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By Neillm Alastair S.

"This paper looks at what has happened in the past decade in the rare earth industry, particularly for those companies outside China trying to develop alternative projects to the Chinese dominated supply chain. The rare earth industry has gone through a metamorphosis over the past decade. The industry was basically unknown outside China until overnight it became the next hot topic on the financial streets of Canada and Australia. Suddenly various junior miners shifted from uranium and other out-of-favor commodities to rare earths as funds were easy to access from an investment community that did not understand the complexities of the space. The initial funding was done on traditional junior mining metrics of grade and deposit size. This has morphed over time to:1) Lights versus heavies2) Making a concentrate3) The importance of separation4) Off-take agreementsAt the peak of the market frenzy certain flagship operations were built using the “Not Made in China” moniker. Unfortunately certain errors were made during implementation, which are finally coming to the surface and making the rest of the pack wondering what will happen next. A review and update of some of the mistakes made and lessons learned will be discussed.BACKGROUNDAbout ten years ago awareness started to form around the rare earth industry and various groups recognized that because of the closure of Molycorp, Mountain Pass, and the dominance of China, there was a risk of uncertainty of reliable supply. This was not news for those active in the industry like Rhodia (now Solvay), the Japanese, South Koreans and other key consumers but to others it was like a light went on and rare earths became the new “.com” trend for investment banks, investors and some mining companies looking for the next hot topic.In the late 1990’s Molycorp accounted for around 20-25% of the world’s supply of rare earths, mostly lights (La, Ce, Pr and Nd), with small amounts of heavies from other sources. Then environmental issues forced the closure of the operation at Mountain Pass. Within six months China had increased production to plug the gap in supply. Around that time China was developing a strategy to leverage their position in rare earths and implemented a series of regulations to increase the value added component of rare earths inside China."

Jan 1, 2016

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By Gary M. Bone

The autonomous control of vehicles interacting forcibly with their environment, such as dozers and tractors, is an unsolved and challenging problem. Forces and motions are inherently coupled between the tool and the means of vehicle propulsion. Furthermore, they are often operated within uncertain and unstructured environments, such as those encountered in underground mining. There is a growing industrial interest in the development of robotic vehicles to improve productivity, efficiency and safety in mining and construction. This paper focuses on the modeling and control of autonomous robotic dozing for a material removal operation. A dozing process model has been developed based on observations of both a fullscale dozer and a scaled-down version. The model characterizes the dynamic interactions between the blade position, material accumulation on the blade, material distribution in the environment, and the motions of the dozer. The dozing control objective is to remove the loose material as rapidly as possible by driving forwards at full power while automatically raising/lowering the blade in response to sensor measurements. Two different controllers were developed to meet this objective. The first controller is based on a set of heuristic rules, and the second is an optimal controller based on the dynamic model. An instrumented scaled-down robotic dozer and dozing environment, designed to emulate the full-scale operation, are used to implement the controllers and compare their performances over multiple dozing passes. Experimental results are presented showing that the model-based controller increased the material removal rate by 33% compared to the rule-based controller. Lastly, technologies for full-scale implementation are discussed, followed by proposed future work and conclusions.

Aug 1, 2013

By E. V. Konopleva, H. J. McQueen

"The isothermal bainite transformation kinetics of low- and medium-carbon alloy steels after hot deformation and the rmocycling treatment (TC) has been studied by the magneto - metric method. Deformation was produced by rolling at 800°C-1000°C. TC included three cycles of rapid (30°C/s) electro-heating up to 900°C-1000°C followed by quenching.Hot deformation retards bainite transformation in the lower part of bainite range (<400°C) and accelerates it in the upper part (>400°C). The effect is greater for higher strain and lower deformation temperature. Deformation also diminishes the overall bainite fraction below 400°C and increases the completeness of reaction above 400°C.Thermocycling provides more uniform ultrafine austenite grains with average size of 3 µm -4 µm compared to 12 µm -14 µm after conventional heating. The transformation rate after TC was almost the same as after conventional heating in low-carbon steel but was faster in medium-carbon with no change in the completeness of reaction. The degree of acceleration increased with rise of transformation temperature.There are a number of factors which are responsible for a change in bainite transformation kinetics in austenite deformed at high temperatures or subjected to TC. One of the most important factors is the refinement of structure, another one is structural and chemical inhomogenity of austenite due to deformation or to rapid heating. To estimate the contribution of these factors, ?-transformation was studied after different austenitizing conditions (low-temperature heating at 850°C- 950°C; high-temperature heating at 1100°C; step treatment – austenitizing at 1100°C, then cooling to 950°C-850°C). The results obtained make it possible to conclude that the structural and chemical inhomogeneity of austenite activate the bainite reaction while the grain refinement retards it. Intensity of the effect produced by each factor depends strongly on the steel composition."

