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By D. W. Davis, P. Landais, L. J. Robb

Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Ph-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter Ol3C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoidand sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By C. E. Baltzer

This paper highlights the electric power situation in Canada, and introduces brief explanation of the salient differences between electrical practice in the United States and Canada. The availability of bask energy in the two countries is touched on, also the hydro versus thermal outlook as applying to Canada. De-v2lopment of thermal-electric power is dealt with in some detail, followed by Canada's thermal-electric power requirements, present and future. The fuel requirements for steam-electric generating plant are assessed on the basis of a survey recently made, and the location and size of the major thermal plant operations are given. Fuel contractual obligations on the part ?of suppliers and consumers are mentioned. Finally, an opinion is expressed in regard to the types of f.uel in ?demand on a regional basis with emphasis on the need for coal in the several areas dealt with.

Jan 1, 1958

By H. F. Naldrett

"AbstractAt the end of May, 1950, Imperial Oil, Limited, had completed a total of 192 D-3 wells in the Leduc-Woodbend field, 62 of which lost circulation in the D-3 zone for periods ranging from two hours to fifty days. The majority of the remaining wells •lost some mud without actual loss of returns. In addition, independent operators completed 69 D-3 wells, of which 9 lost circulation. Included among the latter is the now well known Atlantic No. 3 well, which blew wild out of control for seven months. The well was finally brought under control through two directionally drilled wells, but not before the derrick fell and the well caught fire. Practically all known filler materials have been used in attempt3 to prevent or regain loss of circulation, but none has been successful, except in minor cases. Ordinary sawdust has come to be the most commonly used filler material and is added to the mud before the D-3 zone is contacted. In cases of serious loss of circulation, the on1y successful method of getting returns has been the use of a series of small cement plugs.IntroductionThe Leduc field is twenty miles southwest of Edmonton, Alberta. Geologically, it is on the east limb of the Alberta syncline, in the homoclinal belt. The main productive zones are in the Upper Devonian formation and are known locally as the D-2 zone and D-3 zone, respectively (see Figure 1).The D-3 zone is a dolomitized reef with fair average porosity and permeability, and shows considerable evidence of vertical fracturing. Porosity is mainly due to moderately uniform development of vugs which are interconnected by small crevices. However, the formation is known to be, locally, extremely vuggy and in places cavernous. These latter conditions create very serious drilling problems due to the hazard of loss of circulation, particularly in the gas cap, which has a maximum thickness of 200 feet. The D-3 zone is contacted at an average depth of 5,300 feet."

Jan 1, 1950

By R. P. Charbonnier

"To understand the operation of jigs and other separating processes based on differences in gravity, it is desirable to analyse the motion of various particles in given media under specific conditions. A summary of the earlier theories shows that they lead to unsatisfactory or excessively complicated formulae in cases such as coal jigging. By adopting a simplified theory of the motion of particles in a fluid, the size and duration of the initial accelerated motion of a particle falling in hindered settling can be calculated. Based on this mathematical analysis, examples referring to actual coal jigging practice show that it is desirable to prolong and/or repeat, as frequently as possible, the optimum conditions corresponding to an effective acceleration of the particles. The separation is then obtained according to gravity rather than to particle dimensions, as would be the case if the velocity of the particles• were allowed to approach its terminal value. To achieve this gravity separation, it is suggested that the suction phase of the jigging cycle be artificially prolonged and the frequency of pulsations increased as much as possible for washing the coals of smaller sizes."

Jan 1, 1959

By A. Luszczkiewicz

This paper presents the beneficial effects of non-oxidative leaching of final and intermediate copper sulfide concentrates with sulfuric acid prior to the final cleaning stage of flotation. This unique process, combining leaching and flotation, appears to be advantageous for difficult-to-treat carbonate-bearing Polish copper ores, such as those processed in copper concentrators at KGHM Polish Copper. It was shown that after the chemical decomposition of about 70 % of the total carbonates naturally present in the flotation feed, a considerable enhancement of subsequent flotation results (both grade and recovery). The resulting products of non-oxidative leaching are solid hydrated calcium sulfate (gypsum), soluble magnesium sulfate and gaseous carbon dioxide. The beneficial effect established by the laboratory leaching tests was subsequently confirmed during a pilot plant operation treating final copper concentrate and a problematic intermediate concentrate at the Lubin concentrator.

