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By T. MacKinnon, M. C. Bétournay, D. Eastick, F. C. Delabbio, C. Graves

"The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation.This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory, and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project."

Jan 1, 2005

By Y. Faitakis

In the mining industry, maintenance is a key priority and a major expense. As mining equipment is large in scale, high in cost, and difficult to tow, it is key to maintain equipment on a timely basis. Breakdown in -40°C or away from a maintenance station can cause great costs in repair as well as lost production. It has often been quoted that about 5% of the North American production is lost every year due to unscheduled downtime. About one-third of the downtime is attributable to equipment failures. From this fact alone, it is evident that proper equipment maintenance can add tremendous value to the bottom line. As organizations and equipment become more sophisticated, maintenance expectations begin to evolve. This evolution can be traced through three generations: The first generation (1940?1950): A ?fix it when it broke? attitude prevailed during that time, mostly because the industry was not highly automated. The second generation (1950?1980): Automation and mechanization of the industry increased. The industry now was dependent on machines performing the majority of the work. Preventive maintenance (overhauls at fixed intervals) appeared as the first maintenance practice. Maintenance costs started to rise rapidly. The third generation (1980?): Assets become more complex. Failure modes are better understood and computerized maintenance methods are becoming mainstream. Condition-based maintenance (CBM) starts to gain ground as a cost-effective alternative, replacing the fixed interval overhauls. As corporations amalgamate and market places are becoming more complex, multi-functional teams become responsible for maintenance. At the beginning of the third generation, maintenance organizations began embracing technology to provide efficiencies in maintenance management. A strong push was made to transition from reactive maintenance to proactive maintenance. At the forefront of this push is condition-based maintenance.

Jan 1, 2004

By Y. Faitakis, G. J. Powley, C. Mackenzie

"In the mining industry, maintenance is a key priority and a major expense. As mining equipment is large in scale, high in cost, and difficult to tow, it is key to maintain equipment on a timely basis. Breakdown in -40°C or away from a maintenance station can cause great costs in repair as well as lost production.It has often been quoted that about 5% of the North American production is lost every year due to unscheduled downtime. About onethird of the downtime is attributable to equipment failures. From this fact alone, it is evident that proper equipment maintenance can add tremendous value to the bottom line. As organizations and equipment become more sophisticated, maintenance expectations begin to evolve. This evolution can be traced through three generations:The first generation (1940–1950): A “fix it when it broke” attitude prevailed during that time, mostly because the industry was not highly automated.The second generation (1950–1980): Automation and mechanization of the industry increased. The industry now was dependent on machines performing the majority of the work. Preventive maintenance (overhauls at fixed intervals) appeared as the first maintenance practice. Maintenance costs started to rise rapidly.The third generation (1980–): Assets become more complex. Failure modes are better understood and computerized maintenance methods are becoming mainstream. Condition-based maintenance (CBM) starts to gain ground as a cost-effective alternative, replacing the fixed interval overhauls. As corporations amalgamate and market places are becoming more complex multi-functional teams become responsible for maintenance.At the beginning of the third generation, maintenance organizations began embracing technology to provide efficiencies in maintenance management. A strong push was made to transition from reactive maintenance to proactive maintenance. At the forefront of this push is condition-based maintenance."

Jan 1, 2004

This paper describes the back analysis of the Pavoncelli tunnel, an hydraulic tunnel which was excavated between 1904 and 1915 in South of Italy and experienced severe damages during the 1980 Irpino-Lucano earthquake. A numerical simulation which is intended to study the behaviour of the tunnel during this seismic event is presented, also accounting for the swelling phenomenon that took place during and after construction.