Jan 1, 1997

By W. J. Farley

"The Sherritt Gordon mine is 100 miles north of The Pas in northern Manitoba. Copper-zinc ore was discovered on the property in 1922. Production began in 1931 and continued to June, 1932, when operations were suspended because of the low price of copper. Operations were resumed on August 1st, 1937, and have been carried on continuously from that time to the present (March 1947). The production of metals up to the end of 1945 was copper, 287,129,880 lb.; zinc concentrate (50 per cent) 104,419 tons ; gold, 79,388 oz.; silver, 2,529,974 oz.GENERALThe ore occurs in two deposits, the east and the west. Both are enclosed in gneisses that are highly metamorphosed sedimentary and volcanic derivatives. The rock beneath the deposits, and hence forming their footwall, is gneissoid quartzite; the hanging-wall rock is basic garnetiferous hornblende gneiss. Pegmatite commonly occurs along both foot- and hangingwall peripheries and as isolated blocks and fragments within the ore zone . These blocks and fragments are considered to be residuals of unreplaced host rock .The ore is relatively coarse grained and ranges from the massive to the disseminated type. The metallic sulphides composing these, named in the order of their abundance, are pyrite and pyrrhotite ( 2-1 ratio) , chalcopyrite, sphalerite (marmatite) , and minor chalmeriite; subordinate amounts of gold and silver are recovered . The insoluble content of the ore averages about 35 per cent.Another deposit known as the Bob Lake, much smaller and lower in grade but having very similar relationships, occurs about 3 ½ miles to the northeast of the main Sherritt Gordon ore masses.STRUCTUREThe Sherritt Gordon orebodies are of the replacement type, and lie within a pegmatite sill that has been intruded along a contact between quartzite and hornblende gneiss. The two main orebodies are intimately related, for the east deposit is an erosional remnant of the lower, easterly limit of an orebody once continuous with the west body. The ore lies along the southwest limb of an overturned syncline."

Jan 1, 1954

Accurately modeling and predicting long term mill throughput is one of the challenges facing metallurgists, geologists and mine engineers in their quest to consistently deliver accurate life of mine business plans. Batu Hijau has systematically improved long and short term mill throughput predictions since feasibility and commissioning in 1999. This has been achieved through a combination of ongoing improvement to the geology ore hardness and grade characterisation model, drill and blast optimisation and, by application of these data to model mill throughput. Batu Hijau has demonstrated the ability to consistently estimate long term mill throughput within ±2% accuracy. Aside from reliably predicting expected production rates with the existing plant configuration, this predictive ability provides a solid foundation for identifying operating and design criteria for short term grinding circuit optimisation and future expansions. This paper discusses ongoing throughput prediction model development at Batu Hijau based on geo-metallurgical characterisation. Also discussed are tools used for day to day production performance management. This includes on line "Mine to Mill" variable monitoring to improve operations parameter ecision making and performance assessment.

Nov 1, 2011

By F. Wirfiyata

"Accurately modeling and predicting long term mill throughput is one of the challenges facing metallurgists, geologists and mine engineers in their quest to consistently deliver accurate life of mine business plans.Batu Hijau has systematically improved long and short term mill throughput predictions since feasibility and commissioning in 1999. This has been achieved through a combination of ongoing improvement to the geology ore hardness and grade characterisation model, drill and blast optimisation and, by application of these data to model mill throughput.Batu Hijau has demonstrated the ability to consistently estimate long term mill throughput within ±2% accuracy. Aside from reliably predicting expected production rates with the existing plant configuration, this predictive ability provides a solid foundation for identifying operating and design criteria for short term grinding circuit optimisation and future expansions.This paper discusses ongoing throughput prediction model development at Batu Hijau based on geo-metallurgical characterisation. Also discussed are tools used for day to day production performance management. This includes on line ""Mine to Mill"" variable monitoring to improve operations parameter decision making and performance assessment."