Jan 1, 2007

By G. A. Vissac

In this paper we intend to deal particularly with the economic side of coal washing as it applies to our mines. We will then discuss why the dry-cleaning process has been selected, and give a brief description of our plant, dwelling only on its specific features and referring the reader to the numerous papers published on the subject for any details on the principles and machinery used in dry cleaning. ECONOMIC DISCUSSION The washery introduces an extra cost for depreciation, operation, and loss in treatment. A certain proportion of the coal, now being sold, and which the miners have been paid for. will have to be wasted. As a whole, the total increase in cost would be approximately 60 cents per ton. On the possibility of recovering this amount depends the success of the washery. There are two advantages to be expected from the washery, the first, which occurs at the mine and which will be certain; the second, more difficult to estimate, because it depends upon convincing our customers that they should pay more for a better product.

Jan 1, 1924

"Mining with blast holes drilled upwards may be done to recover sill pillars, or for economic reasons when the distance between the levels is relatively large. If the rock is sufficiently competent to accommodate large stope size, the distance between sublevels could be increased to as much as drilling accuracy allows. The same drill drift can be used for the drilling of both down holes and up holes. In the case of down holes, the initial opening of the stope (drop raise) is not as much a problem as for the inverse drop raise for mining with up holes. This is because, with a drop raise, a lot of space is available at the toe for the blasted rock to expand. In addition, the raise can be blasted in many shots, thus allowing smaller blasts each time. Inverse drop raises are generally much more difficult to blast because of the limited space for muck flow, and must, therefore, be taken down in a single blast, requiring special considerations in order to ensure a success. A case study of a 29 m (95 ft) inverse drop raise successfully blasted in a single shot at Heath Steele Mines is described. The paper covers technical considerations such as drilling accuracy, hole deviation survey, delay extension and protection, initiation methods and initiation sequence. Finally, a novel method for creating the initial opening called ’slot drilling’ is presented. This method, inspired from LKAB in Sweden, consists of drilling a row of interconnected holes using a special guide mounted on a regular production drill hammer.With a case study of blasting an inverse drop raise of 29 m (95 ft) in one blast, this paper further discusses some technical issues that are critical for the development of inverse drop raises. A novel method for creating the initial opening with a slot of interconnected holes is also presented with the experience acquired at different mine sites across the Noranda group."

Jan 1, 2000

By Boyd Davis, Vladimiros Papangelakis, Douglass Duffy, Michael Carlos

"The processing of lateritic saprolite in hyper-concentrated magnesium chloride brines offers several potential advantages for the hydrometallurgical production of nickel. An aggressive HCl-MgCl2 leach at atmospheric pressure can significantly reduce magnesium dissolution, and offers the ability to recover HCl and MgO by a less energy intensive process than conventional techniques via the formation of magnesium hydroxychlorides. Inevitably, the high chloride concentration renders iron fully soluble during leaching and thus requires subsequent iron control and disposal steps. Experimental measurements coupled with OLITM modeling were conducted to investigate the behaviour of iron in concentrated magnesium chloride brines, in terms of chemistry (nature of iron species) and solubility limits. The solubility of ferric chloride in magnesium chloride solutions of concentrations and temperatures relevant to this process was controlled by a previously unreported solid phase: 2.5FeCl3·MgCl2·7.5H2O. Iron precipitation tests on synthetic leach solutions without seeding indicate a metastable akaganeite precipitate which transitions to hematite upon equilibration. Magnesium chloride solubility in ferric chloride solutions was also investigated to allow the simulation of a ternary phase diagram for the MgCl2-FeCl3-H2O system, in order to determine process conditions that avoid unwanted chloride precipitation.INTRODUCTION In the search for more economical processes to treat lateritic saprolite for nickel production, chloride hydrometallurgy has been increasingly investigated. While High Pressure Acid Leaching (HPAL) can frequently economically treat lateritic limonite, the presence of saprolite negatively affects process economics. The higher magnesium content of saprolite increases acid consumption, because magnesium sulphate, unlike iron and aluminum sulphates, does not hydrolyze in HPAL. This soluble magnesium decreases the sulphuric acid strength by an amount greater than the amount of acid stoichiometrically required to leach magnesium, which must also be disposed of or recovered (Jankovic, Papangelakis, & Lvov, 2009). Due to these issues, pyrometallurgy is most commonly employed to treat lateritic saprolite, via the Rotary Kiln-Electric Furnace (RKEF) process; this process uses a rotary kiln to dry and partially reduce nickel and iron oxides before sending the calcine to an electric furnace for smelting to produce a ferronickel product for the stainless steel market. Although the problems encountered during hydrometallurgical processing are avoided and nickel recoveries are high, high capital and energy costs prevent the application of this process to lower grade lateritic saprolite deposits (De Bakker, 2011)."