May 1, 2009

By Antônio Peres, Rogério Guimaraes, Lauro Takata, Harold Wyslouzil

"Serrana’s concentrator, in Araxii, has capacity of producing approximately 800,000 tomes of phosphate rock per year, with a P205 grade of 36%, from ores grading between 13% and 14% P205. The annual mining rate is around 3.5 Mt and the apatite is concentrated according to the following sequence: crushing, grinding, desliming, flotation and low and high intensity magnetic separations.Two industrial flotation columns (3.0 m x 4.5 m x 14.5 m) were commissioned in 1993 as a replacement for circuits of barite and apatite fines flotation. In 1994, four additional flotation columns of the same dimensions were put into operation, replacing 42 Wemco mechanical cells (300 ft3 each), in the barite pre-flotation, coarse apatite (two columns) and tailings regrind flotation Circuits. Overall, 66 mechanical cells (300 ft3 each) were replaced by only six flotation columns, designed by Cominco Engineering Services Ltd - CESL.The present paper describes the stages of process development, pilot plant testwork and implementation of the industrial project, highlighting the most relevant aspects of each of them. The results achieved are related to improvements in flotation selectivity, gains in P205 recovery and better process control, resulting in better quality products and lower production costs. Other benefits included a decrease in flotation reagents, electrical energy and maintenance materials consumption. These factors contributed to a significant decrease in the cost of phosphate rock production at Serrana, in Araxa - M G."

Jan 1, 1999

By V. N. Rampton, C. F. Gleeson

"Exploration results over three overburden drilling anomalies defined by the Ontario Geological Survey in 1981 in the Kirkland Lake area, Ontario are presented. The anomalies come from lowland areas where overburden is thickest. By mapping the bedrock and surficial geology, by prospecting, humus sampling and shallow till sampling over the surrounding upland surfaces, one can initially evaluate such overburden drill anomalies without costly reverse circulation drilling. The drilling should follow, if necessary, only after surficial base data has been obtained. Preliminary work on these three properties has defined the presence of at least two styles of gold mineralization. One occurs in silicified zones in intermediate volcanics closely associated with northwesterly trending faults and shear zones. The second occurs in quartz-carbonate alternation zones in volcanics intruded by quartz-feldspar porphyry dykes. IntroductionThe three examples presented in this paper present first-hand information on an approach to the follow up of several geochemical anomalies that were found by the Ontario Geological Survey when they carried out reverse circulation overburden drilling as part of the Kirkland Lake Initiative Program (KLIP) in 1980 (Routledge et al., 1981). The initial approach is relatively simple, systematic, and cost and technically effective. It readies the properties for further exploration, or conversely, it could downgrade the properties as viable gold targets."

Jan 1, 1987

By M. Maleki-Moghaddam

At the concentration plant of the Gol-E-Gohar Iron Ore Company (Iran) three 9 m × 2.05 m AG mills (fixed speed) are used in parallel in a dry operation. The performance of AG mills has been lower than the target value indicated by an increase in the product size (P80) from 450 µm (target) to 515 µm and low power draw (50% of nominal). By simulation it was found that increasing the liner lifter face angle from 7 to 30o while keeping the original lifter height (i.e., 22.5 cm) could provide an appropriate charge trajectory. When the proposed liners installed in one of the AG mills, the throughput increased by 27%; when 5% (v/v) balls were added the throughput increased by 40%. The product size also decreased from 515 to 501 µm.

Jan 1, 2012

By T. Hadley, E. Catovic

"Northern Minerals Limited’s (ASX: NTU) flagship project is the Browns Range Rare Earth Project (the Project) located in Western Australia, consisting of a number of deposits with high value, heavy rare earth elements, in particular yttrium, terbium, and dysprosium. The deposits are dominated by xenotime mineralisation, which occurs within hydrothermal silicified and hematitic breccias. The Company delivered an initial JORC compliant resource estimate for the Project at the end of 2012 of 10,500 t of contained total rare earth oxides (TREO), which was increased to 28,084t of contained TREO in October 2013 and further enlarged to 47,997 t of contained TREO in February 2014. Concurrent with the growth of the Project resource base, significant progress has been made in developing the metallurgical process for the beneficiation and extraction of rare earth elements (REE’s) from the xenotime mineralisation. Development of the beneficiation circuit evaluated several process options and selected whole-ore flotation and magnetic separation, followed by flotation (hybrid circuit) as the two preferred flowsheets to pilot, following encouraging results on the bench of 83% and 86% recovery to a 20% TREO mineral concentrate respectively. Several downstream hydrometallurgical extraction flowsheets were evaluated. However, the following two preferred process flowsheets were ultimately selected for further detailed investigation during the prefeasibility study: 1. Sulphation bake, water leach, purification, oxalate precipitation, and/or calcination to produce a mixed RE oxide; 2. Sulphation bake, water leach, phosphate precipitation, caustic conversion, HCl leach, and oxalate precipitation to produce a mixed RE oxalate. Excellent heavy rare earth oxide (HREO) extractions (~ 90%) from beneficiation concentrates were achieved on the bench for both circuits, however flowsheet 1 was ultimately selected as the preferred flowsheet to pilot due to lower capital and operating cost. A mixed rare earth oxalate (42% TREO) or oxide (92% TREO) can be produced with low levels of Th and U of 3 ppm and 6 ppm respectively."

