Search Documents

By S. K. Sharma, Sanket Bacchuwar, Prabal Kumar Agrwal, G. V. Rao

"Iron ore processing industries play a vital role in the Indian economy. At present Iron ore of around +64% Fe is used for production of Iron through blast furnace. To produce +64% Fe from low/medium grade ores, crushing & beneficiation is compulsory. But during these processes, large amount of slime is generated. It is estimated that 18% -25% of tailing is generated during the processing of iron ore. The iron ore slime is discarded because of its particle size and chemical composition not being suitable as feed to the blast furnace. Although the fines/slimes can be agglomerated to larger particle, the alumina to silica ratio which is normally more than one pose serious problem during sintering process and subsequent smelting in blast furnace. The alumina content in the slime needs to be reduced for it to be used as the feed for blast furnace. The sample assayed 61.40% Fe, 7.68% SiO2, and 1.52% Al2O3, LOI 2.63% and all other elements were found in critical limit. A series of 27 tests were conducted by using a spiral for optimisation of process parameters to produce a pellet grade concentrate from the stacked slimes obtained from Kirandul. This paper deals with the optimisation studies of various parameters of a spiral concentrator and helps to utilize the fines from tailing ponds.INTRODUCTIONReserves of high-grade iron ores are diminishing all over the world at an alarming rate. As a result, alternative ways of augmenting and conserving precious and non - renewable natural resources are being seriously considered. One such attractive option is the recovery of metal values from slimes / tailings. Iron ore tailings containing around 48 - 60% Fe are generated from the iron ore washing plants and are disposed into tailing ponds without any further utility. These tailings in the form of slimes are not suitable in iron and steel making due to the presence of higher amount of gangue constituents. Several beneficiation techniques have been tried from time to time to reduce the gangue so that the beneficiated products could be effectively used."

Jan 1, 2016

By L. Voisin, G. Damm

"In order to develop a new pyrometallurgical process for eliminating detrimental arsenic and antimony from the impurity-rich matte produced from copper concentrate, and for treating the occasionally generated speiss in nonferrous smelting processes, the phase relations in the Fe-Cu-S-As-Sb system saturated with carbon at 1473 K were investigated. The distribution of elements between the condensed phases at the miscibility gap, where three equilibrated phases of iron-rich alloy, copper-rich alloy, and matte coexist, were also studied. The investigation was carried out by performing a series of laboratory scale experiments in an electrical furnace at 1473 K, followed by a quenching method on the final stage. The samples obtained from the experiments were analyzed by using Inductively Couple Plasma (ICP), Atomic Absorption Spectroscopy (AAS) and Carbon Infrared Spectrometry (CIS) techniques.The results were compared with previous investigations for the Fe-Cu-S-As-C and Fe-Cu-S-Sb-C systems and discussed on the basis of the molar fraction distribution for both arsenic and antimony in the matte phase at five different matte grades. It is expected that by using this phase separation technique it might be feasible both, the cleaning of a complex copper matte and the elimination of arsenic and iron together with an acceptable amount of antimony into the iron-rich alloy phase, which can be discarded as a harmless and smaller deposit."

Jan 1, 2014

Between 1993 and 2003, a series of AG and SAG mill pilot plant trials were conducted using Hardinge Ical pilot plant scale SAG mills on numerous ore samples and ranging across a wide variety of operating conditions. The data from these tests were used to evaluate the design of SAG and AG mill circuits for over a dozen projects, of which about half were eventually constructed and commissioned. The data were also used in the development of SAG mill modelling, scale-up and simulation procedures by several consultants who had access to part of the data set. Recently, we have had the opportunity to bring this data together and further analyse the consolidated dataset. This paper reports on the outcomes of this analysis that has identified the impacts of different AG/SAG circuit flowsheets and operating conditions on energy efficiency and operating cost.

