of my interest is involved with this field. Perhaps this permits a perspective which allows a more accurate and objective view.One further comment here. My job today, as I understand it, is to generally report upon the nature and extent of the response of the metals mining industry to control of the environment. In the case of an industry operating at more than a hundred locations and for various reasons at various stages of progress, it is not an easy job. On the other hand, I wanted to avoid the use of generalities because, especially within the context of environmental or ecological opinion and of the practice of condemnation of industrial segments, I think we've had about enough of generalities until we know far more than we do.Finally, I am quite aware that a statement of future plans to achieve environmental control does not impress or satisfy as many people as it may have done some years ago. Public opinion demands to know what is currently underway, today."

Jan 1, 1972

By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019

By Finley A. Campbell

"Nickel-copper sulphide deposits associated with basic rocks in the Quill Greek area and the White River area in the Yukon Territory have been studied and compared from the view-point of their general geology, structural geology, and the mineralogy of the ores. The relative amounts of the major constituents, magnesium, iron and calcium, and the minor constituents, nickel, cobalt and chromium have been determined spectrographically for two cross sections of the basic rocks at Quill Creek and one at White River. These data, along with petrologic and field evidence, were used to determine the sill and dyke-like character and nature of the basic intrusions. Loss on ignition is employed as a measure of the degree of serpentinization. The distribution determined shows that the serpentinization does not appear to have greatly influenced the inferred original distribution and lithophile associations of magnesium and nickel. The cobalt content may have been altered.The nickel content of the serpentinized peridotites ranges from an average of 0.36 per cent in one section to an average of 0.24 per cent in each of the other two sections studied. The cobalt averages 0.0038 per cent in the samples from the two Quill Creek sections and averages 0.0042 per cent at White River. These results have been compared with other available data.The sulphide ores are later than both the peridotite and gabbroic rocks and may be co-magmatic with them. There is no evidence in these areas to support an origin by lateral secretion; on the contrary, the alteration associated with the ores, the mineralogy and spatial relationship to basic and ultrabasic rocks, indicate the ores are derived from a basic magma."

Jan 1, 1960

By W. Beres, Li. J.

The finite element method (FEM) has been applied to investigate the stress fields and deformation of a TiN/Ti-6A1-4V coating/substrate system subjected to nanoindentation. MSC Patran and MSC Marc were used to prepare the three-dimensional finite element models and to perform the simulations of the Vickers nanoindentation experiments. Pure silicon and TiN/Ti-6A1-4V coating/substrate system were analyzed. The properties of the materials were assumed to be homogeneous and isotropic with a linear hardening behavior. The reverse method was used to extract material properties, such as the yield stress and strain hardening coefficient, from the numerical results by comparing the simulated indentation load vs. penetration depth (P-h) curves with those obtained experimentally. Both non-linear elastic and non-linear elastic-plastic analyses were carried out for the coating/substrate system. The results are given for four different coating thicknesses.

Jan 1, 2004

By CIM Mineral Resource, Mineral Reserve Committee

The CIM Mineral Exploration Best Practice Guidelines (the Exploration Guidelines) have been prepared to assist professional geoscientists and engineers to conduct consistently high-quality work in order to maintain public confidence. The Exploration Guidelines are meant to assist professional geoscientists and exploration practitioners in planning, supervising, and executing exploration programs. In Canada, there are generally two types of public resource reporting: “Disclosure”, as defined by NI 43-101, is the reporting of technical information to the public and market participants for securities legislation purposes where a Qualified Person (QP) must be involved, and reporting of exploration information for governmental agencies to support obligations under laws including the Mining Acts of each of the Provinces and Territories. The Exploration Guidelines are also relevant where the results will not be publicly reported but are intended for internal company use. While this document is intended as guidance for work conducted or supervised by geoscientists in Canada, many of the practices described herein can be adapted to mineral exploration activities in other countries. The Exploration Guidelines are not intended to inhibit original thinking, or to prevent the application of new approaches that may develop into fundamental components of successful mineral exploration programs. Rather than provide prescriptive solutions to specific issues, they include general guidelines for current professional practice and to demonstrate and defend the merits of new methods. These guidelines do not preclude individuals and companies from developing more detailed guidelines specific to their own requirements. The initial version of the Exploration Guidelines was prepared by the Canadian Institute of Mining and Metallurgy and Petroleum (CIM) Exploration Best Practices Committee and adopted by CIM Council on August 20, 2000. On January 9, 2018, CIM Council formed a new committee, the Mineral Resources and Reserves Committee (CIM MRMR Committee) with a mandate to, among other things, update the Exploration Best Practice Guidelines. The mandate for the committee was accepted by CIM Council on March 2, 2018. The new document was adopted by the CIM Council on November 23, 2018.