Jan 1, 2016

By V. Estrada, G. Aguilera

"Since the most of mineral processing are wet, and for more specific applications where it is necessary to increase the purity through leaching and / or concentration, the proper dispersion is the first, and perhaps more crucial stage in the whole chain of processing. This specific process is based on the formation of a dispersion or suspension of mineral, trying to make the mixture as homogeneous as possible, and with specific rheological conditions. Sometimes it is not enough agitation to make it happen, so that chemical additives are used as an aid. However, the addition of chemicals strongly alters the viscosity and other rheological properties of the suspension factor to consider for subsequent steps to ore beneficiation. In other hand, in a process where no chemicals used often employ large quantities of water to achieve dispersion. But if an efficient chemical agent, which optimizes said dispersion through a specific physicochemical effect on the particle surface is used, also it can generate rheological advantages, besides achieving rational use of water and increase the recoveries of the product main about also optimal costs. The aim of this work is to find the optimal rheological conditions for a dispersion of kaolin as study case, looking for stability, best disaggregation, viscosity and pseudoplasticity.To find the optimal additive, the evaluation parameters were: 1) Best degree of dispersion of the suspensions according to the analysis of the flow curve; 2) Best level of disaggregation of particle chemical analysis delaminated by Particle Size Distribution; and 3) Best thixotropic rheological parameters and pseudoplasticity. Finally the optimum additive as one that meets the best combination of parameters is proposed.INTRODUCTIONKaolin is a clay material formed by altering of feldspar composed mainly for kaolinite. Depending on the application, the kaolin as raw material must be refined and processed because the ores of clays contain usually a lot of impurities derived of its sedimentary source, such as feldspar, mica and quartz (Torres, et. al., 2011). According to the experience on the plant floor and the publication of several scientific papers, it is known that the dispersion is a crucial stage in mineral processing (Greene, Duke, & Hunter, 1965) (Raghavan, et. al., 2004), not only because of the disaggregation of particles, besides because of the humectation of them. Is clear that disaggregation of particles give to the suspensions rheological stability, and the humectation improves the effect of further processes like grinding or chemical treatment. The dispersion process involves making a suspension of the mineral with a solvent which is usually water, to obtain a homogeneous dispersion, with the aid of energy of stirring. Sometimes is not enough the agitation (even with high energy) for this to occur, so is necessary the use of dispersing substances which introduce ions and molecules as modifiers of chemical potential, forcing the molecules of the material to disperse. Sometimes their use even could affect the pH of the suspension in a non-desirable condition. (Flores, 2013)."

Jan 1, 2016

By B. Panton, J. Carvalho, E. T. Brown

"A major consideration in the design of high capacity tiedown anchors for dam, bridge and tower foundations is the tensile resistance of the rock mass to pullout, typically as a result of overturning moments or hydrostatic uplift. Rock mass pullout capacity for installed anchors is developed from the tensile strength and fracture propagation properties of intact rock, the orientation and physical properties of the discontinuities and anchor confinement at depth. The typically assumed, but generally conservative, design approach is to calculate anchor pullout capacity using the dead weight of a uniformly shaped inverted “cone” with an assumed initiation point and breakout angle. In some cases, some tensile or shear strength is considered across the area of the assumed pullout cone, however, these strength estimates are based primarily on based on limited historic testing data, empirical relationships for rock mass strength developed for other applications, and engineering judgement.As an alternative to the current foundation anchor design method, this paper presents a new approach to the rock cone pullout problem using Discrete Fracture Networks (DFN) combined with numerical simulations. The simulations presented in the paper investigate the influence of fractures in a synthetic rock mass on ultimate anchor strength. In addition, the global influence on fracture network statistics on rock mass pullout failure is also discussed and it is contended that some of the aleatory and epistemic uncertainty inherent in the design of rock anchors can be reduced by considering fracture statistics in anchor design."