Jan 1, 2014

By D. Komljenovic

This paper presents the use of queuing theory in truck fleet sizing in open pit mining operations. In the first part, a methodology is developed by which an optimal ratio between the size of shovels and trucks may be determined. The second part gives the fundamentals of the queuing theory and its application in analyzing shovel and trucks. The stochastic character of involved times (loading, truck cycle, etc.) is taken into consideration. Using the above theory, the optimal truck fleet size in actual conditions may be estimated. Minimal operating cost of the working system (shovels-trucks) represents the basic requirement of the analyzed process. The methodology was validated on Caterpillar front-shovel ? truck combinations.

Sep 1, 2004

By Steve Wilson, Bern Klein, Jeff Drozdiak, Stefan Nadolski, Andrew Bamber

"In the adaptation of high pressure grinding rolls (HPGRs) to hard-rock mining applications, circuit development has mainly focused on placing HPGRs in the role of tertiary crusher in the preparation of ball mill feed. In order to take advantage of the potential energy benefits associated with HPGR and stirred mill grinding technologies, work was done to investigate the potential of and resultant energy benefits of placing the HPGR in series with a high speed stirred mill in replacement of the conventional cone crusher / ball mill arrangement. The proposed circuit was designed to operate with two stages of HPGR grinding followed by high speed stirred milling.Using a pilot-scale HPGR unit inline with a 20 liter stirred mill, the design criteria, circuit arrangement and consequent comminution energy requirements for a circuit processing copper sulphide ore from Teck Resources’s Mesaba Copper project were determined. These results were then compared to two other circuits, an HPGR / ball mill circuit and a conventional crusher / ball mill circuit processing the same ore.The testwork indicated at a proof-of-concept level that the HPGR / stirred mill circuit could potentially be appropriate for this duty and further work on the concept is merited. While the results indicate that the HPGR component of the circuit was more energy efficient than conventional cone crushing, the energy efficiency of the stirred mill was found to be lower than that of a comparable ball mill undertaking the same duty. However, increased energy efficiency of the stirred mill portion of the circuit is possible with further optimization and further work on the concept is indicated."

Jan 1, 2010

By V. J. Sopuck, O. P. Lavin, Ian Nichol

"A major challenge of contemporary exploration geochemistry is the development of procedures that can locate blind mineralization or mineralization that sub-crops below a cover of transported overburden, the composition of which bears no relation to the underlying mineralization. Over the past few years, the possible existence of diagnostic geochemical features in the country rock associated with volcanogenic massive sulphide deposits has attracted increasing attention both on the local mine scale and on the regional scale. In the present investigation, the nature of the geochemistry of a number of Archean greenstone belts of the Canadian Shield is examined to determine the feasibility of distinguishing productive from non-productive areas of copper-zinc mineralization. The results indicate that productive areas are distinguishable from non-productive areas providing consideration is given to the effects of igneous differentiation on rock compositionIntroductionArchean massive sulphide deposits are an important source of copper and zinc, and to a lesser extent silver and gold, particularly in Canada. As in the case of most other forms of mineralization, there is a continual need to develop new techniques that will improve the chances of success in the search for these deposits. The majority of Archean areas in the northern latitudes are overlain by a variable cover of glacial overburden. Considerable progress has been made in the development of new geochemical exploration techniques for use in glaciated terrain, based on the detection of anomalous dispersion in the glacial overburden. In certain situations, however, as in the search for blind deposits or in areas covered by glaciolacustrine deposits, overburden geochemistry offers little hope for success. In the case of massive sulphide deposits, one possible solution may lie in the detection of anomalous geochemical signatures in the bedrock. Recognizing this possibility, attention has been directed to the investigation of the nature of lithogeochemical dispersion associated with massive sulphide deposits on both regional and local scales, to establish the potential of lithogeochemistry as an aid in the search for these deposits."

