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By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By Robert Y. Lamarche

On exploite le chrysotile dans le sud du Quebec depuis plus de cent ans. Au cours des dernieres decennies, cette variete d'amiante est devenue une des principales substances minerales produites au Quebec. Bien que la production de fibres d'amiante ait diminue de J 365 779 ten /979 a que!que 700 000 ten 1983, le Quebec n'en demeure pas mains une des principa/es sources d'approvisionnement mondial de ce mineral, la valeur des exportations quebecoises ayant ete de l'ordre de 315 millions de dollars en 1983. Dans la presente contribution, nous passons en revue que!ques-unes des notions mineralogiques sur l'amiante, depuis l'etymologie du mot et les proprietes physico-chimiques du mineral, jusqu'd ses principales utilisations commercia/es et industrielles. Un des deux objectifs principaux de noire article est de definir brievement le contexte geologique regional, la lithologie et /'age des roches ultramafiques serpentinisees et de decrire les principales caracteristiques des gftes de chrysotile qu'elles renferment et qui furent exploites a date dans /es Appa/aches du sud quebecois. Nous concluons en dressant un tableau synoptique de la metallogenie et en soulignant le role preponderant qu 'ont joue /es mouvements tectoniques majeurs, a la jonction des plaques et au sein des feuillets et copeaux de la croute oceanique (lithosphere et manteau superieur), sur la genese des gftes de chrysotile dans les roches ultramafiques serpentinisees, et tout particu!ierement dans celles associees aux series ophiolitiques du Paleozaique inf erieur.

Jan 1, 1984

By Jean Robitaille

La découverte du gisement du puits Penna a nécessité une révision complète de tous les circuits du concentrateur Laronde pour permettre, premièrement, l?adaptation du procédé à la nouvelle minéralogie et deuxièmement, l'accroissement du tonnage de 1800* à 4500 t/j. Aux circuits existants de broyage, de flottation du cuivre, de cyanuration et du charbon en pulpe, les circuits suivants furent greffés : broyage semi-autogène, flottation du zinc, manutention des concentrés (épaississage, filtration, entreposage et chargement automatisé), décantation à contrecourant et précipitation au zinc, destruction des cyanures et remblai en pâte. Cet article se veut une revue des différentes étapes du projet d'agrandissement du concentrateur qui se sont effectuées par phases progressives de 1997 à 2000. De plus, une description des nouvelles technologies sélectionnées et implantées est présentée.

May 1, 2001

By K. J. Palmer, D. A. Silva

"Evaluating resources and reserves requires the reliable modelling of geological domains and their grades. “Multiple point statistics” simulation is a relatively new geostatistical method to generate complex, high-resolution geological models by extracting high-order spatial relations from training images. A method based on combining multiple training images is developed to obtain the correct amount of large-scale continuity and short-scale variability. A calibration process matches the geological spatial variability between the final realizations and the drillhole dataset. A case study with data from the Red Dog mine, Alaska, United States, shows an appropriate reproduction of short-scale variability along boundaries between geological units.RÉSUMÉ L’évaluation des ressources et des réserves exige une modélisation fiable des domaines géologiques et de leur teneur. La simulation par « statistique multipoint » est une méthode géostatistique relativement nouvelle pour générer des modèles géologiques complexes à haute résolution par l’extraction de relations spatiales d’ordre supérieur à partir d’images d’entraînement. Une méthode basée sur la combinaison de multiples images d’entraînement est développée afin d’obtenir la bonne quantité de continuité à grande échelle et de variabilité à petite échelle. Un processus d’étalonnage fait correspondre la variabilité géologique spatiale entre les réalisations finales et l’ensemble des données de forage. Une étude de cas avec des données de la mine Red Dog, Alaska, États-Unis, montre une reproduction adéquate de la variabilité à petite échelle le long des limites entre les unités géologiques."