Jan 1, 2015

By J. W. Coetzee, H. E. Deist

Carbon-in-pulp (CIP) and Carbon-in-leach (CIL) processes are used extensively in the gold mining sector to recover aurocyanide from solution. This paper discusses the modelling of these operations, using various simplifying assumptions, in order to simulate the effect of changing operating conditions on the dynamics of the system. It is assumed that the adsorption and leaching rates are a function of concentration difference between the source phase and recipient phase. The simulation was set up using Matlab's Simulink interface. Plant variables are solved using a medium scale Newtonian search algorithm in Matlab, where the differences between the actual and predicted plant outputs are minimized on a continuous time-line.

Jan 1, 2005

By S. S. Al-Thyabat, A. M. Ghrair

"Printed circuit board (PCB) is the main part of any electric or electronic device, providing mechanical support and electric connection for the board eclectic components such as capacitors, resistors, diodes etc. PCB consists of non-conductive substrate overlaid with one or more layers of copper sheets. They also contain appreciable amounts of base metals (copper, nickel, tine, and aluminum) and precious metals (gold, silver, and rare earth elements (REE)) which end up in the landfill at the PCB end-of-life.PCB recycling E-waste in general is a profitable business; many valuable raw materials, precious and base metals, can be extracted with high purity. Approximately, one metric tonne of PCBs may contain 80-1500 g of gold and 160–210 kg of copper. The precious metals recovered from PCBs occur at concentrations higher than commercially mined minerals. Also PCB recycling is very important to our environment since many heavy metals (e.g. lead) may be leached from the landfills to the underground reservoirs. In Jordan, however, the work conducted on E-waste and PCB recycling in particular is limited; currently most of the E-waste is either exported or dumped in the landfill.In this work, a combination of physical (magnetic separation), physicochemical (flotation), and chemical methods (leaching) were used to compare metals concentrations in leach liquors produced from a concentrates resulted from a combination of these methods. It was found the leach liquor of the magnetic fraction of the PCB coarse size gave the highest concentration of Fe, Al, and Ni while concentration of Cu was higher in leach liquor of nonmagnetic sink fraction. On the other hand, metals concentration almost similar for both sink and float of the fine size fractions, indicating even distribution of metals concentrations in the fine size fractions."

Jan 1, 2016

By L. M. Dwarkin

Introduction Avital factor in the success of any coal mining operation is the method of roof support employed. A coal seam in? place has been described as the filling in a geological sandwich and the process of mining as the art of snatching the filling from the midst of the sandwich. The difficulty of this task can be appreciated -in the realization of the tremendous weight bearing on a coal seam due to overlying strata; a weight that can exert pressures of several thousand pounds per square inch. Over the years that mining has been carried on, methods have been evolved by arduous trial and error, making possible the successful extraction of billions of tons of coal. However, these time-proven methods are not enough. The constant demand for faster and cheaper production, the necessity of mining under increasingly difficult conditions, and the requirement for higher standards of safety, call for ever better and more efficient roof support. A recent and very promising development in answer to this need is that of Roof Bolting. Roof Support in General Before proceeding to the subject proper, a brief discussion of the older roof support methods is of value in illuminating the difficulties involved and the problems to be solved.

Jan 1, 1951

By A. H. A. Robinson

Until quite recently-practically up to the present time-all but an insignificant amount of the copper produced in Canada was shipped abroad in the form of ore, matte, blister, etc., there to undergo the further treatment necessary to bring it to the refined state in which it is required by fabricators of copper. Consequently, Canadian manufacturers were forced to import nearly all the copper required in their business; and a considerable portion of the ultimate value to be derived from a Canadian raw material was lost to the country of its origin. In the early days of Canadian copper mining, when both the production and consumption of copper in Canada were much smaller than now, such a condition of affairs was perhaps economically unavoidable, and, in any case, was not a matte~ of sufficient importance to attract general attention. Later on, however, when there had been large and rapid increases both in the production and consumption of copper in Canada, it formed the basis of much adverse criticism, deserved or not, of producers of Canadian copper-criticism that became intensified during the war and subsequent years. Happily, the chief grounds of complaint have now been removed, and there are today copper refineries in Canada, either operating or under construction, that are capable, in the aggregate, of turning out amounts of refined copper greatly in excess of any indicated Canadian consumption.