Jan 1, 2012

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011

By B. McHenry, A. E. Wraith, P. J. Mackey

The Wallaroo smelter on the Yorke Peninsula, South Australia commenced smelting operations in 1861 treating ores from the nearby Moonta and Kadina mines. The plant expanded and modernized on several occasions and was a leader in the successful introduction of new technology to improve operations. It operated continuously until 1923 when local mines became exhausted; in the closing stages of the 19th century it was the largest copper smelter in the world outside of those in Swansea, Wales. In 1892 a small electrolytic refinery was established at Wallaroo, the first in Australia, based on principles developed by Elkington at Pembrey, Wales in 1869. The Wallaroo refinery was specifically built to recover gold and silver from copper produced by smelting gold-containing feed materials shipped from Western Australia. This first venture into electrolytic refining was replaced in 1903 by a somewhat larger refinery which, although modest in size for its time, with a capacity of about 1000 tonnes of cathode copper per year, was very productive in precious metals. Anode copper was produced by an updated version of the reverberatory-based Welsh process until 1910 when barrel-type pneumatic converters were introduced based on American practice; subsequently, anodes were cast by tapping the precious-metals rich "bottoms" portion of converter copper as produced at about one-fifth into the copper blow. The present paper describes the Wallaroo refinery, its anode supply and products, supported by initial observations on a sample of a Wallaroo cathode held in the collection of the South Australia Museum, Adelaide SA, Australia. INTRODUCTION Australia ranked 6th in the world for copper mine production in 2018, with an output of 918,000 tonnes of mined copper, after Chile, Peru, Congo, China and the USA; about 40% of Australian mined copper was smelted in the country. Interestingly, the world ranking of Australia in mined copper has, with a few variations, remained about the same for more than 100 years – of interest, it was also the 6th largest country for copper production at 21,089 tonnes in 1899. At that time, all or most of the copper was smelted in the country (Mackey, 2016). Copper was first discovered in Australia in 1842 in South Australia not far from Adelaide; additional copper discoveries in the region soon followed. At first, copper ore was shipped to Swansea, Wales for smelting (Bampton, 2003). However, in addition to the long, 150 day one-way sea passage, it seems Welsh smelters preferred higher grade of ores – these aspects and likely a mood in the new colony to be independent of Swansea (Evans, 2014) evidently encouraged local smelting at the mine sites using small, Welsh-type reverberatory furnaces fired with hardwood as fuel and operated by Welsh and Cornish migrants. The first large copper smelter in Australia commenced in 1848 at Bremer, near Callington some 60 km east of Adelaide. With larger discoveries on Yorke Peninsula, the Wallaroo copper smelter at Wallaroo Bay on the west coast of the peninsula commenced operations in 1861 (Bell & McCarthy, 2008). Thus began one of the most successful, and in its day, one of the most advanced and innovative plants in Australia if not the world. In the late 1860s, it was considered one of the largest copper smelters in the world (Bell & McCarthy, 2008)

Jan 1, 2019

By C. H. Stockwell

THE Eastern Townships of Quebec have been the chief Canadian source of chromite. Production, however, has never been large and, except for a period of steady but small output between 1894 and 1909, mining has been active only in war time. The known deposits are too small or too low grade to compete with overseas sources in normal times. During the last war, shipping difficulties and a greatly increased demand in the United States resulted in high prices and a ready market for low-.grade material. The Quebec chromite industry flourished and played an important part in relieving the wartime shortage. Shipments in 1918 .amounted to 15,600 tons of crude ore and 6,400 tons of concentrates. At the outbreak of the present war it was natural to turn again to the Quebec field as a possible source of this strategic mineral. Some of the old properties have since been opened by private and government money and some new deposits have been found. Total mill capacity is 750 tons per day, as compared with 200 to 300 tons in 1918. During 1940, 1941, and 1942, about 85 chromite deposits were examined by the Geological Survey in a belt 100 miles long and up to 7 miles wide. A part of this belt, about 35 miles long, in which the geological features ?were not well known, was mapped on a scale of 1/2; mile to an inch.? Small ..areas around some of the deposits were mapped in detail, on scales of 20 to 200 feet to an inch. Some geophysical work was done but did not result in the discovery of ore. Prospecting by stripping and trenching was then undertaken and chromite ore was uncovered at several localities. The above work was done by the writer and by J. W. Ambrose, who has kindly contributed his results for incorporation in this paper. Y. O. Fortier actd as assistant in the geological work and, in 1942, was in charge of a sub-party engaged in geological mapping. The author is indebted to H. C. Cooke and J. W. Ambrose for reading the original manuscript and for offering many helpful suggestions for its improvement.