Jan 1, 2015

By Alan Jessop

A small group has been set up at the Dominion Observatory, Ottawa, to make a survey of terrestrial heat flow throughout Canada. Terrestrial heat flow is the heat rising from the interior of the earth and escaping at the surface, and is calculated from a knowledge of under-ground temperature distribution and the thermal conductivity of rocks. A small number of diamond drill holes are being sunk for the purpose of measuring temperatures below the surface, but the program is inadequate for a thorough survey. Mines and holes drilled for other purposes are being sought by the Dominion Observatory group to supplement their own drilling program. F ROM January, 1.962, to December, 1964, geo-physicists of many nations will be cooperating in the "International Upper Mantle Project." Unlike tl1e International Geophysical Year, which was mainly concerned with the fluid layers surrounding the earth, the Upper Mantle Project is an intensive study of the solid earth. Canada, with its large land area and extensive Precambrian Shield, is an active participant in the project.

Jan 1, 1964

By L. Yuan, J. Qin, J. Xie, Q. D. Qu, Y. P. Liang

"This paper presents key outcomes of a major Asia-Pacific Partnership project between the Commonwealth Scientific and Industrial Research Organisation and Huainan Mining Industry Group Co. Ltd. to develop and demonstrate advanced technologies at Pansan mine, Huainan, China. A comprehensive approach assessed fundamental strata and coal seam methane conditions during mining and optimized mining sequences and coal mine methane capture systems. The project demonstrated a practical approach and procedures for advanced coal and methane co-extraction systems, improved mining safety and efficiency, increased methane capture and use, and reduced fugitive methane emissions.RÉSUMÉ Le présent article donne les principaux résultats d’un grand projet de partenariat Asie- Pacifique entre le CSIRO (Commonwealth Scientific and Industrial Research Organisation) [Organisation de recherche scientifique et industrielle du Commonwealth australien] et le Huainan Mining Industry Group Co. Ltd.; ce projet cherche à développer et à démontrer des technologies avancées à la mine Pansan, à Huainan, en Chine. Une perspective globale a évalué les conditions fondamentales des strates et du méthane dans les couches de charbon durant l’exploitation et a optimisé les séquences d’extraction et les systèmes de captage du méthane dans les mines de charbon. Le projet a permis de démontrer une approche pratique et des procédures pour des systèmes avancés d’extraction conjointe du charbon et du méthane, pour améliorer la sécurité et l’efficacité minières, accroître le captage et l’utilisation du méthane et réduire les émissions fugitives de méthane."

Jan 1, 2015

By R. R. Rogers

ABSTRACT The experiments described demonstrate that crude commercial lithium containing in the order of 0.5 per cent sodium can be refined, the resulting metal containing as low as 0.001 per cent sodium. During the process, the metal is vaporized and condensed at a gauge pressure of less than 0.04 micron. Considerable operating data and a detailed description of the experimental equipment are included. INTRODUCTION DUE TO THE unusual properties of lithium metal, its use is likely to increase considerably during the next few years (1, 2). This is of particular interest to Canadians because there are important deposits of lithium-containing minerals, especially spodumene, in Canada and it is hoped that lithium compounds and lithium metal will be produced from these deposits in the fairly near future. In order to assist in the development of this industry, the Mines Branch of the Department of Mines and Technical Surveys has initiated a programme of research in lithium metallurgy. In 1948, a paper (4) was published on methods of producing lithium metal and its alloys. Data on the corrosion resistance of some lithium alloys were included. In 1949, a paper (3) was published which showed that the addition of a small percentage of lithium to zinc anodes used for cathodic protection will improve their usefulness under certain circumstances.