Nov 23, 2018

By B. Burger, T. Bester, S. Deonarain, L. S. Schultz

"This paper details the process followed to raise drill and equip a 6.1 metre diameter vertical service shaft at Glencore’s Mindola Deeps project in Kitwe, Copperbelt Province, Zambia. The project scope comprises a shaft collar, bulk air intake, a pre-sink to -90 metres and raise drilling the shaft from surface to a final depth of 1,892 metres underground, in four separate lifts of approximately 475 metres each. Equipping of the shaft steelwork, headframe erection and commissioning the shaft for hoisting. In addition, the scope included the development of a decline down from 5430’ level underground to the new shaft position on 6205’ level. This paper will provide some insight into the successes and challenges encountered during execution of the shaft works to date and provide some learnings for future projects of a similar nature. INTRODUCTION The Mindola Mine is situated to the west of the city of Kitwe in the Copperbelt Province of the Republic of Zambia (Figure 1). The mine is owned and operated by Mopani Copper Mines Plc (MCM), whose shareholders are Glencore AG (73.1%), First Quantum (17.9%) and ZCCM Holdings Plc (10%).Productivity at the Mindola mine has been adversely affected because of significant ventilation and ore re-handling challenges, which are caused by the dilapidated infrastructure, and design of the existing vertical and sub vertical shaft system. In the circumstances, it was apparent that it was necessary to sink a new vertical shaft that would increase the volume of fresh air down the mine, improving the underground working environment and the current hoisting restrictions, resulting in an increase in productivity and efficiency. Because there were two existing levels ideally situated and perpendicular to one another and because a third level was in close proximity to that perpendicular and because the mine required a ramp down to shaft bottom in any event, consideration was given to raise drilling the shaft as opposed to using conventional blind sinking methodologies."

Jan 1, 2019

By F. W. Crossland

Losses of metal are often traced to incorrect pH/ORP signals in flotation, leaching, extraction, electrolysis, and precipitation processes, aggravated by pressure changes. IC Controls, a Canadian mining sensor manufacturer, developed a new superior pH/ORP sensor that stops metal losses, reduces environmental footprint and contributes to sustainability. The cause of incorrect pH/ORP signal is rooted in the reference. Reference junctions are designed to allow diffusion of reference chloride ions into the process but also allow process ions to diffuse into the reference. This development is important to mines and hydrometallurgists where sulphide, cyanide, ammonia and other poisoning ions are present in the process. These ions react with reference electrolyte components causing the signal to change, drifting from the correct process value. With fluctuating process pressure, ion in migration dilutes the electrolyte producing similar signal drifts. If process ion in-diffusion could be stopped, the pH/ORP signal would be accurate. IC Controls new pH/ORP sensor stops process ion in-diffusion, and remains accurate over long periods. New processes using higher pressure and fluctuating pressurized reactors will greatly benefit from stable pH readings. Similar to IC Controls' proven model 642 Mining pH sensor, our new model 647 contributes to sustainability through reducing disposal costs from waste reagents, lost metal and fewer used sensors.