Jan 1, 1944

By E. A. Morris

It has been shown that Alberta oil-sands fluid coke can be effectively used to reduce SO2 to elemental sulphur while simultaneously producing sulphur-impregnated activated carbon (SlAC). In the capture of mercury from industrial flue gases, SIAC has proven to be a highly effective adsorbent material. The current research aims at developing an existing SlAC technology to meet the needs of copper smelters for mitigating both mercury and SO2 emissions, while making elemental sulphur as a co-product. The challenge behind this undertaking is that these flue gases generally contain percent levels of 02 and H20 vapour (2-12%). The focus of this study is therefore on the feasibility of reducing SO2 using fluid coke under copper smelter flue gas conditions, as well as the optimisation of SIAC properties for capturing vapour phase mercury. It is hypothesised that mercury capacity is strongly affected by the 02 potential of the activation gas due to changes in surface sulphur types arising from different reduced sulphur species. To verify this, gas chromatography is used to analyse the reaction products while XPS and XANES will be used to describe the nature of sulphur on the SlAC surface. CVAFS analysis of mercury capacity will finalise the hypothesis assessment. Preliminary results indicate that 02 at 5% does not play a significant role in SSA or pore development. As expected, increased residence time contributes to SO2 reduction and elemental S yield.

Jan 1, 2007

By Jin Liu, Torstein A. Utigard

At its Copper Cliff Smelter, Vale Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. Coke supplies a minor proportion of the process heat requirements, limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Extensive experiments were conducted in a miniplant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. The introduction and description of the experimental set up were given in Part 1 of this paper and an early paper published in Yazawa symposium1 together with the results and some in depth discussion on metallurgy. This paper intends to discuss the kinetics of the miniplant flash furnace testwork.

Jan 1, 2015

By A. Gakwaya, K. Ba, M. Guillot, J. Levesque

"In the aerospace industry, parts requiring tight dimensional tolerances and high mechanical properties are often produced by forging. This forming process allows for an optimal use of the material and can produce high quality parts at a reasonable cost. Thanks to CAD techniques, it is now easier to predict flow profiles and in-process defects occurrence as well as wear of the forging dies. However, in order to determine the properties of the forged part with computer simulation methods, a good material constitutive law is a prerequisite. This paper presents a virtual manufacturing process modeling for the closed die forging of a workpiece performed with Abaqus. The hot closed die forging is a regular process applied to manufacture metallic components used in aerospace industry. In this forming process, the material flow and final properties depend on the microstructure evolution during the process that is why it is important to include the microstructure effects in the material model. Based on the stress-strain data measured experimentally, the material parameters of the standard (classical) Johnson-Cook constitutive model and of a modified Johnson-Cook constitutive law including the microstructure effects have been determined. The obtained simulation results are compared with the experimental results for validation.INTRODUCTIONDue to their good physical and mechanical properties such as ductility, fatigue strength, corrosion resistance and rupture, aluminium alloys are often used in the aeronautic and the automobile industries. In this work, we present the forging of an Al-Zn-Mg-Cu alloy, a high strength aerospace alloy recognized for his good combination of physical and mechanical properties. The forging process is simulated in Abaqus Explicit using both the standard Johnson-Cook law (Johnson & Cook, 1983; Hor, 2011; Lin et al., 2012), and its modified version as proposed by Andrade et al., (1994). The Johnson-Cook law offers the advantage of considering the coupled effect of the plastic strain, the plastic strain rate, the temperature of forging and the hardening effect. However, it is a phenomenological model which does not account for the effect of the microstructure evolution. In this work, a modified Johnson-Cook model implemented in a user subroutine is used. It includes the effect of the dynamic recrystallization phenomenon during the hot deformation. The dynamic recrystallization has a noticeable influence on the microstructure and on the properties of the material. The term dynamic means that the process starts and acts during the deformation and this is different from the static mechanism of recrystallization which occurs during an annealing and after cold or hot deformation. Since properties of the alloy used in this work are not readily available in the literature then characterization tests have been done at various temperatures and strain rates, in order to determine the thermomechanical properties and the material behavior during the process of hot forming, more precisely during the hot forging process."

