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By R. Scheepers

"Abstract -Mineral deposits and prospects of the Pan African Saldanian orogenic belt in the south­ western Cape Province South Africa, are reviewed. Despite the entire absence of operating base or precious metal mines in the area, this study has established at !east four metal associations that offer enticing exploration potential .The poly-phase deformed, low-grade metamorphosed volcano-sedimentary Malmesbury Group constitutes a complex, poorly understood supracrustal sequence that has been loosely subdivided into the Tygerberg, Swartland and Boland tectono-stratigraphic terranes by northwesterly trending fault zones. Syn- and post-tectonic granitoids of the Cape Granite Suite selectively intruded these terranes. Early S-types preferred the Tygerberg terrane whereas the later I-types dominate the remaining areas. Anorogenic A-type granites, however, occur in all three domains. Known metallization is directly or indirectly related to the intrusives, yet syngenetic deposits are conspicuously absent from the supracrustals. Four metal associations have been identified.•,Cassiterite-wolfrarnite (± Au, Cu, Mo, Fe-sultides) in quartz and quartz/aplite veins hosted by tourmalinized and locally greissenized S-type granite. Similar exo-granitic veins occur in proximal metamorphites.•,Juxtaposed disseminated, stockwork, breccia and vein style Cu-Mo-Fe-(Au)-sultide mineralization hosted by matie to intermediate intrusives of high K calc-alkaline, 1-type affinity.•,Cu-Mo-Au-sultides hosted by hydraulic breccia pipes, stocks and veins occurring in anorogenic A-type alkali feldspar granites and amphibole quartz syenites.•,Scheelite with minor Cu-Mo-sulfides and Au-associated with endo- and exo-skarns spatially related to I-type monzogranite, granite and alkali feldspar granite .The first three associations occur along the Yzerfontein-Helderberg-Zone, a 180 km lineament in the Tygerberg terrane, a zone exploited by syn-, late- and post-tectonic intrusives and their related mineralization. The fourth association is typical of the Boland terrane. The spatial and temporal relationships between the various metal associations is interpreted as the result of sequential intrusion of relative early high level S-type, followed by intermediate level I-type and finally anorogenic A-type granitoids during the evolution of a contracting continental margin arc and its inner arc. This plate tectonic setting suggests subduction in an easterly direction underneath the Kalahari craton. The spatial configuration of the various terranes at the present erosional levels is the result of rifting and significant differential vertical displacement following cessation of subduction, a terminal tectonic event possibly synchronous with intrusion of the A-type granitoids.Near surface preserved roof zones and cupolas of both S- and I-type granitoids in the Tygerberg and Boland terranes, respectively, render these areas extremely prospective for Sn, W, Mo and Au mineralization. The presence of intermediate to mafic volcanics, a diversity of calcareous lithotypes and favorable plate tectonic setting of the Malmesbury Group suggest potential for the thus far elusive VMS, MVT and Sedex base metal and minor precious metal deposits."

Jan 1, 1994

By M. T. Shehata, R. W. Revie, M. Elboujdaini

Environmentally assisted cracks in linepipe steels are initiated either as a result of stresses in combination with environmental effects, as in stress corrosion cracking (SCC), or as a result of trapped hydrogen in the steel, as in hydrogen-induced cracking (HIC). To understand better the mechanism of the crack initiation process, key metallurgical and environmental elements that can affect the cracking phenomena were investigated and are reviewed in this paper. The complexity of both cracking phenomena results from the dependence of SCC and HIC on multiple metallurgical, mechanical, and environmental parameters that may all influence both crack initiation and propagation; e.g., composition, microstructure and non-metallic inclusions in the steel, applied stress, water chemistry in the field, and ionic concentrations in the groundwater near the pipe surface to name a few for SCC. In addition, for HIC phenomena, one can add the concentration of H2S in the fluids transported in the pipe as well as concentration of CO2, pH, etc. In this paper, cracking of linepipe steels is analyzed critically, with particular attention to the crack initiation process. The paper is divided into two parts: The first part covers SCC and the second covers HIC.