Jan 1, 1980

By Roger Payne, John R. Goode, Feng Gao, James Brown

The Eco Ridge deposit is located in the Elliot Lake mining camp in Northern Ontario, Canada. Between 1955 and 1996, the area produced more than 138,000 t (300 million pounds) of U3O8 and very significant amounts of thorium and heavy rare earths. Based on the NI 43-101 Preliminary Economic Assessment by Roscoe Postle Associates (RPA) dated June 2012, and the economic review by RPA as announced in Pele Mountains’ Press release dated September 12, 2013, the Eco Ridge Mine Project would extract and process 46 Mt of material to produce about 19,000 t (42 million pounds) of U3O8 and about 65,000 t of rare earth oxide (REO) over a 14-year life. This paper discusses process optimization studies including beneficiation and hydrometallurgical testwork. The proposed modified flowsheet includes the flotation and processing of 1) a pyrite concentrate, 2) a dominantly light rare earth elements (LREE) concentrate, 3) a concentrate containing most of the balance of the uranium and heavy rare earths (HREE), and 4) a relatively inert tailings.

Jan 1, 2014

By Richard Mcivor, Largo Albert

"Inco Limited has operated aluminum mine shaft conveyances since 1968. Aluminum conveyances are used where the hoisting in system requires lightweight conveyances to maintain the hoist rope safety factors and mine hoist rope pulls as dictated by government regulations. Inco Ltd. currently has 20 skips (including spares) operating in the Ontario Division mines. The main problems encountered are with galvanic corrosion between dissimilar metals and metal fatigue. This paper will highlight some of the problems encountered and illustrate methods utilized to overcome the problems and improve the conveyances performance.IntroductionAluminum mine shaft conveyances have been in use at Inco Limited's various Sudbury district mines since 1968. All of the conveyances currently in use are skips used for hoisting mine ore and rock. Inco had an aluminum quick change Kimberley-type skip and cage in operation at its Totten Mine in the early 1970s, but this mine is no longer in operation and no further comment will be made.The primary reason why aluminum conveyances are chosen over conventional steel conveyances is because of their light weight. Typically an aluminum conveyance will weigh about 60% to 70% of a steel conveyance of similar design. The lighter weight conveyances will allow higher payloads to be used and still maintain the statutory hoist rope factors of safety. It must be remembered that increasing the payload will increase the power required to raise the load and the hoist will have to have the necessary horsepower for the increased payload or the system will be overloaded.The front dump (Rola-chute) skips are of the bail-less design, i.e. the box structure also supports the load and has the shaft guide shoes attached directly to the side of the box structure. The Copper Cliff North Mine and South Mine skips have a joint in the centre of the conveyance and are installed in the shaft in two sections and connected with pins. This feature allows very long (42 ft) skips to be used in areas where a one-piece bail-type conveyance could not be installed. It is not practical to make sectionalized bail-type conveyances"

Jan 1, 1988

By S. Nikolic, O. O. Kehinde-Philllps, O. T. Djamgouz, D. H. Rousell

"A bulk mining method is employed at the Lockerby mine resulting in the formation of large muck-piles. If these muckpiles remain in the stopes for some time they may agglomerate to the extent that the muck cannot be removed by a scooptram. A laboratory investigation was undertaken with sulphide material from the mine in order to detemine the time that oxidation begins and the flowability of the material as a f unction of several factors. The laboratory results are applied to the conditions in the muck-piles.The time of the beginning of oxidation of the material decreases as the sulphide composition, water content and availability of air increases. Oxidation is retarded by the addition of a copper sulphate solution instead of water. The unconfined yield force (strength} of the material increases with an increase in the sulphide composition, water content and time. The material ceases to be free-flowing before there is visible evidence of oxidation and this suggests that oxidation actually begins earlier and that agglomeration is also due to the capillary action of water.Broken ore should be removed from the stope prior to the time a muck-pile ceases to be free -flowing-perhaps as early as two days f or high-grade ore and 5 days f or low-grade ore. In order to control dust, 1.4 weight per cent of a 5 per cent solution of copper sulphate should be added 10 the muck-pile rather than water. This inhibits oxidation and increases the time that a muck-pile remains free-flowing."