Jan 1, 2012

By L W. Morley

The Division is concerned with physical methods as applied to geo-logical research and mapping. An at-tempt is made to describe long-term goals, illustrated by examples of projects in the fields of aeromagnetic interpretation, palaeomagnetic re-search, Pleistocene and groundwater geophysics, seismic surveying, electromagnetic research and instrument development. Cooperative projects in surveys and research, with universities, private companies and provincial organizations, are frequently undertaken. An outstanding example of this is the recently approved Federal-Provincial Aeromagnetic Survey Plan, the purpose of which is discussed both from an economic and a scientific point of view. HISTORY OF THE DIVISION M AGNETIC, electrical, seismic and gravity methods, as a means of extending the geologist&apos;s sphere of observation beyond the head of his hammer, came into wide-spread use for the first time after World ?war I. Interest in these methods was aroused amongst geologists of the Geological Survey and, in 1928, a group of these geologists and university

Jan 1, 1963

By Étienne Yvenou, Martin Désilets

Le procédé d’électroaffinage du Cu est nécessaire pour atteindre les niveaux de pureté requis pour les applications les plus courantes telles que son utilisation comme conducteur électrique ou thermique.

May 2, 2024

By J. C. Moreno, G. Rios, M. Palacios

The Huelva smelter was commissioned in 1970 coinciding with the shutdown of the old smelter in the Rio Tinto mine site. That new smelter consisted of two Momoda blast furnaces with a capacity of 500 dmtpd of concentrate. Nevertheless, soon after their start-up, it was clear that an increase in the smelting capacity was needed. After an analysis of the existing alternatives at that time, the flash smelting technology was chosen. The new Outokumpu Flash Smelting Furnace (FSF) came into operation on 18 September1975, with an initial capacity of 900 dmtpd of concentrate, using four Venturi-type burners and preheated atmospheric air. Since that date the Huelva Smelter team, together with Outokumpu (now called Outotec), have continuously improved our FSF design, process conditions and operational practices, leading to a present capacity of 3,500 dmtpd of concentrate. Since 1975, five smelting campaigns have been completed, the last ending in November 2013 with the rebuilding of the original FSF hearth. This paper describes the history of these improvements and the lessons learned.

Jan 1, 2014

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016

By Richard W. Hutchinson, Robert W. Hodder

"Pyritic massive sulphide deposits lie conformably above submarine volcanic rocks, and beneath siliceous and manganiferous iron formations. The massive bodies are often zoned, with a barren pyritic top grading downward into pyrite with sphalerite, and occasionally galena, and a chalcopyrite-rich base. They are frequently brecciated, like the lavas beneath them, which contain pyrite and chalcopyrite as coatings on joints and fractures and as dispersed grains. The lavas also exhibit propylitic, argillic and silicic alteration. These sulphide deposits appear to have formed on sea bottom from fluids escaping through the lavas during periods of exhalative and sometimes explosive volcanism. The process may be comparable to the present deposition of base metals from hot brines in the Red Sea. Some porphyry copper deposits resemble the altered, sulphide-impregnated lavas which lie beneath bodies of pyritic massive sulphide. In porphyry copper deposits, pyrite and chalcopyrite occur as veinlets and dispersed grains in intensely fractured tuffs, flows, sub-volcanic intrusions or other host rocks, characterized by propylitic, argillic and silicic alteration. Metal zoning is present; sphalerite and galena often occur in manganiferous veins peripheral to a shell of pyritic veinlets which encloses the mineable zone of chalcopyrite-bearing veinlets. This sulphide distribution appears to have formed from hydrothermal fluids escaping, either passively or violently, from solidifying magma. The fluids may be comparable to hot brines encountered by drilling in the Salton Sea area of California.There are also important differences between massive sulphide and porphyry copper deposits. The former usually occur in differentiated, mafic-to-felsic subaqueous volcanic rocks, whereas porphyry copper deposits are often associated with shallow plutons and subaerial volcanic rocks of intermediate to felsic composition. Calcic-sodic metasomatism accompanies the massive sulphides, whereas potassic metasomatism characterizes the porphyry cop.per deposits. Further, ages of massive sulphides range from Archean (Keewatin) to Tertiary, but porphyry coppers are Triassic to Tertiary in age. These similarities and differences suggest that massive sulphide and porphyry copper deposits are related tectonically and metallogenetically. The former were generated during early stages of crustal evolution, particularly in Archean time, and were repeatedly derived during early stages of younger, individual tectonic cycles. In contrast, the porphyry coppers developed during the later stages of crustal evolution - later in terms of both absolute age and relative age within younger individual tectonic cycles. They appear in younger rocks generally, and specifically in rocks involved in events of the middle and late tectonic stages of orogenic belts. The massive sulphide deposits are of early-magmatic eugeosynclinal affiliation, whereas the porphyry deposits formed in late-magmatic, predominantly subvolcanic settings at the edge of continental plates, where contemporaneous exhalative volcanism was mainly a subaerial phenomenon. Transitional types of deposits exist and are found on continental margins with flanking eugeosynclinal sequences."