Jan 1, 1951

By J. Tuzo Wilson

"AT ANY TIME, it is a pleasure to me to be invited to address The Canadian Institute of Mining and Metallurgy because it represents an industry and men with whom I have been happily, if peripherally, associated continuously for forty years. This year, it is a particular pleasure because I believe that an important subject has arisen which I propose to discuss.This is a major discovery in the earth sciences, first fully revealed this winter, but already widely accepted. The basis of this revolution, for it is no less, is that measurements of three different features of the earth all change in exactly the same ratios. These ratios are the same in all parts of the world. The results from one set are thus being used to make precise numerical predictions about all the sets in all parts of the world. No such accurate correlations and predictions have ever been found before in geology or areal geophysics. The whole subject of earth science has thereby been radically altered.The first of these measurements is that of the direction of magnetic polarity in lava flows. When piles of young lavas are examined with the aid of a pocket compass, it is noted that some flows are magnetized in the direction of the earth's field and some in the reverse direction (Figure 1). By accurately dating enough flows, a time scale of the dates of reversals has been established. During the past four million years, nine reversals have occurred synchronously all over the world (Cox, Darymple and Doell, 1967, McDougall and Chamalaun, 1966) (Figure 2). It appears that the scale can be extended back to Precambrian times (McMahon and Strangway, 1967). This time scale is the first of the 'three identical ratios."

Jan 1, 1968

By Theodore H. Boggs

The battle of the gold standard is not limited to one country alone, or even to a single group of countries. It is being waged merrily in many important commercial and industrial quarters. Though it is not always a practical issue calling for immediate attention, it is none the less, quite widely, engaging the thought of bankers and other students of finance. The controversy arises, in the last analysis, because of the desire of men to secure a stable currency. There are two ways of restoring a reasonably stable currency system: (1) the re-establishment of the gold standard, or (2) the deliberate and artificial management of a paper currency. Both systems are well known. The gold standard was in use prior to the war in the principal commercial countries. A currency of inconvertible paper has been at times employed in the past in various countries; for example in Britain from 1797 to 1821, and in the United States from 1862 to 1879. The gold standard, as all are aware, implies the selection of gold as the standard of value. The unit of value is a fixed weight of gold and, so long as the standard remains unimpaired, all other means of payment are maintained at a parity with standard gold coins. And gold coins alone constitute the standard money, inasmuch as their value as bullion equals their value as coins. Under the gold standard this would not be true of any other form of money, although all other varieties of money, including bank notes, government notes and silver coins would be freely convertible into gold money. Strictly speaking, the gold standard also implies that the gold money in turn shall itself be freely convertible, through melting, into gold bullion and freely exportable.

Jan 1, 1925

By L. A. Wrigglesworth, A. S. Dadson

The orebodies of the Giant Yellow-knife mine occur in zones of schist, in an assemblage of typical Precambrian greenstones which form part of the Yellowknife Greenstone Belt. One of the most interesting problems at the mine concerns the fold-like attitudes assumed by the schist zones. The internal structure of the zones and orebodies provides much evidence of folding. A logical conclusion would be that the zones represent a single horizon which has been folded and drag-folded in the ordinary course of mountain building. However, surface mapping, and correlation of certain marker horizons, in underground work, indicate a homo-clinal succession of steeply dipping flows. If this concept of the geology is correct, the zones must cross-cut the regional strike at a small angle and, in the over-all aspect, the regional dip at a large angle. A mechanical interpretation of the zone structure is presented as a suggestion for the present until new evidence is found.

Jan 1, 1959

By William B. Coker, Vladimir J. Sopuck, J. S. Fox

"Preliminary investigations indicate that organic lake sediments offer some potential for gold exploration within the Canadian Shield of northwestern Saskatchewan. It is also apparent that certain precautions must be taken.Gold is primarily related to the organic fraction of the lake sediments, which, although giving consistant Au contents to those sediments, may restrict the dispersion of Au within the lake itself. It may be necessary to carry out selective extractions on the lake sediments to differentiate between Au related to organic sequestration, indicative of hydromorphic and/ or chemical dispersion, and Au related to inorganics, indicative of mechanical dispersion.Lake sediments are probably only of use for very detailed exploration (i.e. every lake). One to three samples per lake should be appropriate, although a single centre-lake organic-rich sediment sample may be adequate in very small lakes. Each lake sediment sample should be analyzed at least twice and the analytical data carefully monitored and evaluated.The use of As in lake sediments as a pathfinder element for gold is applicable in the search for certain types of gold occurrences.Following detailed lake sediment sampling, basal till sampling can possibly be used to localize areas of potential gold with or without base metal mineralization."