Jan 1, 1984

By Z. Xiao, A. R. Laplante

"The recovery of gold by gravity from grinding circuits differs from virtually all other gravity recovery approaches in that stage (or unit) recoveries are low, typically 1 to 5%, but overall recoveries are generally in the 25 to 60% range, because individual gold particles are presented many times to the primary recovery unit. Full-scale recovery is difficult to predict from benchscale tests. Further, maximizing metallurgical recovery is generally not the primary objective, because of the more efficient downstream recovery circuit (flotation or cyanidation). In this paper, a new concept, the gravity recovery effort, is presented to assist in the design and optimization of gold gravity circuits. It is defined as the product of the circulating load treated by the primary gravity unit, the recovery of this unit, and the gold room recovery. Predicted gold recovery is linked to the recovery effort, the size distribution of gravity recoverable gold (GRG), the dimensionless retention time in the mill and the partition curve of GRG. A case study of economic optimization of the gravity recovery effort is presented. INTRODUCTIONPredicting gold gravity recovery from grinding circuits has always been a hit-and-miss exercise. The problem can be traced to the highly variable gravity recoverable gold (GRG) content of ores, high GRG circulating load, fraction of the circulating load treated, and performance of primary gravity recovery and gold room. Typical values, highs and lows are shown in Table 1."

Jan 1, 2001

By Tassos Grammatikopoulos, Gary Pearse, Massoud Aghamirian, Charlotte Forstner, Stephen Mackie

"SGS Minerals Services (Lakefield, Ontario site) has conducted a number of developmental and pilot programs that examined methods for the beneficiation, extraction and recovery of lithium from a variety of spodumene containing hard rock sources. An overview of the beneficiation programs is presented separately by Aghamirian, Mohns, Grammatikopoulos, Imeson & Pearse (2011). The focus of this discussion will be the hydrometallurgical steps involved in producing a high grade lithium carbonate (Li2CO3) sample from the spodumene concentrate. SGS has applied the standard Li2CO3 hydrometallurgical flow sheet to a number of spodumene concentrates and has determined that all of these samples respond in a similar manner to the process and produce a final product having a Li2CO3 grade of >99.5%. The standard process is sufficiently robust to accommodate the observed variability in the concentrates that have been tested. Advantage of one spodumene deposit over another will thus be gained through process optimization and innovation. Optimization at the beneficiation stage and at the hydrometallurgical stage must be considered. Some aspects of the process optimization of the hydrometallurgical flow sheet will be presented.INTRODUCTION The current activity in the exploration, development, and mining of lithium based minerals is due in large part to the key role that this metal plays in the rechargeable battery industry (U.S. Geological Survey, 2011). Lithium battery technologies are widely applied in a range of portable electronic consumer products. The expanding development and production of hybrid and fully electric vehicles has contributed to the increased interest in finding and developing new lithium sources in order to meet the expected demand from the lithium battery industry. Lithium may be sourced from continental brines (sub-surface salars), hard rock minerals (pegmatite, spodumene), hectorite clay deposits, geothermal brines and oilfield brines. Currently the majority of the lithium products are produced from Li brines. The four major lithium producing countries are Chile, Australia, China, and Argentina (U.S. Geological Survey, 2009; Roskill, 2009). These countries accounted for 97.6% of the total lithium produced in 2010."