Jan 1, 2016

By David Rahal, Saul Ortiz, Maria Escobedo

The general trend in the minerals industry is towards the processing of fine grained, disseminated mineral deposits. This has led to an increase in the number of fine/ultra-fine grinding installations using stirred media mills. The challenge is that both the equipment type and the mineralogy of the deposit have an effect on specific energy consumption. Fresnillo PLC recognized this issue and addressed it by providing samples for testing in a laboratory regrind system. The objective of the test program was to determine the specific energy required to achieve a product size of 10 µm (P80). A specific energy plot was generated for both a lead and zinc flotation concentrate. It indicated that 34 kWh/t and 51 kWh/t were required for the two samples (Pb and Zn respectively). This difference highlights the effect of mineralogy on the energy required for fine grinding. The regrind feed and products were submitted to a range of basic mineralogy tests to quantify the mineral differences that could have changed the specific energy requirements. These tests provided general mineralogy, documented optical textures, and provided particle size microscopy. The lead concentrate was found to contain significant amounts of silicates in addition to the dominant sulphide, pyrite. The zinc concentrate was determined to be mostly sphalerite with minor amounts of quartz, chalcopyrite, pyrite and galena. The material testing results illustrate the importance of basic mineralogy studies in conjunction with comminution testing to determine specific energy consumption.

Jan 1, 2016

By K. Scholey, S. Marcuson

As high grade nickel sulphide ores are being depleted and with the continuing challenges experienced in economically processing nickel laterite ores, it is important to investigate technologies that can extract nickel from low grade ultramafic ores which are present in large quantities worldwide. In the Thompson Nickel Belt, there are some hundred million tonnes of mineralization that are potentially amenable to surface mining. Since the original discovery of the Thompson orebody, recovery of nickel from these ultramafic deposits has been an elusive goal. Research and development projects as well as commercial processing have been attempted. In the 2000's as other resources became scarcer, a major drilling, mine evaluation and research project was initiated at Vale. In 2007, Vale Base Metals Technology Development invited Cytec and potential academic partners to participate in an industry-university research consortium with the goal of developing new technologies and methods of processing the ultramafic deposits. Three university professors, J. Finch of McGill, P. Somasundaran of Columbia and R. Pelton of McMaster accepted, each group attacking the problem with a different approach. This paper describes the management of the research consortium and the significance of the results from Vale's perspective. The next four papers in this session will summarize the project and results from the partners' point of view. Vale is pleased to share the experience of the collaborative research and development with the mining industry.

Jan 1, 2011

By C. A. Sutherland

"Smelting of copper-gold ore from nearby Rossland mines started at Trail in the 1890s. As ore from the Rossland mines became exhausted, lead smelting offhand-sorted galena orefrom other British Columbia mines was initiated. With the development of flotation technology for the separation of lead, zinc, and iron sulphides in the first two decades of this century, the large Sullivan orebody at Kimberley, British Columbia, became the foundation for the growth of a major zinc and lead smelter at Trail. Lead smelting began in 1901, electrolytic zinc in 1916, and by 1984, the Trail metallurgical complex had produced 10 million tons of each metal. Its present capacity is 270000 tonnes per year of zinc and 110 000 tonnes/year of lead.This paper reviews the history of technological changes in the Trail production plants, emphasizing the zinc plant modernization program started in the 1970s, and also the planned introduction of the QSL oxygen lead smelting process in the late 1980s. Lead modernization will increase production capacity to a maximum of 160000 tonnes per year.IntroductionCopper-gold ore was discovered at Rossland, British Columbia, in the year 1890, starting a mining industry that was to last over three decade s. Selected ore was at first transported at high cost to distant U.S. smelters, so there naturally followed a decision to construct a small copper smelter to process the local ore to matte. It was built in 1896 at the mouth of Trail Creek on the Columbia River, about 10 km from Rossland. This little smelter was to develop and diversify in the next 90 years into the world's largest lead-zinc produce.The mining boom that occurred in the northwestern United States and southeastern British Columbia in the period of 1890 to 1910 saw the brief operation of many small local smelters. The only one to survive was the smelter at Trail. The circumstances that permitted its continued life and subsequent growth, form a fascinating history of business deals, litigation, and steady technical progress.Early investment in local railway transportation and options by F.A. Heinze, the smelter' s founder, attracted the attention of the Canadian Pacific Railway Company, which purchased Heinze' s assets in 1898. This provided the capital base for survival and growth of the smelter, which remained and prospered under the Canadian Pacific umbrella for almost ninety years. It was registered as the Consolidated Mining and Smelting Company of Canada Limited in 1906; in 1966, this name was shortened to Cominco Ltd."