Jan 1, 1931

By D. K. Sarkar, Jiawei Xiong

"Self-assembled monolayers (SAM) on the aluminum substrates are used as the adhesion promoter between two aluminum substrates when bonded with the adhesive in adhesive bonding technology. Traditional surface analysis tools are not capable of identifying the presence of SAM on a surface; therefore, EIS has been used to determine their presence on the aluminum substrates. In this study SAMs have been deposited on aluminum using the monomer of (3-Glycidyloxypropyl)trimethoxysilane (GPTS) organosilane. AA6061 aluminum alloys substrates were chemically cleaned with NaOH and HNO3 to remove the native oxides, followed by immersion in silane solutions. In a second method, SAMs were prepared by applying a spin coating of silane solution to the samples. The prepared SAM coated aluminum samples were analysed by EIS in the three electrode corrosion cell using a diluted alkaline solution. The impedance of the SAM coated aluminum is found be higher than the as-received aluminum. It has been also observed that the open circuit potential (OCP) of the SAM coated aluminum is higher than the as-received aluminum. Both elevated values of the impedance and OCP confirm the presence of SAM on aluminum.INTRODUCTIONSelf-assembly (Schreiber, 2000) is defined as the spontaneous formation of complex hierarchical structures from pre-designed building blocks, typically involving multiple energy scales and multiple degrees of freedom. Generally speaking, SAMs are created by the chemisorption of ""head groups"" onto a substrate from either the vapor or liquid phase followed by a slow organization of ""tail groups"" of a molecule. Typically, head groups are connected to a molecular chain in which the terminal end can be functionalized with groups such as –OH, –NH2, –COOH, or –SH to vary the wetting and interfacial properties (Chauhan et al., 2007; Ulman, 1996; Vashist, Lam, Hrapovic, Male, & Luong, 2014). Though there exist several methods to prepare SAM (Chauhan et al., 2007; Chen, Yang, & Zhang, 2014; Cho, Park, Jon, & Choi, 2007; Igor Luzinov, 2000; Reis, de Melo, & Costa, 2006; Song, Zhai, Wang, & Jiang, 2006; Sugimura, Hozumi, Kameyama, & Takai, 2002; Vashist et al., 2014), the two methods vapor phase (Song et al., 2006; Sugimura et al., 2002) and solution(Chen et al., 2014; Igor Luzinov, 2000) are commonly used. Recently, many articles have been published on the fabrication of superhydrophobic surfaces with SAM technology (Cho et al., 2007; Pan, Shen, Shang, & Xing, 2012; Siddaramanna, Saleema, & Sarkar, 2014; Song et al., 2006). Brassard, Sarkar, and Perron (2011) successfully obtained a superhydrophobic film by applying fluoroalkylsilane via self-assembly on monodispersive silica. SAMs are also reported as good candidates for anti-corrosion and adhesion promotion (Chen et al., 2014; Saleema, Sarkar, Paynter, Gallant, & Eskandarian, 2012). However, papers on the characterization of SAM properties are rarely seen. The most commonly used substrate for SAM is silicon and the method implemented is scanning probe microscopy (SPM) such as atomic force microscope (AFM) (Igor Luzinov, 2000; Moores, 2011; Zhang, 2003, 2005). Igor Luzinov (2000) analyzed the epoxysilane SAMs’ surface morphology and microstructure properties using scanning probe microscopy (SPM) and ellipsometry on single-crystal silicon wafers. SAMs have been used to improve the adhesion bonding of aluminum or plastics but no characteristic data have been presented yet (Saleema et al., 2012; Telegdi, 2007; Wang, Xu, Luo, Wang, & Wang, 2009). Recently, Reis et al.(Reis et al., 2006) have studied SAM of alkane diphosphonate (Gardobond X4661) on Al 5052 alloy samples by EIS in a naturally aerated sodium sulfate solution."

Jan 1, 2016

By Herbert D. Drechsler, James B. Stephenson

"AbstractThe paper identifies the major components of price change which affect the determination of the internal rate of return of a mining project. It illustrates several price indexes which may be used to measure general price increases, identifying techniques which might incorporate them into mine valuation procedures. The ""hurdle rate"" for new investment is discussed.IntroductionDECISIONS regarding the value of an orebody and whether or when to mine an orebody are based on an estimate of the cash flows which would be associated with its exploitation. These pro-forma cash flows represent cash in or out of a possible mineable deposit and include exploration and construction costs, sales revenues, operating expenses, taxes, debt borrowings, interest and debt repayment. It has long been recognized that when combining the cash flows occurring over the life of the mine, dollars received or paid out early have greater value than those received or paid out later. This time value of money has been incorporated into mine evaluation calculations through the use of present-value or discounting techniques. Another factor affecting mine valuation, inflation, is not accounted for by valuation techniques now in use. In recent years, price changes have become more volatile. In the past, price change could easily be ignored when evaluating potential mines. Today, the combination of larger investments and greater price volatility leads to great concern about the effects of price change on mine valuation."