Jan 1, 2005

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948

By M. Cala

Underground coal gasification is technology which enables energy to be extracted from coal beds where mining by means of classical methods is either impossible or uneconomical. The process of coal gasification itself is a complex phenomenon which includes chemical and physical processes: thermal, hydrological and mechanical. Additionally, the analysis of underground coal gasification is difficult to carry out for environment reasons, this being due to the local characteristics of the areas where it is carried out. This paper deals with interaction of geo-reactor with surrounding rock mass, it omits the chemical processes inside geo-reactor itself. Due to the complexity of the processes proceeding and during underground coal gasification coupled with minimal practical experience in using this technology, it is difficult to estimate its influence on the surrounding rock mass. Within this scope, the use of numerical programs can be useful. This paper presents a trial of modeling the processes accompanying underground coal gasification. The processes proceeding and during the underground coal gasification are characterized, and the significant, specific phenomena are discussed, with respect to the influence on the surrounding rock mass. For the chosen processes, examples of numerical calculations are presented. These enabled conclusions to be drawn and also provided directions for the modeling of the underground coal gasification processes.

Aug 1, 2013

By T. Fekete, D. L. Flocks, R. T. Hart

The plugging effect of bacteria was investigated by injecting various concentrations of dead bacteria cells though sandstone cores. Pressure profiles along the cores were recorded periodically during the injection cycles. The plugging effect was analyzed using a plot of the ratio of reduced permeabilities to the initial permeability versus input volume. Results indicated that Tock permeability has little effect on plugging, but that the concentration of bacteria in the injection water has a significant effect on plugging characteristics. The pressure profile curves showed that bacteria penetrated several inches through the core but that the greater portion of the bacteria accumulated at the in-put end of the core.

Jan 1, 1960

By John Jiang, Brian R. Hart, Stamen S. Dimov, Aparup Chattopadhyay, Barun K. Gorain

"This paper presents a systematic approach to metallurgy diagnostics using an integrated gold deportment methodology developed for complex refractory gold and copper-gold ore bodies. Quantification of gold deportment for these ore bodies is a challenging task due to reasons such as lower grades, high variability of visible and invisible gold content in different sulphides and iron oxide phases, significant presence of disseminated and composite carbonaceous matters along with associations of various copper sulphide phases. Some case studies are presented in this paper to demonstrate the value of a high confidence gold deportment methodology in developing insights for problem diagnostics and to identify opportunities for metallurgical improvements. A holistic approach involving different fields of expertise is critical for successful development and delivery of solutions for complex ore bodies.INTRODUCTION Studies were initiated on various complex ore deposits and also on samples representing various process streams. These complex copper-gold single refractory, double and triple refractory gold ores are mainly composed of silicates and/or carbonates with moderate amounts of clay and mica, along with minor amounts of sulphides and organic carbonaceous matter. Variable proportions of visible gold and “invisible gold” (sub-microscopic gold) were noted in different mineral phases for various ore types and process stream samples. Invisible gold commonly occurs as solid solution or as colloidal-sized particles in different sulphides and other phases for different refractory ores. The dominance of invisible gold and presence of highly preg-robbing along with finely disseminated carbonaceous matters adversely affects gold recovery in flotation and leach circuits for most of these double and triple refractory ores. This paper discusses applications of an integrated gold deportment technique developed for different types of gold and copper-gold ores, namely, complex copper-gold, double and triple refractory gold ores (Chattopadhyay & Gorain, 2014; Chattopadhyay et al., 2016). Various process streams from flotation and gold leaching circuits were investigated. Different concentrates and tailings samples from flotation circuits whereas feed and discharges from pressure oxidation (POX) and carbon-in-leach (CIL) residues were used from gold processing circuits."

Jan 1, 2017

By Lewis Finch

Oil and .gas reservoirs exist under pressure within the pore spaces of rock structures or traps. Wells are drilled to produce these reservoirs. Under primary operation, the natural energy of expanding fluids in and adjacent to the reservoir forces or drives oil and gas to the wells. There are three basic sources of energy: dissolved gas, water, and gas cap. Typical recovery by primary methods is only 10 to 25 per cent of the oil in place for the dissolved gas drive but is generally higher for the others. Secondary recovery involves the injection of water or gas to supplement natural energy, thereby increasing recovery over that obtainable by primary operation alone. In many cases ultimate recovery with secondary methods is 1.2 to 2.0 times the expected primary recovery. The type programme adaptable in a field depends on its 'primary performance and on certain reservoir characteristics. In the United States, application of secondary recovery methods is becoming increasingly important. About 22 per cent of United States oil production now comes from fields in which injection projects are operating. In 1953, nearly 1.4 million barrels of oil daily came from such fields, more than double the amount in the early 40's. Ultimate primary recovery from known pools is estimated at roughly 73 billion barrels. Secondary recovery projects already in operation will increase this to almost 80 billion, an increase of almost 10 per cent. Unitized secondary recovery projects have been very successful. From unitized projects alone, industry reserves of oil in the United States have been increased by 3 1/2 billion barrels. In Canada, secondary recovery has not been so wide spread mainly because D-3 reef reservoirs which have held the major reserves are under water drive. However, appreciable amounts of water are being injected in the Redwater D-3, Leduc D-2 and Joarcum Viking reservoirs, and gas in the Golden Spike D-3. In both countries, possible achievements in increased recovery through secondary recovery methods now in use and by new ones which may be developed through research and field trial are a challenge to the scientist and the industry.