Jan 1, 2012

"7.1. Glossary of the Platinum-Group Minerals7.1.1. IntroductionA glossary of the platinum-group minerals (POM) serves as a useful introduction to a chapter on their mineralogy. Earlier glossaries (Cabri, 1972, 1976) were prepared for different purposes and composed in a different manner. As for most mineralogical textbooks, from Dana's System of Mineralogy, 3rd Edition (1850) , to Fleischer's Glossary of Mineral Species (1980), this glossary is primarily a chemical classification, arranged here in two tables. Table 7.1 groups the mineralforming compounds of the six platinum-group elements (POE) according to their essential anion(s) or according to the nonPOE element in intermetallic compounds. Table 7.2 is a similar listing for the native metals and alloys of the POE. Both tables include unidentified POM considered to be bona fide new minerals requiring additional study for complete characterization and recognition (see Chapter 9*). Some information on the chemistry of the POM is given in the sections on X-ray data (7 .2) and ore microscopy (7 .3). Because the overwhelming majority of POM have been characterized by the electron microprobe, a more detailed account of representative analyses is given in Chapter 8**. The total POM listed in Tables 7.1 and 7.2 is about 100, after deleting some which would not qualify as discrete species if found today, but which are still recognized on historical grounds; e.g. iridosmine, osmiridium, platiniridium. Tables 7.1 and 7.2 also include 28 unnamed POM; included because they are considered to be probably new species (Cabri 1981 b). The referral scheme for unnamed minerals is the same as in Chapter 9. There are considerably more palladium minerals known than other POM; the proportion of total species (listed in Tables 7.1 and 7 .2) for the POE is: Pd 48%, Pt 21 o/o , Ru and Ir 9% each, Rh 8% and Os 5%. These proportions are in marked contrast to the estimated cosmic abundance, as compiled for average type C1 chondrite by Naldrett and Duke (1980): Pt 29%, Ru 20%, Pd, Ir and Os 15% each, and Rh 6%."

Jan 1, 1979

By A. A. Beland, R. J. Dawson, S. Shewchuk

"Shovel buckets, scraper blades, dipper teeth, mine car wheels and hammermills are examples of equipment which require routine maintenance due to abrasion. Service life can be extended by the use 0/hard/acing and buildup materials. Mining and milling applications are described and field welding procedures discussed.A high-stress abrasion test used to select hard/acing and buildup materials/or hammers in a hammermill is described in detail. Field tests of the selected alloys confirmed their performance, and maintenance records showed a significant saving in down time and cost.The relationship between the abrasion resistance of the alloys and their hardness, work hardening, composition and microstructure is summarized. IntroductionLarge volumes of ore are handled daily by the mining industry. The abrasive nature of most ores results in extensive wear to both handling and processing equipment. If such wear is neglected it may cause lost production time and also, in extreme cases, require the complete replacement of expensive equipment. The well-planned maintenance of components subject to abrasive wear by means of buildup materials and hard facing can result in substantial economic benefits. Such benefits can , however, only be realized through the correct choice of welding process, consumables and deposition methods available to maintenance personnel. Hardfacing MethodsHardfacing is applied by a variety of methods; the three most widely used being arc welding, oxyfuel gas and thermal spraying. Table 1 summarizes the major processes used within each method. Filler metals in the form of rod, wire or powder are necessary to fulfill the individual requirements of each process. The filler rods are available in the cast form or, in the case of ductile metals or alloys, as wrought rod or tube. All types are supplied bare or flux covered. Wire is supplied in two forms, drawn flux cored and drawn solid. Powder filler metals are available in many metals or alloys; they may be simple mechanical mixtures or prefused and atomized alloys made to a specific size range and shape for optimum results for each applicable process."