Jan 1, 1977

By A. Shaak

The town of Hedley is some 200 miles due east of Vancouver and lies in the bottom of the Similkameen River valley, at the junction of Twenty Mile creek, at about the 1,700-foot elevation above sea level. The Nickel Plate mine camp is on Nickel Plate mountain at an elevation of about 5,600 feet, four miles slightly east of north from Hedley, to which it is connected by 9 miles of road, and by 10,000 feet of tramway and electric railway. The latter is used both to transport the ore to the 275-ton mill at Hedley and to furnish the mine with supplies. History The Nickel Plate claim was staked in 1898 to cover the sole outcrop of the Nickel Plate system of orebodies. Soon afterwards it was optioned by the Marcus Daly interests of Butte and underground exploration commenced. Early exploration was successful, and a power plant, tramway, and mill were constructed. The mill began operations in 1904. Production under Daly control ensued from June, 1904, to August, 1909, and amounted to 167,000 tons. The Hedley Gold Mining Company was organized and commenced operations in 1909. The capacity of the mill was increased by stages to 200 tons and a steady production, except for short periods in winter, was maintained until 1930. By 1930, gold to the value of nearly $10,000,000 had been produced since the discovery in 1898. The South American Development Company optioned the property in 1932. Active exploration was conducted during 1933 and 1934 by the Kelowna Exploration Company, a subsidiary of the South American Development Company. This work was sufficiently successful that, coupled with the increase in the price of gold from $20.67 to $35.00 per ounce, production re-commenced in December, 1934, and continued uninterrupted until July, i946, when, along with all B.C. gold mines, a strike closed operations. Under the present ownership, the mill capacity was increased to 275 tons.

Jan 1, 1946

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016

By Peter M. Power

A microscopic study was made of a series of simultaneous slag and metal samples taken from a low carbon basic open hearth heat. An attempt was made to identify the various micro-constituents found. As the various impurities in the bath are oxidized, the metal structure changes from that of high-phosphorus white cast iron to that of low.-carbon steel. A detailed study of phosphorus distribution is included. The acid run-off slag has an .acicular orthosilicate structure which changes on 'shape-up' to a very basic tri-calcium silicate and calciuim ferrite structure. Many unidentified minor constituents are present in the slags. Though metallography will never replace chemic.al analysis of the bath, the microsopic study of polished slags has some promise of being useful in slag control work.

Jan 1, 1956

By I. S. Thompson

"The discovery of low-grade copper-silver mineralization near the town of Tipperary, Ireland, by Gortdrum Mines Limited was the result of reconnaissance geological and geochemical exploration followed by target delineation from induced polarization surveys.Initially, orientation studies at the Tynagh lead-zinc orebody showed that such deposits could be readily detected in stream sediments and soils using cold extraction analysis for total heavy metals. Numerous areas showing stratigraphical and structural similarities to Tynagh were then selected for reconnaissance geochemical prospecting.The Gortdrum deposit was detectable through the presence of anomalous metal values in stream sediments 3,000 feet downstream; soil sampling indicated an area of 2,000 by 700 feet containing 2 Yz to 20 times background cold-extractable metal values. Induced polarization surveys defined the dimensions and attitude of mineralization.Drilling to date has outlined (under 10 to 20 feet of till) low-grade copper-silver mineralization within Lower Carboniferous limestones and shales which have been faulted against Devonian sandstone. Mineralization ex-tends from surface to depths of 250 to 450 feet and consists of bornite-chalcocite-tetrahedrite and some chalcopy-rite in altered limestones and intrusive dikes.The deposit is geologically analogons to the Tynagh and Silvermines orebodies, but in contrast exhibits a predom-inant structural control. Provisionally, it is postulated that mid-Carboniferous folding and faulting produced the pre-mineralization high porosity via recrystallization, shearing and brecciation. Subsequently, hydrothermal solutions from the west, with a probable eommon origin to the volcanic dikes, were introduced along the fault planes. Although syngenetic causes cannot be exempted, the field relationships favour an epigenetic origin."

Jan 1, 1967