Jan 1, 1982

By Alessandro Navarra, Kristian Waters

Mineral concentrators are designed from preliminary geological data, and are therefore subject to geological uncertainty. This uncertainty has a demonstrable impact on the mining lifecycle, and has motivated stochastic strategic mine planning algorithms. The current paper describes how these algorithms may be extended to consider mineral processing operations in conjunction with open-pit mining operations. In particular, the paper describes an effective way to incorporate variable concentrator feed grade into these algorithms, which is the first step toward more elaborate representations of mineral concentrators. The resulting framework will be able to connect geological data to alternate configurations of the downstream resources, hence comparing the benefit of each configuration, and the corresponding capital investments. Sample computations are presented, comparing the NPV and utilization for several different mineral processing capacities.

Jan 1, 2015

By E. McLaren, J. Sanftenberg, C. Cameron, H. Dello Sbarba

"A Ventilation on Demand (VOD) system has been optimized and maintained at Glencore’s Nickel Rim South Mine (NRS) in Sudbury, Ontario, Canada for the past seven years. The system monitors and controls air quality and quantity through real-time, dynamic automation of primary fans, secondary fans, automated airflow regulators, and air monitoring instrumentation with VentSim™ CONTROL, a VOD software. This paper will focus on the implementation of testing procedures and system maintenance methods. Overall, the results show a consistent reduction in energy usage.INTRODUCTIONThe Ventilation on Demand (VOD) system at Glencore’s Nickel Rim South (NRS) mine in Sudbury, Ontario, Canada, involves the control of two 2,980 kW centrifugal surface exhaust fans with Variable Frequency Drives (VFDs), three 335 kW vane-axial surface intake fans with VFDs, 21 automated airflow regulators, six automated dampers, seven automatic doors and 198 underground auxiliary fans with ON/OFF starters. Additionally, the system monitors airflow at 48 locations, carbon monoxide (CO) at 40 locations, nitrogen dioxide (NO2) at 21 locations, and dry bulb and wet bulb temperature at 21 locations. The VOD system is also integrated with a tagging and tracking system to modulate the ventilation system automatically and in real time according to the presence and position of the personnel and vehicles. The tracking system comprises of 75 vehicle tags with diesel status and hydraulic status (ON or OFF), 440 personnel tags, and 200 tracking zones. Finally, it also involves the configuration and updating of 55 level plan and interactive procedures and 24 daily scheduled events. NRS currently uses VentSim™ CONTROL, Ekahau Tracking and PI Datalink to control, monitor, and configure their VOD system."

Jan 1, 2019

By G. Robert Guillet

"Ontario enjoys the advantage of its proximity to the large industrial market of northeastern North America. Together with Quebec and fifteen nearby U.S. states, an industrial base of more than half the total for both countries is provided by a population of 100 million.Mineral fillers such as barite, calcium carbonate, kaolin, mica, silica and talc are of major importance in the manufacture of paper, paint, plastics, rubber, vinyl tile, carpet backing, putty, caulks, sealants and adhesives. Ontario has all of these minerals, but domestic production falls short of demand in some cases, and mica and kaolin are not produced at all.This paper reviews the market and outlines the distribution of the major filler-consuming plants of northeastern North America. It also identifies the principal producers of filler minerals in the United States and Canada.IntroductionOf all the uses for industrial minerals, mineral fillers are probably the least understood. Originally used primarily to add low-cost bulk to a variety of commodities without seriously affecting their properties, filler minerals have become essential components that enhance and extend the properties of their hosts. Hence the term ""extender"" which, for all practical purposes, is synonymous with ""filler"". Today, fillers and extenders are not solely low-cost additives, but ingredients that provide essential characteristics to the products they fill.The major markets for mineral fillers are paint, paper, plastics, rubber, adhesives and floor coverings. But there are many others: putty, pesticides, wire and cable coatings, caulking and asphaltic compounds, oilcloth, wall-paper, joint cements, inks, sealants and many others. Barite, calcium carbonate, kaolin, mica, silica and talc are among the more important filler minerals discussed in this paper, but there are at least a dozen others. And the increasing practice of coating the mineral surfaces with certain coupling agents or metal stearates is constantly expanding the range of characteristics and hence the marketing opportunities.Whiteness, particle shape, fineness of grind and cost are the principal considerations in selecting a filler, but other characteristics such as weight, opacity, hardness and chemical inertness may be dominant considerations in specific applications."