Jan 1, 1988

By Lynn I. Kelley

Potash is the primary industrial mineral produced in Saskatchewan, followed, in terms of gross value, by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium chloride brine and "clinker." Potentially economic deposits of kaolin, diamond and building stone are under evaluation.

Jan 1, 2001

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977

By A. Lloyd, Montgomery, J. Jorgesen, W. J.

"Coals are ranked according to their degree of metamorphism or progressive change in the natural series from lignite to anthracite. The reader is referred to ASTM Standard D-388, ""Standard Classification of Coals by Rank"" for a detailed description of the system in use throughout North America including Canada.Fixed carbon and calorific value (expressed in Btu/ lb) calculated to the mineral-matter-free basis have been chosen as the main characteristics from which rank is established. Higher rank coals are classified according to fixed carbon content, lower rank coals according to the calorific value on a ""moist"" mineral-matter-free basis. Certain adjacent groups are differentiated according to their agglomerating (caking) properties. ""Moist"" refers to inherent moisture. Referring to Table 1, coals having calorific values greater than 14,000 Btu/lb on a moist mineral-matter-free basis and fixed carbon of 69% or more on a dry mineral-matter-free basis are classified according to fixed carbon. Coals having calorific values of less than 14,000 Btu/lb on a moist mineralmatter-free basis are classified according to calorific value on a moist mineral-matter-free basis. Agglomerating coals having 69 to 86% fixed carbon on the dry mineral-matter-free basis are classified in the low or medium volatile group of the bituminous class according to their volatile matter content. Agglomerating coals having calorific values between 10,500 and 11,500 Btu/lb are classified in the high volatile C bituminous coal group; nonagglomerating coals in the same calorific value range are classified in the sub-bituminous A coal group."

Jan 1, 1985

By A. A. Bakke

"The Fort Knox gold deposit is hosted within the Fort Knox Pluton, a Cretaceous multiphase granitic body that intrudes the Fairbanks schist. Gold occurs along the margins of stockwork veins and veinlets, quartz-filled shear zones, and along fractures within the granite. The mineralization is generally sulphide-poor and closely associated with trace amounts of bismuth, tellurium and to a lesser extent with molybdenum and tungsten. At present, proven/probable reserve estimates, based on a cutoff grade of 0.39 g/t Au, are 158.3 million tonnes grading 0.83 g/t Au.The Fairbanks schist comprises the bulk of the country rock. The dominant lithologies present include muscovite-quartz schist and micaceous quartzite. Immediately north and south of the main orebody, mixed metamorphic lithologies of the Cleary sequence, a subunit of the Fairbanks schist, have been mapped. Development of local zones of weakness, most likely due to a broad regional warping event, resulted in brittle-ductile deformation and activation of a northwest-southeast shear couple between contrasting lithologies.The Fort Knox Pluton consists of at least three phases based primarily on textural differences. Intrusion of a fine-grained granite was followed by a medium-grained porphyritic granite. The youngest intrusive phase is a coarse-grained, seriate porphyritic granite, the Vogt Stock. The Vogt Stock forms an elongate dome with the axis in the east-west direction. Structures displayed in the overlying units, believed to be the result of doming, include tension fiSSUres and longitudinal fractures.Premineralization fractures, the result of the magmatic doming, provided conduits for initial stockwork quartz vein development and quartz enrichment in shear zones. Weak development of vein-controlled phyl/ic, potassic, albitic, and argillic alteration styles are present. Evidence of a late thermal event resulting in a low-temperature alteration assemblage of calcite + zeolite (stilbite) + chalcedony + clay occupies breccia zones, joint surfaces, and fractures within the granite."