Jan 1, 1972

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981

By P. K. Kaiser, D. D. Tannant

"A support system for large ground convergence conditions or burst-prone ground must contain holding elements (rockbolts, cable bolts, etc.) that are strong yet capable of sustaining large deformations, i.e., they must absorb as much energy as possible. Steel wire rope anchored in a borehole by a friction bolt provides these desired yield characteristics if the frictional anchorage is placed deep enough into the rockmass, i.e., in non-yielding rock or beyond the expected depth of rock ejected during a rockburst. Pull-out tests were conducted on wire ropes anchored by inflated Swellex bolts to assess the feasibility of this support concept. The test results demonstrate that a Swellex bolt generates a frictional anchorage that allows the wire rope to slide at high loads and to absorb significantly more energy than either a Swellex bolt alone, or a cement-grouted cable.The rope/friction bolt combination can be engineered to provide the desired energy absorption and allowable deformation by varying the installed lengths of the friction bolt and the rope. For yielding rope support, the contact length between the rope and Swellex bolt must be short enough to ensure that the rope can slip well before its tensile capacity is reached. A safe maximum overlap length is about one metre for the wire rope used in this testing. When used as support in the backs of drifts, a swaged button on the ropes end must be used to ultimately mobilize the full rope capacity thereby protecting against gravity-driven falls of ground."

Jan 1, 1995

By C. F. Harris

Following the initial development of the zinc-lead blast furnace, efforts have been directed both at increasing the scope of the process and increasing the cash return. The paper reviews the process developments which enable the process to smelt efficiently a range of material which encompasses high-grade zinc sulphide concentrates. mixed concentrates, Waelz oxide, zinc ashes and other materials blended to give a furnace feed ranging from 25 to 65% zinc and from 1 to 25% lead, with a copper-lead ratio exceeding 1 to 8. The paper also reviews the process developments which have enabled the capacity of a furnace and condenser system of standard size to be boosted from 30,000 to 80,000 tonnes/annum. The benefits achieved are used as a justification for continuation of the development of the zinc-lead blast furnace. Predictions are made of the benefits expected from further developments.