Jan 1, 1956

By Jun Xiao, Xiaodong Li, Chunming He, Daixiong Chen

"Benzohydroxamic acid with double dentate can react with copper to form cyclic hydroxyl oxime acid copper chelate, indicating a good selectivity for copper oxide minerals flotation, especially for malachite. The flotation results of the pure malachite mineral show a strong synergistic collecting effect between hydroximic acid and xanthate at a ratio of 3.5:1, achieving a malachite recovery of 95.5% when certain sodium sulphide is used as a sulphidizing agent in the optimal pH range. Thanks to the synergistic collecting effect, the flotation recovery of malachite of a real refractory ore flotation ,can reach over 92% under the optimum condition, a 12% higher than the recovery achieved with the conventional collectors. In industrial application, the flotation of the copper oxide minerals is improved , leading to a high efficiency utilization of copper oxide resources.INTRODUCTIONBeneficiation of copper oxide ore is one of the recognized challenges in mineral processing industry. Copper oxide ore is a vital component of copper resource in the world, which has abundant reserves. Majority of sulphide deposits has oxidized zone on the top, and some deposits are oxidized to become the large and medium-sized oxide deposits (Willam & Chavez, 2001). Most copper oxide ores have problems in processing such as high slime consumption, poor floatability, complex ore property and low flotation recovery, so it is of great significance in beneficiation of copper oxide ores to develop an efficient collector, especially for malachite (Fu & Gu, 1997; Wen, 2010; Riet, Kier & Elford, 1980). At present, sulphidization-xanthate flotation is the most important method for treating copper oxide ore. In recent years, due to the decreasing ore grade, the utilization of refractory copper oxide ore draws more and more attention (Zhou, 2003), except for sulphidization-xanthate method, chelating flotation method (Lu, 2009), chemical beneficiation method (Lenormed, Salman & Yoon, 1979), microwave radiation flotation method, hydrothermal sulphidization-flotation method (Mao, Wen & Fang, 2014) and ammonia leaching of sulphide precipitation-flotation method (Lekang, Stevik & Bomo, 2003) have occurred."

Jan 1, 2016

By F. Baczek, S. S. Rocks, D. Chaiko, T. Walters

The atmospheric leaching of chalcopyrite concentrates using acidic ferric sulfate lixiviants is well known to suffer from slow leach kinetics and poor copper recoveries. A number of approaches have been proposed for improving both leach kinetics and recoveries in this system. Many of these, while effective, suffer from high CAPEX and/or OPEX. As many mine sites begin transitioning from heap leaching of copper oxides to processing of primary copper sulfides, cost-efficient leach processes that are compatible with existing SX/EW processes will be needed to maintain existing cathode production. To this end, FLSmidth is exploring process options and reactor technology for the hydrometallurgical processing of primary sulfides. One approach that appears to be highly effective at increasing copper recoveries takes advantage of the enhanced reactivity of transitory, surface-defect structures generated during particle fracture. Significant process efficiencies are gained by matching the rate of grinding to the rate of electrochemical leaching in Mechano-Chemical leach processes. The patent-pending FLSmidth® ROL process uses a Stirred Media Reactor (SMRt reactor) to achieve copper recoveries of 97+% in 6 hours or less. This approach overcomes many of the surface passivation problems that have hindered other atmospheric leach processes. New insights to leach mechanisms are presented.