Jan 1, 1995

By J. M. Hong, H. K. Zheng, R. Hu, C. B. Zhou

The Jinping-I double curvature arch dam, located in the middle reach of the Yalong River and with a maximum height of 305 m, is the world highest dam of the same type that has been completed. Since the second and third periods of the reservoir impounding, after which the reservoir water level was raised by about 200 m, a significant amount of leakage was observed out of the drainage holes deployed in the lowest drainage tunnel at the left-bank abutment at EL. 1595 m, with a pressure of 0.3 MPa at one typical hole when it was blocked. In this study, a number of analyses including water quality analysis, digital borehole imaging, tunnel geological mapping and in-situ groundwater monitoring were performed to investigate the source of leaking, the leakage passages and the performance of the grouting curtains. An inverse modeling procedure combining the orthogonal design, finite element forward modeling of the transient seepage flow, artificial neural network and genetic algorithm was invoked to further evaluate the permeability of the foundation rocks whose permeability was underestimated in design, using the in-situ measurements of flow rate and piezometric head. The geological structures that lead to the leakage were identified and the seepage flow behaviors in the dam foundation and the left bank abutment were assessed. Given the connectivity nature of the sub-vertically oriented fractures that induce the leakage event, it is found that some of the drainage holes with relative larger amount of discharge could be closed or blocked for reducing the amount of leakage without remarkably increasing the pore water pressure in the foundation rocks.

Jan 1, 2015

By Olav Mejia

The rising energy costs and environmental considerations in mining necessitate the development of energy-efficient copper and gold processing plants. This paper presents an analysis of technical strategies aimed at reducing energy consumption in these plants. Key approaches include the integration of advanced ore sorting technologies, High Pressure Grinding Rolls (HPGR), Coarse Particle Flotation (CPF), and high-intensity flotation. Ore sorting enables early-stage waste removal, reducing the downstream processing load and associated energy use. HPGR technology, recognized for its energy efficiency, contributes to significant energy savings in comminution circuits by reducing reliance on traditional grinding methods. CPF technology further optimizes flotation performance by enabling the recovery of larger particles, thereby decreasing the need for fine grinding and reducing overall power demand. High-intensity flotation units enhance separation efficiency and mineral recovery in a compact footprint, offering further reductions in energy consumption. Together, these technologies provide energy saving opportunities to achieve a more sustainable and economically viable processing operation. This paper evaluates the effectiveness of each method, highlighting their potential impacts on energy consumption, operational efficiency, and cost-effectiveness in copper and gold processing

May 4, 2025

By R. R. Rogers

Abstract The degree of cathodic protection of steel and the anode corrosion rate were determined when anodes and waters of different compositions were used at temperatures similar to those in domestic hot water tanks. Twenty different anode materials, sixteen of them magnesium-zinc-aluminium alloys, were immersed in six different synthetic waters resembling those to be found in various parts of Canada. The results showed that (1) both the degree of cathode protection and the average anode corrosion rate are affected materially by the composition of the anode material and of the water; (2) poor cathode protection is associated with low anode corrosion rate; (3) when the cathode is fully protected, the anode corrosion rate may be comparatively low or comparatively high, depending upon the composttion of the water; (4) an important relationship exists between the magnesium content of the preferred anode and the composition of the water; (5) the degree of protection is increased as the SO4 + Cl concentration of the water is increased and thus as its specific resistance is decreased. Introduction Fairly recently, the use of the active metal magnesium for the cathodic protection of less active metals has received a considerable amount of attention. This interest has been stimulated by the fact that the wartime demand for magnesium was greatly in excess of the present peacetime demand and there is a natural desire to continue operating the large magnesium plants which were built during the war. Information regarding the use of zinc and aluminium for this purpose also has been published. There is a great demand for domestic hot-water tanks which will resist corrosion satisfactorily. This problem is rather complex in view of the fact that the composition of the water used in such tanks varies greatly and depends upon the locality. The present investigation deals with the effect of water composition and anode composition on the cathodic protection of steel under conditions approaching those which exist in hot water tanks.

Jan 1, 1948

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014