Jan 1, 1987

By J. G. Kelly

"IntroductionOver the past twenty-five years of improvements to scooptrams In the Ontario Division of Inco Ltd., records indicate that on average, an 8 yard capacity machine at 80% availability will load, haul and dump about 100TPH from an average stoping area. This, essentially, means that Inco mines are limited to 2000 TPD as an approximate maximum production cap per minute. Some of the improvements made to scooptrams over this period have been:• dry disc and oil immersed brakes on larger loaders;• to replace air over hydraulic systems;• modulated shift transmissions;• greater breakout and tramming capacities by using larger engines and buckets;• operators' compartments have been enlarged and better seats,• joystick controls and air-conditioned cabs have been utilized'• major cost savings have been realized through tire maintenance improvements; and• major savings, safety improvements and increased ore recovery by using remote controls.After reciting the improvements listed above, and the list is by no means exhaustive, it is quite obvious that scooptrams are a mature product and that major design or performance improvements will not occur in the futre. Any futher improvements will be incremental in nature. Loading, hauling, and dumping with scooptrams is a batch process and as such is limited in its total output.Continuous Load/Crush/Convey Systems:In order to improve productivity, a radical new system was required. The target was 2000 tons per shift. In 1984, to meet the goal, Inco acquired the rights to a contiunous loader from Canadian Mine Services. Inco made modifications to the original prototype machine, such as: (I) conversion from rail mounted to crawlers for increased mobility; (2) a hydraulic cooling system was added; (3) flight bars were changed from cast to forged; (4) motor horsepower increased to 200 hp from 150 hp. Emerging from these modifications came a machine known as the CL-looo Oscilloader (Fig. 1).The CL-looo Oscilloader is an electric hydraulic 35-ton machine which is crawler mounted and has a drawbar pull of 30 tons. It has an adjustable frequency, oscillating lip which simulates the digging action of a manual .shovel. This action agitates and lifts the muckpile enough to allow it to settle by gravity onto the chain and flight conveyor table which then removes the ore to the tail end for discharge into either a crusher, a conveyor, a truck, or a combination of these.Late in 1985, six oscilloaders were fabricated and put into Inco mines for field trials. At Creighton Mine some early field trials were conducted with a rail mounted continuous loader loading directly into 140 cu.ft. Granby cars. Much of the field testing was in VRM drawpoints with the Oscilloader loading into 20-ton trucks or into Teletrams . At Levack Mine, by puttmg the truck on remote control, it was possible to have the operator run the Oscilloader and load his own truck (Fig. 2). At McCreedy West Mine, Copper Cliff North Mine, and Copper Cliff South Mine, the Oscilloaders discharged directly into 26-ton trucks."

Jan 1, 1988

By W. T. Robson

Introduction Ground failure, violent or otherwise, is a problem to be contended with wherever underground operations are carried out. The character and extent of the failure, whether superficial or of more serious proportions, is determined by a number of factors, among which might be mentioned: the depth and dimensions of the underground workings; the types and distribution of wall rocks; structural features of the ore and enclosing rocks; the degree of metamorphism; the dip of the orebody; concentration of mining operations; the rate of mining; the history of the excavations made on the orebody in question. This last factor implies the consideration of such points as the arrangement and distribution of stoping both past and present, the current sequence of scoping, the type and effectiveness of the support used in old and current workings, and the amount and distribution of unmined parts of the lode. With such a variety of conditions, it is only natural that the situation at one place in a mine will not be the same as that obtaining in another part of the same mine and, more than likely, will be quite different in another property.