Jan 1, 2015

By S. R. Stopic

The EU-financed INTREAT Project (Integrated treatment of industrial wastes to¬wards prevention of regional water resources contamination) addresses the environmental pollution associated with solid and liquid wastes/effluents produced by complex sulphide ore mining and metallurgical activities. The results concerning the electrolytic recovery of cop¬per from effluents formed after mixing of streams from Copper Refining, Precious Metals Plant and Electrolyte Regeneration in the Balkan Area will be shown. The waste water is characterized by low pH values and high contents of heavy metals, such as Cu, Ni, Bi, As, Sb. The majority of these waste water flow untreated into the natural water streams and through the network of existing rivers, which end up in the river Danube. The influence of current density and flow rate on the deposition rate, the quality of copper and the process efficiency will be presented. The full continuous process is based on cells with rotating disc cathodes and represents a pre-treatment step before common neutralisation in a cascade line

Jan 1, 2007

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By H. Hitchen

THE PURPOSE of this paper is to indicate the working capacity of different types of ropes for various engineering and mining duties. ROPE CONSTRUCTIONS There are approximately one hundred different designs of ropes in use today but, normally, only about ten are necessary for mining and engineering duties. The rest are designed for unusual equipments, or are different ways of combining wires of special shapes. Basically, the various designs of mining ropes consist of round, triangular, and oval strands, constructed with one or several layers of wire over a single wire, or a compound construction of sever.al wires. To suit different installations ropes are made with 3, 4, 5, or more of these types of strands over a central core, the ?co re itself being manufactured from either a fibrous material or a combination of steel wires. Nevertheless, in mining, the demand for 'locked coil rope', wl1ich may be considered as a single strand, is steadily increasing, especially for use on vertical shaft winding engines. So far as the locked coil rope is concerned, many constructions have been developed to suit different requirements, such as - in addition to winding ropes - aerial carrying Topes, shaft guide ropes and haulage ropes.

Jan 1, 1957

By A. Vien, A. J. Neale, B. C. Flintoff, R. P. Edwards

Froth flotation is one of the most widely used and effective processes for mineral beneficiation. First introduced in 1911, flotation technology has seen many developments over the past 80+ years. Innovations in reagent chemistry, equipment design, process analysis and process control have given design and plant engineers a powerful set of "tools" for process optimization. However, it does not follow that all flotation systems are optimized. As Klimpel observes: "The problem with the industrial flotation process is that it is relatively easy to get reasonable results, and relatively difficult to get excellent results" Klimpel (I 988). While reasonable was sufficient in the past, competitive forces will make excellent necessary in the future. Judging by the activities in many Canadian plants this transition is already underway. This paper examines the role of some of the optimization "tools" in effecting this change.

Jan 1, 1994

By Aidan Giblett, Michael McGlynn, Peter Radziszewski

"On the basis that 99% of the energy input into a mill is converted into heat, it is possible to estimate the amount of energy captured in the slurry, the amount that is lost to the environment as well as the possible means to reduce such losses. As a result it becomes possible to estimate the potential amount of energy that can be captured by technologies such as thermoelectric generators or even Sterling engines. Furthermore, it has been suggested that the energy recovery potential dry grinding circuit could be as high as twice that of wet grinding circuits.In this paper, the energy recovery potential of dry grinding will be explored by examining the case of the Newmont Carlin mine dry grinding circuit. The paper will open with a review of the energy recovery potential of a few wet grinding applications followed by a description of the dry grinding circuit and a definition of the control volume around that circuit. A thermodynamic model will be used to estimate the circuit discharge temperature and an estimate of any losses as well as provide an estimate of the potential impact of different means to reduce energy losses. The paper will close with a discussion of the assumptions used in model development."

Jan 1, 2016

For the last few years, a new and innovative technique has been successfully used to determine refractory and castable thickness in various metallurgical vessels. The acousto ultrasonic-echo (AU-E) technique uses stress waves to detect metal penetration and delaminations within refractory linings. In addition, it is capable of measuring the thickness of refractory layers and build-up material. The inspection and measurements can be carried out while the furnace is in full operation. The present paper discusses the principles of the AU-E technique, and its advantages and limitations. A number of case studies are presented to demonstrate various capabilities of this new Non-Destructive Testing (NDT) technique.