Jan 1, 2014

By C. Yanqui

"Discontinuum Mechanics is based on two foundations: the idealization of the internal structure of substances, and the principle of the arithmetic mean value. For a linear discontinuum, the methods of Crystallography are used to describe their structure, in which nodes stands for the position of the homologous points such as molecules, grains, or any other motif. The principle of the mean value states that the value of any discrete function at a node is equal to the arithmetic average of the values of this function at the neighboring nodes. This principle leads to an elliptical linear differential equation of the second order, with coefficients given by the statistical second moments of the Cartesian components of the metric vector. As long as those coefficients are components of a symmetric second-order tensor, there are three mutually perpendicular directions, in which the variances reach their extreme values and the covariances are zero, showing that the mean value principle transforms the discontinuum into a statistically equivalent orthotropic continuum.The application of Discontinuum Mechanics to linear rock masses is simple and direct. It is sufficient to define the motif as the plane of geological discontinuity, and the metric vector as the normal vector to this plane, whose magnitude is the spacing between two consecutive planes belonging to the same set of discontinuities. Furthermore, heterogeneities of rock masses can be also included in this description by substituting the plane of discontinuity by a zone of weakness. In this way, the magnitude of the normal vector results from the product of the spacing and the RQD or the RMR. In going further in this theory, at least three conclusions show up. First, in the evaluation of rock masses, it is necessary to determine the orientation, spacing, and RMR for each set of discontinuities. Second, the conventional method of finding the principal families from the contours of equal concentration of poles on the stereographic projection excluding the spacing does not have any physical meaning. Third, any problem of rock mechanics can be solved in a rigorous and reliable way by integrating the differential equation of the mean value."

Jan 1, 2015

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By W. L. Falconer

"IntroductionThe very recent emphasis on the importance of the northern portions of the Alberta basin as a prospective oil province has led the oil companies northward into new and undeveloped territory. Northern Alberta is a land of continuous forest, covering a plains-type topography. The plains are only occasionally broken by sharp, broad river valleys. Tributary streams head up quickly and very soon lose themselves in large undrained areas. It is these pseudo-swamps that cause most of the troubles and headaches of the oil explorer.The rivers have served as the main transportation arteries since people first ventured into this area. The bush is being pushed back, but the advance is slow and there is very little more than trappers' trails beyond a few miles from the Northern Alberta Railway lines and the recently built Grimshaw or McKenzie Highway. Indeed, bush and muskeg flank many miles of the railways and roads within as close a distance as fifty miles of Edmonton. Northern Alberta is pioneer country in the truest sense of the word, and our greatest problems derive from this fact. In all pioneer areas, the first requirement is the development of access roads, and before active oil exploraton can get down to the job at hand these roads and trails must be an accomplished fact. There are two factors in Northern Alberta which offer discouragement to the oil explorer: the first and greatest stumbling block is presented by the numerous muskegs, large and small; the second is the fact that road building uses up so much of reservation time. Of course, the second is aggravated by, and a direct result of, the first. So we come back to the main problem facing the development of the north - the muskegs."

Jan 1, 1950

By G. Vibert Douglas

"Gold occurs in Nova Scotia in three ways, saddle reefs, fissure veins, and fossil placers. Of these the saddle reefs are the commonest. They have been the source of most of the gold and have also been the subject of most of the literature on the gold occurrences.The Meguma or Gold-bearing series of Nova Scotia is a conformable succession of quartzite's and slates, possibly Precambrian in age, which have been folded into a number of anticlines and synclines that strike (Fig. 1) roughly east and west. This folding has been termed Acadian and is probably a westward continuation of the Caledonian revolution in Britain. It may have started in the Ordovician and continued through the Silurian and into the Lower Devonian. It was followed by the intrusion of the great Devonian granite batholiths. It is thought that the mineralization is connected with the late phases of the cooling of the granite. As the name saddle reef implies, the veins form on the crests and flanks of the anticlines, possibly in the synclinal troughs as well. The beds favoured by the solutions are the slates. The reason for this is apparent when it is realized that in order to fold over 30,000 feet of sediments (the thickness of the Meguma according to E. R. Faribault) through p radians of arc it is necessary to have a differential movement between the top and bottom beds of p times the thickness of the sediments. In the case of the Gold-bearing series, in which strong quartzite beds lie between incompetent slate beds, most of this differential movement was taken up in the slates. The evidence for this is the remarkably fine drag folding and the intense shearing and comminution of some of the beds of slate (Fig. 1). The quartzites exhibit some shearing and faulting, but there is little doubt that the greater permeability lay along the incompetent slate beds. The mineralizing solutions followed these beds and also passed from one slate bed to another through a joint or fault in the intervening bed of quartzite. These joining veins are called angulars in Nova Scotia. Within the veins the gold is in shoots and the real problem is to find out what controls the position and extent of the shoots."

Jan 1, 1954