Jan 1, 1946

By K. Howard Poulsen

Shear zones are tabular tructures which tend to occur either discordantly within, or concordantly along the margins of, competent rock masse uch as plutons, sill or flows. They contain deformed equivalents of their host rock and are common sites for gold mineralization localized in tructure oriented y tematically relative to the shear zones and internal linear fabric. Apan from genetic implications, hear zone analysis proves useful in exploration for this type of deposit because the zones are generally wider and more continuous than associated mineralization and because there is an element of predictability to mineralization geometry (i.e. vein orientation. plunge).

Jan 1, 1986

By H. Fuchs, W. Hilger, E. Prosser

"The Lone Gull discovery of Urangesellschaft Canada Limited was made in 1974 as a result of extensive exploration activities for unconformity related uranium deposits in the Baker Lake area of the Northwest Territories. The structurally controlled mineralization is hosted in Aphebian metasediments and intrusive granitic stocks located approximately 2 km south of the unconformity between the Lower Proterozoic Aphebian and the Middle Proterozoic The/on Formation.The original discovery was made with a helicopter mounted radiometric system during systematic prospection over the unconformity. Diamond drilling was first carried out in 1977 and continued, with an interruption in 1981, to the present. A total of 25,500 metres and 199 holes have been drilled and outlined three ore zones. Preliminary geological reserves are estimated at some 16 million kgs. U30 8 at an average grade of approximately 0.4%.IntroductionUrangesellschaft initially entered exploration in Canada as a participant in joint ventures in 1968, and was incorporated in Canada in 1974 as Urangesellschaft Canada Limited. Subsequently, UG was among the first companies to apply exploration criteria developed from the Athabasca Basin, namely the Middle Proterozoic unconformity over Archean/ Aphebian basement, for selection of exploration targets in the geologically similar Thelon Basin.The Baker Lake area in the Keewatin District of the Northwest Territories was selected from the extensive Thelon Basin because it had the best accessibility (Fig. 1). The hamlet of Baker Lake located close to the geographical centre of Canada, is largely an Inuit settlement with a population of approximately 1,100 inhabitants. The distance from Baker Lake to the Lone Gull property is about 80 km. Baker Lake is connected to the tidewater of Hudson's Bay via Chesterfield inlet and is serviced by scheduled domestic flights several times weekly from Churchill, Manitoba, about 650 km to the south."

Jan 1, 1986

By John Taylor

"The Highvale Mine in Alberta is owned by TransAlta Utilities Corpora/ion and operated by Mana/fa Coal Lid. It is the largest coal mine in Canada and in 1982 supplied 8.6 million 1onnes of sub-bituminous ""B"" coal to TransAlta's Sundance Ceneraling Plan/. Annual produclion is scheduled to increase in 1983 when the firs/ unit of the new Keephil/s Generating Plant comes on stream and is expec/ed to exceed 11 million tonnes by 1985 when the second unit is commissioned. Coal is mined from several pits in a multi-seam operation. Comprehensive maintenance, drainage and environmental programs form a major part of the operation.IntroductionThe Highvale Mine is located eighty kilometres west of Edmonton, Alberta on the south shore of Lake Wabamun (Fig. I). The mine is owned by TransAlta Utilities Corporation (T.A.U.) and is operated by Manalta Coal Ltd. In 1982, 8.6 million tonnes of coal were supplied to T.A.U.'s 2100 MW Sundance Generating Plant, making it the largest producing coal mine in Canada. By 1985, with two 375 MW units on line at T.A. U .'s new Keephills Generating Plant, annual production is estimated to exceed eleven million tonnes. The generating plants accept crushed unwashed coal from the mine via the coal handling plant system conveyor belts. The coal is classified as sub-bituminous ""B"" and has an average heating capacity of 18.6 MJ I kg.HistoryPrior to 1943 only small scale mining took place in the Highvale area. Between 1943 and 1961 two strip mining companies, Mount Royal Collieries and Continental Collieries operated on the present mine site. Both operations excavated coal along the south shore of Lake Wabamun."

Jan 1, 1985

By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012