Jan 1, 2005

By M. F. Goudge

Introduction It is only fitting on this occasion of the fiftieth anniversary of the incorporation of the Institute that we should indulge in a bit of retrospection and review the progress that has been made within this period in the various branches of the mining industry- progress that is so closely associated with the members of this Institute. Such a moment of retrospection will enable us better to appreciate the present status of the industry and to perceive more clearly the trends that should guide us in making sound plans for the future. The past half century has been a period of amazing industrial progress in Canada. In this period, the economy of our country has changed from one based chiefly on agriculture and the export of raw materials, to an economy based largely on a well integrated manufacturing industry. In all' o( these major developments, industrial minerals have played an important part and will play an increasingly, important part in the future. By ?industrial minerals? we mean the various non-metallic minerals (exclusive of fuels) as well as the rocks, sands, and clays used for industrial purposes. They are now used so widely and in such large quantities that modern industry could not function without them, and their continued availability at low cost is vital to the industrial future of Canada. The key position occupied by industrial minerals in modern Canadian industry was well illustrated two years ago when a strike occurred in the only Canadian plant producing soda-ash and calcium chloride at a time when those materials were already in short supply and unavailable from other sources. Within a short time of the shutdown of this plant, in which the two principal raw materials are limestone and salt, the great aluminium reduction plants on the Saguenay river were forced to curtail operations because of the lack of soda-ash, essential to the process of extracting aluminium from its ore. Automobile production, already harassed by a shortage of steel, was further hampered when glass for windshields and windows could not be supplied because the glass industry was slowed down almost to a standstill for want of soda-ash. Soap became almost unobtainable both to the housewife and to industrial users, because soda-ash is required in its manufacture. As a consequence of the soap shortage, the production o synthetic rubber at Sarnia was threatened because soap in large quantities is essential to the polymerization process. Motorists on gravelled highways all over Eastern Canada drove through clouds of dust because calcium chloride, used for dust laying, was not to be had. There were other cases of dislocation of industry related to the shutdown of this particular plant, but the above illustrates the wide ramifications of industrial minerals in modern industry. However, it is extremely doubtful if many Canadian citizens realized that these apparently unrelated happenings were connected in any way with limestone and salt.

Jan 1, 1948

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016

By A. J. Rigby

Computer generated, actual-scale furnace models have been imported into a rendering software application to provide for impressively realistic surface features and lighting. When these models are imported into a 3D engine framework, it is possible to create content-rich virtual environments allowing for complete interactivity and could provide for a powerful tool to conceptualize refractory lining designs. This technology has been applied to illustrate the optimized design concept of an anode-refining vessel, which can be expected to be completely relined in six days and to last for 4-5 years with minimal partial relining. This technology could easily be applied to other smelter furnace, converter and refining vessel designs.

Jan 1, 2007

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn&apos;t occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

"2.1. General Considerations and Properties2.1.1. IntroductionOur present knowledge of the platinum-group elements (POE) is extensive, the reason being two-fold. The elements have many uses and, moreover, they exhibit extremely varied chemical behaviour, depending on their state of oxidation and chemical environment. The present chapter reviews a selected body of material which is of particular relevance to mineralogy and geochemistry.Comprehensive treatises on the POE include those by Mellor (1956-1957), Gmelin (1938-1957) and Pascal (1958). The inorganic chemistry, particularly coordination chemistry, has been dealt with in works by Griffith (1967), Hartley (1973) and Livingstone (1975), and the analytical chemistry by Walsh and Hausman (1963), Beamish (1966) and Beamish and Van Loon (1972, 1977). Darling (1973) and Savitsky (1978) have reviewed the metallurgical properties and applications of the metals. Goldberg and Helper (1968) have reviewed the thermochemistry and oxidation potentials of POE systems, and Wagman et at. (1969) have also provided selected values of their thermodynamic properties. The geochemistry of the POE has been reviewed by Yushko-Zakharova et at. (1967), Cousins (1973), Cabri (1974), and Naldrett and Duke (1980).Platinum was used briefly as a coinage metal in ImperialRussia. Otherwise, the principal early use for platinum and its alloys was in the fabrication of chemically resistant apparatus. Subsequently, a large part of platinum production was utilized for catalysts in the sulphuric acid and ammonia industries. Platinum has been replaced by vanadium pentoxide in the manufacture of sulphuric acid, but, in recent times, catalytic upgrading of petroleum and emission control systems for automobiles have opened further huge markets for the metal. All of the POE find uses either as reagents or catalysts in the synthesis of organic compounds, e.g., in the Wacker process, which uses palladium chloride to catalyze the production of acetaldehyde from ethylene. There are, of course, a large number of specialized uses for the elements, particularly in alloys, temperature measurement devices, cancer therapy and so on."

Jan 1, 1979