Jan 1, 1979

By C. Chapman, P. Cowx

"INTRODUCTIONTetronics Research and Development Co. Limited has installed several plasma torches for steel heating in continuous caster tundishes. An extensive demonstration program on a 14 tonne tundish reported the following advantages of plasma heating.• close control of steel temperature to ± 5°C;• a reduction of the furnace tapping temperature of up to 20ºC, leading to savings in energy and refractories costs ;• improvement in steel quality, to produce a slab product with an equi-axed crystal structure and a reduced number of large sub-surface slag inclusions;• the virtual elimination of oxygen pickup in the tundish; and• the capability of making ferroalloy trim additions to the tundish to permit a change of steel grade during casting, greatly decreasing inventory costs.The Need for Tundish HeatingIn the continuous casting of steel, the function of the tundish is to transfer the molten metal between the ladle to one or more continuously fed casting moulds. Figure I shows a typical temperature profile of molten steel in the tundish over the first cast cycle. It is observed that a rapid drop in temperature occurs both at the start of the cast, due to the tundish refractories absorbing heat, and also during ladle changeover. In addition, as a result of thermal losses through the ladle sidewalls, there is a gradual decline in the bulk steel temperature over the entire heat cycle. Consequently, in normal tundish operation, it is necessary to cast with a high superheat (25°C to 30°C + above steel liquidus temperature) in order to prevent freeze-up of the strand. Problems of high temperature variation and the potential of the steel solidifying in the tundish are greater for small caster units of low thermal mass . A high steel superheat increases the steelmaking vessel process time and refractory wear and prevents the formation of a uniform equi-axed solidification structure in the cast steel, resulting in centre line segregation and porosity. The large drop in the casting temperature that occurs during unsteady state operation causes an increase in the number of sub-surface inclusions, reducing the value of the product. Accordingly, plasma heating may be employed to maintain the molten steel at an optimum temperature to produce a slab of consistent quality."

Jan 1, 1989

By G. Dodbiba, A. Otsuki, T. Fujita, J. Ponou, A. Shibayama

"The different types of nano to submicron particles, which are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The information is very useful for mineral processing treatment. The IFA can measure the particle size distribution in low to high concentration of particles in liquids and non-light transparent liquids. Here, mainly the emulsion and bubble size measurements are described.Emulsion (w/o type) is prepared with oil and water mixture. The nano to micro emulsion particle size is usually measured by light scattering method. The particle size distribution of emulsion of light oil measured by IFA agreed well with the one by the dynamic light scattering (DLS) method. The water size distribution in emulsions of gasoline is difficult for the small reflection index and C heavy oil is difficult for the black color by DLS method. The IFA can measure both emulsions.There are many methods to measure fine air bubbles, however, the finer nano size measurement apparatuses are DLS method and IFA. A “ghost” peak appeared in the large particle micron meter size in DLS method. The mean diameter in IFA is similar with DLS for the nano meter size. INTRODUCTIONParticle size distribution measurement of nano to submicron particle, emulsion and bubble size distribution are very useful for ultrafine particle separation and characterization of fine particles by the necessity of recent fine minerals separation (For example, Li et al.2016, Mikhlin et al.2016, Wang et al.2013). As for the size measurement of solid particles in liquids, three different types of nano to submicron particles, that are well-dispersed nano particles, coagulated nano particles or settled submicron particles, have been measured by the interactive force apparatus (IFA). The particle size distributions are compared with the one of dried particles measured by TEM or SEM. The well-dispersed nano particle size distribution by IFA is influenced by the nano size surfactant micelles and becomes smaller, when compared with the TEM result. The size distribution of nano size of magnetite particles in water is influenced by the isoelectric point and the mean diameter of coagulation becomes larger. The particle coagulation in diluted suspension is about 2nm smaller when compared with the higher concentration. The submicron nickel particle size distribution is well agreed the result by SEM. The coagulation effect is small in the submicron size of nickel powder in water (Fujita et al., 2013). In this paper, the emulsion and bubble size measurements are mainly described."

Jan 1, 2016

By J. Smit, F. Parada, R. Parra, E. Balladares, M. P. Merino

"In this study, a two-step process was developed for recovering copper, molybdenum, zinc and iron (hematite). In the first step, grinded slags (-65 mesh) were sulphated with SO3 at 350-500ºC to form iron, copper and zinc sulphates. In the next step, the formed sulphates were decomposed to hematite, copper and zinc sulphates and oxysulphates at 700-750ºC. The generated SO3 was recirculated back to the sulphation step. The generated calcine in the decomposition step is leached with 25 gpl acid at 50ºC to dissolve the copper, zinc and molybdenum for further conventional separation and recovery. The hematite residue, of intense red color, can be used as pigment, in the ceramic industry or as pellet feed. The fine crystalline silica remains in the hematite residue."

Jan 1, 2014