Jan 1, 1980

By Mei-Yan Yang, Ltd. Yunnan Yuntong Zinc Co., Yong-Xiang Li, Xing-Zheng Dai, Hong-Liang Wang, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"The removal of iron asgoethite from the high iron bearing solutions generated in zinc hydrometallurgy using a strong airflow device was investigated. The influence of oxygen flow, copper ion concentration, temperature and reaction time on iron precipitation as goethite was studied. The optimum conditions were: oxygen flow 0.2-0.35m3/h, copper ion concentration 0.25-0.5g/L, temperature 80-90oC, zinc oxide powder neutralizing agent and a reaction time of5to 7hours. Under the optimal conditions, the Fe2+concentration was reduced to 0.025g/L after iron precipitation, and the goethite residue contained 38.7wt.%Fe. The SEM and XRD analyses showed that the iron was present as well formed FeOOH crystals in the iron residue, and the amount of iron sulphate was very low. Production practice shows that, when the average iron concentration in the feed solution was 11.61g/L and 4.08g/L after precipitation, the weight of iron removed was 1,439kg/day. When the average iron concentration in the feed solution was 14.51g/L and 2.73g/L after precipitation, the weight of iron removed was 2,454kg/day. This represents a ~70 percent increase in iron removal.INTRODUCTIONThe objective of iron removal is to produce a small volume of iron residue, and our industrial goethite process meets this requirement. The high Fe(II) solution in our reactor isoxidized/hydrolyzed to precipitate goethite and the precipitate is sent to a pyro metallurgical furnace for final residue treatment. Some literature discusses (DengYong-guiet al., 2008;Meiguang-guiet al., 2001;Zhongzhu-qianet al., 1980) research on iron hydrolysis; one of the reported rate limiting parameters was the low availability of the oxidant when using air and another was the inhomogeneous air distribution. There are two iron hydrolysis-goethite precipitation methods; the Electrolytic Zinc process (EZ) and the Vieille Montagne process (VM) (Lei Xiang, 2006; Xuguo-qiang, 2007;ZhaoYonget al.,2005). The EZ method hydrolyzes the Fe3+directly to FeOOH. The weakness of the EZ process is the low recovery rate of the associated minor metals. The VM method reduces the iron to the ferrous state and then oxidizes the Fe(II)to Fe(III),with simultaneous hydrolysis/precipitation of the Fe(III) as FeOOH. Before iron hydrolysis, the minor metals, such as indium, could be selectively precipitated, because Fe(II)requires a high pH for hydrolysis. So the VM method has a high recovery rate for the minor metals. There levant goethite precipitation reaction is:"

Jan 1, 2016

By A. Lewis, J. Zachwieja, M. Widell, P. Zhou, W. W. Geissler, M. Svensson, A. Movahedi, H. Nordberg

Flotation collectors for sulfide minerals has been traditionally based on xanthate, thiophosphate, thiophosphinate and thiocarbamate, all derived from sulfur chemistry. Tecflote™ is a new family of patented collectors based on nitrile chemistry which can supplement or replace thiol collectors, depending on the ore types. A steep grade-recovery curve typical of Tecflote™ collectors was observed when using Tecflote™ as the main collector for the rougher and cleaner steps allowing a better recovery compared to current thiol collectors while maintaining the desired grade. Additional recovery increase has also been observed by the addition of scavenger steps using Tecflote™ collector in combination with current thiol-based collector. The selectivity seen in the lab is transferred to full scale trial and is clearly seen in the rough flotation where the increase in the rough concentrate grade of 5% after pumping Tecflote S11 directly into the tank cell. The mechanisms for Tecflote’s selectivity towards sulfides are currently under investigation and will be discussed. Results of TOF-SIMS analysis will be presented, demonstrating the collector’s selective affinity to different mineral surfaces in flotation. INTRODUCTION The history of collectors used today started in 1882 when Zeise first made xanthates. It was first used in flotation in 1925 – Cornelius Keller’s first patent (Fuerstenau, Jameson, Yoon, 2007). Between 1928 and 1930 American Cyanamid filed 7 patents for dithiophosphate, including flotation and chemical synthesis of the reagent, the first of which was filed by Christmann in 1928 (Christmann, 1933). Synthesize of thionocarbamates for mineral flotation was filed in 1954, by Dow Chemical Company (Harris, 1954). Now that the head grades have been declining over the last decades the need to find more selective collectors to extract difficult and complex ores has pushed the industry to look at different chemistries. Thiol collectors standard to the industry rely on the sulfur in the collector molecule to bond to the mineral surface. The electronic property of this group is modified by the adjacent chemical groups, such as additional S, P or N have the effect of changing the selectivity of the collector (Wills & Finch, 2016). In the case of xanthate the length of the hydrophobic group also has an effect on the selectivity with some minerals such that the ethyl xanthate is more selective against pyrite and pyrrhotite than the long chain xanthates (Wills & Finch, 2016).

Jan 1, 2019